Molecular and isotopic partitioning of low-molecular-weight hydrocarbons during migration and gas hydrate precipitation in deposits of a high-flux seepage site     

Thomas Pape  André Bahr  Janet Rethemeyer  John D. Kessler  Heiko Sahling  Kai-Uwe Hinrichs  Stephan A. Klapp  William S. Reeburgh  Gerhard Bohrmann 《Chemical Geology》2010,269(3-4):350-363

Detailed knowledge of the extent of post-genetic modifications affecting shallow submarine hydrocarbons fueled from the deep subsurface is fundamental for evaluating source and reservoir properties. We investigated gases from a submarine high-flux seepage site in the anoxic Eastern Black Sea in order to elucidate molecular and isotopic alterations of low-molecular-weight hydrocarbons (LMWHC) associated with upward migration through the sediment and precipitation of shallow gas hydrates. For this, near-surface sediment pressure cores and free gas venting from the seafloor were collected using autoclave technology at the Batumi seep area at 845 m water depth within the gas hydrate stability zone.Vent gas, gas from pressure core degassing, and from hydrate dissociation were strongly dominated by methane (> 99.85 mol.% of ∑[C₁–C₄, CO₂]). Molecular ratios of LMWHC (C₁/[C₂ + C₃] > 1000) and stable isotopic compositions of methane (δ¹³C = ? 53.5‰ V-PDB; D/H around ? 175‰ SMOW) indicated predominant microbial methane formation. C₁/C₂₊ ratios and stable isotopic compositions of LMWHC distinguished three gas types prevailing in the seepage area. Vent gas discharged into bottom waters was depleted in methane by > 0.03 mol.% (∑[C₁–C₄, CO₂]) relative to the other gas types and the virtual lack of ¹⁴C–CH₄ indicated a negligible input of methane from degradation of fresh organic matter. Of all gas types analyzed, vent gas was least affected by molecular fractionation, thus, its origin from the deep subsurface rather than from decomposing hydrates in near-surface sediments is likely.As a result of the anaerobic oxidation of methane, LMWHC in pressure cores in top sediments included smaller methane fractions [0.03 mol.% ∑(C₁–C₄, CO₂)] than gas released from pressure cores of more deeply buried sediments, where the fraction of methane was maximal due to its preferential incorporation in hydrate lattices. No indications for stable carbon isotopic fractionations of methane during hydrate crystallization from vent gas were found. Enrichments of ¹⁴C–CH₄ (1.4 pMC) in short cores relative to lower abundances (max. 0.6 pMC) in gas from long cores and gas hydrates substantiates recent methanogenesis utilizing modern organic matter deposited in top sediments of this high-flux hydrocarbon seep area.  相似文献   

Modelling shallow landslide susceptibility: a new approach in logistic regression by using favourability assessment   总被引：2，自引：0，他引：2  

María José Domínguez-Cuesta  Montserrat Jiménez-Sánchez  Ana Colubi  Gil González-Rodríguez 《International Journal of Earth Sciences》2010,99(3):661-674

A new method for estimating shallow landslide susceptibility by combining Geographical Information System (GIS), nonparametric kernel density estimation and logistic regression is described. Specifically, a logistic regression is applied to predict the spatial distribution by estimating the probability of occurrence of a landslide in a 16 km² area. For this purpose, a GIS is employed to gather the relevant sample information connected with the landslides. The advantages of pre-processing the explanatory variables by nonparametric density estimation (for continuous variables) and a reclassification (for categorical/discrete ones) are discussed. The pre-processing leads to new explanatory variables, namely, some functions which measure the favourability of occurrence of a landslide. The resulting model correctly classifies 98.55% of the inventaried landslides and 89.80% of the landscape surface without instabilities. New data about recent shallow landslides were collected in order to validate the model, and 92.20% of them are also correctly classified. The results support the methodology and the extrapolation of the model to the whole study area (278 km²) in order to obtain susceptibility maps.  相似文献   

History of the Middle Berriasian transgression on the Jura carbonate platform: revealed by high-resolution sequence- and cyclostratigraphy (Switzerland and France)     

