Response of hepatic trace element concentrations in fish exposed to elemental and organic contaminants     

Peter J. Hanson 《Estuaries and Coasts》1997,20(4):659-676

Multivariate analysis of contaminant data from a multi-year monitoring program demonstrates alterations in the hepatic chemistry of metals in fish exposed to organic contaminants. Metals (Ag, As, Cd, Cu, Fe, Hg, Mn, Ni, Pb, Se, Sn, Zn) and organic chemicals (PCBs, DDTs, chlordanes, dieldrins, PAHs) were measured in liver and associated sediments for winter flounder (Pleuronectes americanus) from 23 sites along the northeast Atlantic coast and for Atlantic croaker (Micropogonias undulatus) from 30 sites along the southeast Atlantic and Gulf of Mexico coasts of the United States. Concentrations of habitat contaminants varied from nil to levels signifying important anthropogenic inputs and thus provided a range in chronic exposures and related contaminant stress levels with which to investigate the response of hepatic chemistry in fish representative of viable populations. The data, analyzed by principal component, principal component regression, and biplot procedures, demonstrated an opposing relationship between micronutrient elements, principally Zn, and exposure to organic contaminants in winter flounder. This relationship was not present in Atlantic croaker that were resident in less contaminated habitats. Based on median concentrations in sediment, exposure of winter flounder to important organic contaminants (polycyclic aromatic hydrocarbons, polychlorinated biphenyls, DDTs) exceeded that for Atlantic croaker by 7 to 50 times. Coincident with depletion of hepatic Zn and Cd in winter flounder was accumulation of Hg and Ag. My results, in agreement with those of others, implicate the negative effects of hepatic detoxification of organic contaminants on metal binding in liver, which can cause depletion of essential elements while contaminant and potentially toxic elements accumulate.  相似文献   

Sources and paleoclimatic significance of Holocene Bignell Loess, central Great Plains, USA     

Joseph A. Mason  Peter M. Jacobs  Paul R. Hanson  Xiaodong Miao  Ronald J. Goble 《Quaternary Research》2003,60(3):330-339

This paper reexamines the stratigraphy, sources, and paleoclimatic significance of Holocene Bignell Loess in the central Great Plains. A broadly similar sequence of loess depositional units and paleosols was observed in thick Bignell Loess sections up to 300 km apart, suggesting that these sections record major regional changes in the balance between dust deposition and pedogenesis. New optical ages, together with previously reported radiocarbon ages, indicate Bignell Loess deposition began 9000–11,000 yr ago and continued into the late Holocene; some Bignell Loess is <1000 yr old. There is little evidence that Holocene Loess was derived from flood plain sources, as previously proposed. Instead, thick Bignell Loess occurs mainly near the downwind margins of inactive dune fields, particularly atop escarpments facing the dunes. Thus, the immediate loess source was dust produced when the dunes were active. Previous work indicates that widespread episodes of dune activity are likely to have resulted from drier-than-present climatic conditions. The regionally coherent stratigraphy of Bignell Loess can be interpreted as a near-continuous record of climatically driven variation in dune field activity throughout the Holocene.  相似文献   

Erodibility of cohesive streambeds in the loess area of the midwestern USA   总被引：2，自引：0，他引：2  

G. J. Hanson  A. Simon 《水文研究》2001,15(1):23-38

Excess stress parameters, critical shear stress (τ_c) and erodibility coefficient (k_d), for degrading channels in the loess areas of the midwestern USA are presented based on in situ jet‐testing measurements. Critical shear stress and k_d are used to define the erosion resistance of the streambed. The jet‐testing apparatus applies hydraulic stresses to the bed and the resulting scour due to the impinging jet is related to the excess stress parameters. Streams tested were primarily silt‐bedded in texture with low densities, which is typical of loess soils. Results indicate that there is a wide variation in the erosion resistance of streambeds, spanning six orders of magnitude for τ_c and four orders of magnitude for k_d. Erosion resistance was observed to vary within a streambed, from streambed to streambed, and from region to region. An example of the diversity of materials within a river system is the Yalobusha River Basin in Mississippi. The median value of τ_c for the two primary bed materials, Naheola and Porters Creek Clay Formations, was 1·31 and 256 Pa, respectively. Streambeds composed of the Naheola Formation are readily eroded over the entire range of shear stresses, whereas only the deepest flows generate boundary stresses great enough to erode streambeds composed of the Porters Creek Clay Formation. Therefore, assessing material resistance and location is essential in classifying and modelling streambed erosion processes of these streams.  相似文献   

U-Pb calcite age of the Late Permian Castile Formation, Delaware Basin: a constraint on the age of the Permian-Triassic boundary (?)     

