Cotton Fiber/ZrO2, A New Material for Adsorption of Cr(VI) Ions in Water     

Alfredo Alberto Muxel  Sonia Maria Nobre Gimenez  Flaveli Aparecida de Souza Almeida  Rení Ventura da Silva Alfaya  Antonio Alberto da Silva Alfaya 《洁净——土壤、空气、水》2011,39(3):289-295

The natural cotton fiber was used to synthesize an anion exchange, containing ZrO₂ film on its surface, NCFZC (natural cotton fiber/ZrO₂ composite). This anion exchanger was produced by the reaction of the zirconium oxychloride and hydroxyl groups on surface of the natural cotton fiber. The material was used for Cr(VI) ions adsorption studies. Adsorption equilibrium time and optimum pH for Cr(VI) adsorption were found to be 6 h and 4.0, respectively. The Langmuir and Temkin isotherms were used to models adsorption equilibrium data. The adsorption capacity of NCFZC was found to be 1.33 mmol/g. Kinetic studies showed that the rate of adsorption of Cr(VI) on NCFZC obeyed a pseudo‐second‐order kinetic model.  相似文献   

Local sea level change scenarios for the end of the 21st century and potential physical impacts in the lower Ria de Aveiro (Portugal)     

Carina L. Lopes  Alfredo Rocha 《Continental Shelf Research》2011,31(14):1515-1526

Sea level change is an important consequence of climate change due to its impact on society and ecosystems. Analyses of tide-gauge data have indicated that the global sea level has risen during the 20th century and several studies predict that the mean sea level will continue to rise during the 21st century, intensifying coastal hazards worldwide. In Portugal, the Ria de Aveiro is expected to be one of the regions most affected by sea level change.The main aim of this study is to evaluate the potential impacts of the mean sea level change on the hydrodynamics and morphodynamics of the Ria de Aveiro. With this purpose, local mean sea level change was projected for the period 2091-2100 relative to 1980-1999, for different Special Report on Emission Scenarios (SRES) scenarios developed by the Intergovernmental Panel on Climate Change (IPCC). These projections revealed an increase in the mean sea level between 0.28 m under scenario B1 and 0.42 m under scenario A2.The results obtained for sea level rise scenario A2 projection were used to force the morphodynamic model MORSYS2D, previously implemented for the Ria de Aveiro. The modelling results were compared with model forecasts for the present sea level. The residual sediment transport and its balance at the lagoon inlet were computed and analysed for both situations. While the residual sediment transport is generally seaward, sediments tend to deposit inside the inlet due to the weak sediment transport at its mouth. The direction of the residual flux will not change with the sea level rise, but sediment fluxes will intensify, and accretion inside the inlet will increase.The rise in mean sea level will also affect the lagoon hydrodynamics. The tidal prism at the lagoon mouth will increase by about 28% in spring tide. In the lower lagoon only a slight increase of the tidal asymmetry is predicted.  相似文献   

Gratkorn: A benchmark locality for the continental Sarmatian s.str. of the Central Paratethys     

M. Gross  M. Böhme  J. Prieto 《International Journal of Earth Sciences》2011,100(8):1895-1913

This paper presents one of the richest and most complete vertebrate faunas of the late Middle Miocene (~12 Ma) of Central Europe. Up to now, sixty-two vertebrate taxa, comprising all major groups (fishes, amphibians, reptiles, birds, mammals), have been recorded. Based on sedimentological and palaeobiological evidences, this Fossillagerstätte is assumed to originate from a floodplain paleosol formed on top of a braided river sequence. The fauna points to a highly structured, somewhat vegetated landscape with a wide array of habitats (e.g., fluvial channels, sporadically moist floodplains, short-lived ponds, savannah-like open areas and screes). It was preserved due to a rapid drowning and the switch to a freshwater lake environment. Palaeoclimatological data, derived from pedogenic features as well as from biota, indicate an overall semi-arid, subtropical climate with distinct seasonality (mean annual precipitation 486 ± 252 mm, mean annual temperature ~15°C). This underlines the late Middle/early Late Miocene dry-spell in Central Europe. From taphonomical point of view, the irregularly distributed but roughly associated larger vertebrate remains refer to an in situ accumulation of the bone bed. Splintered bones, gnawing marks as well as rhizoconcretions and root corrosion structures record some pre- and post-burial modification of the taphocoenose. However, the findings of pellet remains argue for a very fast burial and thus to a low degree of time-averaging. For this reason, the fossil fauna reflects the original vertebrate community rather well and is a cornerstone for the understanding of late Middle Miocene terrestrial ecosystems in this region. Certainly, Gratkorn will be one of the key faunas for a high-resolution continental biostratigraphy and the comprehension of Europe’s faunal interchanges near the Middle/Late Miocene transition.  相似文献   

First record of Karydomys (Rodentia, Mammalia) from the German part of the North Alpine Foreland Basin     

Jérôme Prieto  Herbert Scholz 《Swiss Journal of Geoscience》2013,106(2):303-307

Karydomys, a rare genus of cricetid rodents from the Middle Miocene of central Europe, had previously been reported only from the Swiss part of the North Alpine Foreland basin; documented evidence from the German part was lacking. This paper describes several new specimens of Karydomys from the German localities Höll and Laimering 3. A correlation of both localities to the Bavarian local biostratigraphic scale OSM F is proposed. Taxonomically, the fossils are most probably linked to K. wigharti from Hambach 6C (north-west Germany), and thus assigned to K. cf. wigharti. In spite of the scarcity of Karydomys fossils in the Upper Freshwatermolasse, the taxon is an important biostratigraphical marker because of its short stratigraphical range.  相似文献   

Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System     

M. Prieto  A. Fernández-González  U. Becker  A. Putnis 《Aquatic Geochemistry》2000,6(2):133-146

The Lippmann diagram for the system(Ba, Sr)SO₄-H₂O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO₄ due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO₄) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa²⁺ = 0.000446 ) at the peritectic point.  相似文献   

Extended X-ray emission in the radio-loud galaxy 3C 382     

M. Almudena Prieto † 《Monthly notices of the Royal Astronomical Society》2000,316(2):442-448

ROSAT /HRI observations of the powerful radio-loud galaxy 3C 382 reveal extended X-ray emission associated with the source. On the basis of this new spatial component, a previous ROSAT /PSPC spectral analysis of the source is revised. Allowing for the presence of an additional thermal component in the PSPC spectrum, the non-thermal component is found to be compatible with the extrapolation of the well-defined 3C 382, 2–10 keV, power-law spectrum into the soft X-ray region. The thermal – extended – component would then account for the soft excess emission previously reported for this source. The origin of this thermal component is not clear. Its luminosity compares with that of rich Abell clusters; yet, the galaxy environment in 3C 382 appears of moderate optical richness. An alternative is that it is the result of a massive extended gaseous atmosphere sustained by the deep gravitational potential well of 3C 382.  相似文献   

Geomorphological and sedimentological features in Quaternary fluvial systems affected by solution-induced subsidence (Ebro Basin, NE-Spain)     

Gerardo Benito  Francisco Gutirrez  Alfredo Prez-Gonzlez  Maria J. Machado 《Geomorphology》2000,33(3-4)

The Quaternary evolution and the morpho-sedimentary features of some of the most important rivers in Spain (Ebro and Tagus rivers among others) have been controlled by subsidence due to alluvial karstification of the evaporitic bedrock. The subsidence mechanism may range from catastrophic collapse to slow sagging of the alluvium by passive bending. In the Ebro Basin, the mechanisms and processes involved in karstic subsidence were studied through the analysis of present-day closed depressions as well as through old subsidence depressions (palaeocollapses and solution-induced basins) and associated deformations recorded in the Quaternary alluvial sediments. The Gállego–Ebro river system is presented as a case study of channel adjustments and geomorphic and sedimentary evolution of fluvial systems in dissolution-induced subsidence areas. In this fluvial system, evaporite dissolution during particular Quaternary time intervals (namely early and middle Pleistocene) have lead to the development of a solution-induced basin, approximately 30 km-long by 8 km-wide, filled by Quaternary deposits with a total thickness in excess of 190 m. The main river response to balance the subsidence in the alluvial plain was aggradation in the central reach of the subsiding area, and degradation both in the upstream reach and in the valley sides where alluvial fans and covered pediments may prograde over the fluvial sediments. The main sinking areas are recognized in the sedimentary record by anomalous thickenings in the alluvial deposits and fine-grained sediments deposited in backswamp and ponded areas.  相似文献   

Isotopes in the Hueco Bolson aquifer, Texas (USA) and Chihuahua (Mexico): local and general implications for recharge sources in alluvial basins     

Christopher J. Eastoe  Barry J. Hibbs  Alfredo Granados Olivas  James F. Hogan  John Hawley  William R. Hutchison 《Hydrogeology Journal》2008,16(4):737-747

Stable isotope data for the Hueco Bolson aquifer (Texas, USA and Chihuahua, Mexico) distinguish four water types. Two types relate to recharge from the Rio Grande: pre-dam (pre-1916) river water with oxygen-18 and deuterium (δ¹⁸O, δD, ‰) from (?11.9, ?90) to (?10.1, ?82), contrasts with present-day river water (?8.5, ?74) to (?5.3, ?56). Pre-dam water is found beneath the Rio Grande floodplain and Ciudad Juárez, and is mixed with post-dam river water beneath the floodplain. Two other types relate to recharge of local precipitation; evidence of temporal change of precipitation isotopes is present in both types. Recharge from the Franklin and Organ Mountains plots between (?10.9, ?76) and (?8.5, ?60) on the global meteoric water line (GMWL), and is found along the western side of the Hueco Bolson, north of the Rio Grande. Recharge from the Diablo Plateau plots on an evaporation trend originating on the GMWL near (?8.5, ?58). This water is found in the southeastern Hueco Bolson, north of the river; evaporation may be related to slow recharge through fine-grained sediment. Pre-dam water, recognizable by isotope composition, provides information on groundwater residence times in this and other dammed river basins.  相似文献   

Modern tectonic stress field in the Mediterranean region: evidence for variation in stress directions at different scales   总被引：4，自引：0，他引：4  

Samira Rebaï  Hervé Philip  Alfredo Taboada 《Geophysical Journal International》1992,110(1):106-140

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On the Two-body Problem with Slowly Decreasing Mass     

C. Prieto  J.A. Docobo 《Celestial Mechanics and Dynamical Astronomy》1997,68(1):53-62

We intend to present two approximate analytic solutions of the two-body problem with slowly decreasing mass which are obtained through the integration of the Hamilton equations. The law of mass variation used was m = -αn on the first case, and mi = αimin(i); i = 1,2 on the second which gives rise to a perturbed Keplerian problem dependent on one and two small parameters respectively. Practical applications are included. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献