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151.
Yamada M Takada H Toyoda K Yoshida A Shibata A Nomura H Wada M Nishimura M Okamoto K Ohwada K 《Marine pollution bulletin》2003,47(1-6):105-113
Polycyclic Aromatic Hydrocarbons (PAHs) are one of the components found in oil and are of interest because some are toxic. We studied the environmental fate of PAHs and the effects of chemical dispersants using experimental 500 l mesocosm tanks that mimic natural ecosystems. The tanks were filled with seawater spiked with the water-soluble fraction of heavy residual oil. Water samples and settling particles in the tanks were collected periodically and 38 PAH compounds were analyzed by gas chromatography-mass spectrometry (GC-MS). Low molecular weight (LMW) PAHs with less than three benzene rings disappeared rapidly, mostly within 2 days. On the other hand, high molecular weight (HMW) PAHs with more than four benzene rings remained in the water column for a longer time, up to 9 days. Also, significant portions (10-94%) of HMW PAHs settled to the bottom and were caught in the sediment trap. The addition of chemical dispersant accelerated dissolution and biodegradation of PAHs, especially HMW PAHs. The dispersant amplified the amounts of PAHs found in the water column. The amplification was the greater for the more hydrophobic PAHs, with an enrichment factor of up to six times. The increased PAHs resulting from dispersant use overwhelmed the normal degradation and, as a result, higher concentrations of PAHs were observed in water column throughout the experimental period. We conclude that the addition of the dispersant could increase the concentration of water column PAHs and thus increase the exposure and potential toxicity for organisms in the natural environment. By making more hydrocarbon material available to the water column, the application of dispersant reduced the settling of PAHs. For the tank with dispersant, only 6% of chrysene initially introduced was detected in the sediment trap whereas 70% was found in the trap in the tank without dispersant. 相似文献
152.
Livestock wastes as a source of estrogens and their effects on wildlife of Manko tidal flat,Okinawa 总被引:9,自引:0,他引:9
The Manko tidal flat in the southern part of Okinawa Island is an important visiting and wintering area for migratory birds and was added to the Ramsar Convention Register of Wetlands in 1999. This area used to be an inlet extending to the inner part of Naha Port, but recent reclamation projects have restricted its connection to the East China Sea. As is typical in rural regions of subtropical islands, the inhabitants in the Manko basin raise livestock, especially pigs, without employing sufficient waste treatment methods. As sewage treatment works are considered to be one of the main sources of environmental estrogens in urban areas, the significance of livestock farming as a source of estrogens in rural area is examined in this study. In the present study, total estrogenic activities in water and sediment samples from the Manko tidal flat and its basin were measured using a recombinant yeast screen method. Estrogenic activities (equivalent to 17beta-estradiol, E2) were around 10 ng l(-1) in water samples and more than 10 microg kg(-1) in some sediment samples. In addition, the concentrations of estrone (E1) and E2 in water samples measured using LC/MS/MS indicated a high contribution of environmental estrogens from livestock wastes. 相似文献
153.
Thomas H.?WilsonEmail author Kazuhiko?Kano Osamu?Nishizawa 《Pure and Applied Geophysics》2004,161(1):93-122
Regional and local characteristics of active fault patterns and elevation variation throughout Honshu, Japan are characterized in terms of their fractal dimensions; this allows variation in these complex variables to be compared directly to the scalar properties of net Quaternary vertical displacement, elevation and 10- and 110-year horizontal strains. The comparisons reveal that, throughout Honshu as a whole, there is significant correlation (r=0.75) between Quaternary vertical displacement, elevation, and its fractal properties. There is poor correlation, however, of elevation and its fractal properties to horizontal crustal strain, and also between Quaternary vertical displacement and horizontal crustal strain. A slight negative correlation is observed between the fractal properties of the active fault system and horizontal crustal strain measured over 10- and 110-year time periods (–0.43 and –0.26, respectively). The correlation between the 10-year (1985–1994) and 110-year (1883–1994) area strains, 0.48, reveals the occurrence of considerable change in the distribution of regional strain over these short time frames. Local computations of the correlation between data sets made for overlapping 160 km length windows of data spaced every 20 km along analysis lines reveal internal fluctuations in the correlation between variables. The local correlation between Quaternary vertical displacement and elevation is highest through central Japan and the Kinki Triangle. There is weak negative correlation between area strain and fractal dimensions of the active fault network. The local correlation between the fractal dimensions of active faults and horizontal area strain over the recent 10-year time period averages about –0.6 through central Japan in an area that extends across the Kinki Triangle through the northern part of central Honshu and northeast across the Itoigawa Shizuoka Tectonic Line. In general, regions of greatest complexity in the active fault network are associated with persistent negative area or compressional strain. Sparsely faulted areas in general coincide with areas of positive or roughly zero area strain. The presence of negative correlation through central Japan and the Kinki Triangle area in the recent 10-year period results from a decrease of area strain within an increasingly complex active fault system that reaches maximum negative values concentrated in the Kinki Triangle during the 1985–1994 time period. 相似文献
154.
Aiming Lin Tadashi Maruyama Stallard Aaron Katsuyoshi Michibayashi Alfredo Camacho Ken-ichi Kano 《Tectonophysics》2005,402(1-4):21
The Woodroffe thrust, central Australia, is a > 1.5-km-wide mylonitized shear zone marked by large volumes of mm- to cm-scale pseudotachylyte veins. The pseudotachylytes display typical melt-origin features, including rounded and embayed clasts, spherulitic and dentritic microlites, and flow structures within a fine-grained matrix. Three types of pseudotachylyte are identified on the basis of deformation texture, vein morphology, and host-rock lithology: cataclasite-related (C-Pt), mylonite-related (M-Pt), and ultramylonite-related (Um-Pt). The M-Pt and Um-Pt veins intrude into mylonite and ultramylonite and are themselves overprinted by subsequent mylonitization. These pseudotachylytes contain an internal foliation defined by flattened porphyroclasts and layering of the fine-grained vein matrix, and the foliation is generally oriented parallel to foliation in the surrounding mylonite and ultramylonite. These observations constrain the timing and environment of M-Pt and Um-Pt pseudotachylyte formation to a protracted period of deformation and mylonitization within the ductile regime of the crust. The M-Pt and Um-Pt veins, as well as the host mylonite, are overprinted by cataclasis and multiple generations of late-stage C-Pt veins that were generated in the brittle-dominated regime of the upper crust during uplift and exhumation of the shear zone.The coexistence of multiple generations of voluminous C-Pt, M-Pt, and Um-Pt veins indicates that the pseudotachylyte veins represent a large number of large earthquakes and accompanying seismic slip over an extended period of seismicity on the Woodroffe thrust. The timing and distribution of pseudotachylyte indicate that the earthquakes nucleated at the base of the brittle-dominated seismogenic zone and propagated down through the brittle–ductile transition into the ductile-dominated regime of the crust. 相似文献
155.
Motomu Toda Masayuki Yokozawa Akihiro Sumida Tsutomu Watanabe Toshihiko Hara 《Carbon balance and management》2007,2(1):6