Jonas Tresch  André Strasser 《International Journal of Earth Sciences》2010,99(1):139-163

The Middle Berriasian deposits of the Jura platform in Switzerland and France have already been well studied in terms of high-resolution sequence stratigraphy and different orders of depositional sequences (large-, medium-, and small-scale) have been defined. The hierarchical stacking pattern of the sequences and the time span represented by the investigated interval imply that sea-level fluctuations in the Milankovitch frequency band as well as differential subsidence caused the observed changes of accommodation on the Jura platform. The present study focuses on three small-scale sequences within the transgressive interval of a large-scale sequence. The initial flooding of the platform is marked by a facies change from supra- and intertidal (Goldberg Formation) to shallow-marine subtidal deposits (Pierre Chatel Formation). Detailed logging and facies analysis of 11 sections allow recognizing small environmental changes that define elementary sequences within the well-established small-scale sequences and distinguishing between autocyclic and allocyclic processes in sequence formation. It is concluded that the small-scale sequences correspond to the 100-ka orbital eccentricity cycle, while allocyclic elementary sequences formed in tune with the 20-ka precession cycle. Based on the correlation of elementary and small-scale sequences it can be shown that the Jura platform has been flooded stepwise by repeated transgressive pulses. Differential subsidence and pre-existing platform morphology further controlled sediment accumulation and distribution during the transgression. The combination of high-resolution sequence stratigraphy and cyclostratigraphy then enables the reconstruction of hypothetical palaeogeographic maps in time increments of a few ten thousand years.  相似文献   

Procedure for the selection of runout model parameters from landslide back-analyses: application to the Metropolitan Area of San Salvador, El Salvador   总被引：1，自引：1，他引：0  

José Cepeda  José Alexander Chávez  Celina Cruz Martínez 《Landslides》2010,7(2):105-116

The existing procedures for the selection of runout model parameters from back-analyses do not allow integrating different types of runout criteria and generally lack a systematic approach. A new method based on receiver operating characteristic (ROC) analyses and aimed at overcoming these limitations is herein proposed. The method consists of estimating discrete classifiers for every runout simulation associated with a set of model parameters. The set of parameters that yields the best prediction is selected using ROC metrics and space. The procedure is illustrated with the back-analyses of a rainfall-triggered debris flow that killed 300–500 people in the Metropolitan Area of San Salvador in 1982. The selected model parameters are used to estimate forward predictions for scenarios that correspond to different return periods. The proposed procedure may be useful in the assessment of areas potentially affected by landslides. In turn, this information can be used in the production or updating of land use plans and zonations, similar to that currently being carried out by the Office for Urban Planning of the Metropolitan Area of San Salvador in El Salvador.  相似文献   

Spectrometric analyses in comparison to the physiological condition of heavy metal stressed floodplain vegetation in a standardised experiment     

Christian Götze  András Jung  Ines Merbach  Rainer Wennrich  Cornelia Gläßer 《Central European Journal of Geosciences》2010,2(2):132-137

Floodplain ecosystems are affected by flood dynamics, nutrient supply as well as anthropogenic activities. Heavy metal pollution poses a serious environmental challenge. Pollution transfer from the soil to vegetation is still present at the central location of Elbe River, Germany. The goal of this study was to assess and separate the current heavy metal contamination of the floodplain ecosystem, using spectrometric field and laboratory measurements. A standardized pot experiment with floodplain vegetation in differently contaminated soils provided the basis for the measurements. The dominant plant types of the floodplains are: Urtica dioica, Phalaris arundinacea and Alopecurus pratensis, these were also chemically analysed. Various vegetation indices and methods were used to estimate the red edge position, to normalise the spectral curve of the vegetation and to investigate the potential of different methods for separating plant stress in floodplain vegetation. The main task was to compare spectral bands during phenological phases to find a method to detect heavy metal stress in plants. A multi-level algorithm for the curve parameterisation was developed. Chemo-analytical and ecophysiological parameters of plants were considered in the results and correlated with spectral data. The results of this study show the influence of heavy metals on the spectral characteristics of the focal plants. The developed method (depth CR1730) showed significant relationship between the plants and the contamination.  相似文献   

