Phytoremediation assessment of native plants growing on Pb–Zn mine site in Northern Tunisia     

Salima Chaabani  Chiraz Abdelmalek-Babbou  Hela Ben Ahmed  Anis Chaabani  Abdelaziz Sebei 《Environmental Earth Sciences》2017,76(16):585

Pollution by heavy metals presents an environmental concern, and their toxicity threats soil, water, animals and human health. Phytoremediation can be used as a solution to remediate contaminated soils. The aim of this study was to identify native plants collected from tailings: material of Pb–Zn mine sites of Fedj Lahdoum and Jebel Ressas (two abandoned mines located, respectively, in the northwest of Tunisia and in the south of Tunis City). The tolerance of plant to heavy metals (lead, zinc and cadmium) is evaluated. Soil samples were collected and analyzed for Pb, Zn and Cd concentration. The total soil Pb, Zn and Cd are, respectively, reached 6132 mg kg^?1, 11,052 mg kg^?1 and it doesn’t exceed 479 mg kg^?1 for Cd. The highest content of Zn in plants was detected in shoots of Rumex bucephalophorus (1048 mg kg^?1), and the highest Pb concentration was detected in roots of Chrysopogon zizanioides (381 mg kg^?1), while for Cd Silene colorata it accumulated the highest content in roots (51 mg kg^?1). From all plants, only 12 have a translocation factor for Pb which is higher than one. Among all plants, only 17 have a translocation factor that is higher than one for Zn, while for Cd only 13 plants indicate TF > 1. As for the biological absorption coefficient, all samples indicate a rate which is lower than one. These plants can be primarily hyper accumulators and useful in remediation of lead- and zinc-contaminated soils after further biochemistry researches in mechanism of accumulation and translocation of heavy metals in plants.  相似文献   

Hydrogeochemical evaluation of fractured Limestone aquifer by applying a geochemical model in eastern Nile Valley,Egypt     

Mohamed Gad  Ahmed Saad 《Environmental Earth Sciences》2017,76(18):641

Rock water interactions play an important role in the flow of groundwater. Groundwater samples were collected from deep production wells with depths ranging from 120 to 230 m. Complete chemical analysis of 40 groundwater samples was collected from the fractured limestone aquifer including major cations (Na⁺, K⁺, Ca²⁺, Mg²⁺) and major anions (Cl^?, SO₄ ^2?, HCO₃ ^?, CO₃ ^2?). A geochemical modeling (NETPATH Software) was applied for environmental simulate net geochemical mass-balance reactions between initial and final waters along a hydrologic flow path. This program simulates selected evolutionary waters for every possible combination of the plausible phases that account for the composition of a selected set of chemical constraints in the system. The groundwater of the Eocene aquifer mainly belongs to fairly fresh water with salinity contents ranging from 228 to 3595 ppm. The measured groundwater levels range between 8 and 25 m near the river Nile to the limestone plateau (eastwards). Consequently, groundwater flows from east to westward toward the river Nile. Groundwater aquifer in the study area is mainly composed of fractured limestone; the saturated states of the PCO₂, calcite, aragonite, dolomite, siderite, gypsum, anhydrite, hematite, and goethite in addition to H₂ gas were estimated. The undersaturated state of carbon dioxide reflects closed conditions and very low probability of recent recharge, and it reveals also the high tendency of water to precipitates carbonate species. Undersaturation by carbonate minerals is only restricted to some pockets distributed on the different places of the aquifer in the study area. The majority of groundwater samples of Eocene aquifer in the study area indicated that groundwater is not suitable for irrigation with treatment and requires good drainage.  相似文献   

Climate change impact on rainfall spatio-temporal variability (Macta watershed case,Algeria)     

Abdelkader Elouissi  Mohammed Habi  Boumedienne Benaricha  Sid Ahmed Boualem 《Arabian Journal of Geosciences》2017,10(22):496

This work describes the climate change impact study on rainfall patterns in Macta watershed, located in the northwest of Algeria. The monthly rainfall data collection, verification and validation have built a database with 42 stations, each with 42 years of observations from 1970 to 2011. The study of annual total rainfall has identified a downward trend and quantifies the deficits that are within the observation time series. The division of the annual rainfall series into four periods allowed to highlighting the increase in inter-year temporal variability with the coefficient of variation increases from 17 to 27%. The study shows an annual rainfall deficit increment from 13 to 25%. The standard deviation values decrease significantly for the last two periods showing a spatial variability. Multivariate statistical study by the hierarchical clustering method resulted in the formation of station groups indicating the unification of monthly rainfall patterns.  相似文献   

Development of design storm hyetographs in hyper-arid and arid regions: case study of Sultanate of Oman     

Ayman Georges Awadallah  Abdelrahman Younis Elsayed  Ahmed Mohammed Abdelbaky 《Arabian Journal of Geosciences》2017,10(20):456

