The Hizeh-Jan Kaolin Deposit of NW Iran:the TetradEffect in REE Distribution Patterns     

ABEDINI Ali  REZAEI AZIZI Mansour 《《地质学报》英文版》2019,93(1):74-87

The Hizeh-Jan kaolin deposit(northwest of Varzeghan, East-Azarbaidjan Province, NW Iran) is a product of the alteration of Eocene andesitic rocks. Based on mineralogical examinations, kaolinite, quartz, smectite, pyrophyllite, muscovite-illite, alunite, calcite, diaspore, goethite and hematite are the most abundant mineral phases in this deposit. The geochemical indicators, such as Y/Ho and Zr/Hf, indicate the non-CHARAC(non-Charge-radius control) behavior of these pairs, which are likely to be due to the occurrence of the tetrad effect phenomenon in this deposit. Simultaneous concave and convex shapes in the chondrite-normalized REE distribution patterns are a remarkable feature of the kaolin samples. Bivariate diagrams of the size of the third tetrad effect(T_3) versus geochemical parameters such as Y/Ho, Nb/Ta and Zr/Hf ratios display two distinct populations for the kaolin samples. The first population is characterized by high T_3 values(>0.13), which are near or on the fault zone. The second population is characterized by low T_3 values(<0.13), and are farther from the fault zone. The obtained results from the geochemical data have furnished compelling evidence that fluidrock interaction, overprint of hypogene processes by supergene ones, and structural control, are key controlling factors for the occurrence of tetrad effects in REE distribution patterns in the Hizeh-Jan kaolin deposit.  相似文献   

Geochemical Investigation of the Cretaceous Crude Oil Reservoirs and Source Rock Samples in One of the Abadan Plain Oilfields, SW Iran     

Elham ASADI MEHMANDOSTI  Mahnaz AMIRHOSEYNI  Seyed Ali MOALLEMI  Azizollah HABIBI 《《地质学报》英文版》2022,96(2):546-558

Crude oil and source rock samples from one of the main oilfields of the Abadan Plain, Zagros, Iran were analyzed geochemically. Rock-Eval pyrolysis was conducted on Kazhdumi (Upper Cretaceous) and Gadvan (Lower Cretaceous) formations, which are the probable source rocks for the oil in the region. The results indicated that the Kazhdumi Formation can be classified as a fair-to-excellent source rock, while the Gadvan Formation can be identified as having poor-to-good source rock in the basin. Based on the cross-plots of HI versus OI and S2 versus TOC, types II and III kerogen were identified from studied source samples in the area. Determination of the main fraction percentages of the Sarvak and Fahliyan crude oils represented that the oils from the Sarvak reservoir are paraffinic-naphthenic and aromatic-intermediate, whilst that from the Fahliyan reservoir is paraffinic and paraffinic-naphthenic. Biomarker ratios of the saturated fractions of oil from both reservoirs indicate that the source rocks formed in reducing marine environments with carbonate-shale lithology. Furthermore, biomarker data helped to distinguish the degree of biodegradation in the studied oils. According to geochemical analysis, oil samples from the Fahliyan reservoir were generated at a higher thermal maturity than the Sarvak reservoir samples.  相似文献   

Optimization approach to retrieve soil surface parameters from single-acquisition single-configuration SAR data     

Arsalan Ghorbanian  Mahmod Reza Sahebi  Ali Mohammadzadeh 《Comptes Rendus Geoscience》2019,351(4):332-339

This study suggests a novel approach to the retrieval of soil surface parameters using a single-acquisition single-configuration synthetic-aperture radar (SAR) system. Soil surface parameters such as soil moisture and surface roughness are key elements for many environmental studies, including Earth surface water cycles, energy exchange, agriculture, and geology. Remote sensing techniques, especially SAR data, are commonly used to retrieve such soil surface parameters over large areas. Several backscattering models have been proposed for soil surface parameters retrieval from SAR data. However, commonly, these backscattering models require multi configuration SAR data, including multi-polarization, multi-frequency, and multi-incidence angle. Here we propose a methodology that employs single-acquisition single-configuration SAR data for the retrieval of soil surface parameters. The originality is to use single-acquisition single-configuration SAR data to retrieve the soil surface parameters using an optimization approach by the genetic algorithm (GA); we have used the modified Dubois model (MDM) in HH polarization as the backscattering model. Three HH polarization and C band data sets from Quebec (Radarsat-1), Ontario (SIR-C), and Oklahoma (AIRSAR) were analyzed. The retrieved values of soil moisture and soil surface roughness were then compared to ground truth measurements with corresponding parameters. We employed diverse criteria, including the mean absolute error (MAE), the root mean square error (RMSE), the coefficient of performance (CP), and the correlation coefficient to investigate the performance of the proposed methodology. This analysis suggests the capability of the GA for the retrieval of soil surface parameters. Based on our findings, this method presents a viable alternative approach to the retrieval of soil surface parameters when only single-acquisition single-configuration SAR data is available.  相似文献   

