Trace gases and PM2.5-bound metal abundance over a tropical urban environment,South India     

M  Abdul Shukkur  V.G  Gopikrishna  N.G  Vishnu  Mohan  Mahesh 《Journal of Atmospheric Chemistry》2021,78(3):193-208

Pre and Post-Monsoon levels of ambient SO₂, NO₂, PM_2.5 and the trace metals Fe, Cu, etc. were measured at industrial and residential regions of the Kochi urban area in South India for a period of two years. The mean PM_2.5, SO₂ and NO₂ concentrations across all sites were 38.98?±?1.38 µg/m³, 2.78?±?0.85 µg/m³ and 11.90?±?4.68 µg/m³ respectively, which is lower than many other Indian cities. There was little difference in any on the measured species between the seasons. A few sites exceeded the NAAQS (define acronym and state standard) and most of the sites exceeded WHO (define acronym and state standard) standard for PM_2.5. The average trace metal concentrations (ng/m³) were found to be Fe (32.58)?>?Zn (31.93)?>?Ni (10.13)?>?Cr (5.48)?>?Pb (5.37)?>?Cu (3.24). The maximum concentration of trace metals except Pb were reported in industrial areas. The enrichment factor, of metals relative to crustal material, indicated anthropogenic dominance over natural sources for the trace metal concentration in Kochi’s atmosphere. This work demonstrates the importance of air quality monitoring in this area.

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Arsenic in freshwater systems: Influence of eutrophication on occurrence,distribution, speciation,and bioaccumulation   总被引：2，自引：0，他引：2  

M. Azizur Rahman  H. Hasegawa 《Applied Geochemistry》2012

Arsenic exists in a variety of chemical forms, and microbial metabolism results in the occurrence of thermodynamically unstable arsenite (As^III) and methylarsenic compounds in freshwaters (rivers and lakes). The inorganic forms (As^V and As^III) and the methylated forms (methylarsonic acid; MMAA^V and dimethylarsinic acid; DMAA^V) are the main species of As in freshwaters while the bulk of the total dissolved As is inorganic species. Although the predominant forms of methylarsenic compounds are consistently DMAA^V followed by MMAA^V, the DMAA^III and MMAA^III species have also been found in freshwaters. Several observations have revealed that phytoplankton activities are responsible for the seasonal variations of methylarsenic compounds in freshwaters. Although it was unclear if the occurrences of methylarsenic compounds were from the breakdown of larger molecules or the end-products of phytoplankton biosynthesis, recent studies have revealed that less toxic As–glutathione complexes are intermediates in the biosynthesis of organoarsenic compounds by phytoplankton. Recent studies have also revealed that eutrophication plays an important role in the production, distribution, and cycling of methylarsenic compounds in freshwaters. In this review, the recent reports on the influence of eutrophication on distribution, speciation, and bioaccumulation in freshwaters are discussed.  相似文献   

Estimation of concentration and exposure doses due to radon by using CR-39 plastic track detectors in the residences of Sudhnuti, Azad Kashmir, Pakistan     

Muhammad Rafique  Saeed Ur Rahman  Muhammad Akram  Matiullah 《Environmental Earth Sciences》2012,66(4):1225-1232

This paper presents the results of indoor radon concentration measurements in 120 dwellings of district Sudhnuti of Azad Kashmir. Measurements were taken with CR-39 passive alpha track detector. CR-39 based box type radon detectors were installed in a bedroom and living rooms of each house. The detectors were retrieved after exposing to indoor radon for period of 6 months and then etched in 6 M NaOH at 80°C for 16 h, the observed track densities were converted in to the indoor radon concentration. Indoor radon concentration varied from 20 ± 12 to 170 ± 4 Bq m⁻³ for the houses of the district Sudhnuti. Arithmetic mean (AM), geometric mean (GM) and geometric standard deviations (GSD) were found to be 82 ± 6, 77 ± 6 and 1.51, respectively. The minimum value of weighted average radon concentration was recorded in one of the house of Mang town, whereas the maximum value was found in the Pattan Sher Khan region. Doses due to indoor radon exposure vary from 0.50 ± 0.31 to 4.28 ± 0.11 mSv year⁻¹ AM, GM and GSD. of mean effective doses were found to be 2.06 ± 0.13, 1.95 ± 0.18 and 1.51, respectively. According to the recommendations made by the Health Protection Agency, UK (200 Bq m⁻³) all the houses surveyed are within the safe limits.  相似文献   

