Determining the trophic guilds of fishes and macroinvertebrates in a seagrass food web     

Joseph J. Luczkovich  Garcy P. Ward  Jeffrey C. Johnson  Robert R. Christian  Daniel Baird  Hilary Neckles  William M. Rizzo 《Estuaries and Coasts》2002,25(6):1143-1163

We established trophic guilds of macroinvertebrate and fish taxa using correspondence analysis and a hierarchical clustering strategy for a seagrass food web in winter in the northeastern Gulf of Mexico. To create the diet matrix, we characterized the trophic linkages of macroinvertebrate and fish taxa present inHalodule wrightii seagrass habitat areas within the St. Marks National Wildlife Refuge (Florida) using binary data, combining dietary links obtained from relevant literature for macroinvertebrates with stomach analysis of common fishes collected during January and February of 1994. Heirarchical average-linkage cluster analysis of the 73 taxa of fishes and macroinvertebrates in the diet matrix yielded 14 clusters with diet similarity ≥ 0.60. We then used correspondence analysis with three factors to jointly plot the coordinates of the consumers (identified by cluster membership) and of the 33 food sources. Correspondence analysis served as a visualization tool for assigning each taxon to one of eight trophic guilds: herbivores, detritivores, suspension feeders, omnivores, molluscivores, meiobenthos consumers, macrobenthos consumers and piscivores. These trophic groups, corss-classified with major taxonomic groups, were further used to develop consumer compartments in a network analysis model of carbon flow in this seagrass ecosystem. The method presented here should greatly improve the development of future network models of food webs by providing an objective procedure for aggregating trophic groups.  相似文献   

Geographies of Displacement: The Karenni and The Shan Across The Myanmar-Thailand Border   总被引：1，自引：0，他引：1  

Carl Grundy-Warr  & Elaine Wong Siew Yin 《Singapore journal of tropical geography》2002,23(1):93-122

First, central to our analysis is the argument that human movement within and across borders fundamentally challenges the view of geopolitics based upon fixed territorial states, inter-state relations, national identities and citizenship; indeed the whole idea of "national geographic". Using the examples of the Karen and Shan peoples, we explore the processes and patterns of forced relocation, displacement and migration in the border regions of Myanmar and Thailand. Our main concern is with forced displacement as a result of political and ethnic conflict; specifically, how the Burmese military regime's desire for "national unity" within Myanmar's "national space" has influenced the militarily inspired displacements of hundreds of thousands of villagers and civilians within the border zones inhabited mostly by so-called "national minorities". We examine the particular problems of the so-called "internally displaced persons" within "national" boundaries compared with the "refugees" and "undocumented migrants" who make it across "international" space into Thailand. We illustrate the ways displaced people are represented by state agencies and the media as "threats" and "transgressors". We consider some of the "long term" aspects of the displacement problem along the Myanmar-Thai border and the vital contribution geographers can make to the study of displacement.  相似文献   

Progress and new directions in high temperature calorimetry revisited     

Alexandra Navrotsky 《Physics and Chemistry of Minerals》1997,24(3):222-241

 High temperature reaction calorimetry has seen considerable advances over the past twenty years. New and more sensitive calorimeters, improved sample handling techniques, and better control of the final dissolved state has made solution calorimetry and drop solution calorimetry, using molten lead borate and other solvents, very versatile and reliable techniques. This paper summarizes these advances and presents examples of specific applications to problems of transition metal oxide chemistry, high pressure geophysics, melt and glass energetics, and metastable materials relevant to the earth sciences. Received June 3, 1996 / Revised, accepted Spetember 23, 1996  相似文献   

Chemical and isotopic equilibrium between CO₂ and CH₄ in fumarolic gas discharges: Generation of CH₄ in arc magmatic-hydrothermal systems     

Jens Fiebig  Giovanni Chiodini  Andrea Rizzo  Johannes C. Hunziker 《Geochimica et cosmochimica acta》2004,68(10):2321-2334

The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH₄) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH₄ and CO₂ of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H₂O-H₂-CO₂-CO-CH₄ geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH₄, CO₂ and H₂O implying that carbon isotope partitioning between CO₂ and CH₄ in both systems is controlled by aquifer temperature.N₂/³He and CH₄/³He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH₄ may have been primarily generated through the reduction of CO₂ by H₂ in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH₄ and subsequent re-equilibration with co-existing CO₂ cannot be ruled out entirely. CO₂/³He ratios and δ¹³C_CO2 values imply that the evolved CO₂ either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH₄ during thermometamorphism.  相似文献   

U-Th dating of Lake Lisan (late Pleistocene dead sea) aragonite and implications for glacial east Mediterranean climate change     