M.L. Becker  E.T. Rasbury W.J. Meyers  G.N. Hanson 《Earth and Planetary Science Letters》2002,203(2):681-689

Organic-rich calcite laminated with gypsum in the evaporitic, non-fossiliferous Castile Formation of the Delaware Basin, southwest USA, yields a Total Pb/U isochron age of 251.5±2.8 Ma (MSWD=1.3). The Castile Formation is almost certainly Late Permian based on its ⁸⁷Sr/⁸⁶Sr value of 0.706923, identical to the distinct minimum in the late Permian Sr curve. In this paper we explore the potential for using U-Pb calcite ages to date traditionally undatable sections and show how this southern-midcontinent USA (far west Texas and southeast New Mexico) deposit can be correlated to the type section in China. We accept that diagenetic alteration can bias U-Pb results, but the data set we present shows no evidence for such alteration. Clearly with alteration the age we present would represent a minimum age for the Castile Formation. If the age actually dates the Castile Formation then it requires the Permian-Triassic boundary to be younger than 251.5±2.8 Ma.  相似文献   

Growth and characterization of synthetic iron-bearing olivine     

D. R. Hanson  M. Young  F. J. Ryerson 《Physics and Chemistry of Minerals》1991,18(1):53-63

Single crystals of olivine were grown at 0.1 MPa total pressure in a floating-zone image furnace. Composition of crystals grown ranged from 67 mol% forsterite to 90 mol% forsterite. Improvements in the crystal growth technique allowed growth of large crystals (0.005 m diameter, 0.070 m length) with very low dislocation density, no visible bubbles, and no cracks. The most significant improvement was the addition of a platinum-wound resistance heater internal to the image furnace. This heater provided the dual improvements of better control over oxygen fugacity from a CO/CO₂ gas mix and alteration of the crystal growth interface resulting in a significant reduction in crystal defects. No subgrain boundaries have been observed in crystals growth here and dislocation densities on the order of 10⁸-10⁹ m^-2 have been achieved. Iron concentration is nearly uniform across the diameter (0.005 m) of crystals and varies approximately 5 mol% along the crystal length (0.040 to 0.050 m).  相似文献   

The Cortlandt complex: evidence for large-scale liquid immiscibility involving granodiorite and diorite magmas     

J.F. Bender  G.N. Hanson  A.E. Bence 《Earth and Planetary Science Letters》1982,58(3):330-344

Granodiorite and diorite plutons of the Rosetown complex, N.Y., which are associated with the nearby Cortlandt complex, have chemical and textural characteristics indicating that large-scale liquid immiscibility played a major role in their petrogenesis. Rare earth element, zirconium, niobium and phosphorus abundances are much greater in the diorite precluding the possibility that the Rosetown diorite and granodiorite are related by fractional crystallization. The trace element data also eliminate the possibility that the granodiorite represents: (1) a partial melt of crustal rocks including basalt; (2) a granitic cumulate; or (3) a residue from an aqueous fluid derived either from a silicate melt or crustal rocks. Liquid immiscibility appears to be viable model for the origin of the Rosetown granodiorite and iron-rich diorite. This model is supported by the following: (1) the major element compositions occur in a two-liquid field on a Greig diagram; (2) both bodies have similar Sr isotope compositions; (3) common phases in the two rock types have overlapping compositions; (4) the major and trace element data of the diorite and granodiorite are similar to the experimentally determined partition data of immiscible liquid pairs; and (5) possible ocelli of iron-rich diorite are found in the granodiorite.  相似文献   

Geochemistry and origin of the early Precambrian crust of northeastern Minnesota   总被引：2，自引：0，他引：2  

Joseph G Arth  Gilbert N Hanson 《Geochimica et cosmochimica acta》1975,39(3):325-362