Timing of metamorphism and deformation in the Swat valley,northern Pakistan:Insight into garnet-monazite HREE partitioning     

Kyle P.Larson  Asghar Ali  Sudip Shrestha  Mathieu Soret  John M.Cottle  Rafique Ahmad 《地学前缘(英文版)》2019,10(3):849-861

New metamorphic petrology and geochronology from the Loe Sar dome in the Swat region of northern Pakistan place refined constraints on the pressure, temperature and timing of metamorphism and deformation in that part of the Himalayan orogen. Thermodynamic modelling and monazite petrochronology indicate that metamorphism in the area followed a prograde evolution from ～525 ± 25 ℃and 6 士 0.5 kbar to ～610 ± 25 ℃ and 9 士 0.5 kbar, between ca. 39 Ma and 28 Ma. Partitioning of heavy rare earth elements between garnet rims and 30-28 Ma monazite are interpreted to indicate coeval crystallization at peak conditions. Microtextural relationships indicate that garnet rim growth post-dated the development of the main foliation in the area. The regional foliation is folded about large-scale N-S trending fold axes and overprinting E-W trending folds to form km-scale domal culminations. The textural relationships observed indicate that final dome development must be younger than the 30-28 Ma monazite that grew with garnet rims post-regional foliation development, but pre-doming-related deformation. This new timing constraint helps resolve discrepancy between previous interpretations,which have alternately suggested that N-S trending regional folds must be either pre-or post-early Oligocene. Finally, when combined with existing hornblende and white mica cooling ages, these new data indicate that the study area was exhumed rapidly following peak metamorphism.  相似文献   

A comparison between vertically integrated and multilevel models of tidal dynamics in channels     

Anwar Ali 《Estuarine, Coastal and Shelf Science》1982,14(4):405-419

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Late Cenozoic tectonics and stratigraphy of northwestern Anatolia: the effects of the North Anatolian Fault to the region     

Ali?ElmasEmail author 《International Journal of Earth Sciences》2003,92(3):380-396

In northwest Anatolia, there is a mosaic of different morpho-tectonic fragments within the western part of the right-lateral strike-slip North Anatolian Fault (NAF) Zone. These were developed from compressional and extensional tectonic regimes during the paleo- and neo-tectonic periods of Turkish orogenic history. A NE-SW-trending left-lateral strike-slip fault system (Adapazari-Karasu Fault) extends through the northern part of the Sakarya River Valley and began to develop within a N–S compressional tectonic regime which involved all of northern Anatolia during Middle Eocene to early Middle Miocene times. Since the end of Middle Miocene times, this fault system forms a border between a compressional tectonic regime in the eastern area eastwards from the northern part of the Sakarya River Valley, and an extensional tectonic regime in the Marmara region to the west. The extension caused the development of basins and ridges, and the incursions of the Mediterranean Sea into the site of the future Sea of Marmara since Late Miocene times. Following the initiation in late Middle Miocene times and the eastward propagation of extension along the western part of the NAF, a block (North Anatolian Block) began to form in the northern Anatolia region since the end of Pliocene times. The Adapazari-Karasu Fault constitutes the western boundary of this block which is bounded by the NAF in the south, the Northeast Anatolian Fault in the east, and the South Black Sea Thrust Fault in the north. The northeastward movement of the North Anatolian Block caused the formation of a marine connection between the Black Sea and the Aegean/Mediterranean Sea during the Pleistocene.  相似文献   

Interactions of copper, organic acids, and sulfate in goethite suspensions   总被引：1，自引：0，他引：1  

Muhammad A. Ali  David A. Dzombak 《Geochimica et cosmochimica acta》1996,60(24):5045-5053

Sorption of copper and sulfate onto goethite (-FeOOH) in aqueous solution is examined in Cu---SO₄ binary-sorbate systems and in Cu-SO₄-organic acid (either phthalic acid or chelidamic acid) ternary-sorbate systems. Compared to single-sorbate systems, sorption of Cu onto goethite was enhanced at low pH values in the presence of sulfate. Sorption data for Cu and SO₄ in Cu---SO₄ binary-sorbate systems were described with the Generalized Two Layer Model by proposing formation of a Cu---SO₄ ternary surface complex. Addition of sulfate to a Cu-phthalic acid binary sorbate system had little effect on Cu sorption. However, addition of sulfate to Cu-chelidamic acid binary-sorbate systems resulted in significant reduction of Cu sorption at low pH values, primarily due to competition for surface sites between sulfate and Cu-chelidamic acid ternary surface complexes. While organic acids such as humic substances can potentially influence sorption of metal ions, results from this study suggest that the extent of such influence may be strongly dependent on the presence of other sorbing anions, such as sulfate. Sorption of Cu and SO₄ in Cu---SO₄-organic acid ternary-sorbate systems was predicted reasonably well, based on surface reactions and equilibrium constants derived from fitting of sorption data from single- and binary-sorbate systems. These modeling results provide a validation of the extrapolation of sorption from simple systems to multicomponent systems through surface complexation modeling.  相似文献   