Alexandra Haase-Schramm  Steven L. Goldstein  Mordechai Stein 《Geochimica et cosmochimica acta》2004,68(5):985-1005

U-series dating can be an effective means to obtain accurate and precise ages on Quaternary carbonates. However, most samples require a correction for U and Th in admixed detritus. This complication is often addressed through generation of U-Th isochrons, requiring analyses of several coeval samples. In addition, presence of water-derived (hydrogenous) Th in the carbonate can cause inaccuracies in isochron ages.This study reports a high-resolution U-series chronology of sediments deposited by Lake Lisan, the last glacial precursor of the Dead Sea. The strategy employed combines multiple measurements from a few stratigraphic heights and fewer analyses from many heights in a single described and measured section. The resulting chronology is based on ages at 22 heights in a ∼40-m-thick section covering the interval of ∼70-14 calendar ka BP. The effects of admixed detritus are evaluated using trace elements. Nearly pure aragonite samples, indicated by very low abundances of insoluble elements such as Nb and Zr, were found to contain hydrogenous Th, which causes the uncorrected U-²³⁰Th age of a modern sample to be ∼2.5 ka. Nevertheless, accurate ages have been obtained by correcting for the detrital and aqueous interferences. The resulting ages are in stratigraphic order, and their accuracy is evidenced by consistency of Lisan Formation U-series and ¹⁴C ages with the coral-based calendar-radiocarbon age calibration.The U-Th ages provide a context to unravel the limnological history of Lake Lisan. Boundaries between the Lower, Middle, and Upper stratigraphic units correspond to the MIS 4/3 and 3/2 transitions, respectively. During MIS 2 and 4 the lake generally showed a stable two-layer configuration and a positive fresh-water balance, reflected by deposition of laminated aragonite-detritus. Dry intervals during MIS 2 and 4 are indicated by thick gypsum layers and an inferred depositional hiatus, which are temporally associated with Heinrich events H1 at ∼17 ka and H6 at ∼65 ka, respectively. During MIS 3 the lake level was unstable with intermittent dry periods indicated by abundant clastic layers and a significant hiatus between ∼43-49 ka. Clastic layers are associated with Dansgaard-Oeschger events during MIS 3, and indicate lake level declines during abrupt Northern Hemisphere warmings. Overall, the climate of the Eastern Mediterranean region shows a strong linkage to the Northern Hemisphere climate, with increasing lake size and stability during cold periods, and fluctuations and dessication during warmings and Heinrich events.  相似文献   

Electrodialytic remediation of CCA-treated waste wood in pilot scale     

Anne J. Pedersen  Iben V. Kristensen  Lisbeth M. Ottosen  Alexandra B. Ribeiro  Arne Villumsen 《Engineering Geology》2005,77(3-4):331-338

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.  相似文献   

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis   总被引：8，自引：0，他引：8  

Lisbeth M. Ottosen  Anne J. Pedersen  Alexandra B. Ribeiro  Henrik K. Hansen 《Engineering Geology》2005,77(3-4):317-329

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.  相似文献   

Modeling defects and plasticity in MgSiO3 post-perovskite: Part 1—generalized stacking faults     

Alexandra M. Goryaeva  Philippe Carrez  Patrick Cordier 《Physics and Chemistry of Minerals》2015,42(10):781-792

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The role of boundary organizations in climate change adaptation from the perspective of municipal practitioners     

Alexandra Graham  Carrie L. Mitchell 《Climatic change》2016,135(3-4):381-393

In climate change impact research it is crucial to carefully select the meteorological input for impact models. We present a method for model selection that enables the user to shrink the ensemble to a few representative members, conserving the model spread and accounting for model similarity. This is done in three steps: First, using principal component analysis for a multitude of meteorological parameters, to find common patterns of climate change within the multi-model ensemble. Second, detecting model similarities with regard to these multivariate patterns using cluster analysis. And third, sampling models from each cluster, to generate a subset of representative simulations. We present an application based on the ENSEMBLES regional multi-model ensemble with the aim to provide input for a variety of climate impact studies. We find that the two most dominant patterns of climate change relate to temperature and humidity patterns. The ensemble can be reduced from 25 to 5 simulations while still maintaining its essential characteristics. Having such a representative subset of simulations reduces computational costs for climate impact modeling and enhances the quality of the ensemble at the same time, as it prevents double-counting of dependent simulations that would lead to biased statistics.  相似文献   

Extreme drought and excessive moisture conditions in two Canadian watersheds: comparing the perception of farmers and ranchers with the scientific record     

Gregory P. Marchildon  Elaine Wheaton  Amber J. Fletcher  Jessica Vanstone 《Natural Hazards》2016,81(1):245-263

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