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111.
Detailed petrographic and mineralogic investigations of an albite-lepidolite granite at Echassières (Massif Central, France; scientific deep drill program) shows the existence of hydrothermal stages which are closely related to the magmatic and structural history. According to fluid inclusion data, K-Ar datations and 18O/16O-D/H compositions of secondary minerals, two successive hydrothermal periods have been recognized. The early one (273–268 million years) produced a series of aluminous phyllosilicates: muscovite, pyrophyllite, donbassite, tosudite, kaolinite which are observed as vein deposits (<10 mm wide) and alteration products of primary minerals in wall-rocks. The vein system was sealed by monomineralic assemblages during a cooling period (400–150°C). This early hydrothermal alteration stage was controlled by interactions of rock with low salinity (1–10 wt% NaCl equivalent) fluids expelled from the granitic body during the cooling processes. The chemical properties of these fluids were the following: low pH, very low Mg and Fe and high Li, Na and K contents. Thermodynamic calculations show that the sequence pyrophyllite, Li-bearing donbassite, tosudite is mostly temperature dependent. From the chemical composition of secondary minerals and isotopic data it can be deduced that these fluids, which have a meteoric origin, have been expelled from the granite body during its cooling period and after interaction with it at high temperature. The late hydrothermal stage corresponds to deposits of fluorite and Fe-Mg rich illite (151 million years) in subvertical fractures. Temperature conditions did not exceed 250° C and fluids came through the surrounding metamorphic rocks into the granitic body. IIlite/smectite mixed-layer minerals have been identified in subvertical fractures which were opened during Tertiary periods. In the host micaschists, successive hydrothermal alterations took place during the cooling of the Beauvoir granite. Early magmatic fluids interacted with these micaschists. Locally, the metamorphic assemblage is replaced by a metasomatic one. Secondary topaz and (F, Li)-rich mica crystals were formed over a range of 450 of 150°C. Later hydrothermal fluids reacted with the country rocks to form phengite-biotite, chlorite-illite and kaolinite over a range of 300 to 150°C. Illite/smectite mixed-layer minerals crystallized in the roof micaschists and within the Beauvoir granite during the Tertiary alteration period. Meteoric water invaded open fractures producing supergene alteration mineral assemblages.  相似文献   
112.
Summary This study uses a 1°×1° lat/long dataset, extracted from ECMWF re-analyses for the 15-year period 1979–1993 (ERA-15), to diagnose the synoptic-scale kinematic, thermodynamic and moisture environments in the vicinity of named tropical cyclones (TCs) in the eastern North Pacific. Based on the NCDC best track dataset, TCs are partitioned into one of three categories: weak (W), strong (S) or intensifying (I). In total, 63TCs are examined: 8Ws and 20Is at point A (maximum intensification) and 11Ws, 13Ss and 11Is at point B (maximum frequency). Composite maps are compiled for all five groups, and six individual case studies are examined, four for extreme TC cases and two for cases involving dry air intrusions.For the most part, peak values and patterns of composited ERA-15 variables display circulation, thermodynamic and moisture characteristics that are compatible with the strength represented by a groups classification. Intercomparison between Ws and Is at points A and B yielded larger conditional instability of low-level air parcels and upper-level outflow within the region of maximum intensification (point A).The intrusions of dry versus moist mid-level air are addressed for each storm with the assistance of 72-hour backward trajectories. Trajectory density maps indicate two preferred paths of air parcels that reach the environment of W storms at point A on the 700 and 500hPa levels. The first one crossed Central America in the region of the Isthmus of Tehuantepec and the second one south of the Central American mountains. Several storms revealed that these trajectories were associated with dry air intrusions into the larger storm area, and this might be one reason for their weak status at point A. One documented example is Kevin (1985). By the time it reached point B, the dry air was replaced by air that was moist and Kevin intensified, although it remained a W system. In contrast, Narda (1989) received a dry air intrusion from Central Mexico at 500hPa as a weak storm at point B and did not intensify. Despite possible analyses problems, the documentation in this study of mid-level dry air intrusions into eastern Pacific TCs from the Mexican-Central American region suggests a hitherto unexploited forecast potential. Received January 15, 2002; revised November 28, 2002; accepted December 19, 2002 Published online: May 8, 2003  相似文献   
113.
