Potential use of faujasite–phillipsite and phillipsite–chabazite tuff in purification of treated effluent from domestic wastewater treatment plants     

Reyad A. Al Dwairi  Khalil M. Ibrahim  Hani N. Khoury 《Environmental Earth Sciences》2014,71(12):5071-5078

Characterization of zeolitic tuff from Jabal Hannoun (HN) and Mukawir (MR) was carried out to examine the ability of using low-cost natural materials in domestic wastewater treatment. The grain size between 0.3 and 1 mm (0.3–1 mm) of the HN and MR has the highest total zeolite grade (faujasite–phillipsite and phillipsite–chabazite) and suitable cation exchange capacity. They were used as fixed-bed ion exchangers and adsorbents. The zeolitic tuff efficiently removed the organic and nitrogen compounds, Pb and Zn from the effluent. One bed volume (1 BV) of the zeolitic tuff is capable to remove up to 95 % of total organic carbon form 500 BV of the effluent. The removal percent of total nitrogen by HN and MR is close to 95 and 90 %, respectively. The zeolitic tuff has an excellent efficiency to remove Pb and Zn from the effluent. 1 BV of HN completely cleans Zn and Pb from 680 and 730 BV of the effluent, respectively, whereas 1 BV of MR is able to clean completely Zn and Pb from 500 and 685 BV of the effluent, respectively. The greater performance of the HN compared with the MR may be explained by its higher zeolites grade and presence of faujasite.  相似文献   

Mapping groundwater conditions in different geological environments in the northern area of UAE using 2D earth resistivity imaging survey   总被引：1，自引：1，他引：0  

A. M. Ebraheem  M. M. Al Mulla  M. M. Sherif  O. Awad  S. F. Akram  N. B. Al Suweidi  A. Shetty 《Environmental Earth Sciences》2014,72(5):1599-1614

A water resources database was developed and used to characterize the geological and hydrogeological settings of groundwater aquifers in the northern part of the United Arab Emirates. An intensive 2D Earth Resistivity Imaging (ERI) survey was conducted in selected areas to assess the available groundwater resources and delineate the salt-water intrusion. Drilling information of the existing monitoring wells as well as their records of water table elevations and groundwater salinity were used to measure the horizontal and vertical variations in lithology, degree of saturation, and groundwater salinity and thus to improve the interpretation of ERI data. The results of the chemical analyses of water samples collected from the wells along with the 2D ERI survey profiles were used to obtain an empirical relationship between the inferred earth resistivity and the amount of total dissolved solids. This relationship was used along with the true resistivity sections resulting from the inversion of 2D ERI data to identify and map three zones of water-bearing formation (fresh, brackish, and salt-water zones) in the coastal areas. The results indicated that the depth to the fresh-brackish interface exceeded 50 m at the upstream of the wadies and was in the order of 10 m or less in the vicinity of shoreline. Because of the high resistivity contrast between dry and water saturated fractured rocks; this method was very successful in detecting water-filled fractures and cavities in the carbonate aquifer. The application of this method was unsuccessful in clayey aquifers as it was not possible to isolate lenses of gravel and/or saturated with saline or brackish water from the surrounding clayey materials.  相似文献   

Petroleum system analysis of the Khatatba Formation in the Shoushan Basin,north Western Desert,Egypt     

Mohamed Ragab Shalaby  Mohammed Hail Hakimi  Wan Hasiah Abdullah 《Arabian Journal of Geosciences》2014,7(10):4303-4320

