Copper partitioning in a melt-vapor-brine-magnetite-pyrrhotite assemblage   总被引：4，自引：0，他引：4  

Adam C. Simon  Thomas Pettke  Philip M. Piccoli 《Geochimica et cosmochimica acta》2006,70(22):5583-5600

The effect of sulfur on the partitioning of Cu in a melt-vapor-brine ± magnetite ± pyrrhotite assemblage has been quantified at 800 °C, 140 MPa, f_O2 = nickel-nickel oxide (NNO), logf_S2=-3.0 (i.e., on the magnetite-pyrrhotite curve at NNO), logf_H2S=-1.3 and logf_SO2=-1. All experiments were vapor + brine saturated. Vapor and brine fluid inclusions were trapped in silicate glass and self-healed quartz fractures. Vapor and brine are dominated by NaCl, KCl and HCl in the S-free runs and NaCl, KCl and FeCl₂ in S-bearing runs. Pyrrhotite served as the source of sulfur in S-bearing experiments. The composition of fluid inclusions, glass and crystals were quantified by laser-ablation inductively coupled plasma mass spectrometry. Major element, chlorine and sulfur concentrations in glass were quantified by using electron probe microanalysis. Calculated Nernst-type partition coefficients (±2σ) for Cu between melt-vapor, melt-brine and vapor-brine are , , and , respectively, in the S-free system. The partition coefficients (±2σ) for Cu between melt-vapor, melt-brine and vapor-brine are , , and , respectively, in the S-bearing system. Apparent equilibrium constants (±1σ) describing Cu and Na exchange between vapor and melt and brine and melt were also calculated. The values of are 34 ± 21 and 128 ± 29 in the S-free and S-bearing runs, respectively. The values of are 33 ± 22 and60 ± 5 in the S-free and S-bearing runs, respectively. The data presented here indicate that the presence of sulfur increases the mass transfer of Cu into vapor from silicate melt. Further, the nearly threefold increase in suggests that Cu may be transported as both a chloride and sulfide complex in magmatic vapor, in agreement with hypotheses based on data from natural systems. Most significantly, the data demonstrate that the presence of sulfur enhances the partitioning of Cu from melt into magmatic volatile phases.  相似文献   

Early Holocene brackish closed basin conditions in Georgian Bay, Ontario, Canada: microfossil (thecamoebian and pollen) evidence     

Francine McCarthy  Sarah Tiffin  Adam Sarvis  John McAndrews  Stephan Blasco 《Journal of Paleolimnology》2012,47(3):429-445

Microfossils have been critical in unravelling the complex postglacial history of Georgian Bay. Thecamoebians (testate amoebae/rhizopods) record paleolimnological conditions, and pollen stratigraphy allows correlation across the basin, where sedimentation has been spatially and temporally discontinuous. Because parts of Georgian Bay have been non-depositional or erosional since the end of the Nipissing transgression (~5,000 (5,800 cal) BP), early Holocene features are exposed on the lakebed. Among these are shoreline features, such as submerged beaches and relict channels, associated with low-level Lake Hough that was driven far below the level of basin overflow. Cores taken throughout Georgian Bay record the existence of closed basin conditions that persisted several centuries around 7,500 (8,300 cal) BP, corresponding to the late Lake Hough lowstand. Evidence for hydrologic closure includes a low-diversity centropyxid-dominated thecamoebian fauna around the boundary between pollen subzones 2a and 2b in the Flowerpot Beach core, Flowerpot and Killarney basins, and in Severn Sound. This low-diversity centropyxid-dominated fauna is interpreted as recording the development of slightly brackish conditions as a result of a hydrologic deficit associated with relatively arid conditions in the Great Lakes basin during the early Holocene pine zone (~8,800–7,200 (9,900–8,050 cal) BP). The rest of the Holocene record in Georgian Bay (where it is preserved) is more diverse and dominated by difflugiid thecamoebians: predominantly Difflugia oblonga prior to human settlement, and Cucurbitella tricuspis since high-density human occupation and agriculture (and resulting eutrophication) began with the Wendat First Nations people around Severn Sound about 750 years ago. The implication that water budget fluctuations leading to discernible variations in lake level and water chemistry occurred in the relatively recent geologic past is significant to studies of global climate change and resource management in the Great Lakes, one of the world’s largest freshwater resources.  相似文献   