The geochemical processes occurring within meromictic Lake A (maxdepth 120 m) on northern Ellesmere Island, Canada, were investigated to determinethe history of the lake and to provide a baseline for future studies. The lake contained seawaterdiluted by freshwater input that had been mixed prior to the lake's isolation from tidalaction. Input of freshwater after isolation of the lake created vertical stratification resultingin the creation of distinct oxic, suboxic and anoxic zones. Dissolved oxygen was present to 13 m,and sulphide beneath 32 m. Manganese and iron cycling dominated the redox chemistrybetween these depths. Total manganese concentrations reached 176 M, higher thanin most other natural stratified lake or marine environments.  相似文献   
114.
Following the spill of fuel oils from the New Carissa in February 1999, approximately 300 km of beaches on the Pacific coast of North America were surveyed. A long-term observation program focused on the documentation of stranded tar balls in the vicinity of the spill site. Systematic beach surveys which were conducted over the period March 1999 to April 2001 and semi-logarithmic scale, time-series plots proved the most useful format for identifying trends. Beach monitoring continued through to August 2001. by which time 212 tar balls had been analyzed by GC/MS for their chemical characteristics. The samples of tar balls collected between February 1999 and August 2001 were qualitatively compared with New Carissa source oils (NCSO) and 101 (48%) were not consistent with NSCO. The presence of tar balls that are not related to an incident can confound attempts to define cleanup or endpoint criteria and to assess possible injury to natural resources.  相似文献   
115.
Estimates of spatial and temporal variations in suspended sand concentrations (SSC) made with a multi-transducer Acoustic Backscatter Sensor (ABS) under a repeated wave group over a mobile rippled bed in the wave research flume at the National Hydraulics Laboratory in Ottawa, Canada, reveal an number of complex and intriguing patterns. Ensemble averages of 8 nearly identical wave groups provided much more robust estimates of SSC and allowed a detailed examination of the wave group effects. The largest SSC near the bed (< 0.10 m) occurs in phase with the largest waves in the group. Above approximately 0.10 m elevation, SSC lags behind the near bed SSC by as much as 2–3 waves; introducing significant curvature (on a semi-log plot) to the SSC profile. The log linear segments of the SSC profile grow and decay systematically on the scale of the wave group. The range in lengths of log-linear profile segments ( 0.03–0.355 m) suggest that the boundary layer thickness also fluctuates throughout the passage of the wave group. Furthermore, there are significant variations in the patterns of SSC, which occur under the largest and smallest waves in the group. Under the largest waves vertical bands of alternating high and low SSC produce an intra-wave modulation in the upper water column ( 0.075–0.30 m). The equivalent horizontal excursion of these bands scales to the ripple length. Under the smaller waves the intra-wave modulation of the SSC disappears and is replaced by temporally homogenous suspension that expands vertically through several individual wave cycles. The former pattern of homogenous suspension appears to be associated with growth of a boundary layer due to the persistent uni-directional horizontal flow during this part of the group together with the persistence of antecedent bed generated turbulence and vorticity which maintains the suspension. The latter pattern of bands of high and low SSC indicates a strong temporal and spatial constraint on the SSC (phase coupling) induced by the presence of the bedforms which may be enhanced by strong reversals in both flow and vorticity under the large waves in the group.  相似文献   
116.
Introduction Scattering of incident waves by local topographies is one of the most attractive topics in the field of engineering seismology. They can be resolved by either a numerical method or an analyti-cal method. The numerical methods include finite difference method, finite element method, boundary element method, etc. The analytical method is the wave function expansion method. Al-though numerical methods can be used for arbitrary-shaped topographies, the analytical solutions are still …  相似文献   
117.