The Middle Jurassic Khatatba Formation is an attractive petroleum exploration target in the Shoushan Basin, north Western Desert, Egypt. However, the Khatatba petroleum system with its essential elements and processes has not been assigned yet. This study throws the lights on the complete Khatatba petroleum system in the Shoushan Basin which has been evaluated and collectively named the Khatatba-Khatatba (!) petroleum system. To evaluate the remaining hydrocarbon potential of the Khatatba system, its essential elements were studied, in order to determine the timing of hydrocarbon generation, migration and accumulation. Systematic analysis of the petroleum system of the Khatatba Formation has identified that coaly shales and organic-rich shales are the most important source rocks. These sediments are characterised by high total organic matter content and have good to excellent hydrocarbon generative potential. Kerogen is predominantly types II–III with type III kerogen. The Khatatba source rocks are mature and, at the present time, are within the peak of the oil window with vitrinite reflectance values in the range of 0.81 to 1.08 % Ro. The remaining hydrocarbon potential is anticipated to exist mainly in stratigraphic traps in the Khatatba sandstones which are characterised by fine to coarse grain size, moderate to well sorted. It has good quality reservoir with relatively high porosity and permeability values ranging from 1 to 17 % and 0.05–1,000 mD, respectively. Modelling results indicated that hydrocarbon generation from the Khatatba source rocks began in the Late Cretaceous time and peak of hydrocarbon generation occurred during the end Tertiary time (Neogene). Hydrocarbon primarily migrated from the source rock via fractured pathways created by abnormally high pore pressures resulting from hydrocarbon generation. Hydrocarbon secondarily migrated from active Khatatba source rocks to traps side via vertical migration pathways through faults resulting from Tertiary tectonics during period from end Oligocene to Middle Miocene times.  相似文献   

Diagenesis in the Middle Jurassic Khatatba Formation sandstones in the Shoushan Basin,northern Western Desert,Egypt     

Mohamed R. Shalaby  Mohammed H. Hakimi  Wan Hasiah Abdullah 《Geological Journal》2014,49(3):239-255

The Middle Jurassic Khatatba Formation acts as a hydrocarbon reservoir in the subsurface in the Western Desert, Egypt. This study, which is based on core samples from two exploration boreholes, describes the lithological and diagenetic characteristics of the Khatatba Formation sandstones. The sandstones are fine‐ to coarse‐grained, moderately to well‐sorted quartz arenites, deposited in fluvial channels and in a shallow‐marine setting. Diagenetic components include mechanical and chemical compaction, cementation (calcite, clay minerals, quartz overgrowths, and a minor amount of pyrite), and dissolution of calcite cements and feldspar grains. The widespread occurrence of an early calcite cement suggests that the Khatatba sandstones lost a significant amount of primary porosity at an early stage of its diagenetic history. In addition to calcite, several different cements including kaolinite and syntaxial quartz overgrowth occur as pore‐filling and pore‐lining cements. Kaolinite (largely vermicular) fills pore spaces and causes reduction in the permeability of the reservoir. Based on framework grain–cement relationships, precipitation of the early calcite cement was either accompanied by or followed the development of part of the pore‐lining and pore‐filling cements. Secondary porosity development occurred due to partial to complete dissolution of early calcite cements and feldspar. Late kaolinite clay cement occurs due to dissolved feldspar and has an impact on the reservoir quality of the Khatatba sandstones. Open hydraulic fractures also generated significant secondary porosity in sandstone reservoirs, where both fractures and dissolution took place in multiple phases during late diagenetic stages. The diagenesis and sedimentary facies help control the reservoir quality of the Khatatba sandstones. Fluvial channel sandstones have the highest porosities and permeabilities, in part because of calcite cementation, which inhibited authigenic clays or was later dissolved, creating intergranular secondary porosity. Fluvial crevasse‐splay and marine sandstones have the lowest reservoir quality because of an abundance of depositional kaolinite matrix and pervasive, shallow‐burial calcite and quartz overgrowth cements, respectively. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Prediction of Land Cover Change Using Markov and Cellular Automata Models: Case of Al-Ain,UAE, 1992-2030   总被引：1，自引：0，他引：1  

M. M. Yagoub  Abdallah Ahmad Al Bizreh 《Journal of the Indian Society of Remote Sensing》2014,42(3):665-671

The UAE has witnessed rapid urban development and economic growth in recent years. With its ambitious vision to become one of the advanced nations by 2021, planners and policy-makers need to know the most likely direction of future urban development. In this study, remotely sensed imagery coupled with cellular automata models were used to predict land cover in Al Ain, the second largest city in the Emirate of Abu Dhabi. Markov and cellular automata models were used for 1992 and 2006 to predict land cover in 2012. Land Use and Land Cover maps for the study area were derived from 1992, 2006, and 2012 Landsat satellite images (TM, ETM⁺). The models achieved an overall accuracy of approximately 80 %. A Markov model was applied for 2006 and 2012 to predict land cover in 2030. The results conformed to the general trend of the Al Ain Master Plan 2030. This study demonstrates that remote sensing, with the availability of free Landsat data, is a viable technology that could be used to help in the prediction process especially in developing countries, where data availability is a problem.  相似文献   