Projected changes in the physical climate of the Gulf Coast and Caribbean     

Michela Biasutti  Adam H. Sobel  Suzana J. Camargo  Timothy T. Creyts 《Climatic change》2012,112(3-4):819-845

As the global climate warms due to increasing greenhouse gases, the regional climate of the Gulf of Mexico and Caribbean region will also change. This study presents the latest estimates of the expected changes in temperature, precipitation, tropical cyclone activity, and sea level. Changes in temperature and precipitation are derived from climate model simulations produced for the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC AR4), by comparing projections for the mid- and late-21st century to the late 20th century and assuming a “middle-of-the-road” scenario for future greenhouse gas emissions. Regional simulations from the North America Regional Climate Change Program (NARCCAP) are used to corroborate the IPCC AR4 rainfall projections over the US portion of the domain. Changes in tropical cyclones and sea level are more uncertain, and our understanding of these variables has changed more since IPCC AR4 than in the case of temperature and precipitation. For these quantities, the current state of knowledge is described based on the recent peer-reviewed literature.  相似文献   

Very high resolution rainfall patterns measured by TRMM precipitation radar: seasonal and diurnal cycles     

Michela Biasutti  Sandra E. Yuter  Casey D. Burleyson  Adam H. Sobel 《Climate Dynamics》2012,39(1-2):239-258

The TRMM Precipitation Radar is used to construct a high resolution (0.05°?×?0.05°) climatology of rainfall over the latitude band extending to about 36° North and South. This study describes climatological patterns of rainfall frequency and intensity at high spatial resolution, with special focus on the seasonal and diurnal cycles in the frequency of rainfall events. We use this Tropics-wide dataset to highlight small-scale precipitation features that are too fine to be captured by the most widely used satellite-based rainfall datasets. The results shed light on the roles of changes in the wind direction, the land-sea thermal contrast, small-scale variations in sea surface temperature, and orography in shaping the seasonal and diurnal cycles of rainfall. In some regions of the tropics, diurnally locked local circulations are largely responsible for sharp gradients in the spatial distribution of seasonal mean precipitation. In other regions, we show that climatological rainfall frequency changes very sharply at coastlines, even though rainfall in these regions is expected to be controlled by relatively large scale weather systems.  相似文献   

Impact of stratospheric variability on tropospheric climate change     

Mauro Dall’Amico  Peter A. Stott  Adam A. Scaife  Lesley J. Gray  Karen H. Rosenlof  Alexey Yu. Karpechko 《Climate Dynamics》2010,34(2-3):399-417

An improved stratospheric representation has been included in simulations with the Hadley Centre HadGEM1 coupled ocean atmosphere model with natural and anthropogenic forcings for the period 1979–2003. An improved stratospheric ozone dataset is employed that includes natural variations in ozone as well as the usual anthropogenic trends. In addition, in a second set of simulations the quasi biennial oscillation (QBO) of stratospheric equatorial zonal wind is also imposed using a relaxation towards ERA-40 zonal wind values. The resulting impact on tropospheric variability and trends is described. We show that the modelled cooling rate at the tropopause is enhanced by the improved ozone dataset and this improvement is even more marked when the QBO is also included. The same applies to warming trends in the upper tropical troposphere which are slightly reduced. Our stratospheric improvements produce a significant increase of internal variability but no change in the positive trend of annual mean global mean near-surface temperature. Warming rates are increased significantly over a large portion of the Arctic Ocean. The improved stratospheric representation, especially the QBO relaxation, causes a substantial reduction in near-surface temperature and precipitation response to the El Chichón eruption, especially in the tropical region. The winter increase in the phase of the northern annular mode observed in the aftermath of the two major recent volcanic eruptions is partly captured, especially after the El Chichón eruption. The positive trend in the southern annular mode (SAM) is increased and becomes statistically significant which demonstrates that the observed increase in the SAM is largely subject to internal variability in the stratosphere. The possible inclusion in simulations for future assessments of full ozone chemistry and a gravity wave scheme to internally generate a QBO is discussed.  相似文献   

