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21.
Accumulation of metabolic CO2 can acidify marine waters above and beyond the ongoing acidification of the ocean by anthropogenic CO2. The impact of respiration on carbonate chemistry and pH is most acute in hypoxic and anoxic basins, where metabolic CO2 accumulates to high concentrations. The bottom waters of the Lower St. Lawrence Estuary (LSLE), where persistently severe hypoxia has developed over the last 80 years, is one such case. We have reconstructed the evolution of pH in the bottom waters from historical and recent data, and from first principles relating the stoichiometry of CO2 produced to oxygen consumed during microbial degradation of organic matter. Based on the value of the atmospheric partial pressure of CO2 that best reproduces the preformed dissolved inorganic carbon concentration in the bottom waters, we estimate the average ventilation age of the bottom waters to be 16?±?3 years. The pH of the bottom waters has decreased by 0.2 to 0.3 over the last 75 years, which is four to six times greater than can be attributed to the uptake of anthropogenic CO2. The pH decrease is accompanied by a decline in the saturation state with respect to both calcite and aragonite. As of 2007, bottom waters in the LSLE are slightly supersaturated with respect to calcite (Ωc?≈?1.06?±?0.04) but are strongly undersaturated with respect to aragonite (Ωa?≈?0.67?±?0.03). 相似文献
22.
23.
Diana Rodriguez Ana Rodriguez Amparo Soto Alfonso Aranda Yolanda Diaz-de-Mera Alberto Notario 《Journal of Atmospheric Chemistry》2008,59(3):187-197
The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221)
and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction
chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at
atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data
were used to derive the Arrhenius expressions , , (in units of cm3 molecule−1 s−1). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO3, O3 and Cl have been calculated. 相似文献
24.
Christian Wolf Alfonso Aragón-Salamanca Michael Balogh Marco Barden Eric F. Bell Meghan E. Gray Chien Y. Peng David Bacon Fabio D. Barazza Asmus Böhm John A. R. Caldwell Anna Gallazzi Boris Häußler Catherine Heymans Knud Jahnke Shardha Jogee Eelco van Kampen Kyle Lane Daniel H. McIntosh Klaus Meisenheimer Casey Papovich Sebastian F. Sánchez y Taylor Lutz Wisotzki Xianzhong Zheng 《Monthly notices of the Royal Astronomical Society》2009,393(4):1302-1323
We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of σ cz ≈ 2000 km s−1 . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of log M * /M⊙ =[10, 11] where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At log M * /M⊙ < 10 , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment. 相似文献
25.
Ramn Pellitero Jos M. Fernndez‐Fernndez Nstor Campos Enrique Serrano Alfonso Pisabarro 《第四纪科学杂志》2019,34(4-5):342-354
New 10Be dates for glacial landforms in the Fuentes Carrionas area (Cantabrian Mountains, nothern Spain) are presented. Mapped and dated landforms in Fuentes Carrionas made possible a palaeoglacier reconstruction for four glacial stages. Results were compared to other nearby palaeoenvironmental proxies, so a final approximation on the mean annual temperature and annual precipitation that caused the four glacial advance stages is proposed. Glaciers reached their maximum extension at 36 ka, in a cold and dry environment. A second advance stage took place between 18.5 and 19.5 ka, during the Last Glacial Maximum (LGM), when glaciers advanced in a wet environment, with positive rainfall anomalies. A third glacial advance was dated during the Oldest Dryas, in which climate shifted to extremely cold and dry conditions. Finally, a last stage has been identified and proposed to the Younger Dryas, in which precipitation anomalies are negligible. Our results confirm some of the previously made palaeoglacial and palaeoenvironmental inferences for the Iberian Peninsula, as well as provide valuable and accurate anomalies, which are useful for climate modelling. 相似文献
26.
Javier Alcocer Elva G. Escobar Alfonso Lugo Luis A. Oseguera 《International Journal of Salt Lake Research》1999,8(2):113-126
The effects of multiple stressors on the benthic macroinvertebrate community were monitored in Tecuitlapa Norte, a shallow,
perennially-astatic, warm, mesosaline, sodaalkaline lake in Mexico. Physico-chemical and biological variables were determined
monthly for one year. Tecuitlapa Norte displayed a clear seasonal environmental pattern (dry and rainy seasons). The benthic
macroinvertebrate community consisted of five species:Culicoides occidentalis sonorensis Jorgensen,Ephydra hians Say,Stratiomys sp.,Eristalis sp., andLimnophora sp. of which the first two were dominant and the rest scarce.C. occidentalis was the most important species numerically (76 percent of the total), whileE. hians dominated the biomass (73 percent of the total). Primarily salinity and secondarily pH appear to be the most important environmental
factors controlling dominance of benthic organisms in Tecuitlapa Norte. Seasonal abundance dynamics of the dominant organisms
was associated with phases in their reproductive cycles: environmentally-triggered (i.e., temperature rise, water-level descent)
pupation and emergence periods. We concluded that whereas physical and chemical factors (i.e., salinity, pH) exerted the primary
control on benthic macroinvertebrate community composition in Tecuitlapa Norte, another assembly of variables (e.g., water-level,
temperature) influenced species distribution and abundance. 相似文献
27.