Dynamics of hourly sea level at Hillarys Boat Harbour,Western Australia: a chaos theory perspective     

Rahman Khatibi  Mohammad Ali Ghorbani  Mohammad Taghi Aalami  Kasim Kocak  Oleg Makarynskyy  Dina Makarynska  Mahdi Aalinezhad 《Ocean Dynamics》2011,61(11):1797-1807

Water level forecasting using recorded time series can provide a local modelling capability to facilitate local proactive management practices. To this end, hourly sea water level time series are investigated. The records collected at the Hillarys Boat Harbour, Western Australia, are investigated over the period of 2000 and 2002. Two modelling techniques are employed: low-dimensional dynamic model, known as the deterministic chaos theory, and genetic programming, GP. The phase space, which describes the evolution of the behaviour of a nonlinear system in time, was reconstructed using the delay-embedding theorem suggested by Takens. The presence of chaotic signals in the data was identified by the phase space reconstruction and correlation dimension methods, and also the predictability into the future was calculated by the largest Lyapunov exponent to be 437 h or 18 days into the future. The intercomparison of results of the local prediction and GP models shows that for this site-specific dataset, the local prediction model has a slight edge over GP. However, rather than recommending one technique over another, the paper promotes a pluralistic modelling culture, whereby different techniques should be tested to gain a specific insight from each of the models. This would enable a consensus to be drawn from a set of results rather than ignoring the individual insights provided by each model.  相似文献   

CFD simulation and experimental analysis of flow dynamics and grinding performance of opposed fluidized bed air jet mill     

M. Sri Raj Rajeswari  K.A.M. Azizli  S.F.S. Hashim  M.K. Abdullah  M. Abdul Mujeebu  M.Z. Abdullah 《International Journal of Mineral Processing》2011,98(1-2):94-105

This paper presents a three dimensional Computational Fluid Dynamics (CFD) model to investigate the flow dynamics of solid–gas phases during fine grinding in an air jet mill. Alpine 100AFG fluidized bed air jet mill is considered for the study and the jet milling model is simulated using FLUENT 6.3.2 using a standard k-ε model. The model is developed in GAMBIT 2.3.16 and meshed by tet/hybrid (T-Grid) and Triangular (Pave) meshes. The effects of operating parameters such as solid feed rate, grinding air pressure and internal classifier speed on the performance of the jet mill are analyzed. The CFD simulation results are presented in the forms of dual phase vector plot, volume fraction of phases and particle trajectories during fine grinding process. The mass of ground feed entering and leaving the cyclone (underflow) is also computed by simulation. The proposed model gives realistic predictions of the flow dynamics within the jet mill. Experiments are conducted on the Alpine 100AFG jet mill to study the particle size, morphology and mass of the ground product. The numerical results are found in good agreement with the experimental results.  相似文献   

Scaling property of regional floods in New South Wales Australia     

Elias Ishak  Khaled Haddad  Mohammad Zaman  Ataur Rahman 《Natural Hazards》2011,58(3):1155-1167

Regional flood frequency analysis (RFFA) is often used in hydrology to estimate flood quantiles when there is a limitation of at-site recorded flood data. One of the commonly used RFFA methods is the index flood method, which is based on the assumptions that a region satisfies criterion of simple scaling and it can be treated homogeneous. Another RFFA method is quantile regression technique where prediction equations are developed for flood quantiles of interest as function of catchment characteristics. In this paper, the scaling property of regional floods in New South Wales (NSW) State in Australia is investigated. The results indicate that the annual maximum floods in NSW satisfy a simple scaling assumption. The application of a heterogeneity test, however, reveals that NSW flood data set does not satisfy the criteria for a homogeneous region. Finally, a set of prediction equations are developed for NSW using quantile regression technique; an independent test shows that these equations can provide reasonably accurate design flood estimates with a median relative error of about 27%.  相似文献   

