Influence of biogenic Fe(II) on the extent of microbial reduction of Fe(III) in clay minerals nontronite, illite, and chlorite     

Deb P. Jaisi  Chongxuan Liu 《Geochimica et cosmochimica acta》2007,71(5):1145-1158

Microbial reduction of Fe(III) in clay minerals is an important process that affects properties of clay-rich materials and iron biogeochemical cycling in natural environments. Microbial reduction often ceases before all Fe(III) in clay minerals is exhausted. The factors causing the cessation are, however, not well understood. The objective of this study was to assess the role of biogenic Fe(II) in microbial reduction of Fe(III) in clay minerals nontronite, illite, and chlorite. Bioreduction experiments were performed in batch systems, where lactate was used as the sole electron donor, Fe(III) in clay minerals as the sole electron acceptor, and Shewanella putrefaciens CN32 as the mediator with and without an electron shuttle (AQDS). Our results showed that bioreduction activity ceased within two weeks with variable extents of bioreduction of structural Fe(III) in clay minerals. When fresh CN32 cells were added to old cultures (6 months), bioreduction resumed, and extents increased. Thus, cessation of Fe(III) bioreduction was not necessarily due to exhaustion of bioavailable Fe(III) in the mineral structure, but changes in cell physiology or solution chemistry, such as Fe(II) production during microbial reduction, may have inhibited the extent of bioreduction. To investigate the effect of Fe(II) inhibition on CN 32 reduction activity, a typical bioreduction process (consisting of lactate, clay, cells, and AQDS in a single tube) was separated into two steps: (1) AQDS was reduced by cells in the absence of clay; (2) Fe(III) in clays was reduced by biogenic AH₂DS in the absence of cells. With this method, the extent of Fe(III) reduction increased by 45-233%, depending on the clay mineral involved. Transmission electron microscopy observation revealed a thick halo surrounding cell surfaces that most likely resulted from Fe(II) sorption/precipitation. Similarly, the inhibitory effect of Fe(II) sorbed onto clay surfaces was assessed by presorbing a certain amount of Fe(II) onto clay surfaces followed by AH₂DS reduction of Fe(III). The reduction extent consistently decreased with an increasing amount of presorbed Fe(II). The relative reduction extent [i.e., the reduction extent normalized to that when the amount of presorbed Fe(II) was zero] was similar for all clay minerals studied and showed a systematic decrease with an increasing clay-presorbed Fe(II) concentration. These results suggest a similar inhibitory effect of clay-sorbed Fe(II) for different clay minerals. An equilibrium thermodynamic model was constructed with independently estimated parameters to evaluate whether the observed cessation of Fe(III) reduction by AH₂DS was due to exhaustion of reaction free energy. Model-calculated reduction extents were, however, over 50% higher than experimentally measured, indicating that other factors, such as blockage of the electron transfer chain and mineralogy, restricted the reduction extent. Another important result of this study was the relative reducibility of Fe(III) in different clays: nontronite > chlorite > illite. This order was qualitatively consistent with the differences in the crystal structure and layer charge of these minerals.  相似文献   

Natural vibrations of shear wall buildings on flexible supports     

A. Coull  P. R. Mukherjee 《地震工程与结构动力学》1978,6(3):295-316

A shear wall building is considered as an assembly of plane and curvilinear shear walls tied together by floor slabs to act as a composite unit. Based on this conception and the continuous medium approach, the governing dynamic equations and boundary conditions are derived from energy principles, using Vlasov's theory of thin-walled beams. All primary and secondary inertia forces, as well as the influence of elastic foundation flexibility, have been taken into consideration. A numerical solution of the dynamic equations is achieved by employing the Ritz-Galerkin technique, yielding both natural frequencies and mode shapes. The technique is applicable to buildings containing coupled and non-coupled, open section shear walls oriented in plan in any arbitrary manner. The use of the method is illustrated by the example of a complex building with unsymmetric plan, and the analytical natural frequencies of two shear wall building models are compared with those obtained experimentally by other investigators.  相似文献   

Some thermodynamical and microphysical aspects of monsoon clouds     

A Mary Selvam  A S Ramachandra Murty  R Vijayakumar  S K Paul  G K Manohar  R S Reddy  B K Mukherjee  Bh. V. Ramana Murty 《Journal of Earth System Science》1980,89(2):215-230

The thermodynamical and microphysical characteristics of monsoon clouds in the Poona, Bombay and Rihand regions were investigated using extensive aircraft in-cloud observations. The number of clouds sampled at Poona, Bombay and Rihand is 2199, 169 and 104 respectively. The temperatures inside the cloud are colder than its environment at Poona and Rihand. The maximum difference is about 3°C at the cloud base level and the difference decreased with height. At Bombay the difference is less than 1°C and at some levels the temperatures inside the cloud are warmer than its environment. The lapse rates of temperatures inside the cloud are slightly less than those in the immediate environment of the cloud. The environmental lapse rates are nearly equal to the saturated adiabatic value. The positive increments in liquid water content (LWC) are associated with the increments in temperature inside the cloud. Similarly positive increments in temperatures inside the cloud are associated with the increments in temperature of its immediate environment at the same level or the layer immediately above. The maximum cloud lengths observed at Poona and Bombay respectively are 14 and 3 km. The horizontal cross-section of LWC showed a maximum number of 13 peaks in clouds at Poona while only 7 peaks were observed at Bombay. The location of maximum LWC in the horizontal cross-section is more or less at the centre of the cloud. The LWC profile showed an increase with height from the base of the cloud at Poona and Bombay. There is no marked variation of LWC with height at Rihand. The total droplet concentration at different altitudes at Poona and Bombay is in the range 28–82 cm^?3. The size distribution of cloud droplets experienced a broadening effect with increase in height from the cloud base at Poona. The broadening effect at Bombay is not as marked as that at Poona.  相似文献   