A global perspective on African climate   总被引：4，自引：1，他引：3  

Alessandra Giannini  Michela Biasutti  Isaac M. Held  Adam H. Sobel 《Climatic change》2008,90(4):359-383

We describe the global climate system context in which to interpret African environmental change to support planning and implementation of policymaking action at national, regional and continental scales, and to inform the debate between proponents of mitigation v. adaptation strategies in the face of climate change. We review recent advances and current challenges in African climate research and exploit our physical understanding of variability and trends to shape our outlook on future climate change. We classify the various mechanisms that have been proposed as relevant for understanding variations in African rainfall, emphasizing a “tropospheric stabilization” mechanism that is of importance on interannual time scales as well as for the future response to warming oceans. Two patterns stand out in our analysis of twentieth century rainfall variability: a drying of the monsoon regions, related to warming of the tropical oceans, and variability related to the El Niño–Southern Oscillation. The latest generation of climate models partly captures this recent continent-wide drying trend, attributing it to the combination of anthropogenic emissions of aerosols and greenhouse gases, the relative contribution of which is difficult to quantify with the existing model archive. The same climate models fail to reach a robust agreement regarding the twenty-first century outlook for African rainfall, in a future with increasing greenhouse gases and decreasing aerosol loadings. Such uncertainty underscores current limitations in our understanding of the global climate system that it is necessary to overcome if science is to support Africa in meeting its development goals.  相似文献   

The 2dF–SDSS LRG and QSO survey: the QSO luminosity function at 0.4 < z < 2.6     

Scott M. Croom  Gordon T. Richards  Tom Shanks  Brian J. Boyle  Michael A. Strauss  Adam D. Myers  Robert C. Nichol  Kevin A. Pimbblet  Nicholas P. Ross  Donald P. Schneider  Robert G. Sharp  David A. Wake 《Monthly notices of the Royal Astronomical Society》2009,399(4):1755-1772

  相似文献   

Subduction Influence on Oxygen Fugacity and Trace and Volatile Elements in Basalts Across the Cascade Volcanic Arc   总被引：2，自引：0，他引：2  

Rowe  Michael C.; Kent  Adam J. R.; Nielsen  Roger L. 《Journal of Petrology》2009,50(1):61-91

