Tracing Ni, Cu, and Zn kinetics and equilibrium partitioning between dissolved and particulate phases in South San Francisco Bay, California, using stable isotopes and high-resolution inductively coupled plasma mass spectrometry     

Alison K. Gee  Kenneth W. Bruland 《Geochimica et cosmochimica acta》2002,66(17):3063-3083

Additions of the low occurrence stable isotopes ⁶¹Ni, ⁶⁵Cu, and ⁶⁸Zn were used as tracers to determine the exchange kinetics of metals between dissolved and particulate forms in laboratory studies of natural water and suspended sediments from South San Francisco Bay, CA. Dissolved metal isotope additions were made so that the isotope ratios (rather than total metal partitioning) were significantly altered from initial ambient conditions. Dissolved metal concentrations were determined using an organic ligand sequential extraction technique followed by analysis with high-resolution inductively coupled plasma mass spectrometry (HR-ICPMS). Exchangeable particulate concentrations were extracted using a 20% acetic acid leach followed by determination using HR-ICPMS. Equilibrium and kinetic sorption parameters were quantified according to a general model for trace metal partitioning assuming pseudo-first-order kinetics. Partition coefficients (K_D) were tracked as a function of time over the fortnight experiment. For Ni, Cu, and Zn the initial ambient K_D values were found to be 10^3.65, 10^3.88, and 10^4.52 L kg⁻¹, respectively. As a result of the dissolved metal isotope additions, the partition coefficients for all three metals dropped and then increased back to near ambient K_D values after 14 days. Curve-fitting concentration versus time profiles from both dissolved and exchangeable particulate data sets allowed determination of kinetic rate constants. The best estimates of forward and backward kinetic rate constants for Ni, Cu, and Zn respectively are k′_f = 0.03, 0.07, 0.12 d⁻¹ and k_b = 0.13, 0.12, 0.15 d⁻¹. These results predict that sorption equilibria in South Bay should be reached on the order of a month for Ni, on the order of 3 weeks for Cu, and on the order of 2 weeks for Zn. Together, the dissolved and exchangeable particulate data indicate more sluggish sorption kinetics for Ni than for Cu and Zn and suggest that different chemical forms control the speciation of these three metals in South Bay. Order of magnitude metal sorption exchange rates were estimated using these kinetic results. These calculations indicate that sorption exchange between dissolved and suspended particulate phases can cause dynamic internal cycling of these metals in South San Francisco Bay.  相似文献   

Household vulnerability to famine: Survival and recovery strategies among Berti and Zaghawa migrants in Northern Dafur,Sudan, 1982–1989     

Alison S. Pyle  Omer Abdel Gabbar 《GeoJournal》1993,30(2):141-146

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Variations in Typhoon Landfalls over China   总被引：1，自引：1，他引：1  

Emily A. FOGARTY  James B. ELSNER  Thomas H. JAGGER  Kam-biu LIU  Kin-sheun LOUIE 《大气科学进展》2006,23(5):665-677

The interannual variability in typhoon landfalls over China is investigated using historical and modern records. For the purpose of substantiating and elaborating upon the claim of north to south variation in tropical cyclone activity over China, a north-to-south anti-correlation in yearly activity is confirmed in the historical cyclone records. When cyclone activity over the province of Guangdong is high （low）, it tends to be low （high） over the province of Fujian. A similar spatial variation is identified in the modern records using a factor analysis model, which delineates typhoon activity over the southern provinces of Guangdong and Hainan from the activity over the northern provinces of Fujian, Taiwan, Zhejiang, Shanghai, Jiangsu, and Shandong. A landfall index of typhoon activity representing the degree to which each year follows this pattern of activity is used to identify correlated climate variables. A useful statistical regression model that includes sea-level pressure differences between Mongolia and western China and sea-surface temperature （SST） over the northwestern Pacific Ocean during the summer explains 26% of the interannual variability of the landfall index. It is suggested that a stronger than normal north-south pressure gradient increases the surface easterly wind flow over northern China： this, coupled with lower SST over the Pacific, favors typhoons taking a more westerly track toward southern China.  相似文献   

Block-effective macrodispersion for numerical simulations of sorbing solute transport in heterogeneous porous formations     

