Spatial Geochemistry: A Characterisation of Heterogeneity in Reference Materials     

L. Paul Bédard  Alexandre Néron 《Geostandards and Geoanalytical Research》2014,38(2):177-188

Geochemical reference materials (RMs) for microbeam techniques are typically characterised by averages and dispersion statistics (e.g., standard deviation, variance) that are calculated for a number of measurements (beam shots). It is proposed that the mapping of RMs will add spatial information that better characterises the grouping and magnitudes of the heterogeneities and provides the information necessary to define a minimum analytical mass. A simple mathematical solution is proposed, which can be easily computed and understood. The analogous notions to sill and range from geostatistics are applied to the minimum analytical mass versus the relative standard deviation. To assess grouping and magnitudes of the heterogeneities, a ‘proximity number’ is computed for each average value ± ‘n’ standard deviations (magnitude). Different chemical anomalies have been simulated to demonstrate the behaviour of the proximity number. To further test the proposed spatial geochemistry concept, sulfide‐ and oxide‐bearing RMs have been selected because many are crippled with nugget effect. They have been mapped with a micro‐XRF apparatus, and results are presented for CHR‐Bkg, CHR‐Pt+, MASS‐1, MASS‐3, WMS‐1 and WMS‐1a. MASS‐1 and MASS‐3 are the most suitable RMs for microbeam techniques. Spatial geochemistry offers a new approach to better characterise reference materials.  相似文献   

High-resolution aquifer analog of fluvial–aeolian sediments of the Guarani aquifer system     

Dominik Höyng  Fernando Mazo D’Affonseca  Peter Bayer  Edson Gomes de Oliveira  José Alexandre J. Perinotto  Fábio Reis  Holger Weiß  Peter Grathwohl 《Environmental Earth Sciences》2014,71(7):3081-3094

The Guarani aquifer system (GAS) represents one of the biggest aquifers in the world and is the most relevant groundwater resource in South America. For the first time, by combining field and laboratory measurements, a high-resolution aquifer analog model of fluvial–aeolian sediments of the GAS in São Paulo State (Brazil) is constructed. Three parallel sections of frontal outcrops, 28 m × 5.8 m, and two parallel sections of lateral outcrops, 7 m × 5.8 m, are recorded during open-pit mining of sandy sediments and describe in detail the three-dimensional distribution of the local lithofacies and hydrofacies. Variations of hydraulic conductivity, K, and porosity, n, are resolved on the centimeter scale, and the most permeable units of the fluvial–aeolian facies association are identified. The constructed aquifer analog model shows moderate hydraulic heterogeneity and a mean K value of 1.36 × 10^?4 m/s, which is greater than the reported range of K values for the entire GAS in São Paulo State. The results suggest that the examined sedimentary unit constitutes a relevant portion of the GAS in São Paulo State in the context of groundwater extraction and pollution. Moreover, the constructed aquifer analog is considered an ideal basis for future numerical model experiments, aiming at in-depth understanding of the groundwater flow and contaminant transport patterns at this GAS portion or at comparable fluvial–aeolian facies associations.  相似文献   

Constraints on the formation environment of two chondrule‐like igneous particles from comet 81P/Wild 2          下载免费PDF全文

Zack Gainsforth  Anna L. Butterworth  Julien Stodolna  Andrew J. Westphal  Gary R. Huss  Kazu Nagashima  Ryan Ogliore  Donald E. Brownlee  David Joswiak  Tolek Tyliszczak  Alexandre S. Simionovici 《Meteoritics & planetary science》2015,50(5):976-1004

Using chemical and petrologic evidence and modeling, we deduce that two chondrule‐like particles named Iris and Callie, from Stardust cometary track C2052,12,74, formed in an environment very similar to that seen for type II chondrules in meteorites. Iris was heated near liquidus, equilibrated, and cooled at ≤100 °C h^‐1 and within ≈2 log units of the IW buffer with a high partial pressure of Na such as would be present with dust enrichments of ≈10³. There was no detectable metamorphic, nebular, or aqueous alteration. In previous work, Ogliore et al. (2012) reported that Iris formed late, >3 Myr after CAIs, assuming ²⁶Al was homogenously distributed, and was rich in heavy oxygen. Iris may be similar to assemblages found only in interplanetary dust particles and Stardust cometary samples called Kool particles. Callie is chemically and isotopically very similar, but not identical to Iris.  相似文献   

On the Origin of the Spin of Planets and Stars and its Connection with Gravitomagnetism     

Alexandre Chaloum Elbeze 《Earth, Moon, and Planets》2012,108(3-4):151-163

The origin of the spin of planets and stars is, to a certain extent, still unexplained. In general, we attribute their rotation to the swirl of their constituent primitive gases. In this paper, we try to show that the rotation of celestial bodies depends only on their mass, apparent radius and tilt of their spin axes. We reach this conclusion within the framework of gravitomagnetism, implied by the Einstein’s general relativity theory (GR). Our results show that it might possible, in principle, to calculate the mass of spinning objects by measuring their apparent radius, the speed of rotation and the tilt of the axis of rotation.  相似文献   

Mineralogy and geochemistry of the sodium metasomatism-related uranium occurrence of Aricheng South, Guyana   总被引：2，自引：0，他引：2  

