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21.
Amandine Courdouan Iso Christl Sbastien Meylan Paul Wersin Ruben Kretzschmar 《Applied Geochemistry》2007,22(12):2926
Dissolved organic matter (DOM) from the Opalinus Clay, a potential host rock for the disposal of radioactive waste, was isolated under strictly anoxic conditions from ground rock material and compared with DOM of in situ pore water samples. For the extractions, deionized water, synthetic pore water (SPW, water containing all major ions at pore water concentrations but no organic matter) and 0.1 M NaOH were used. The influence of the solid-to-liquid ratio, extraction time, acid-pretreatment and O2 exposure of the rock material on the isolated DOM were investigated. Liquid chromatography coupled with a total organic C detector (LC-OCD) and reverse-phase ion chromatography were used to characterize the DOM size distributions and to determine the low molecular weight organic acid (LMWOA) contents in the pore water samples and the rock extracts.The results revealed that only a small portion of the total organic C of the rock material (<0.38%) was extractable, even after removal of carbonates by acid-pretreatment. The concentrations of dissolved organic C (DOC) were found to range from 3.9 ± 0.4 to 8.0 ± 0.8 mg/L in the anoxic extracts. The pore waters exhibited similar DOC concentrations ranging from 1.2 to 15.8 ± 0.5 mg/L. The analysis by LC-OCD showed that the DOM extracted under anoxic conditions and the pore water DOM mainly consisted of hydrophilic compounds of less than 500 Da. The DOM extracted with SPW was most similar in size to the pore water DOM. Grinding the rock under oxic conditions increased the DOC yields and shifted the size distribution toward higher molecular weight compounds compared to the strictly anoxic treatment. Acetate, lactate and formate were identified in all extracts and in the pore water. In total, LMWOA accounted for 36% of the total DOC in both pore water and SPW extracts. The results imply that controlled anoxic conditions and the use of SPW as an extractant are required to isolate DOM from Opalinus Clay rocks which most resembles the in situ pore water DOM with respect to its size distribution and the LMWOA contents. 相似文献
22.
Amandine Cozic Eric Viollier Jean-François Chiffoleau Joël Knoery Emmanuelle Rozuel 《Estuaries and Coasts》2008,31(6):1063-1071
Concentrations of volatile hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary
(France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved
metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum
concentrations were 0.80 nM for H2S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the
five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver–VRSC conditional stability
constants. Major interactions were observed between H2S and Ag, which may partially account for the absence of volatile H2S at the lowest salinities. OCS, MeSH, and DMS did not interact with Ag, as revealed by their insignificant K′ values. Variations in concentrations along the salinity gradient may be explained by the influence of phytoplanktonic compounds. 相似文献
23.
Elena Ortu Odile Peyron Amandine Bordon Jacques Louis de Beaulieu Consolata Siniscalco Rosanna Caramiello 《Quaternary International》2008,190(1):71
The high topographic complexity of the Alpine region is the origin of important climate differences that characterise the different areas of the Alps. These differences might have had a strong influence on vegetation and on migrations of human populations in the past. Based on an improved database containing about 3000 modern pollen samples, the standard “Modern Analogue Technique” has been applied to five pollen sequences from the subalpine belt of the South-western Italian Alps (Laghi dell’Orgials, 2240 m, Lago delle Fate, 2130 m, Torbiera del Biecai, 1920 m, Rifugio Mondovì, 1760 m, Pian Marchisio, 1624 m) to provide quantitative climate estimates for the Lateglacial and Holocene periods. Consistent climate trends are reconstructed for the different sequences. Sites recorded in detail the climate variations when they were located at the limit of two ecotones. Sites above the tree line recorded lower temperature values and less important variations. Climate was cold and dry during the Oldest and Younger Dryas and close to present-day values during the Bølling/Allerød interstadial. At the beginning of the Holocene, climate changed to warmer and moister conditions; a high number of climate fluctuations are recorded at several sites. A climate optimum is recorded in the Atlantic period, which caused a development of fir above its present-day altitudinal distribution. Climatic differences recorded at the various sites are discussed taking into account the limits of the method. 相似文献
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25.
Collignon A Hecq JH Glagani F Voisin P Collard F Goffart A 《Marine pollution bulletin》2012,64(4):861-864
Neustonic microplastic and zooplankton abundance was determined in the North Western Mediterranean Sea during a summer cruise between July 9th and August 6th 2010, with a break between July 22 th and 25th due to a strong wind event. Ninety percent of the 40 stations contained microplastic particles (size 0.3-5mm) of various compositions: e.g., filaments, polystyrene, thin plastic films. An average concentration of 0.116 particles/m(2) was observed. The highest abundances (>0.36 particles/m(2)) were observed in shelf stations. The neustonic plastic particles concentrations were 5 times higher before than after the strong wind event which increased the mixing and the vertical repartition of plastic particles in the upper layers of the water column. The values rise in the same order of magnitude than in the North Pacific Gyre. The average ratio between microplastics and mesozooplankton weights was 0.5 for the whole survey and might induce a potential confusion for zooplankton feeders. 相似文献