Alison E. Lawrence  Yoram Rubin 《Advances in water resources》2007

Heterogeneity is prevalent in aquifers and has an enormous impact on contaminant transport in groundwater. Numerical simulations are an effective way to deal with heterogeneity directly by assigning different hydraulic property values to each numerical grid block. Because hydraulic properties vary on different scales, but they cannot be sampled exhaustively and the number of numerical grid blocks is limited by computational considerations, the dispersive effects of unmodeled heterogeneity need to be accounted for. Dispersion tensors can be used to model the dispersion caused by unmodeled heterogeneity. The concept of block-effective macrodispersion tensors for modeling the effects of small-scale variability on solute transport introduced by Rubin et al. [Rubin Y, Sun A, Maxwell R, Bellin A. The concept of block-effective macrodispersivity and a unified approach for grid-scale- and plume-scale-dependent transport. J Fluid Mech 1999;395:161–80] is extended in this paper for use with reactive solutes. The tensors are derived for reactive solutes with spatially variable retardation factors and for solutes experiencing spatially uniform rate-limited sorption. The longitudinal block-effective macrodispersion coefficient is largest for perfect negative correlation between the log-hydraulic conductivity and the retardation factor. Because dispersion tensors, as they are usually implemented in numerical simulations, produce symmetric spreading, the applicability of the concept depends on the portion of the plume asymmetry caused by small-scale variability. The presented results show that the concept is applicable for rate-limited sorption for block sizes of one and two integral scales.  相似文献   

Rb‐Sr and Sm‐Nd isotopic and REE studies of igneous components in the bulk matrix domain of Martian breccia Northwest Africa 7034          下载免费PDF全文

Laurence E. Nyquist  Chi‐Yu Shih  Francis M. McCubbin  Alison R. Santos  Charles K. Shearer  Zhan X. Peng  Paul V. Burger  Carl B. Agee 《Meteoritics & planetary science》2016,51(3):483-498

The bulk matrix domain of the Martian breccia NWA 7034 was examined petrographically and isotopically to better understand the provenance and age of the source material that make up the breccia. Both ¹⁴⁷Sm‐¹⁴³Nd and ¹⁴⁶Sm‐¹⁴²Nd age results for mineral separates from the bulk matrix portion of breccia NWA 7034 suggest that various lithological components in the breccia probably formed contemporaneously ~4.44 Ga ago. This old age is in excellent agreement with the upper intersection ages (4.35–4.45 Ga) for U‐Pb discordia and also concordia defined by zircon and baddeleyite grains in matrix and igneous‐textured clasts. Consequently, we confirm an ancient age for the igneous components that make up the NWA 7034 breccia. Substantial disturbance in the Rb‐Sr system was detected, and no age significance could be gleaned from our Rb‐Sr data. The disturbance to the Rb‐Sr system may be due to a thermal event recorded by bulk‐rock K‐Ar ages of 1.56 Ga and U‐Pb ages of phosphates at about 1.35–1.5 Ga, which suggest partial resetting from an unknown thermal event(s), possibly accompanying breccia formation. The NWA 7034 bulk rock is LREE enriched and similar to KREEP‐rich lunar rocks, which indicates that the earliest Martian crust was geochemically enriched. This enrichment supports the idea that the crust is one of the enriched geochemical reservoirs on Mars that have been detected in studies of other Martian meteorites.  相似文献   

Enhancing the effectiveness of policy-relevant integrative research in rural areas     

Piran C L White  Steve Cinderby  Dave Raffaelli  Annemarieke de Bruin  Alison Holt  Meg Huby 《Area》2009,41(4):414-424

There has been much debate about the importance of policy-relevant research in geography over the last decade. There has also been an increasing recognition by policymakers of the importance of integrative (interdisciplinary and transdisciplinary) approaches to policy-relevant research. However, geographers have been more reluctant than their colleagues in other social and natural sciences to embrace integrative research collaborations. For integrative research to achieve its full potential and to encourage greater participation from the geographical research community, we need to increase our understanding of its potential value, but also some of the challenges that it poses, and how these can be overcome. In this paper, we consider the processes involved in conducting successful integrative research from the perspective of researchers involved in these projects. We base our analysis on the results of a questionnaire survey of international integrative research programmes on environmental issues in rural areas, combined with our own experiences of working in integrative research. We conclude that effective integrative research depends on the establishment of a clear conceptual framework, the use of appropriate temporal and spatial scales in the research, effective language and communication, time and commitment, and trust and respect. We also highlight the value of stakeholder involvement in integrative research to ensure the policy relevance of the work and provide a mechanism to assist with effective knowledge transfer of the results.  相似文献   