The Callovo-Oxfordian claystones located at 500 m depth at Bure (Meuse, France) are currently being investigated by Andra (the French National Radioactive Waste Management Agency) for testing the feasibility of long-term and deep geological nuclear waste disposal. In order to evaluate its potential as a geological barrier, it is very important to study, assess and describe its physico-chemical variability. The molecular biomarker composition of 150 samples of these claystones and their surrounding limestones carry diverse information on the sources of the sedimentary organic matter, the chemistry of the depositional environment, the preservation and diagenesis conditions. It also allows assessing the degree of lateral and vertical variability of the organic matter within these sedimentary series. The abundance of unsaturated biomarkers, the distribution of steroids and hopanoids and CPI values >2 prove the thermal immaturity of the organic matter. The co-occurrence of plankton, bacteria and land plant biomarkers indicate that the organic matter is a mixture of marine and continental contributions. The data also reveal that the organic matter was deposited under oxic and open-sea conditions except for a brief event of photic zone anoxia at the beginning of the Middle Callovian. In the claystones, the geosynthesis of diasterenes is favored to the detriment of the formation of steranes, especially in smectite-rich levels, and the organic matter is rapidly isolated from oxidizing then reducing conditions after the deposition due to the protective effect of clays. On the scale investigated, the claystones are characterized by a unique molecular facies and are thus homogenous from their organic content point of view. Yet, detailed investigation of specific molecular families indicates changes related to major claystone–limestone transitions. The homogeneity of these claystones can be explained by the paleogeographic position of their depositional setting and the plane and sub-horizontal paleotopography on which they were deposited. This study demonstrates the efficiency of organic geochemistry in the assessment of the variability of geological barriers.  相似文献   
118.
The Cloud Type product, developed by the Satellite Application Facility to support to nowcasting and very short-range forecasting (SAFNWC) of EUMETSAT and based on Météosat-8/SEVIRI, identifies cloud categories, and especially low and very low clouds which are first estimates of areas where fog is likely to occur. This cloud type is combined with precipitation information from radar data and with hourly diagnostic analyses of 2-metre relative humidity and 10-metre wind to elaborate an hourly analysis of fog probability. This analysis provides four levels of fog probability with a 3-kilometre horizontal resolution: No risk, low-level risk, medium-level risk and high-level risk. An evaluation of such fog probability analyses versus a one-year set of French hourly SYNOP reports shows encouraging results (potential of detection = 0.73 for low and medium and high-level risks), even if false alarm ratios remain high. Most of the non-detections occur at twilight and are due to satellite non-detections. Eventually, we show case studies that clearly illustrate the high potential of the method.  相似文献   
119.
The Balkuyumcu region, located in the southwestern part of Ankara in the Izmir-Ankara suture zone (central Anatolia, Turkey), consists of basic andesitic, andesitic, dacitic and rhyolitic rocks extruded during the Early Miocene (20–22 Ma) as a result of post-collisional volcanism. Balkuyumcu volcanic rocks can be divided into two groups on the basis of their mineralogy and composition: The basic andesitic (BA) and andesitic, dacitic and rhyolitic (ADR) groups. The ADR and BA group of rocks have adakite-like and calc-alkaline characteristics, respectively. The ADR group has higher SiO2 content, Sr/Y and La/Yb ratios and low MgO, Mg#, Y and Yb contents than the BA group. Both groups have nearly the same Sr, Nd isotopic compositions and display similar normalized multi-element patterns with enrichments in LILE and LREE, depletions in Nb, Ti, Zr, P and a lack of Eu anomalies. Major, trace element and Sr, Nd isotopic data indicate that both groups of rocks were derived from the same source but affected by different magmatic processes during ascent. The adakite-like rocks may have been produced by partial melting of thickened lower continental crust. Fractional crystallization also played a major role in their formation. However, the BA group rocks were derived from partial melting of lower continental crust that was probably delaminated. These rocks appear to have had limited interaction with mantle peridodite during ascent to the surface.  相似文献   
120.
An effective and accurate technique for the numerical solution of 2-D electromagnetic scattering problems with 3-D sources is presented. This solution introduces a set of the usual boundary integral equations and uses a scalar Green's function. In this scalar version, the unknowns of the problem are the boundary values of the longitudinal fields and their normal derivatives in the Fourier domain. A generalization of the usual boundary integral formulation enables us to handle a large class of models composed of piecewise homogeneous domains, including contiguous domains, multiply-connected domains and unbounded domains. This formulation involves the solution of a system of linear equations, and results in a significant saving in computation time in comparison with other rigorous methods.
  The requirements for the numerical implementation of this solution are described in detail. Numerical tests were carried out using the important example of electromagnetic tomography. The specific symmetry properties of the response function in this case are illustrated. Numerical accuracy is verified over a large frequency range, up to 1  MHz.  相似文献   
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