New data on the Late Cenozoic basaltic volcanism in Syria,applied to its origin     

V.G. Trifonov  A.E. Dodonov  E.V. Sharkov  D.I. Golovin  I.V. Chernyshev  V.A. Lebedev  T.P. Ivanova  D.M. Bachmanov  M. Rukieh  O. Ammar  H. Minini  A.-M. Al Kafri  O. Ali 《Journal of Volcanology and Geothermal Research》2011,199(3-4):177-192

New data on geology and 21 K–Ar dates of the Late Oligocene–Quaternary basalts in Syria, combined with analysis of the new and previous data are used to reconstruct the volcanic history and relations between it and tectonic events. Volcanism began at the end of Oligocene (26–24 Ma) and was concentrated in the Late Oligocene–Early Miocene along a N-trending band, which stretches from the Jebel Arab (Harrat Ash Shaam) up to Kurd Dagh and southern Turkey. Activity waned in the Middle Miocene (17–12 Ma), but was resumed in the same band in the Tortonian and increased in the Messinian and Early Pliocene (6.3–4 Ma), when volcanism spread to the Shin Plateau and its coastal extension. After a brief hiatus ～ 4–3.5 Ma, volcanism became still more intensive and spread from the N-trending band to the east into the northern margin of the Mesopotamian Foredeep and to the west into the Dead Sea Transform zone. Additional eruptions continued into the Holocene.Volcanism lasted > 25 million years in the Jebel Arab Highland and > 15 million years in the Aleppo Plateau. The long duration of volcanism in the same parts of the moving Arabian plate and absence of records of one-way migration of the activity mean that the magmatic sources moved together with the plate, i.e., they were situated within the lithosphere mantle. Coincidence of the tectonic and volcanic stages of the Arabian plate development proves that volcanic activity depended on the geodynamic situation, caused by the plate motion. Situated within the lithosphere, magmatic sources within this transverse band were possibly caused by thermal and deforming influences of the asthenospheric lateral flow, moved laterally from the Ethiopia–Afar deep superplume.  相似文献   

Numerical study of soil heterogeneity effects on contaminant transport in unsaturated soil (model development and validation)     

M. Mousavi Nezhad  A. A. Javadi  A. Al‐Tabbaa  F. Abbasi 《国际地质力学数值与分析法杂志》2013,37(3):278-298

The movement of chemicals through soil to groundwater is a major cause of degradation of water resources. In many cases, serious human and stock health implications are associated with this form of pollution. The study of the effects of different factors involved in transport phenomena can provide valuable information to find the best remediation approaches. Numerical models are increasingly being used for predicting or analyzing solute transport processes in soils and groundwater. This article presents the development of a stochastic finite element model for the simulation of contaminant transport through soils with the main focus being on the incorporation of the effects of soil heterogeneity in the model. The governing equations of contaminant transport are presented. The mathematical framework and the numerical implementation of the model are described. The comparison of the results obtained from the developed stochastic model with those obtained from a deterministic method and some experimental results shows that the stochastic model is capable of predicting the transport of solutes in unsaturated soil with higher accuracy than deterministic one. The importance of the consideration of the effects of soil heterogeneity on contaminant fate is highlighted through a sensitivity analysis regarding the variance of saturated hydraulic conductivity as an index of soil heterogeneity. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Geochemical and oxygen isotope perspective of a new R chondrite Dhofar 1671: Affinity with ordinary chondrites          下载免费PDF全文

Arshad Ali  Sobhi J. Nasir  Iffat Jabeen  Ahmed Al Rawas  Neil R. Banerjee  Gordon R. Osinski 《Meteoritics & planetary science》2017,52(9):1991-2003