Water quality along a river continuum subject to point and diffuse sources     

Colin Neal  Helen P. Jarvie  Alison Love  Margaret Neal  Heather Wickham  Sarah Harman 《Journal of Hydrology》2008,350(3-4):154-165

The water quality along the River Kennet, in the Thames basin of southern England, was examined in terms of the influence of point- and diffuse-nutrient inputs. The river is supplied mainly from a Cretaceous Chalk aquifer and hence the waters are of a calcium bicarbonate type. The nitrate largely comes from agricultural sources, with concentrations decreasing downstream due to plant uptake and probable denitrification. In contrast, soluble reactive phosphorus (SRP) is largely associated with sewage inputs and concentrations increase downstream in line with effluents from major towns such as Newbury and Reading. Adjacent to the river in the lower half of the catchment is the Kennet and Avon Canal and the two are in places hydrologically connected. The canal inputs may influence calcium carbonate (calcite) precipitation and increase suspended sediment and particulate phosphorus concentrations in the river. Monitoring upstream and downstream of Marlborough sewage treatment works (STW) showed that SRP concentrations in the effluent were highly variable due to variable efficiency of P stripping and still sufficiently concentrated to dominate downstream river SRP with potential impacts on stream ecology. Biological recovery in this river following P stripping at STWs is complex and controlling those spikes in SRP that are above a threshold of 100 μg l⁻¹ may be a critical requirement. More stringent effluent targets than are currently recommended may be needed (less than 800 μg RP l⁻¹) to achieve good ecological status in this river depending on SRP concentrations upstream.  相似文献   

辽东半岛海城-大石桥菱镁矿矿床成因探讨     

胡古月  孙新胜  郑军  余旭辉  王东波  李延河  赵悦  陈翰  徐莺  Alison Ord 《地质学报》2022,96(4):1340-1355

辽东半岛古元古界辽河群大石桥组三段地层中赋存有全球最大工业储量的菱镁矿矿床.在总结和整理已发表的辽东半岛晶质菱镁矿床地质和地球化学数据的基础上,本次研究进行了Mg和B同位素测试及研究工作,获得以下认识:① 菱镁矿矿体呈北东东走向,产于大石桥组三段,但不同矿床的矿体厚度差异较大(30～300 m),菱镁矿矿体与顶、底板高...  相似文献   

Playing the 'disabled role' in local travel     

Alison Porter 《Area》2000,32(1):41-48

Summary This paper describes how people with a range of physical impairments use the 'disabled role' to enable them to make local journeys in Swansea. It examines the processes by which interaction between people and social institutions serves to overcome transport disability and to reinforce prevailing meanings and structures of disability.  相似文献   

Stability of clinohumite in the system MgO-SiO2-H2O     

Alison Pawley 《Contributions to Mineralogy and Petrology》2000,138(3):284-291

The low-pressure stability of clinohumite has been investigated in phase-equilibrium experiments on the reaction forsterite + brucite = clinohumite. The reaction was bracketed between 2.45 and 2.84 GPa at 650 °C, extending to between 1.37 and 1.57 GPa at 850 °C. At temperatures above the reaction brucite = periclase + vapour, the reaction clinohumite = forsterite + vapour was bracketed between 1.27 and 1.52 GPa at 900 °C, rising to between 1.90 and 2.00 GPa at 1000 °C. The position of the reaction forsterite + brucite = clinohumite is ∼0.5 GPa below the position determined in previous work, the difference arising either from pressure uncertainties in both studies, from enhanced reaction to clinohumite in this study due to the presence of excess brucite in the starting material, or from different concentrations of defects in the two samples. The brackets on the reaction were combined with other measured and estimated thermodynamic data for clinohumite to determine its enthalpy of formation and entropy, in a revised version of the thermodynamic dataset of Holland and Powell (1998). The values obtained were ΔH _f =−9607.29±3.05 kJ mol⁻¹, S=445 J mol⁻¹ K⁻¹. These data were used to calculate positions of other reactions involving clinohumite. The calculations suggest a larger stability field for clinohumite than implied by the results of previous experimental studies, indicating a need for more high-pressure phase-equilibrium studies to provide better thermodynamic data. Received: 30 April 1999 / Accepted: 8 November 1999  相似文献