Seasonal Changes in Mayfly Communities and Abundance in Relation to Water Physicochemistry in Two Rivers at Different Elevations in Northern Peninsular Malaysia     

Suhaila Abdul Hamid  Mohd Ravi Che Salmah  Hamady Dieng  Abu Hassan Ahmad  Tomomitsu Satho  Fumio Miake 《湿地科学》2011,9(3):240-250

A field study was performed at rivers in Gunung Jerai forest reserve(Kedah,Malaysia) to assess seasonal changes in mayfly community structure and abundance in relation to altitude and water physicochemistry.Rivers at lower(Batu Hampar River) and higher(Teroi River) elevations were visited through dry and wet seasons in September 2007 to August 2008.Monthly visits were made to 20 sites on each river,and water and aquatic insects were sampled using D-pond aquatic nets.Water was warmer,more acid,and more turbid in Teroi River during wet season.Ammonia was the only nutrient exhibiting significant seasonal variations(greater during wet season).Chemical oxygen demand content was higher in Teroi River where biochemical oxygen demand content was low during wet season.Species richness was higher in Batu Hampar River,but displayed seasonal variations only in Teroi River.Among the eight families encountered,Baetidae was the commonest.Baetid abundance was usually high during wet season,and those belonging to the dominant genus(Baetis) were more abundant in Teroi River.Heptageniidae was the second commonest family;its predominant genus,Thalerospyrus was more abundant in Teroi River during dry season.Caenidae,Leptophlebiidae and Oligoneuriidae were only found in Batu Hampar River where their abundances peaked during dry season,i.e.,Habrophlebiodes sp.and Isonychia sp.Ephemerellidae and Teloganodidae occurred only in Teroi River,with the first found only during dry season.Mayflies were recorded under very distinct physicochemical conditions,illustrating their potential usefulness for assessing water quality.Caenids,leptophlebids,oligoneurids ephemerellids and teloganodids seem to be particularly sensitive to temperature,acidity,turbidity,chemical oxygen demand and biochemical oxygen demand,parameters that varied with river altitude.  相似文献   

New ophiolite occurrences in Sudan and constraint on the western boundary of the Nubian Shield: Petrographical and geochemical evidence     

E.A. Ali  E.M. Abdel Rahman 《Journal of African Earth Sciences》2011,59(1):101-110

Important mafic–ultramafic masses have been located for the first time in the intersection area between the Keraf Shear Zone and the Nakasib Suture Zone of the Nubian Shield. The masses, comprising most of the members of the ophiolite suite, are Sotrebab and Qurun complexes east of the Nile, and Fadllab complex west of the Nile. The new mafic–ultramafic masses are located on the same trend of the ophiolitic masses decorating the Nakasib Suture. A typical complete ophiolite sequence has not been observed in these complexes, nevertheless, the mafic–ultramafic rocks comprise basal unit of serpentinite and talc chlorite schists overlain by a thick cumulate facies of peridotites, pyroxenites and layered gabbros overlain by basaltic pillow lavas with dolerite dykes and screens of massive gabbros. Associated with pillow lavas are thin layers of carbonates and chert. The best section of cumulate mafic–ultramafic units has been observed in Jebel Qurun and El Fadlab complexes, comprising peridotites, pyroxenites and layered gabbros. Dolerite dykes and screens of massive gabbros have been observed with basaltic pillow lava sections in Wadi Dar Tawaiy. The basal ultramafic units of the complexes have been fully or partly retrograded to chlorite magnetite schist and talc to talc-carbonate rocks (listowenites), especially in the Jebel Qurun and Sotrebab complexes. Petrographically, the gabbros (layered and massive) and the basaltic pillow lavas show mineral assemblages of epidote amphibolite facies. The mafic members from the three complexes show a clear tholeiitic trend and oceanic floor affinity. The pillow lavas plot in the field of oceanic floor basalt, namely in the back arc field. Primitive mantle normalized spider diagram of the pillow lavas reveals a closer correspondence to Enrich-Mid-Oceanic Ridge Basalt (E-MORB) type, which is confirmed by the flat chondrite normalized Rare Earth Elements (REE) pattern. Field, petrographical and geochemical evidence supports ophiolitic origin of the three complexes. The newly discovered ophiolitic complexes mark the western continuation of the Nakasib Suture Zone.  相似文献   

