Strontium in coral aragonite: 1. Characterization of Sr coordination by extended absorption X-ray fine structure     

Adrian A. Finch  Nicola Allison  Steven R. Sutton  Matthew Newville 《Geochimica et cosmochimica acta》2003,67(6):1197-1202

Aragonite was analyzed from Porites lobata, Pavona gigantea, Pavona clavus, and Montastrea annularis corals by Sr K-edge extended absorption X-ray fine structure (EXAFS) and compared with aragonite, strontianite, and mechanically mixed standards. Bulk analyses were performed and data compared with equivalent micro-EXAFS analyses on small (∼400 μm³) analytical volumes with a microfocused X-ray beam. As a result of the architecture of the coral skeleton, the crystals within the microanalytical volume are not randomly oriented, and the microanalytical X-ray absorption spectra show orientational dependence. However, refinement of bulk and microanalytical data provided indistinguishable interatomic distances and thermal vibration parameters in the third shell (indicative of Sr speciation). The Sr K-edge EXAFS of all the coral samples refine, within error, to an ideally substituted Sr in aragonite, in contrast to previous studies, in which significant strontianite was reported. Some samples from that study were also analyzed here. Strontianite may be less widely distributed in corals than previously thought.  相似文献   

Elevation Dependence of Winter Wheat Production in Eastern Washington State with Climate Change: A Methodological Study     

Allison M. Thomson  Robert A. Brown  Steven J. Ghan  R. Cesar Izaurralde  Norman J. Rosenberg  L. Ruby Leung 《Climatic change》2002,54(1-2):141-164

Crop growth models, used in climate change impact assessments to project production on a local scale, can obtain the daily weather information to drive them from models of the Earth's climate. General Circulation Models (GCMs), often used for this purpose, provide weather information for the entire globe but often cannot depict details of regional climates especially where complex topography plays an important role in weather patterns. The U.S. Pacific Northwest is an important wheat growing region where climate patterns are difficult to resolve with a coarse scale GCM. Here, we use the PNNL Regional Climate Model (RCM) which uses a sub-grid parameterization to resolve the complex topography and simulate meteorology to drive the Erosion Productivity Impact Calculator (EPIC) crop model. The climate scenarios were extracted from the PNNL-RCM baseline and 2 × CO₂ simulationsfor each of sixteen 90 km² grid cells of the RCM, with differentiation byelevation and without correction for climate biases. The dominant agricultural soil type and farm management practices were established for each grid cell. Using these climate and management data in EPIC, we simulated winter wheat production in eastern Washington for current climate conditions (baseline) and a 2 × CO₂ `greenhouse' scenario of climate change.Dryland wheat yields for the baseline climate averaged 4.52 Mg ha^–1 across the study region. Yields were zero at high elevations where temperatures were too low to allow the crops to mature. The highest yields (7.32 Mgha^–1) occurred at intermediate elevations with sufficientprecipitation and mild temperatures. Mean yield of dryland winter wheat increased to 5.45 Mg ha^–1 for the 2 × CO₂ climate, which wasmarkedly warmer and wetter. Simulated yields of irrigated wheat were generally higher than dryland yields and followed the same pattern but were, of course, less sensitive to increases in precipitation. Increases in dryland and irrigated wheat yields were due, principally, to decreases in the frequency of temperature and water stress. This study shows that the elevation of a farm is a more important determinant of yield than farm location in eastern Washington and that climate changes would affect wheat yields at all farms in the study.  相似文献   

东南极冰盖Lambert冰川流域的物质平衡研究   总被引：4，自引：0，他引：4  

任贾文  Ian Allison  效存德  秦大河 《中国科学D辑》2002,32(2):134-140

Lambert冰川流域是南极冰盖最大的冰流系统, 因而在整个南极冰盖的物质平衡中占有非常重要的地位. 近年来穿越该冰川流域的路线考察所获得的现场观测资料和浅冰芯研究结果显示, 该冰川东、西两侧的积累速率分布和近期变化有明显差异: 东侧积累速率较高且近几十年来呈增加趋势, 西侧积累速率较低且过去几十年为明显减小. 冰体运动速度测量和冰流通量计算表明, 该冰川东侧运动速度较快, 冰流量也较大, 说明该冰川冰量补给主要来源于东侧区域. 计算出的考察断面上游物质积累总量大于流出的冰通量约13%, 意味着该流域目前处于物质正平衡状态, 如果保持目前气候状态, 冰盖将会增厚.  相似文献   

