LMWOA (low molecular weight organic acid) exudation by salt marsh plants: Natural variation and response to Cu contamination     

Ana P. Mucha  C. Marisa R. Almeida  Adriano A. Bordalo  M. Teresa S.D. Vasconcelos 《Estuarine, Coastal and Shelf Science》2010

This work aimed to evaluate, in vitro, the capability of roots of two salt marsh plants to release low molecular weight organic acids (LMWOAs) and to ascertain whether Cu contamination would stimulate or not organic acids exudation. The sea rush Juncus maritimus and the sea-club rush Scirpus maritimus, both from the lower Douro river estuary (NW Portugal), were used. Plants were collected seasonally, four times a year in 2004, during low tide. After sampling, plant roots were washed for removal of adherent particles and immersed for 2 h in a solution that matched salinity (3) and pH (7.5) of the pore water from the same location to obtain plant exudates. In one of the seasons, similar experiments were carried out but spiking the solution with different amounts of Cu in order to embrace the range between 0 and 1600 nM. In the final solutions as well as in sediment pore water LMWOAs were determined by high performance liquid chromatography. Plants were able to release, in a short period of time, relatively high amounts of LMWOAs (oxalate, citrate, malate, malonate, and succinate). In the sediment pore water oxalate, succinate and acetate were also detected. Therefore, plant roots probably contributed to the presence of some of these organic compounds in pore water. Exudation differed between the plant species and also showed some seasonally variation, particularly for S. maritimus. The release of oxalate by J. maritimus increased with Cu increase in the media. However, exudation of the other LMWOAs did not seem to be stimulated by Cu contamination in the media. This fact is compatible with the existence of alternative internal mechanisms for Cu detoxification, as denoted by the fact that in media contaminated with Cu both plant species accumulated relatively high amounts (29–83%) of the initially dissolved Cu. This study expands our knowledge on the contribution of globally dominant salt marsh plants to the release of LMWOAs into the environment.  相似文献   

Palaeoceanographic changes in the North Atlantic during the Mid‐Pleistocene Transition (MIS 31–19) as inferred from planktonic foraminiferal and calcium carbonate records     

Iván Hernández‐Almeida  Francisco Javier Sierro  José‐Abel Flores  Isabel Cacho  Gabriel Michael Filippelli 《Boreas: An International Journal of Quaternary Research》2013,42(1):140-159

Marine sediments from the Integrated Ocean Drilling Project (IODP) Site U1314 (56.36°N, 27.88°W), in the subpolar North Atlantic, were studied for their planktonic foraminifera, calcium carbonate content, and Neogloboqudrina pachyderma sinistral (sin.) δ¹³C records in order to reconstruct surface and intermediate conditions in this region during the Mid‐Pleistocene Transition (MPT). Variations in the palaeoceanography and regional dynamics of the Arctic Front were estimated by comparing CaCO₃ content, planktonic foraminiferal species abundances, carbon isotopes and ice‐rafted debris (IRD) data from Site U1314 with published data from other North Atlantic sites. Site U1314 exhibited high abundances of the polar planktonic foraminifera N. pachyderma sin. and low CaCO₃ content until Marine Isotope Stage (MIS) 26, indicating a relatively southeastward position of the Arctic Front (AF) and penetration of colder and low‐salinity surface arctic water‐masses. Changing conditions after MIS 25, with oscillations in the position of the AF, caused an increase in the northward export of the warmer North Atlantic Current (NAC), indicated by greater abundances of non‐polar planktonic foraminifera and higher CaCO₃. The N. pachyderma sin. δ¹³C data indicate good ventilation of the upper part of the intermediate water layer in the eastern North Atlantic during both glacial and interglacial stages, except during Terminations 24/23, 22/21 and 20/1. In addition, for N. pachyderma (sin.) we distinguished two morphotypes: non‐encrusted and heavily encrusted test. Results indicate that increases in the encrusted morphotype and lower planktonic foraminiferal diversity are related to the intensification of glacial conditions (lower sea‐surface temperatures, sea‐ice formation) during MIS 22 and 20.  相似文献   

Contribution to the crystal chemistry of beryl     

H. de Almeida Sampaio Filho  G. P. Sighinolfi  E. Galli 《Contributions to Mineralogy and Petrology》1973,38(4):279-290

Chemical analyses and crystallographic and some optical data have been obtained for 28 samples of beryl from Bahia State, Brazil. The larger range of variability in the chemical composition is shown by Mg, Fe and Li. Sodium is the more diffuse alkali element. Potassium is always very limited. Calcium appears in noticeable amounts only in three samples. The Ti, Cr, Rb, and Cs elements were also tested. The samples studied here can be defined as sodium-potassium beryls with low alkali content. Unit cell parameters show the following ranges: a=9.210–9.245 and c=9.190–9.220 Å. From a statistical analysis of these data it may be seen that: an increase of Fe and (Fe+Mn+Mg) percentage has a positive correlation with a, but no influence on c, which in turn has a close positive correlation with Li and is negatively correlated with Be. Less negative correlations also exist between the pairs {Be, Li}, {a,Al}, {Al, Fe} and {Al, (Fe+Mn+Mg)}. A positive correlation also exists between sodium and the parameter a.  相似文献   

