Impact melting of the Cachari eucrite 3.0 Gy ago     

D.D. Bogard  G.J. Taylor  K. Keil  M.R. Smith  R.A. Schmitt 《Geochimica et cosmochimica acta》1985,49(4):941-946

Both the host phase and glass veins of the Cachari eucrite have been analyzed by microprobe and neutron activation analysis for their chemical compositions and by mass spectrometry for their ³⁹Ar-⁴⁰Ar gas retention ages. Cachari is chemically similar to other non-cumulate eucrites. The vesicular glass veins vary from pure glass, to devitrified glass, to areas that are substantially crystalline. The glassy areas have nearly the same concentrations of major and trace elements as the unmelted portions of Cachari, but some differences, probably due to preferential dissolution, occur along melt contacts. The glass formed by shock melting of Cachari host or of rock identical to it. ³⁹Ar-⁴⁰Ar data for the host and glass suggest distinctly different ages of 3.04 ±.07 Gy and 3.47 ±.04 Gy, respectively. The time of glass formation, which may also be the time of brecciation, is most likely given by the 3.0 Gy age of the host. The higher age for the glass is interpreted to represent incomplete Ar degassing during the 3.0 Gy event due to the greater resistance to Ar diffusion shown by the glass compared to the host. Event ages significantly younger than 4.5 Gy have now been determined for several eucrites and howardites and suggest a long dynamic regolith history for the parent body.  相似文献   

Interaction of cations on octahedral and tetrahedral sites in simple spinels: A comment     

Alexandra Navrotsky 《Physics and Chemistry of Minerals》1984,10(4):192-193

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A thermochemical study of glasses and crystals along the joins silica-calcium aluminate and silica-sodium aluminate     

Alexandra Navrotsky  Gilles Peraudeau  Paul McMillan  Jean-Pierre Coutures 《Geochimica et cosmochimica acta》1982,46(11):2039-2047

Enthalpies of solution in molten 2PbO · B₂O₃ at 985 K are reported for series of glasses xCa_0.5AlO₂-(1?x)SiO₂ (O ≤ x ≤ 0.99) and xNaAlO₂-(1?x)SiO₂ (0 ≤ x ≤ 0.56). The data are compared to values for the corresponding crystalline aluminosilicates and to preliminary data for systems containing KAlO₂ and Mg_0.5AlO₂. The enthalpies of mixing of glasses become more exothermic with increasing basicity of the mono- or divalent oxide. The tendency toward immiscibility on the silica-rich side, indicated by the shape of the heat of mixing curve between x = 0 and x = 0.4, is pronounced in the calcium aluminate system, but not in the sodium aluminate system. The shape of the heat of mixing curve, which is roughly symmetrical about x = 0.5, can be rationalized in terms of glass structure by considering essentially random substitution of Si and Al on a continuous three dimensional tetrahedral framework, with stabilization arising from electrostatic interactions between aluminum and the nonframework cation balancing the destabilizing effects arising from perturbation of the aluminosilicate framework by the nonframework cation. These trends are consistent with the variation of physical properties of aluminosilicate melts.  相似文献   

Derivation Of Refractive Index And Temperature Gradients From Optical Scintillometry To Correct Atmospherically Induced Errors For Highly Precise Geodetic Measurements     

Alexandra I. Weiss  Maria Hennes  Mathias W. Rotach 《Surveys in Geophysics》2001,22(5-6):589-596

Refraction effects of optical beams are generally caused by an inhomogeneous propagation medium and are a major source of systematic errors in the precise optical determination of angles and distances in the atmospheric surface layer. In this contribution a method for deriving vertical temperature and refractive index gradients from optical scintillation is presented. Knowledge of these gradients is required for the compensation of atmospherically induced errors for highly precise terrestrial geodetic measurements, like direct transfer and levelling. The advantage of the present optical method is, that temperature and refractive index gradients can be derived as line-averaged values over the propagation path, which is not possible by meteorological point measurements. Field observations have been carried out with a displaced-beam scintillometer over flat terrain and under different atmospheric conditions in order to verify this method. The experiments show, that this method allows to derive accurate correction values for precise terrestrial geodetic measurements.  相似文献   

Eine Bestimmungsmethode für die radioaktiven Isotope55Fe und59Fe in Meerwasser     

Hans Kautsky  Dieter E. Schmitt 《Ocean Dynamics》1962,15(5):199-204

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Chemical composition of Luna 20 rocks and soil and Apollo 16 soils     