Discussion     

S. Mukherjee  K. L. Chakraborty 《Mineralium Deposita》1974,9(1):91-92

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Tracking Galaxy Evolution Through Low-Frequency Radio Continuum Observations using SKA and Citizen-Science Research using Multi-Wavelength Data     

Ananda Hota  C. Konar  C. S. Stalin  Sravani Vaddi  Pradeepta K. Mohanty  Pratik Dabhade  Sai Arun Dharmik Bhoga  Megha Rajoria  Sagar Sethi 《Journal of Astrophysics and Astronomy》2016,37(4):41

We present a brief review of progress in the understanding of general spiral and elliptical galaxies, through merger, star formation and AGN activities. With reference to case studies performed with the GMRT, we highlight the unique aspects of studying galaxies in the radio wavelengths where powerful quasars and bright radio galaxies are traditionally the dominating subjects. Though AGN or quasar activity is extremely energetic, it is extremely short-lived. This justify focussing on transitional galaxies to find relic-evidences of the immediate past AGN-feedback which decide the future course of evolution of a galaxy. Relic radio lobes can be best detected in low frequency observations with the GMRT, LOFAR and in future SKA. The age of these relic radio plasma can be as old as a few hundred Myr. There is a huge gap between this and what is found in optical bands. The very first relic-evidences of a past quasar activity (Hanny’s Voorwerp) was discovered in 2007 by a Galaxy Zoo citizen-scientist, a school teacher, in the optical bands. This relic is around a few tens of thousand years old. More discoveries needed to match these time-scales with star formation time-scales in AGN host galaxies to better understand black hole galaxy co-evolution process via feedback-driven quenching of star formation. It is now well-accepted that discovery and characterization of such faint fuzzy relic features can be more efficiently done by human eye than a machine. Radio interferometry images are more complicated than optical and need the citizen-scientists to be trained. RAD@home, the only Indian citizen-science research project in astronomy, analysing TIFR GMRT Sky Survey (TGSS) 150 MHz data and observing from the Giant Meterwave Radio Telescope (GMRT), was launched in April 2013. Unique, zero-infrastructure zero-funded design of RAD@home as a collaboratory of 69 trained e-astronomers is briefly described. Some of the new-found objects like episodic radio galaxies, radio-jet and companion galaxy interaction, radio galaxy bent by motion of the intra-filament medium in a Mpc-scale galaxy filament etc. are briefly presented as demonstration of its potential. Citizen-science has not only opened up a new way for astronomy research but also possibly the only promising way to extract maximum science out of the Big Data in the SKA-era. This possibly can convert the Big Data problem into a prospect. Citizen-science can contribute to the knowledge creation in never-seen-before speed and in approach. As it is based on internet, it can provide an equal opportunity of academic-growth to people even in the under-developed regions where we always need to put our optical and radio telescopes. This can liberate the research-activity of city-based research-institutes out of the four brick walls and alleviate various socio-economic and geo-political constraints on growth of citizens educated in undergraduate-level science but located in remote areas.  相似文献   

Atmospheric motion vector retrieval using improved tracer selection algorithm     

Inderpreet Kaur  S. K. Deb  C. M. Kishtawal  P. K. Pal  Raj Kumar 《Theoretical and Applied Climatology》2015,119(1-2):299-312

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Evidence for structural discordance in the inverted metamorphic sequence of Sikkim Himalaya: Towards resolving the Main Central Thrust controversy     

Saibal Gupta  Aditi Das  Sudipta Goswami  Ananda Modak  Suman Mondal 《Journal of the Geological Society of India》2010,75(1):313-322

