Newtontoppen granitoid rocks, their geology, chemistry and Rb-Sr age     

A. M. TEBEN'KOV  Y. OHTA  JU. A. BALA&#;OV  A. N. SIROTKIN 《Polar research》1996,15(1):67-80

A post-tectonic Caledonian granite in southern Ny Friesland has been fully mapped and the following new names are proposed: the Chydeniusbreen granitoid suite, consisting of the Raudberget granitoid body in the north; the Newtontoppen granitoid body in the middle; and the Ekkoknausane granitoid body in the south
The contact relationships, internal structures and distribution of various rock types infer an asymmetric lopolith or a harpolith-like body, a large sickle-shaped intrusion stretched in the direction of general tectonic transport, for the Newtontoppen granitoid body.
Seven rock types are described in the Newtontoppen granitoid and four emplacement stages are recognised. The major rock types seem to have an alkali-calcic to alkalic bulk rock chemistry and show a transition between I- and S-type granite derived from anatectic melting of various protoliths under relatively high temperature conditions. Possible later K₂0 introduction modified the earlier formed rock types.
A Rb-Sr whole rock age of 432 ± 10 Ma has been obtained by a seven point isochron with MSDW = 2.59 and an initial Sr isotope ratio = 0.715. This age is approximately 30 Ma older than the previously obtained K-Ar whole rock and Rb-Sr biotite ages, ca. 400 Ma, which represents the period of cooling. The high initial Sr isotope ratio supports the interpretation of an anatectic origin.  相似文献   

Rb-Sr whole rock and U-Pb zircon datings of the granitic-gabbroic rocks from the Skålfjellet Subgroup, southwest Spitsbergen     

YU. A. BALA&#;OV  J. J. PEUCAT  A. M. TEBEN'KOV  Y. OHTA  A. N. LARIONOV  A. N. SIROTKIN  M. BJORNERUD 《Polar research》1996,15(2):167-181

Recent remapping and new age determinations has shed light on the understanding of Precambrian rocks northwest of Hornsund, southwest Spitsbergen. The Skålfjellet Subgroup has been regarded as the eastern equivalent of the Vimsodden Subgroup, and both of these occur within the Precambrian Eimfjellet Group of southwest Spitsbergen. Although the Eimfjellet Group is considered to be older than the oldest unconformity in the area, the age of the rocks has not been known. The granitic-gabbroic rocks in the Skålfjellet Subgroup have been considered to be the products of granitisation for many years, but recent observations show that they are exotic blocks incorporated into the basic eruptive rocks which are the main constituents of the subgroup. These plutonic rocks have a wide range of compositions, from syenite via granite to gabbroic cumulates, which suggests the existence of a well-differentiated plutonic body at depth.
U-Pb zircon and Pb evaporation datings yielded magmatic ages of ca. 1,100 to 1,200 Ma, and a conformable age has been obtained by Rb-Sr whole rock dating. Detrital zircons from the micaceous schists of the Isbjørnhamna Group, which underlies the Skålfjellet Subgroup, show a poorly defined discordia with an upper intercept age of ca. 2,200 Ma and a lower intercept age of ca. 360 Ma. These dating results define the magmatic age of the granitic-gabbroic rocks as late Mesoproterozoic, early Grenvillian. This age is in broad agreement with that of the metavolcanic rock clasts of the Pyttholmen meta-pyroclastic-conglomeratic unit at Vimsodden, which is considered to be the westernmost occurrence of the Skålfjellet Subgroup.
A Rb-Sr whole rock age determination of the shaly phyllites from the Deilegga Group was performed in order to place constraints on the age of younger Precambrian event; however, no good isochron was obtained.  相似文献   

Municipal Landfilling Practice And Its Impact On Groundwater Resources In And Around Urban Toronto,Canada   总被引：2，自引：1，他引：2  

K.W.F. Howard  N. Eyles  S. Livingstone 《Hydrogeology Journal》1996,4(1):64-79

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Hydrous pyrolysis of a Type III source: fractionation effects during primary migration in natural and artificially matured samples     

C.S. Mishra  U. Samanta  A. Gupta  N.J. Thomas  K.N. Misra 《Organic Geochemistry》1996,25(8):489-505