J.C Laul  E.A Schmitt 《Geochimica et cosmochimica acta》1973,37(4):927-942

The abundances of 24 major, minor and trace elements have been measured by INAA in Luna 20 metaigneous rocks 22006,1 and 22007,1, breccia 22004 and soil 22001,9 and in Apollo 16 soils 62281, 66041 and 66081. An additional 12 trace meteoritic and non-meteoritic elements have also been determined in 22001 and 62281 soils by RNAA. The bulk compositions of L 20 and Ap 16 rocks and soils show close similarity between the two highland sites. There are appreciable differences in bulk compositions between the L 20 highland and the L 16 mare site (120 km apart), suggesting little intermixing of rocks and soils from either site. Luna 20 rocks 22006 and 22007 are nearly identical in chemical composition to Ap 16 metaigneous rocks 61156 and 66095. Luna 20 rocks are feldspathic and are similar to low K-type Fra Mauro basalts. Such rocks and anorthositic gabbros appear to be the major components in highland soils. Luna 20 soil can be distinguished from Ap 16 soils by lower abundances of Al₂O₃, CaO and large ion lithophilic elements. Luna 20 breccia 22004 probably is compacted soil. All L 20 samples show negative Eu anomalies with $\text{Sm}\text{Eu}$ ratios of 5.8, 7.2, 3.9 and 3.3 for rocks 22006, 22007, breccia 22004 and soil 22001, respectively. Norite-KREEP is insignificant, ≤1 per cent, at the L 20 highland site. The derivation of the L 20 soil may be explained by ≈33 per cent of L 20 metaigneous rocks and ≈ 65 per cent anorthositic gabbroic breccia rocks like 15418 (with a positive Eu anomaly) and ≈ 2 per cent meteoritic contributions. Interelement correlations observed previously for maria are also found in highland samples. Luna 20 and Ap 16 soils are low in alkalis. Both soils show an apparent Cd-Zn rich component similar to that observed at the mare sites and high 11 abundances relative to mare sites. The Ap 16 (62281) soil contains a fractionated meteoritic component (probably ancient) of ≈ 1.5 per cent in addition to ≈ 1.9 per cent Cl like material. Luna 20 soil may simply contain 1.9 per cent Cl equivalent.  相似文献   

Application of Generalized Likelihood Uncertainty Estimation (GLUE) at different temporal scales to reduce the uncertainty level in modelled river flows     

Ragab Ragab  Alexandra Kaelin  Muhammad Afzal  Ioanna Panagea 《水文科学杂志》2020,65(11):1856-1871

ABSTRACT

In this study, the distributed catchment-scale model, DiCaSM, was applied on five catchments across the UK. Given its importance, river flow was selected to study the uncertainty in streamflow prediction using the Generalized Likelihood Uncertainty Estimation (GLUE) methodology at different timescales (daily, monthly, seasonal and annual). The uncertainty analysis showed that the observed river flows were within the predicted bounds/envelope of 5% and 95% percentiles. These predicted river flow bounds contained most of the observed river flows, as expressed by the high containment ratio, CR. In addition to CR, other uncertainty indices – bandwidth B, relative bandwidth RB, degrees of asymmetry S and T, deviation amplitude D, relative deviation amplitude RD and the R factor – also indicated that the predicted river flows have acceptable uncertainty levels. The results show lower uncertainty in predicted river flows when increasing the timescale from daily to monthly to seasonal, with the lowest uncertainty associated with annual flows.  相似文献   

Development of an Absolute Accelerometer for Extra-Solar Planet Detection     

Schmitt  J.  Connes  P.  Bertaux  J.L. 《Earth, Moon, and Planets》1998,81(1):83-90

The method of stellar radial velocity variations has recently shown its capability by the first discovery of several extra-solar planets. Accuracies achieved today are in the range 3-10 m/s. The AAA (absolute astronomical accelerometer) is an instrument which aims to reach the photon noise limit for the measurement of velocity changes, with systematic errors of about 1 m/s, long term. The principle is to use a servo-controlled CCD spectrograph as a null detector, and to register always the lines of the star on the same CCD pixels. Thus, systematic errors linked to the Earth-induced large variations are cancelled. A tunable Fabry-Perot channelled spectrum is also following the star spectrum, while the FP thickness is measured by heterodyne detection of the beats between a tunable laser diode and a stabilized laser diode. A complete prototype of the instrument is operating with laboratory sources and the first results are presented. It is planned to use this system with a new spectrograph, to be coupled to the 152 cm telescope at Observatoire de Haute Provence.  相似文献   

Sea surface stress measurements     

K. F. Schmitt  C. A. Friehe  C. H. Gibson 《Boundary-Layer Meteorology》1978,15(2):215-228

Sea-surface stress measurements were made from a rigid tower in shallow water near San Diego, California, by both the direct covariance and inertial dissipation techniques. Stress estimates from the dissipation technique were generally higher than the directly measured values, with average drag coefficients of 0.99 x 10^-3 and 0.77 x 10^-3, respectively, for 8-m wind speeds of 5 to 7 m s^-1. In the inertial subrange, ratios of vertical to streamwise velocity spectra averaged 1.06 ± 0.16, significantly less than the isotropic value of 4/3 observed over land, suggesting that turbulence over water may be altered by the presence of waves.  相似文献   

Calculation of effect of cation disorder on silicate spinel phase boundaries     

Alexandra Navrotsky 《Earth and Planetary Science Letters》1977,33(3):437-442

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