Inverted metamorphism in the Himalayas is closely associated with the Main Central Thrust (MCT). In the western Himalayas, the Main Central Thrust conventionally separates high grade metamorphic rocks of the Higher Himalayan Crystalline Sequence (HHCS) from unmetamorphosed rocks of the Inner sedimentary Belt. In the eastern Himalayas, the Inner sedimentary Belt is absent, and the HHCS and meta-sedimentary Lesser Himalayan Sequence (LHS) apparently form a continuous Barrovian metamorphic sequence, leading to confusion about the precise location of the MCT. In this study, it is demonstrated that migmatitic gneisses of the sillimanite zone in the higher structural levels of the HHCS are multiply deformed, with two phases of penetrative fabric formation (S_1HHCS and S_2HHCS) followed by third folding event associated with a spaced, NW-SE trending, north-east dipping foliation (S_3HHCS). The underlying LHS schists (kyanite zone and lower) are also multiply deformed, with the bedding S₀ being isoclinally folded (F_1LHS), and subsequently refolded (F_2LHS and F_3LHS). The contact zone between the HHCS and LHS is characterized by ductile, top-to-the southwest shearing and stabilization of a pervasive foliation that is consistently oriented NW-SE and dips northeast. This foliation is parallel to the S_3HHCS foliation in the HHCS, and the S_2LHS in the LHS. Early lineations in the HHCS and LHS also show different dispersions across the contact shear zone, implying that pre-thrusting orientations of the two units were distinct. The contact shear zone is therefore interpreted to be a plane of structural discordance, shows a shear sense consistent with thrust movement and is associated with mineral growth during Barrovian metamorphism. It may well be considered to represent the MCT in this region.  相似文献   

New record of <Emphasis Type="Italic">Plectoidothyris</Emphasis> from the Middle Jurassic Sequence of Jaisalmer Basin,Western India: Implications on the easterly brachiopod migrations     

Debahuti Mukherjee 《Journal of the Geological Society of India》2010,76(3):267-274

The Bathonian sediments of the Jaisalmer Basin, India host a terebratulide brachiopod Plectoidothyris which has been previously known from the Bajocian rocks of the Boreal Province. The sharp and prominent plication of the anterior commissure and increased length of costae separates the Jaisalmer specimens from other known species of the genus and the population represents an endemic species — Plectoidothyris jaisalmerensis. The population was only cursorily described earlier lacking in details of precise stratigraphic control and was wrongly assigned to a different genus. The present study is based on a large number of specimens from different localities with precise stratigraphic data, coupled with this some recent findings of time-diagnostic ammonites have helped determine the Plectoidothyris jaisalmerensis duration in the Jaisalmer Basin as the Late Bathonian. Presence of lower Jurassic Boreal brachiopod genera in the Middle Jurassic rocks of Ethiopian and Indo — Madagascan biogeographic provinces has been noticed earlier whereto Plectoidothyris is a new addition while it is also the first report of the genus from the Jurassic of India. The brachiopod migrations from the north to south of the Tethys provide evidences for opening of shallow water routes in the Tethyan seaway and are probably indicative of warmer water conditions in the Indo-Madagascan and African areas during the Middle Jurassic.  相似文献   

Extended Finite Element Method for the Analysis of Discontinuities in Rock Masses   总被引：1，自引：0，他引：1  

Debasis Deb  Kamal C. Das 《Geotechnical and Geological Engineering》2010,28(5):643-659

The strength and deformability of rock mass primarily depend on the condition of joints and their spacing and partially on the engineering properties of rock matrix. Till today, numerical analysis of discontinuities e.g. joint, fault, shear plane and others is conducted placing an interface element in between two adjacent rock matrix elements. However, the applicability of interface elements is limited in rock mechanics problems having multiple discontinuities due to its inherent numerical difficulties often leading to non-convergent solution. Recent developments in extended finite element method (XFEM) having strong discontinuity imbedded within a regular element provide an opportunity to analyze discrete discontinuities in rock masses without any numerical difficulties. This concept is based on partition of unity principle and can be used for cohesive rock joints. This paper summarizes the mathematical frameworks for the implementation of strong discontinuities in 3 and 6 nodded triangular elements and also provides numerical examples of the application of XFEM in one and two dimensional problems with single and multiple discontinuities.  相似文献   

Groundwater recharge in natural dune systems and agricultural ecosystems in the Thar Desert region, Rajasthan, India   总被引：2，自引：1，他引：1  

Bridget R. Scanlon  Abhijit Mukherjee  John Gates  Robert C. Reedy  Amarendra K. Sinha 《Hydrogeology Journal》2010,18(4):959-972

Water and nutrient availability for crop production are critical issues in (semi)arid regions. Unsaturated-zone Cl tracer data and nutrient (NO₃ and PO₄) concentrations were used to quantify recharge rates using the Cl mass balance approach and nutrient availability in the Thar Desert, Rajasthan, India. Soil cores were collected in dune/interdune settings in the arid Thar Desert (near Jaisalmer) and in rain-fed (nonirrigated) and irrigated cropland in the semiarid desert margin (near Jaipur). Recharge rates were also simulated using unsaturated zone modeling. Recharge rates in sparsely vegetated dune/interdune settings in the Jaisalmer study area are 2.7–5.6 mm/year (2–3% of precipitation, 165 mm/year). In contrast, recharge rates in rain-fed agriculture in the Jaipur study area are 61–94 mm/year (10–16% of precipitation, 600 mm/year). Minimum recharge rates under current freshwater irrigated sites are 50–120 mm/year (8–20% of precipitation). Nitrate concentrations are low at most sites. Similarity in recharge rates based on SO₄ with those based on Cl is attributed to a meteoric origin of SO₄ and generally conservative chemical behavior in these sandy soils. Modeling results increased confidence in tracer-based recharge estimates. Recharge rates under rain-fed agriculture indicate that irrigation of 20–40% of cultivated land with 300 mm/year should be sustainable.  相似文献