The temporal distribution of the design storm is an important input in hydrological models. This research aims to develop design storm profiles representative of arid and hyper-arid areas based on actual storm recordings. Two hundred thirty-six rainfall storms were collected from seventeen rainfall gauges that cover the coastal zone of Oman for the period from 1993 to 2007. Storms were classified into four categories according to their total durations. Design storm hyetographs were derived from raw rainfall records for all four categories using the Alternating Block Method (ABM) and were also computed by ABM applied on the Intensity-Duration-Frequency (IDF) curves. Both design storm profiles were compared and it was found that the ABM_IDF storm profiles were equivalent to the four ABM_Storms profiles from a practical point of view as they produce similar peak discharges. The storm profiles developed in the current research were also compared to the commonly used Soil Conservation Service (SCS) dimensionless distributions and the UK50 storm profiles. The results showed that the most conservative commonly used SCS type II and the UK50 summer profiles are not safe to be used in design purposes in arid and hyper arid regions, despite their wide utilization in many codes of practice in these regions. The study recommends using the newly developed dimensionless storm profiles derived from the actual records.  相似文献   

Contribution of the geomagnetism to the region of the massif Jbel Saghro geology,Eastern Anti-Atlas,Morocco     

Abdelhalim Miftah  Driss El Azzab  Ahmed Attou  Ahmed Manar 《Arabian Journal of Geosciences》2017,10(21):460

Our investigation relates to the interpretation of the magnetic data of Jbel Saghro, by aeromagnetic processing using Geosoft and ArcGis software. The data were obtained from digitizing the preexisting maps. From the magnetic field anomaly maps, different anomalies were identified with differences in intensities, sizes, and shapes and in being isolated or interfered. The directions are in general ENE-WSW, NNW-SSE, W-E, and NW-SE which are in good agreement with the general tectonic structure of the region. In order to correspond the anomalies to their natural sources and their geometrical configuration, it was necessary to calculate the residual polar. This avoids the presence of two lobes for the same source, what makes it possible to delimit the geological sources laterally. Thus, the attribution of each magnetic anomaly to its geological source becomes possible. Indeed, generally magnetic anomaly of strong intensities and big wavelengths is associated to very magnetized structures related to the Precambrian basement, and the negative a.m. is connected to structures of weak magnetization located in general in the cover. The application of the tilt angle filter allowed the localization of the outcrops of the inliers and new geophysical lineaments. On the other hand, the local maxima of the horizontal gradient made it possible to reveal the large structural features concerning the main tectonic events of the area.  相似文献   

Robust approach for optimal positioning and ranking potential rainwater harvesting structure (RWH): a case study of Iraq     

Khamis Naba Sayl  Nur Shazwani Muhammad  Ahmed El-Shafie 《Arabian Journal of Geosciences》2017,10(18):413

Rainwater harvesting (RWH) structure is considered as the best solution to conserve water for arid regions. The selection of RWH location is based on several key determinants such as hydrology, environment, topography, and socio-economic. This study proposed a robust methodology to identify and select the location of RWH using geographical information systems (GIS) and remote sensing (RS) with multi-criteria decision techniques in areas where data are scarce. Several thematic maps were extracted such as vegetation cover, soil group, slope, land use, and digital elevation (DEM). The RWH sites were ranked based on four major indexes: evaporation, cost-benefit, sediment, and hydrological index. Sensitivity analysis shows that the variance inverse (VI) and rank order method (ROM) considered all indices that effect ranking as compared to the analytic hierarchy process (AHP) and fuzzy-AHP. Sensitivity analysis also proved that the proposed method is suitable to be used for RWH site selection in arid regions.  相似文献   

Retention of a heavy metal by marl collected from aquifer substratum     

Mourad Bellaloui  Abdenacer Metouchi  Ahmed Foukrache  Said Larabi  Farida Semaoune 《Arabian Journal of Geosciences》2017,10(19):425

One of the objectives of this work is to characterize marl samples collected from the bedrock aquifer (at 30 m depth) of Wadi Al Ghoula located in Draria southwest of Algiers. The other objective is to make a kinetics study, linear and non-linear isotherm study, and mass transfer study of the adsorption of copper onto marl in aqueous solution. The fitness of kinetics and isotherm models was evaluated by using some error analysis function. One of the major results using an XRF technique is an evidence of the presence of calcite in the weight of 13.82%. The XRD patterns of these samples confirmed the presence of montmorillonite, kaolinite, illite, calcite, and quartz. On the other hand, the FTIR analysis clarified the presence of calcite. The specific surface area of 20,999 m²/g was obtained using the BET, which indicates that the material has a predominance for the mesoporous character. The instrumental neutron activation analysis (INAA), a nondestructive method, gives the elemental composition of the adsorbent. Based on the value of the coefficient of determination, the adsorption kinetics of copper in aqueous solution using marl as adsorbent follows the pseudo-second-order model. And according to the value of the coefficient of determination obtained for the two models, the intraparticle diffusion and liquid film diffusion control the process of adsorption of copper onto marl with low predominance for the second model of diffusion in the first stage of adsorption. The linear and the non-linear treatments of the two-parameter isotherm models (Langmuir, Freundlish, Temkin) show that the fitting best model of isotherm is the empirical Freundlish isotherm. For the three-parameter isotherm models (Toth, Sips, and Redlish-Peterson), the Sips model is the more accurate fitting model than the two other isotherms in the non-linear approach. Some error analysis functions are used to choose the best results.  相似文献   