A core from the Cambay Shale Formation of the Cambay Basin, containing immature Type III organic matter, was pyrolysed at 300°C for different durations of time to different maturation levels. Fractionation effects were studied employing a three-step extraction technique after removal of the expelled pyrolysate. The extractable organic matter (EOM) obtained on extraction of the whole core is assumed to be that present in open pores, while that obtained on finely crushing the sample is assumed to be that present in closed pores. The EOM obtained from 1 cm chips is termed EOM from semi-open pores. The gross composition of the pyrolysates expelled during pyrolysis is not similar to the oils reservoired in the area, and there is no significant fractionation observed between expelled pyrolysates and unexpelled EOM. Our study indicates movement of fluids between closed, semi-open and open pores. In both systems, there is a higher concentration of EOM in open pores than in semi-open and closed pores, and the fraction of EOM in open pores is much greater in the artificial system than in the natural system. Fractionation effects on n-alkane and isoprenoid hydrocarbon-based parameters were also studied. n-Alkenes are present in semi-open and closed pores of the immature core and in the core after it was pyrolysed to 300°C for 6 and 48 h, but are absent in the open pores. n-Alkenes are present in closed pores in the naturally matured core. Presence of n-alkenes in the pyrolysates expelled during the 6 and 48 h experiments, but their absence in the open pores of the core, indicates that expulsion also occurs through temporary microfractures during laboratory pyrolysis, whereas in the natural system expulsion from closed pores seems to be only via semi-open and open pores.  相似文献   

Surface chemical analysis in coal preparation research: complementary information from XPS and ToF-SIMS     

A. N. Buckley  R. N. Lamb 《International Journal of Coal Geology》1996,32(1-4)

The application of X-ray photoelectron spectroscopy (XPS) to coal surface characterisation for preparation research is described. Progress towards the acquisition of complementary surface chemical information by time-of-flight secondary ion mass spectrometry (ToF-SIMS) is also discussed. Surface-based beneficiation techniques such as flotation are assuming greater importance as the proportion of fines in raw coal increases due to the proliferation of high capacity mining methods. A necessary condition for the floatability of a coal particle is adequate hydrophobicity, and the degree of hydrophobicity of the flotation concentrate is one factor influencing the ease with which its dewatering can be affected. The hydrophobicity of a coal is very difficult to measure directly because of microporosity, and it is often necessary to deduce the degree of hydrophobicity from a knowledge of the surface chemistry. XPS is able to provide sufficient analytical data to allow relative levels of hydrophobicity to be estimated. In principle, ToF-SIMS should be able to supply additional information enabling refinement of such estimates; however, there are insufficient data at present to allow the ionic fragments detected to be related to specific functional groups at the coal surface.  相似文献   

Benchmarking the thermomechanical behaviour of clays — a progress report — the CEC interclay project     

N.C. Knowles  R.M. Jeffries  B. Come 《Engineering Geology》1996,41(1-4):65-71

In 1989 a small-scale exercise conducted by the CEC as part of its research programme into the underground storage of radioactive waste highlighted the difficulty of making accurate predictions a priori, of the geomechanical behaviour of clay. Given source data about the Boom clay from the underground research facility at Mol, three organisations independently performed f.e. analyses of two somewhat hypothetical problems. While the results were very broadly in agreement, they were shown to be sensitive to both the type of constitutive model used and the way data was fitted to the model.

Subsequently, the CEC sponsored a more comprehensive benchmark exercise called INTERCLAY II. This involves eleven organisations from various member states of the EC in a project encompassing the three aspects of software development for predictive modelling: verification, validation on the laboratory scale and the treatment of in-situ tests. The paper briefly describes the exercise currently in progress and presents the main results achieved to date concentrating on validation aspects.  相似文献   

Effects of temperature on strength and compressibility of sand-bentonite buffer   总被引：1，自引：0，他引：1  

B.E. Lingnau  J. Graham  D. Yarechewski  N. Tanaka  M.N. Gray 《Engineering Geology》1996,41(1-4):103-115

Dense sand-bentonite buffer (γ_d = 1.67Mg/m³) has been proposed in Canada as one of several barriers for isolating nuclear fuel waste. The buffer will be required to function under conditions of high total pressures and elevated temperatures approaching 100°C. Summary results are presented from two test programs: (1) isothermal consolidated undrained triaxial (CIU¯) tests; and (2) isothermal drained constant-p′ (CID) triaxial tests. Specimens were consolidated at effective stresses up to 9.0 MPa and temperatures up to 100°C.

The results indicate parallel hardening lines at systematically lower values of specific volume at elevated temperatures. In shear, increased temperatures produced lower values of maximum deviator stressq_f, and higher pore water pressure changesΔu_f. The net result is curved peak strength envelops in plots ofq_f versusp_f′ that are higher at elevated temperatures, even though the strengths,q_f of individual specimens are lower. The critical state strength envelope is curved inq, p′-planes.