Dhofar 1671 is a relatively new meteorite that previous studies suggest belongs to the Rumuruti chondrite class. Major and REE compositions are generally in agreement with average values of the R chondrites (RCs). Moderately volatile elements such as Se and Zn abundances are lower than the R chondrite values that are similar to those in ordinary chondrites (OCs). Porphyritic olivine pyroxene (POP), radial pyroxene (RP), and barred olivine (BO) chondrules are embedded in a proportionately equal volume of matrix, one of the characteristic features of RCs. Microprobe analyses demonstrate compositional zoning in chondrule and matrix olivines showing Fa‐poor interior and Fa‐rich outer zones. Precise oxygen isotope data for chondrules and matrix obtained by laser‐assisted fluorination show a genetic isotopic relationship between OCs and RCs. On the basis of our data, we propose a strong affinity between these groups and suggest that OC chondrule precursors could have interacted with a ¹⁷O‐rich matrix to form RC chondrules (i.e., ?¹⁷O shifts from ~1‰ to ~3‰). These interactions could have occurred at the same time as “exotic” clasts in brecciated samples formed such as NWA 10214 (LL3–6), Parnallee (LL3), PCA91241 (R3.8–6), and Dhofar 1671 (R3.6). We also infer that the source of the oxidation and ¹⁷O enrichment is the matrix, which may have been enriched in ¹⁷O‐rich water. The abundance of matrix in RCs relative to OCs, ensured that these rocks would be apparently more oxidized and appreciably ¹⁷O‐enriched. In situ analysis of Dhofar 1671 is recommended to further strengthen the link between OCs and RCs.  相似文献   

The motion of artificial satellites in the set of Eulerian redundant parameters     

Mohammed Adel Sharaf  Mervat El-Sayed Awad  Samiha Al-Sayed Abdullah Najmuldeen 《Earth, Moon, and Planets》1991,55(1):21-44

In this paper, the connections between orbit dynamics and rigid body dynamics are established throughout the Eulerian redundant parameters, the perturbation equations for any conic motion of artificial satellites are derived in terms of these parameters. A general recursive and stable computational algorithm is also established for the initial-value problem of the Eulerian parameters for satellites prediction in the Earth's gravitational field with axial symmetry. Applications of the algorithm are considered for the two cases of short and long term predictions. For the short-term prediction, we consider the problem of the final state prediction of some typical ballistic missiles in the geopotential model with zonal harmonic terms up to J ₃₆, while for the long-term prediction, we consider the perturbed J ₂ motion of Explorer 28 over 100 revolutions.  相似文献   

Comparative Analyses of the Point Cloud Produced by Using Close-Range Photogrammetry and Terrestrial Laser Scanning for Rock Surface     

Abdullah Harun Incekara  Dursun Zafer Seker 《Journal of the Indian Society of Remote Sensing》2018,46(8):1243-1253

Point cloud produced by using theoretically and practically different techniques is one of the most preferred data types in various engineering applications and projects. The advanced methods to obtain point cloud data in terrestrial studies are close range photogrammetry (CRP) and terrestrial laser scanning (TLS). In the TLS technique, separated from the CRP in terms of system structure, denser point cloud at certain intervals can be produced. However, point clouds can be produced with the help of photographs taken at appropriate conditions depending on the hardware and software technologies. Adequate quality photographs can be obtained by consumer grade digital cameras, and photogrammetric software widely used nowadays provides the generation of point cloud support. The tendency and the desire for the TLS are higher since it constitutes a new area of research. Moreover, it is believed that TLS takes the place of CRP, reviewed as antiquated. In this study that is conducted on rock surfaces located at Istanbul Technical University Ayazaga Campus, whether point cloud produced by means photographs can be used instead of point cloud obtained by laser scanner device is investigated. Study is worked on covers approximately area of 30 m?×?10 m. In order to compare the methods, 2D and 3D analyses as well as accuracy assessment were conducted. 2D analysis is areal-based whereas 3D analysis is volume-based. Analyses results showed that point clouds in both cases are similar to each other and can be used for similar other studies. Also, because the factors affecting the accuracy of the basic data and derived product for both methods are quite variable, it was concluded that it is not appropriate to make a choice regardless of the object of interest and the working conditions.  相似文献