  相似文献   

南秦岭横丹浊积岩系—晚古生代发育于扬子板块被动陆缘上的弧前盆地充填物   总被引：14，自引：3，他引：14  

闫全人  A.D.Hanson 《地质通报》2002,21(8):495-500

南秦岭横丹浊积岩系是一套巨厚的浊流沉积，以向南或南东倾的单斜构造产出。由下而上，该沉积层序包括深水盆地、深水浊积扇和斜坡水道3个相序。相应地，沉积物粒度变粗，厚度变大，火山质组分含量增加，凝灰层大量发育，表明横丹浊积岩系为活动型浊积岩；其古水流方向为NNW－NNE向，物源区为南侧的碧口火山岩系。另外，横丹浊积岩系内还见石英岩、重结晶大理岩成分的砾石，说明其物源还包括被动陆缘环境的沉积物。相序、组构、沉积特征和物源区综合分析表明，横丹浊积岩系为弧前盆地充填物。构筑这一弧前盆地的动力学机制是洋壳板块向南俯冲于扬子板块被动陆缘之下，时代可能晚于中晚泥盆世。  相似文献   

Advanced techniques in site characterization and mining hazard detection for the underground coal industry     

David R. Hanson  Thomas L. Vandergrift  Matthew J. DeMarco  Kanaan Hanna 《International Journal of Coal Geology》2002,50(1-4)

Today's highly productive coal mining systems represent large capital investments. Careful geotechnical planning and design are essential to protect these systems and to help ensure their overall success. Too often, however, the ability of the mine operator to adequately characterize the geotechnical environment and keep up with changing geologic conditions lags the advance rate of the mining equipment. Seismic tomographic imaging, based on the same principles as medical Computer-Aided-Tomography (CAT) Scans, offers the ability to identify changing geologic conditions, loading patterns, and the location of nearby abandoned mine workings. Although seismic tomography has been used for many years in the oil industry, until recently its practicality in the mining industry has been limited because the processes involved interfered with mining productivity and were labor-intensive in terms of data collection and interpretation. New advancements in signal processing have greatly enhanced the speed, resolution, and range of applications of tomographic imaging in underground coal mine settings.Many tomography applications in the mining industry use seismic velocity and/or attenuation tomography within a volume enclosed by the seismic source and receiver array. Although results obtained using this geometry work well in many situations, recent developments in reflection tomography show promise in eliminating the requirement that the target volume be surrounded by sources/receivers. For example, in-seam seismic reflection tomography may now be used to image structures and/or old workings from one general location in the mine (e.g., face areas of mains and panel developments) well ahead of planned developments—largely eliminating the need to probe-hole drill on regular intervals. These new developments have greatly expanded the ability of the mine operator to cost-effectively characterize previously inaccessible areas of the property.This paper gives an overview of the theories and processes involved in seismic tomography applicable to coal mine settings. Recent examples are presented of tomographic imaging applied to a variety of coal mine ground control problems and old works detection in the United States and Europe. The applicability of both seismic refraction and seismic reflection tomography is discussed.  相似文献   

Scale and timing of Rare Earth Element redistribution in the Taconian foreland of New England     

Barbara Bock  J. A. Hurowitz  S. M. Mclennan  G. N. Hanson 《Sedimentology》2004,51(4):885-897

Clastic sedimentary rocks, deposited on eastern North America in response to the Taconian Orogeny, commonly have Sm/Nd isotope relationships indicating substantial isotope disturbance near or subsequent to the time of sedimentation that may be associated with severe depletion in light rare earth elements (LREE). Affected units [Normanskill Formation (Austin Glen and Pawlet Members), Frankfort Formation and Perry Mountain Formation] are widely separated both geographically (western New York to western Maine) and stratigraphically (Middle Ordovician to Silurian). A model is proposed for the most likely explanation of the observed REE and Sm/Nd isotope relationships involving a two‐stage process. In the first stage, REE are redistributed on a mineralogical scale (dissolution/precipitation on a sample scale) often with the involvement of REE‐enriched trace phases such as apatite and monazite. This stage typically takes place during diagenesis but may also take place later during metamorphism and/or recent weathering, and results in isotope re‐equilibration on a sample scale. The second stage occurs when one or more of these phases is redissolved and REE are transported on large advective scales. Where LREE‐enriched phases are involved, this gives rise to LREE depletion in whole rocks. The timing of this second stage cannot be constrained from Sm/Nd isotope data and may take place at any time subsequent to the isotope re‐equilibration. Such complex histories of REE redistribution may result in serious errors in estimating Nd model ages but not in estimating the Nd isotope composition at the age of sedimentation. Thus, Sm/Nd ratios even of unmetamorphosed sedimentary rocks have to be carefully evaluated before the calculation of depleted mantle model ages for the provenance.  相似文献