The effect of drained heating on buffer to 100°C is not marked. Compressibilities, stiffnesses, strengths, and pore water pressure generation are all affected, but none of the changes are great.  相似文献   

Comments on the paper by G.M. Gonzaga et al.     

O. H. Leonardos  R. N. Thompson  R. Fleicher  S. A. Gibson  D. P. Svisero  R. K. Weska 《Mineralium Deposita》1996,31(4):343-344

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The mean and turbulence structure simulation of the monsoon trough boundary layer using a one-dimensional model withe-l ande-ε closures     

Kusuma G. Rao  V. N. Lykossov  A. Prabhu  S. Sridhar  E. Tonkacheyev 《Journal of Earth System Science》1996,105(3):227-260

An attempt has been made here to study the sensitivity of the mean and the turbulence structure of the monsoon trough boundary layer to the choice of the constants in the dissipation equation for two stations Delhi and Calcutta, using one-dimensional atmospheric boundary layer model withe-ε turbulence closure. An analytical discussion of the problems associated with the constants of the dissipation equation is presented. It is shown here that the choice of the constants in the dissipation equation is quite crucial and the turbulence structure is very sensitive to these constants. The modification of the dissipation equation adopted by earlier studies, that is, approximating the Tke generation (due to shear and buoyancy production) in theε-equation by max (shear production, shear + buoyancy production), can be avoided by a suitable choice of the constants suggested here. The observed turbulence structure is better simulated with these constants. The turbulence structure simulation with the constants recommended by Aupoixet al (1989) (which are interactive in time) for the monsoon region is shown to be qualitatively similar to the simulation obtained with the constants suggested here, thus implying that no universal constants exist to regulate dissipation rate. Simulations of the mean structure show little sensitivity to the type of the closure parameterization betweene-l ande-ε closures. However the turbulence structure simulation withe-ε. closure is far better compared to thee-l model simulations. The model simulations of temperature profiles compare quite well with the observations whenever the boundary layer is well mixed (neutral) or unstable. However the models are not able to simulate the nocturnal boundary layer (stable) temperature profiles. Moisture profiles are simulated reasonably better. With one-dimensional models, capturing observed wind variations is not up to the mark.  相似文献   

Thorium and uranium isotopes in a manganese nodule from the Peru basin determined by alpha spectrometry and thermal ionization mass spectrometry (TIMS): Are manganese supply and growth related to climate?     

A. Bollhöfer  A. Eisenhauer  N. Frank  D. Pech  A. Mangini 《International Journal of Earth Sciences》1996,85(3):577-585

Thorium- and uranium isotopes were measured in a diagenetic manganese nodule from the Peru basin applying alpha- and thermal ionization mass spectrometry (TIMS). Alpha-counting of 62 samples was carried out with a depth resolution of 0.4 mm to gain a high-resolution²³⁰Th_excess profile. In addition, 17 samples were measured with TIMS to obtain precise isotope concentrations and isotope ratios. We got values of 0.06–0.59 ppb (²³⁰Th), 0.43–1.40 ppm (²³²Th), 0.09–0.49 ppb (²³⁴U) and 1.66–8.24 ppm (²³⁸U). The uranium activity ratio in the uppermost samples (1–6 mm) and in two further sections in the nodule at 12.5±1.0 mm and 27.3–33.5 mm comes close to the present ocean water value of 1.144±0.004. In two other sections of the nodule, this ratio is significantly higher, probably reflecting incorporation of diagenetic uranium. The upper 25 mm section of the Mn nodule shows a relatively smooth exponential decrease in the²³⁰Th_excess concentration (TIMS). The slope of the best fit yields a growth rate of 110 mm/Ma up to 24.5 mm depth. The section from 25 to 30.3 mm depth shows constant²³⁰Th_excess concentrations probably due to growth rates even faster than those in the top section of the nodule. From 33 to 50 mm depth, the growth rate is approximately 60 mm/Ma. Two layers in the nodule with distinct laminations (11–15 and 28–33 mm depth) probably formed during the transition from isotopic stage 8 to 7 and in stage 5e, respectively. The Mn/Fe ratio shows higher values during interglacials 5 and 7, and lower ones during glacials 4 and 6. A comparison of our data with data from adjacent sediment cores suggests (a) a variable supply of hydrothermal Mn to sediments and Mn nodules of the Peru basin or (b) suboxic conditions at the water sediment interface during periods with lower Mn/Fe ratios.  相似文献