A hyperspectral experiment over tropical forests based on the EO-1 orbit change and PROSAIL simulation     

Lênio Soares Galvão  Alana Almeida de Souza  Fábio Marcelo Breunig 《地理信息系统科学与遥感》2020,57(1):74-90

ABSTRACT

We designed a unique hyperspectral experiment from the Earth Observing One (EO-1) orbit change to evaluate solar illumination effects over tropical forests in Brazil. Ten nadir-viewing Hyperion images collected over a fixed site and period of the year (July to August) were selected for analysis. We evaluated variations in reflectance and in 16 narrowband vegetation indices (VIs) with increasing solar zenith angle (SZA) from the pre-drift (2004–2008) to the EO-1 drift period (2011–2016). To detect changes in reflectance and shadows, we applied spectral mixture analysis (SMA) and principal component analysis (PCA) and calculated the similarity spectral angle (θ) between the vegetation spectra measured with variable SZA. The magnitude of the illumination effects was also evaluated from change-point analysis and nonparametric Mann-Whitney U tests applied over the time series. Finally, we complemented our experiment using the PROSAIL model to simulate the VIs variation with increasing SZA resultant from satellite drift. The results showed significant changes in Hyperion reflectance and VIs, especially when the EO-1 crossed the study area at earlier times and larger SZA in 2015 (9:05 a.m.; SZA = 59°) and 2016 (8:30 a.m.; SZA = 67°). Compared to the pre-drift period (10:30 a.m.; SZA = 45°), the SZA differences of 14° (2015) and 22° (2016) increased the shade fractions and decreased the vegetation brightness. PCA separated the pre-drift and drift reflectance datasets, showing shifts in scores due to changes in brightness. θ increased with SZA, indicating changes in the shape of the vegetation spectra with drift. For most VIs, the change-point analysis indicated 2015 (SZA = 59°) as the predominant year of detected changes. Compared to the EO-1 original orbit, the Plant Senescence Reflectance Index (PSRI), Anthocyanin Reflectance Index (ARI) and Structure Insensitive Pigment Index (SIPI) presented the largest positive changes during drift, while the Photochemical Reflectance Index (PRI), Visible Atmospherically Resistant Index (VARI) and Enhanced Vegetation Index (EVI) had the largest negative changes. The effect size of the illumination geometry on these VIs was large, as indicated by increasing values of the Cohen’s r metric toward 2016. The anisotropy of the Hyperion VIs was generally consistent with that from PROSAIL in the simulated pre-drift and drift periods. Focusing on structural indices, it affected the relationships between VIs and simulated leaf area index (LAI) at large SZA.  相似文献   

Effects of trace metal and exposure to air on serotonin and dopamine levels in tissues of the mussel Perna perna   总被引：1，自引：0，他引：1  

Almeida EA  Bainy AC  Medeiros MH  Di Mascio P 《Marine pollution bulletin》2003,46(11):1485-1490

We evaluated levels of serotonin (5HT) and dopamine (DOPA) in muscle and digestive glands of the mussel, Perna perna, collected at different times of day; exposed to air for 24 h, followed by re-submersion; and after exposure to different metals. Mussels collected at different periods of day showed little oscillation in 5HT and DOPA levels. Mussels exposed to metals showed significant changes in 5HT and DOPA levels in digestive gland and muscle, as did mussels exposed to air. Our data suggest that analyses of 5HT and DOPA in tissues of mussels could serve as a tool to evaluate the presence and effects of heavy metal contamination in mussels. Care in data interpretation is required, however, since other environmental factors such as exposure of mussels to air (i.e. at low tides) can also cause changes in DOPA and 5HT levels. Additional research is necessary to separate such natural environmental effects from effects of contaminants.  相似文献   

An audio-magnetotelluric investigation in Terceira Island (Azores)   总被引：2，自引：0，他引：2  

Fernando A. Monteiro Santos  Antnio Trota  Antnio Soares  Rafael Luzio  Nuno Loureno  Liliana Matos  Eugnio Almeida  Joo L. Gaspar  Jorge M. Miranda 《Journal of Applied Geophysics》2006,59(4):314-323

Ten audio-magnetotelluric soundings have been carried out along a profile crossing the Serra do Cume caldera in the eastern part of the Terceira Island (Azores). The main objectives of this investigation were to detect geoelectrical features related with tectonic structures and to characterize regional hydrological and hydrothermal aspects mainly those related to geothermal fluid dynamics.Three-dimensional numerical investigation showed that the data acquired at periods shorter than 1 s are not significantly affected by ocean effect. The data was analysed using the Smith's decomposition method in order to investigate possible distortions caused by superficial structures and to estimate a global regional strike. The results suggest that in general the soundings were not distorted. A regional N55°W strike was chosen for the two-dimensional data inversion.The low-resistivity zones (10–30 ohm-m) displayed in the central part of the 2-D geoelectrical model have been interpreted as caused by hydrothermal circulation. The low-resistivity anomalies at the ends of the profile might be attributed to alteration zones with interaction of seawater intrusion. High-resistivity (> 300 ohm-m) values have been related with less permeable zones in the SW of Cinco Picos and Guilherme Moniz caldera walls.  相似文献   