The effects of fire on rock weathering: some further considerations of laboratory experimental simulation     

Robert J. Allison  Giles E. Bristow 《地球表面变化过程与地形》1999,24(8):707-713

Fire in the natural environment is a widespread agent of geomorphological and biological change. Temperatures can exceed 1000°C. There is often a rapid rise from ambient conditions through a steep thermal gradient, promoting rock disintegration. Laboratory simulation studies have established that temperature changes which are representative of natural fires affect rock material properties, which can then be related to weathering susceptibility. This study extends previous work by more closely replicating the natural environment, (a) through the simulation of rainfall and (b) by encasing samples to reflect the exposure of a single rock face to a passing fire event. Rock samples collected on Cyprus were prepared and tested following previously reported procedures. Change in modulus of elasticity was monitored using a non-destructive ultrasonic method. The data corroborate previous work but with somewhat different degrees of change. The new results are more likely to be representative of natural conditions and real-world change. The rate of rock disintegration and effects such as case-hardening appear to be a function of rock thermal characteristics, material properties and environmental constraints such as diurnal temperature range. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Book Review: Clay and Shale Slope Instability edited by William C. Haneberg and Scott A. Anderson,GSA Reviews in Engineering Geology Series,The Geological Society of America,Boulder, Colorado, 1995. No. of pages: v + 158. Price $60.00 (hb). ISBN 0-8137-4110-6     

Robert J. Allison 《地球表面变化过程与地形》1997,22(6):606-607

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Lateral terminations of salt walls and megaflaps: An example from Gypsum Valley Diapir,Paradox Basin,Colorado, USA     

Frederic O. Escosa  Mark G. Rowan  Katherine A. Giles  Kyle T. Deatrick  Allison M. Mast  Richard P. Langford  Thomas E. Hearon  Eduard Roca 《Basin Research》2019,31(1):191-212

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Palaeoenvironmental records from fossil corals: The effects of submarine diagenesis on temperature and climate estimates     

Nicola Allison  Adrian A. Finch  David A. Clague 《Geochimica et cosmochimica acta》2007,71(19):4693-4703

The geochemistry of coral skeletons may reflect seawater conditions at the time of deposition and the analysis of fossil skeletons offers a method to reconstruct past climate. However the precipitation of cements in the primary coral skeleton during diagenesis may significantly affect bulk skeletal geochemistry. We used secondary ion mass spectrometry (SIMS) to measure Sr, Mg, B, U and Ba concentrations in primary coral aragonite and aragonite and calcite cements in fossil Porites corals from submerged reefs around the Hawaiian Islands. Cement and primary coral geochemistry were significantly different in all corals. We estimate the effects of cement inclusion on climate estimates from drilled coral samples, which combine cements and primary coral aragonite. Secondary 1% calcite or ∼2% aragonite cement contamination significantly affects Sr/Ca SST estimates by +1 °C and −0.4 to −0.9 °C, respectively. Cement inclusion also significantly affects Mg/Ca, B/Ca and U/Ca SST estimates in some corals. X-ray diffraction (XRD) will not detect secondary aragonite cements and significant calcite contamination may be below the limit of detection (∼1%) of the technique. Thorough petrographic examination of fossils is therefore essential to confirm that they are pristine before bulk drilled samples are analysed. To confirm that the geochemistry of the original coral structures is not affected by the precipitation of cements in adjacent pore spaces we analysed the primary coral aragonite in cemented and uncemented areas of the skeleton. Sr/Ca, B/Ca and U/Ca of primary coral aragonite is not affected by the presence of cements in adjacent interskeletal pore spaces i.e. the coral structures maintain their original composition and selective SIMS analysis of these structures offers a route to the reconstruction of accurate SSTs from altered coral skeletons. However, Mg/Ca and Ba/Ca of primary coral aragonite are significantly higher in parts of skeletons infilled with high Mg calcite cement. We hypothesise this reflects cement infilling of intraskeletal pore spaces in the primary coral structure.  相似文献   

Discordant RbSr and PbPb whole rock isochron ages for the Archaean basement of Sierra Leone     

R.D. Beckinsale  N.H. Gale  R.J. Pankhurst  A. Macfarlane  M.J. Crow  J.W. Arthurs  A.F. Wilkinson 《Precambrian Research》1980,13(1):63-76