A nanoscopic hydro-thermo-mechanical model for nuclear waste shale/clay repositories     

H. R. Ahmed  S. N. Abduljauwad 《Arabian Journal of Geosciences》2017,10(20):448

Shales or highly compacted engineered clay layers are being used as buffers in deep surface nuclear waste repositories. Due to the complex natural structure and fabric of clay and non-clay minerals associated with high in situ stresses, high temperatures, and the practical difficulties in the replication of the field stress and temperature conditions in the lab testing facilities, swell potential from the macro and micro investigations does not provide reliable and universally applicable results. In this study, a comprehensive molecular-level simulation-based volume change constitutive model has been developed for clay minerals incorporating the effects of cation exchange capacity, density, water content, in situ stress state, temperature, exchangeable-cations type and proportion, pore fluids, and the dissolved salts. The molecular simulations were performed using molecular mechanics, molecular dynamics, and Monte Carlo simulation techniques. Comparing the model predictions with the results of the lab tests, the model has been proven to be quite precise in the prediction of the swell potential of these strata under various overburden pressures and temperatures. There is several fold increase in swelling of clay samples at 80 °C as compared to the equivalent specimen tested at 25 °C. The effect of higher temperature is lesser at lower initial water content (higher density) while at higher water content (lower density) the structure has been found to be more vulnerable at higher temperatures. About 100 times higher confining pressure results in the same swell at 80 °C as in its counterpart specimen at 25 °C, the corresponding swell increase factor in case of 50 °C specimens is about 45. A sharp increase in swelling with a drop in in situ pressure emphasizes the probability of higher swell as a result of an accidental reduction in in situ pressure such as the higher concentration of nuclear reactions. In this study, the cohesive energy density (CED) was found to be highly sensitive to various volume change variables, such as water content, density, CEC, type, and percentage of exchangeable and non-exchangeable cations. Contrary to all the previous models, CED-based model developed in this study is universal in nature and can be adopted for any case with minimal basic material input parameters. The good agreement found between the predicted and real values for the swell potential of the undisturbed samples suggests that the model presented here can effectively be used for the assessment of the swelling potential of shale/clay deposits to be used as buffers to the nuclear waste storage.  相似文献   

Assessment of physico-chemical and microbiological surface water quality using multivariate statistical techniques: a case study of the Wadi El-Bey River,Tunisia     

Gasmi Taoufik  Imen Khouni  Ahmed Ghrabi 《Arabian Journal of Geosciences》2017,10(7):181

Located in the northeastern part of Tunisia, Wadi El Bey drains the watershed through farmland, industrial, and urban areas of the region. It serves to discharge treated wastewater of different types. In this work, the variations of the water quality of Wadi El Bey were studied and evaluated, during 2 years (2012–2013), using multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis (CA). In addition, the similarities or dissimilarities among the sampling points were as well analyzed to identify spatial and temporal variations. The results obtained based on the cluster analysis, led to identify three similar water quality zones: relatively polluted (LP), moderately polluted (MP), and highly polluted (HP). The inorganic and organic parameters, temperature, conductivity, dissolved oxygen, chemical oxygen demand, salmonella, and enterococcus, seemed to be the most significant parameters of water quality. Three factors were identified as responsible for the data structure, explaining 60.95% of the total variance. The first factor is the physical and non-organic chemical parameters explaining 23.48% of the total variance. The second and third factors are, respectively, the microbiological (21.26%) and organic-nutrient (16.2%).This study shows that multivariate statistical methods can help the water managers to understand the factors affecting the water quality.  相似文献   

Characterization of some bacterial strains isolated from the Egyptian eastern and northern coastlines with antimicrobial activity of Bacillus zhangzhouensis OMER4     

Mohamed O.Soliman  Waleed B.Suleiman  Mohamed M.Roushdy  Eman N.Elbatrawy  Ahmed M.Gad 《海洋学报(英文版)》2022,41(3):86-93

Marine microorganisms were considered to be important sources of marine bioactive compounds. The major objective of the study was to isolate and characterize bacteria with antimicrobial activities from the various marine environment of Egypt. In this respect, thirty-five bacterial isolates were recovered from sediment samples collected from different spots along the Egyptian Red Sea coastline and Alexandria coastline during the summer season of 2017 and 2018. According to the morphological, phys...  相似文献