28.
The occurrence of a thin band of marine limestone (Graua Limestone) within a thick succession of fluviatile sandstones in south-eastern Ethiopia is direct evidence of flooding of part of the East African craton (Horn of Africa). According to the presence of abundant orbitolinid foraminifers (Palorbitolina lenticularis Blumenbach andPraeorbitolina cormyi Schroeder), the age of the Graua Limestone can be referred to the Early Aptian. Stratigraphy and palaeogeographic reconstructions for the Early Cretaceous in the surrounding regions (Kenya, Somalia, Yemen, Socotra, Oman, Syria, Lebanon, Israel, Egypt and Libya) show that the Early Aptian transgression was of regional extent. Our data seem to confirm that this transgression was of relatively short duration. This pulse cannot be related to tectono-eustatic mechanisms, which are too slow. A short-lived event should be invoked: either a regional tectonic pulse or the desiccation of the proto-South Atlantic. 相似文献
29.
NATURAL AND ANTHROPOGENIC FACTORS CONTROLLING GULLY EROSION IN THEBASALTIC UPLAND OF SOUTHERN BRAZIL
This paper describes an analysis of natural and anthropogenic factors controlling the evolution of gullies in a rural basin in the basaltic upland in the State of Rio Grande do Sul, Southern Brazil. In this region of deep ferrallitic soils with more than 60% clay, runoff and erosion are of increasing concern. In the TaboAo drainage basin (100 km^2), gully erosion was studied in a field survey that measured rills and gullies. Eighty-four gullies were identified. They had an average length of 136 m, were 10 m wide, and 3 m deep and had a volume of 15.458 m3. Each gully was characterised in terms of factors that included slope, geological structure, presence of piping, drainage, soil use, and the presence of surface and subsurface flow. On average, the main channels had knickpoints varying from 2 m to 7 m, and their evolution in the vertical plane increased until bed-rock basalt material was reached, after which gullies increase in width and length. Gully development was also monitored from 1991 to 2003. Subsurface flow appears to be the principal agent controlling their development. Results show that both natural (slope, surface curvature, geological structure and rainfall) and anthropogenic (soil use, road construction) factors are important in gully development. The change in cultural practices throughout the drainage basin from conventional to direct seeding has led to increased subsurface flow, which was more important than surface runoff in causing erosion. However, the higher rainfall during E1 Nifio Southern Oscillation (ENSO) events and the consequently higher subsurface flow were the dominant factors. From 1991 to 2003 a total land loss of 1,013 m3 was observed in one gully, with 236 m^3 lost during the 1992 ENSO and 702 m3 during the 1997 ENSO; 95% of the total volume lost occurred during ENSO periods. 相似文献
30.
Alfonso F. Davila Christoph Gross Alberto G. Fairén Thomas Kneissl James M. Dohm 《Icarus》2011,212(2):579-589
Different lines of evidence point to hydrological cycling in the martian past. The extent, duration, and magnitude of this cycling remains unclear, as well as the magnitude of aqueous processes on the surface. Here, we provide geomorphic and mineralogic evidence of a large inter-crater sedimentary basin located in the Terra Sirenum region, which was once covered by a body of liquid water with an areal extent of at least 30,000 km2 and a depth of approximately 200 m. The topographic basin, which is modified by a number of large impact craters, is partly controlled by ancient impact and tectonic structures. As a result of evaporation of the large body of water, salt flats formed in the lowest topographic reaches of the basin. Hydrated phyllosilicates occur in close proximity to the salt flats and in the ejecta and rim materials of small impact craters with stratigraphic relations that suggest that they underlie the evaporite deposits. Crater statistics place the maximum age of aqueous activity during the Late Noachian epoch. The relatively pristine mineral deposits in the basin have a high potential to yield information of the geochemistry and water activity during the ancient Noachian Period when conditions were seemingly more conducive to life. 相似文献