Evaluation of Ground Vibration due to Surface Blasting at a Celestite Open-pit Mine     

Ali Kahriman 《Fragblast: International Journal for Blasting and Fragmentation》2001,5(1):21-34

In bench blast design, not only the technical and economical aspects, such as block size, uniformity and cost, but also the elimination of environmental problems resulting from ground vibration and air blast should be taken into consideration. Prediction of ground vibration components is of great importance when responding to and avoiding environmentally-related complaints. This paper presents the results of ground vibration measurements carried out in a celestite open-pit mine during blast optimisation studies. The particle velocity components (longitudinal, transversal, vertical and peak) and the airblast measurement results were evaluated considering the scaled distance relationship. The statistical analysis of 47 data sets yielded an empirical relationship between peak particle velocity and scaled distance. This approach which is suggested for the present site gives the 50% line and the upper bound 95% prediction limit with reasonable correlation.  相似文献   

Fluid Inclusion Studies and Geochemistry of Rare Earth Elements of Hydrothermal Fluorites from Pohrenk, Kirsehir, Central Turkey     

Sükrü KOC  Ali RECBER 《《地质学报》英文版》2001,75(1)

Fluorite mineralization occurs along fractures and cracks of Middle Eocene and Pliocene limestones and marls in the north and northeast of the Pohrenk region (Qicekdagi, Kirsehir). Tb/Ca - Tb/La and Y/Ho ratios were obtained from REE contents of fluorites which have revealed that mineralization is of hydrothermal type. Negative Ce anomalies and positive Eu anomalies reflect that hydrothermal solutions once had high oxygen fugacity. Fluid inclusion studies indicate that homogenization temperatures of mineralization varied between 90℃ and 200℃, and hydrothermal solutions are composed of NaCl + KCl + MgCl2 + H2O. In addition, salinity measurements show that hydrothermal solutions were mixed with meteoric or rock formation water. Geologic setting, REE geochemistry and fluid inclusion studies suggest that mineralization was deposited from a solution generated by mixing of magmatic and meteoric water under epithermal conditions.  相似文献   

Bundelkhand mafic dykes, Central Indian Shield: Implications for the role of sediment subduction in Proterozoic crustal evolution     

Mohammad Erfan Ali Mondal and  Talat Ahmad 《Island Arc》2001,10(1):51-67

Abstract The Archean to Paleo–Proterozoic Bundelkhand massif basement of the central Indian shield has been dissected by numerous mafic dykes of Proterozoic age. These dykes are low‐Ti tholeiites, ranging in composition from subalkaline basalt through basaltic‐andesite to dacite. They are enriched in light rare earth elements (LREE), large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE: Nb, P and Ti). Negative Sr anomaly is conspicuous. Nb/La ratios of the dykes are much lower compared with the primitive mantle, not much different from the average crustal values, but quite similar to those of continental and subduction related basaltic rocks. Bulk contamination of the mantle derived magma by crustal material is inadequate to explain the observed geochemical characteristics; instead contamination of the mantle/lithospheric source(s) via subduction of sediment is a better proposition. Thus, in addition to generating juvenile crust along the former island arcs, subduction processes appear to have influence on the development of enriched mantle/lithospheric source(s). The Bundelkhand massif basement is inferred to represent subduction related juvenile crust, that experienced lithospheric extension and rifting possibly in response to mantle plume activities. The latter probably supplied the required heat, material (fluids) and extensional environment to trigger melting in the refractory lithospheric source(s) and emplacement of the mafic dykes. Proterozoic mafic magmatic rocks from Bundelkhand, Aravalli, Singhbhum and Bastar regions of the Indian shield and those from the Garhwal region of the Lesser Himalaya display remarkably similar enriched incompatible trace elements characteristics, although limited chemical variations are observed in all these rocks. This may indicate the existence of a large magmatic province, different parts of which might have experienced similar petrogenetic processes and were probably derived from mantle/lithospheric source(s) with similar trace element characteristics. The minor, less enriched to depleted components of the Jharol Group of the Aravalli terrane and those from the Singhbhum terrane may represent protracted phases of rifting, that probably caused thinning and mobilization of the lithosphere, facilitating the eruption/emplacement of the asthenospheric melts (with N‐ to T‐types mid‐oceanic ridge basalts signatures) and deposition of deep water facies sediments in the younger developing oceanic basins. In contrast, Bundelkhand region did not experience such protracted rifting, although dyke swarms were emplaced and shallow water Bijawar Group and Vindhyan Supergroup sediments were deposited in continental rift basins. All these discrete Proterozoic terranes appear to have experienced similar petrogenetic processes, tectonomagmatic and possibly temporal evolution involving subduction processes, influencing the lithospheric source characteristics, followed by probably mantle plume induced ensialic rifting through to the development of oceanic basins in the Indian shield regions and their extension in the Lesser Himalaya.  相似文献