Paul Alexandre 《Mineralium Deposita》2010,45(4):351-367

The Aricheng South uranium occurrence is associated with Na metasomatism that affected the granitoids of the Kurupung Batholith in western Guyana. The mineral paragenesis indicates that late-magmatic albitization was followed by chlorite alteration of biotite. A minor amount of uraninite occurs in fractures in the newly formed albite crystals, often in company of calcite. The main mineralization stage occurred later than albitization and chloritization and is represented by brannerite disseminated in a groundmass of fine-grained hydrothermal zircon. Whole rock geochemistry supports the temporal dissociation of albitization from the main ore stage. Brannerite, zircon, and uraninite are often partially altered to secondary brannerite, zircon, and coffinite, respectively. Stable oxygen (chlorite, calcite) and hydrogen (chlorite) isotope compositions suggest that a highly evolved meteoric fluid, or at least one corresponding to a very high rock/fluid ratio (δ¹⁸O of approx. 3.4% to 4‰ and δD of approx. −80‰) may have caused the pre-ore alteration assemblage. The fluids in equilibrium with main ore stage zircon have δ¹⁸O of approx. 6.8‰ and appear to be of magmatic origin. The Aricheng occurrence geochemically, mineralogically, thermally, and paragenetically resembles the Valhalla U deposit in northern Australia despite differences between the deposits’ host lithologies, whereas the Lagoa Real and Espinharas U deposits in Brazil have host rock lithology that resembles that of Aricheng.  相似文献   

Fault zone structure and fluid–rock interaction of a high angle normal fault in Carrara marble (NW Tuscany,Italy)     

G. Molli  G. Cortecci  L. Vaselli  G. Ottria  A. Cortopassi  E. Dinelli  M. Mussi  M. Barbieri 《Journal of Structural Geology》2010,32(9):1334-1348

We studied the geometry, intensity of deformation and fluid–rock interaction of a high angle normal fault within Carrara marble in the Alpi Apuane NW Tuscany, Italy. The fault is comprised of a core bounded by two major, non-parallel slip surfaces. The fault core, marked by crush breccia and cataclasites, asymmetrically grades to the host protolith through a damage zone, which is well developed only in the footwall block. On the contrary, the transition from the fault core to the hangingwall protolith is sharply defined by the upper main slip surface. Faulting was associated with fluid–rock interaction, as evidenced by kinematically related veins observable in the damage zone and fluid channelling within the fault core, where an orange–brownish cataclasite matrix can be observed. A chemical and isotopic study of veins and different structural elements of the fault zone (protolith, damage zone and fault core), including a mathematical model, was performed to document type, role, and activity of fluid–rock interactions during deformation. The results of our studies suggested that deformation pattern was mainly controlled by processes associated with a linking-damage zone at a fault tip, development of a fault core, localization and channelling of fluids within the fault zone. Syn-kinematic microstructural modification of calcite microfabric possibly played a role in confining fluid percolation.  相似文献   

Landslide kinematics inferred from in situ measurements: the Cliets rock-slide (Savoie,French Alps)     

Desrues  Mathilde  Malet  Jean-Philippe  Brenguier  Ombeline  Carrier  Aurore  Mathy  Alexandre  Lorier  Lionel 《Landslides》2022,19(1):19-34

This paper presents an analysis of two large rock toppling/sliding events which occurred in January 2014 and February 2019 at the Cliets unstable slope (Savoie, French Alps). To understand the mechanism involved and its control by external forcings, a multi-technique analysis approach is used combining geological observations, meteorological data analysis, topographic measurements and simple physical modeling. The pre-failure stage of the events is more particularly analyzed. No direct relationships are found between triggering factors and surface motion though a kinematics analysis highlights the transition toppling-sliding. It showed that, at first order, this transition occurred 4 years before the first failure of 2014, while it happened 2 months before the second failure of 2019. From this date, the environment is considered like a block sliding on an inclined plane. By applying a frictional model (Helmstetter et al. in Journal of Geophysical Research: Solid Earth 109(B2), 2004), we illustrated that the two events belong to an unstable velocity-weakening sliding regime. The time to failure (Voight in Science 243(4888):200–203, 1989) is forecasted with the model, and the results are consistent with the observations. They confirm that the gravitational factor is predominant over the triggering factors for the two events.

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Paleoenvironmental dynamics in central-eastern Brazil during the last 23 000 years: tropical peatland record in the Cerrado biome     

Camila Rodrigues Costa  Cynthia Fernandes Pinto da Luz  Ingrid Horák-Terra  Plínio Barbosa de Camargo  Uidemar Morais Barral  Carlos Victor Mendonça-Filho  Thamyres Sabrina Gonçalves  Alexandre Christófaro Silva 《第四纪科学杂志》2023,38(1):61-75

The Cerrado biome is the second largest in Brazil, but the evolution of the Cerrado during the late Quaternary is not yet fully known. This study identifies paleoenvironmental changes during the last 23 000 years, based on a tropical mountain peatland record, in the Serra do Espinhaço Meridional in central-eastern Brazil. A multi-proxy approach was used that involved palynological analysis, stable isotopes (δ¹³C, δ¹⁵N), geochemistry, radiocarbon dating and multivariate statistics derived from a peatland core from Rio Preto (Minas Gerais state). The study reveals a very humid and cold climate during the late Pleistocene, with an increase in temperature and decrease in humidity at the Pleistocene–Holocene transition. During this period there was strong instability in the landscape (episodes of erosion). At the beginning of the Holocene there was a reduction in humidity with greater landscape stability. The current sub-humid climatic conditions seem to have been established in the mid-/late Holocene, with periods of landscape instability. Our findings agree with other Cerrado records that contradict previously established hypotheses, such as the Amazonian Refuge and the Pleistocene Arc.  相似文献