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11.
A.E.KELEPERTSIS E.KONTIS 《中国地球化学学报》1997,16(1):8-19
The mineralogy and geochemistry data are presented for thirty-seven shales,four concretions,two carbonate sediments and seven lignites from the Marathousa coal field of the Megalopolis Basin in Greece.The argillaceous rocks consist of chlorite,illite,kaolinte,albite,quartz.opal-A,calcite and dolomite;the concretions of aragonite,gypsum and pyrite;and the carbonate rocks of calcite,quartz and illite.The mineral matter in the lignites consists of gypsum,quartz,albite,chlorite,illite,opal-A,dolomite,pyrite,and rarely calcite and kaolinite Athree-factor model explains the total variaition of major and trace elements in the argillaceous sediments.The first factor is an aluminosilicate factor and involves the following elements:Al,Si,Mg,Na,K,Ti,Mn,Nb,Y,Rb,Zn,Cu,Ni,Cr,Nband V,associated with chlorite,albite and illite.The second factor involves the elements Ca,Sr,Ba,Znand Sc and is related to carbonate lithology and mainly the carbonate concretions with gypsum.The third factor involves Fe and Ce with a weak association with Mn.The diagenesis of the Marathousa sediments and lignites was not very advanced as indicated by (a) the total thickness of the sequence (500m),(b) the presence of biogenic silica(opal-A) and (c) the age of the deposit(Pleistocene).FOr these reasons the rpresence of chlorite,illite and kaolinite in the sediments and lignite is due not to diagenetic reactions but to weathering of the flysch and metamorphic rocks at the edges of the Megalopolis Basin and transport of the weathering products(illite,chlorite,kaolinite)into the basin of deposition.The diagenetic minerals of the Marathousa sequence include pyrite,gypsum,dolomite and aragonite. 相似文献
12.
Copper, zinc, lead, manganese, arsenic, iron, cadmium and molybdenum were measured in specimens of Rumex acetosella and Minuartia verna and in soils where these plants grow. In Macedonia and the Chalkidiki peninsula both plants occur on newly investigated sulphide-mineralized ground. There are highly significant correlations between the levels of copper, zinc and lead in the plants and those in the soils. Where high concentrations of arsenic occur in the soil, this is also reflected in the plants. Because of the common association of gold and arsenic, it is suggested that analysis of Rumex and Minuartia for arsenic may be a useful prospecting tool since most of the ore occurrences in the Serbomacedonian massif are auriferous. The high levels of manganese in both plants from a manganese mineralized area indicate a strong possibility of using biogeochemical methods to define zones of some types of mineralization of this element also. 相似文献
13.
A.E. Kelepertsis 《地学学报》1993,5(1):52-60
The mobilities of major and trace elements have been investigated in hydrothermally altered volcanic rocks of Pliocene age on the island of Lesvos. One type of hydrothermal assemblage, montmorillonite-K-feldspar-goethite, was recognized in outcrops north of Mytilini town. The alteration occurs a few metres under the surface of unaltered volcanic rocks of high-K andesite and high-K basaltic andesite composition. The unaltered latite-andesite consists of plagioclase, clinopyroxene, sanidine and magnetite with quartz, calcite, pumpellyite and montmorillonite as subordinate secondary minerals. The main control over major oxide distribution appears to be the extent of conversion of plagioclase to K-feldspar. Three distinct groups of elements were revealed to be positively correlated:
- 1 Si, Mg, Ca, Na, Mn, Sr and Ba, which are leached during the alteration process. This group of elements reflects their association with plagioclase feldspar and clinopyroxene.
- 2 Fe, K, Ti, P, Nb, Zr, Y, Rb, Ni, Cr, V. This group includes elements which are enriched relative to the unaltered volcanic rock, reflecting their association with K-feldspar, iron hydroxides and Ti and P-bearing minerals.
- 3 Ti, P, Nd, La, Ce. From this group of elements it is indicated that Nd, La and Ce are associated with Ti- and P-bearing minerals.
14.
A soil geochemical survey was undertaken in the cultivated region of Agia in Thessaly area, Central Greece. The objectives
of the study were to assess the levels of soil contamination in respect to average concentrations of toxic metals in the region,
to determine the associations between the different toxic elements and their spatial distribution and to identify possible
sources of contamination that can explain the spatial patterns of soil pollution in the area. One hundred seventy three soil
samples were collected and analysed by ICP-AES after digestion with a mixture of HClO4–HNO3–H2O. The study focused on eleven elements (Cu, Pb, Zn, Ni, Co, Mn, As, V, Cr, Fe and Mg) and all of them except Pb have mean
concentrations above the average global soil composition. The elements Ni, Cr, Mn and V show concentrations that according
to G.L.C guidelines the Agia soils are classified as slightly contaminated to contaminated. Factor analysis explained 84.02%
of the total variance of the data through four factors. Combined with spatial interpretation of its output, the method successfully
grouped the elements according to their sources and provided evidence about their natural or anthropogenic origin. 相似文献