Fluids or melts derived from a subducting plate are often citedas a mechanism for the oxidation of arc magmas. What remainsunclear is the link between the fluid, oxygen fugacity, andother major and trace components, as well as the spatial distributionof the impact of those fluids. To test the potential effectsof addition of a subduction-derived fluid or melt to the sub-arcmantle, olivine-hosted melt inclusions from primitive basalticlavas sampled from across the central Oregon Cascades (43°–45°N)have been analyzed for major, trace and volatile elements andfO₂. Oxygen fugacity was determined in melt inclusions fromsulfur speciation determined by electron microprobe and fromolivine–chromite oxygen geobarometry. The overall rangein fO₂ based on sulfur speciation measurements is from <–0·25log units to + 1·9 log units (FMQ, where FMQ is fayalite–magnetite–quartzbuffer). Oxygen fugacity is positively correlated with fluid-mobiletrace element and light rare earth element contents in basaltsgenerated by relatively low-degree partial melting. Establishinga further correlation between fO₂ and fluid-mobile trace elementabundances with position along the arc requires the basaltsto be subdivided into shoshonitic, calc-alkaline, low-K tholeiiteand enriched intraplate basalt groups. Melt inclusions fromenriched intraplate and shoshonitic lavas show increasing fO₂and trace element abundances closer to the trench, whereas calc-alkalinemelt inclusions exhibit no significant across-arc variations.Low-K tholeiitic melt inclusions record an increase in incompatibletrace elements closer to the trench; however, there is no correlatedincrease in fO₂. The correlation observed in enriched intraplateand shoshonitic melt inclusions is interpreted to reflect aprogressively greater proportion of a fluid-rich, oxidized subductioncomponent in magmas generated nearer the subduction zone. Significantly,calc-alkaline melt inclusions with high ratios of large ionlithophile elements to high field strength elements, characteristicof ‘typical’ arc magmas, have oxidation states indistinguishablefrom low-K tholeiite and enriched intraplate basalt melt inclusions.The lack of across-arc geochemical variation in calc-alkalinemelt inclusions may suggest that these basalts are not necessarilythe most appropriate magmas for examining recent addition ofa subduction component to the sub-arc mantle. Flux and batchmelt model results produce a wide range of predicted amountsof melting and subduction component added to the mantle source;however, general trends characterized by increased melting andproportion of the subduction component from enriched intraplate,to low-K tholeiite, to calc-alkaline are robust. The model resultsdo not require enriched intraplate, low-K tholeiite and calc-alkalinemagmas to be produced from the same more fertile mantle source.However, enriched intraplate magmas, in contrast to calc-alkalineand low-K tholeiite magmas, cannot be generated from a depletedmantle source. Flux or batch melting of either the more fertileor depleted mantle sources used to generate the low-K tholeiite,calc-alkaline, and enriched intraplate magmas cannot reproduceshoshonitic compositions, which require a significantly depletedmantle source strongly metasomatized by a subduction component.The potential mantle source for shoshonitic basalts has a predictedfO₂ (after oxidation) from + 0·3 to + 2·4 logunits (FMQ) whereas the mantle source for low-K tholeiite, calc-alkaline,and enriched intraplate magmas may range from –1·1to + 0·7 log units (FMQ). KEY WORDS: basalt; Cascades; melt inclusions; oxidation state; volatiles  相似文献   

Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part II: synthesis of a S-spiro-like dithiolane triterpenoid     

Pierre Adam  Philippe Schaeffer  Sylvestre Gug  Estelle Motsch  Pierre Albrecht 《Organic Geochemistry》2009,40(8):885-894

A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches.  相似文献   

Thermal convection in ice-I shells of Titan and Enceladus     

Giuseppe Mitri  Adam P. Showman 《Icarus》2008,193(2):387-396

Cassini-Huygens observations have shown that Titan and Enceladus are geologically active icy satellites. Mitri and Showman [Mitri, G., Showman, A.P., 2005. Icarus 177, 447-460] and McKinnon [McKinnon, W.B., 2006. Icarus 183, 435-450] investigated the dynamics of an ice shell overlying a pure liquid-water ocean and showed that transitions from a conductive state to a convective state have major implications for the surface tectonics. We extend this analysis to the case of ice shells overlying ammonia-water oceans. We explore the thermal state of Titan and Enceladus ice-I shells, and also we investigate the consequences of the ice-I shell conductive-convective switch for the geology. We show that thermal convection can occur, under a range of conditions, in the ice-I shells of Titan and Enceladus. Because the Rayleigh number Ra scales with δ³/ηb, where δ is the thickness of the ice shell and ηb is the viscosity at the base of the ice-I shell, and because ammonia in the liquid layer (if any) strongly depresses the melting temperature of the water ice, Ra equals its critical value for two ice-I shell thicknesses: for relatively thin ice shell with warm, low-viscosity base (Onset I) and for thick ice shell with cold, high-viscosity base (Onset II). At Onset I, for a range of heat fluxes, two equilibrium states—corresponding to a thin, conductive shell and a thick, convective shell—exist for a given heat flux. Switches between these states can cause large, rapid changes in the ice-shell thickness. For Enceladus, we demonstrate that an Onset I transition can produce tectonic stress of ∼500 bars and fractures of several tens of km depth. At Onset II, in contrast, we demonstrate that zero equilibrium states exist for a range of heat fluxes. For a mean heat flux within this range, the satellite experiences oscillations in surface heat flux and satellite volume with periods of ∼50-800 Myr even when the interior heat production is constant or monotonically declining in time; these oscillations in the thermal state of the ice-I shell would cause repeated episodes of extensional and compressional tectonism.  相似文献