The continental record of Ediacaran volcano‐sedimentary successions in southern Brazil and their global implications     

Liliane Janikian  Renato Paes De Almeida  Ricardo Ivan Ferreira Da Trindade  Antonio Romalino Santos Fragoso‐Cesar  Manoel Souza D′Agrella‐Filho  Elton Luis Dantas  Eric Tohver 《地学学报》2008,20(4):259-266

The Ediacaran is one of the most important periods on Earth evolution, including the first appearance of soft‐bodied macrofossils, major climatic changes and a supposed rise in free oxygen. In southernmost Brazil, this period is represented by Camaquã Supergroup, including the Bom Jardim Group and the Acampamento Velho Formation, both of which record continental palaeoenvironmental changes in a more than 5000 m thick stratigraphic succession. Age constraints are given by seven Ar‐Ar and U‐Pb determinations on volcanic rocks, which bracket these units between c. 605 and 574 Ma, revealing the best dated and most continuous documented Ediacaran continental succession to date. Depositional systems evolution supports a Phanerozoic‐type glacial context during the last Neoproterozoic glacial event and presents the Picada das Graças Formation (580 ± 3.6 Ma) as the first dated non‐glacial unit coeval to the Gaskiers Formation.  相似文献   

Nondestructive determination of the physical properties of Antarctic meteorites: Importance for the meteorite—parent body connection     

T. A. Harvey  J. L. MacArthur  K. H. Joy  D. Sykes  N. V. Almeida  R. H. Jones 《Meteoritics & planetary science》2023,58(12):1707-1746

Photogrammetry is a low-cost, nondestructive approach for producing 3-D models of meteorites for the purpose of determining sample bulk density. Coupled with the use of a nondestructive magnetic susceptibility/electrical conductivity field probe, we present measurements for the interrogation of several physical properties, on a set of Antarctic meteorites. Photogrammetry is an effective technique over a range of sample sizes, with meteorite bulk density results that are closely comparable with literature values, determined using Archimedean glass bead or laser scanning techniques. The technique is completely noncontaminating and suitable for the analysis of rare or fragile samples, although there are limitations for analyzing reflective samples. It is also flexible, and, with variations in equipment setup, may be appropriate for samples of a wide range of sizes. X-ray computed tomography analyses of the same meteorite samples yielded slightly different bulk density results, predominantly for samples below 10 g, although the reason for this is unclear. Such analyses are expensive and potentially damaging to certain features of the sample (e.g., organic compounds), but may be useful in expanding the measurements to accommodate an understanding of internal voids within the sample, lending itself to measurement of grain density. Measurements of bulk density are valuable for comparisons with estimates of the bulk densities of asteroids that are suggested as meteorite parent bodies.  相似文献   

Mathiasite-loveringite and priderite in mantle xenoliths from the Alto Paranaíba Igneous Province,Brazil: genesis and constraints on mantle metasomatism     

Vidyã V. Almeida  Valdecir de A. Janasi  Darcy P. Svisero  Felix Nannini 《Central European Journal of Geosciences》2014,6(4):614-632

Alkali-bearing Ti oxides were identified in mantle xenoliths enclosed in kimberlite-like rocks from Limeira 1 alkaline intrusion from the Alto Paranaíba Igneous Province, southeastern Brazil. The metasomatic mineral assemblages include mathiasite-loveringite and priderite associated with clinopyroxene, phlogopite, ilmenite and rutile. Mathiasite-loveringite (55–60 wt.% TiO₂; 5.2–6.7 wt.% ZrO₂) occurs in peridotite xenoliths rimming chromite (～50 wt.% Cr₂O₃) and subordinate ilmenite (12–13.4 wt.% MgO) in double reaction rim coronas. Priderite (Ba/(K+Ba)< 0.05) occurs in phlogopite-rich xenoliths as lamellae within Mg-ilmenite (8.4–9.8 wt.% MgO) or as intergrowths in rutile crystals that may be included in sagenitic phlogopite. Mathiasite-loveringite was formed by reaction of peridotite primary minerals with alkaline melts. The priderite was formed by reaction of peridotite minerals with ultrapotassic melts. Disequilibrium textures and chemical zoning of associated minerals suggest that the metasomatic reactions responsible for the formation of the alkali-bearing Ti oxides took place shortly prior the entrainment of the xenoliths in the host magma, and is not connected to old (Proterozoic) mantle enrichment events.  相似文献   

On the Use of Random Material in Dam Cores: Case of the Manso Dam,Brazil     

Ferreira  Breno S.  Almeida  Marcio S. S.  Lopes  Francisco R.  Reis Cavalcanti  Maria do Carmo  Pires Filho  Celso José 《Geotechnical and Geological Engineering》2022,40(4):1973-1987

Geotechnical and Geological Engineering - The Manso Dam, in the Brazilian State of Mato Grosso, intended for flood control and electricity generation, was built by a state-owned energy company in...  相似文献