Tracing subsurface migration of contaminants from an abandoned municipal landfill   总被引：1，自引：1，他引：0  

E. A. Rahim Bahaa-eldin  I. Yusoff  S. Abdul Rahim  W. Y. Wan Zuhairi  M. R. Abdul Ghani 《Environmental Earth Sciences》2011,63(5):1043-1055

This paper aims at determining of inorganic leachate contamination for a capped unsanitary landfill in the absence of hydrogeological data. The 2D geoelectrical resistivity imaging, soil physicochemical characterization, and surface water analysis were used to determine contamination load and extent of selective heavy metal contamination underneath the landfill. The positions of the contaminated subsoil and groundwater were successfully delineated in terms of low resistivity leachate plumes of <10 Ωm. Leachate migration towards the reach of Kelang River could be clearly identified from the resistivity results and elevated concentrations of Fe in the river downslope toe of the site. Concentration of Fe, Mn, Ca, Na, K, Mg, Cu, Cr, Co, Ni, Zn, and Pb was measured for the subsoil samples collected at the downslope (BKD), upslope (BKU), and the soil-waste interface (BKI), of the landfill. The concentration levels obtained for most of the analyzed heavy metals significantly exceed the normal range in typical municipal solid waste landfill sites. The measured heavy metal contamination load in the subsoil is in the following order Fe ? Mn > Zn > Pb > Cr > Cu. Taking into consideration poor physical and chemical characteristics of the local soil, these metals first seem to be attenuated naturally at near surface then remobilize unavoidably due to the soil acidic environment (pH 4.2-6.18) which in turn, may allow an easy washing of these metals in contact with the shallow groundwater table during the periodic fluctuation of the Kelang River. These heavy metals are believed to have originated from hazardous industrial waste that might have been illegally dumped at the site.  相似文献   

Study of regional monsoonal effects on landslide hazard zonation in Cameron Highlands, Malaysia   总被引：1，自引：1，他引：0  

Abd Nasir Matori  Abdul Basith  Indra Sati Hamonangan Harahap 《Arabian Journal of Geosciences》2011,5(5):1069-1084

In general, landslides in Malaysia mostly occurred during northeast and southwest periods, two monsoonal systems that bring heavy rain. As the consequence, most landslide occurrences were induced by rainfall. This paper reports the effect of monsoonal-related geospatial data in landslide hazard modeling in Cameron Highlands, Malaysia, using Geographic Information System (GIS). Land surface temperature (LST) data was selected as the monsoonal rainfall footprints on the land surface. Four LST maps were derived from Landsat 7 thermal band acquired at peaks of dry and rainy seasons in 2001. The landslide factors chosen from topography map were slope, slope aspect, curvature, elevation, land use, proximity to road, and river/lake; while from geology map were lithology and proximity to lineament. Landslide characteristics were extracted by crossing between the landslide sites of Cameron Highlands and landslide factors. Using which, the weighting system was derived. Each landslide factors were divided into five subcategories. The highest weight values were assigned to those having the highest number of landslide occurrences. Weighted overlay was used as GIS operator to generate landslide hazard maps. GIS analysis was performed in two modes: (1) static mode, using all factors except LST data; (2) dynamic mode, using all factors including multi-temporal LST data. The effect of addition of LST maps was evaluated. The final landslide hazard maps were divided into five categories: very high risk, high risk, moderate, low risk, and very low risk. From verification process using landslide map, the landslide model can predict back about 13–16% very high risk sites and 70–93% of very high risk and high risk combined together. It was observed however that inclusion of LST maps does not necessarily increase the accuracy of the landslide model to predict landslide sites.  相似文献