Field mapping and structural studies in northern Sierra Leone by an I.G.S. team have established a stratigraphic sequence in this part of the Archaean of the West African Craton. An older “Leonian” granite-greenstone terrain is identified which experienced a tectonic-metamorphic event before the formation of the granite-greenstone terrain which ended with the Liberian tectonic-metamorphic event. Granite gneisses in the Fadugu district with Leonian structures yield statistically acceptable but discordant Pb-Pb and Rb-Sr whole-rock isochron ages of 2959±50 Ma and 2753±61 Ma, respectively (2 σ errors). These ages may be correlated with radiometric ages for the Leonian and Liberian structures elsewhere in Sierra Leone, and it is concluded that the Fadugu Rb-Sr whole-rock isochron has been reset by the Liberian event. The Pb-Pb whole-rock isochron for the Fadugu gneisses and a previously determined (but recomputed and partially checked) Rb-Sr whole-rock isochron age of 2980+80 Ma for granite gneisses from southeastern Sierra Leone provide a definitive age for the Leonian tectonic-metamorphic event at about 2970 Ma. Both the initial ⁸⁷Sr/⁸⁶Sr ratios and present-day first-stage model ²³⁸U/²⁰⁴Pb value for the Leonian granitoids are indistinguishable from mantle values, but do not preclude the possibility that these granitoids were derived from parental material with a short history in the crust or lower crust. The Rb-Sr whole-rock isochron age of 2753+61 Ma for the Fadugu granite gneiss provides a definitive age for the Liberian event in northern Sierra Leone. A succession of rocks older than the Leonian (i.e., older than 2970 Ma) has been identified in the field but not yet dated.  相似文献   

Climate Change Impacts for the Conterminous USA: An Integrated Assessment     

Allison?M.?ThomsonEmail author  Norman?J.?Rosenberg  R.?Cesar?Izaurralde  Robert?A.?Brown 《Climatic change》2005,69(1):27-41

As carbon dioxide and other greenhouse gasses accumulate in the atmosphere and contribute to rising global temperatures, it is important to examine how a changing climate may affect natural and managed ecosystems. In this series of papers, we study the impacts of climate change on agriculture, water resources and natural ecosystems in the General Circulation Model (GCM)-derived climate change projections, described in Part 1, to drive the crop production and water resource models EPIC (Erosion Productivity Impact Calculator) and HUMUS (Hydrologic Unit Model of the United States). These models are described and validated in this paper using historical crop yields and streamflow data in the conterminous United States in order to establish their ability to accurately simulate historical crop and water conditions and their capability to simulate crop and water response to the extreme climate conditions predicted by GCMs. EPIC simulated grain and forage crop yields are compared with historical crop yields from the US Department of Agriculture (USDA) and with yields from agricultural experiments. EPIC crop yields correspond more closely with USDA historical county yields than with the higher yields from intensively managed agricultural experiments. The HUMUS model was validated by comparing the simulated water yield from each hydrologic basin with estimates of natural streamflow made by the US Geological Survey. This comparison shows that the model is able to reproduce significant observed relationships and capture major trends in water resources timing and distribution across the country.  相似文献   

Climate Change Impacts for the Conterminous USA: An Integrated Assessment     

Allison?M.?ThomsonEmail author  Norman?J.?Rosenberg  R.?Cesar?Izaurralde  Robert?A.?Brown 《Climatic change》2005,69(1):89-105

During this century global warming will lead to changes in global weather and climate, affecting many aspects of our environment. Agriculture is the sector of the United States economy most likely to be directly impacted by climatic changes. We have examined potential changes in dryland agriculture (Part 3) and in water resources necessary for crop production (Part 4) in response to a set of climate change scenarios. In this paper we assess to what extent, under these same scenarios, water supplies will be sufficient to meet the irrigation requirement of major grain crops in the US. In addition, we assess the overall impacts of changes in water supply on national grain production. We apply the 12 climate change scenarios described in Part 1 to the water resources and crop growth simulation models described in Part 2 for the conterminous United States. Drawing on data from Parts 3 and 4 we calculate what the aggregate national production would be in those regions in which grain crops are currently produced by applying irrigation where needed and water supplies allow. The total amount of irrigation water applied to crops declines under all climate change scenarios employed in this study. Under certain of the scenarios and in particular regions, precipitation decreases so much that water supplies are too limited; in other regions precipitation becomes so plentiful that little value is derived from irrigation. Nationwide grain crop production is greater when irrigation is applied as needed. Under irrigation, less corn and soybeans are produced under most of the climate change scenarios than is produced under baseline climate conditions. Winter wheat production under irrigation responds significantly to elevated atmospheric carbon dioxide concentrations [CO₂] and appears likely to increase under climate change.  相似文献