Multiple generation magmatic and hydrothermal processes in a Martian subvolcanic environment based on the analysis of Yamato-000593 nakhlite meteorite     

Ildiko Gyollai  Elias Chatzitheodoridis  Ákos Kereszturi  Máté Szabó 《Meteoritics & planetary science》2023,58(2):218-240

We studied the occurrence of secondary minerals and inferred their formation in the Yamato-000593 Martian meteorite using multiple technological approaches such as electron probe micro analysis, optical microscope, Raman spectroscopy, scanning electron microscopy, as well as Fourier transform-infrared microscopy and spectroscopy. Two separate hydrothermal alteration events and their sequence of formation (based on superpositional relationship) can be identified: an elevated temperature phase producing high-temperature sulfidic hydrothermal alteration and a lower temperature hydrothermal alteration phase by iron-rich fluids. This meteorite shows signatures more compatible with magmatic effects, rather than impact-induced hydrothermal alteration, as has been proposed earlier. The sulfidic alteration probably formed by magmatic hydrothermal fluids, whereas iron-rich hydrothermal fluid circulation after a possible early impact event has also been proposed, when the fluids cooled down to 50 °C. Most of the secondary minerals formed at alkaline-neutral conditions, and the few observed signatures (clay–silica-bearing veins, siderite-iron-oxide veins) of briny conditions are probably from local spatial effects in larger cavities. The ferrous minerals (hematite and siderite) along the fractures could be crystallized from Fe-HCO₃-bearing fluids. Alternatively, the primary magmatic minerals could have been oxidized easily (Fe-rich olivines, magnetite) during the cooling to iron oxides (hematite, goethite). The results suggest the possible existence of at least ephemerally habitable environments on Mars, mainly at volcanically heated locations. Following published geochemical models, the carbonates formed within acidic-circumneutral condition, which was followed by formation of phyllosilicates in alkaline condition.  相似文献   

Micro-XCT chondrule classification for subsequent isotope analysis     

Noah Jäggi  Antoine S. G. Roth  Miriam Rüfenacht  Maria Schönbächler  André Galli 《Meteoritics & planetary science》2023,58(7):1039-1055

Chondrules are microscopic, recrystallized melt droplets found in chondritic meteorites. High-resolution isotope analyses of minor elements require large enough element quantities which are obtained by dissolving entire chondrules. This work emphasizes the importance of X-ray computed tomography (XCT) to detect features that can significantly affect the bulk chondrule isotope composition. It thereby expands on other works by looking into chondrules from a wide range of chondrites including CR, CV, CB, CM, L, and EL samples before turning toward complex and time-consuming chemical processing. The features considered are metal and igneous rims, compound chondrules, matrix remnants, and metal contents. In addition to the identification of these features, computed tomography prevents the inclusion of non-chondrule samples (pure matrix or metal) as well as samples where two different chondrule fragments with potentially different isotope compositions are held together by matrix. Matrix surrounding chondrules is also easily detected and the affected chondrules can be omitted or reprocessed. The results strongly encourage to perform XCT before dissolution of chondrules for isotope analysis as a non-invasive method.  相似文献   

Mushroom production as an alternative for rural development in a forested mountainous area     

José A. BONET  José R. GONZáLEZ-OLABARRIA  Juan MARTíNEZ DE ARAGóN 《山地科学学报》2014,11(2):535-543

Wild mushrooms are recognized as important non-wood forest products in mountainous ecosystems, but their real potential for generating rural economies has not been fully evaluated due to the difficulties in obtaining reliable productivity data, minimizing their true potential as contributor to rural economies. Mushroom yield models based on large data series from Pinus forest ecosystems in the region of Catalonia(Spain), combined with data from the Spanish National Forest Inventory allow us to estimate the potential mushroom productivity by forest ecosystems. The results of 24,500 tons/yr of mushrooms of which 16,300 tons are classified as edible and 7,900 tons are commonly marketed demonstrate the importance of mushroom productions in Catalonian pine forests, mostly located in mountainous areas where the development of agricultural activities is limited. Economic mushroom value is estimated at 48 million € for the edible mushroom and 32 million € for those corresponding to marketable yields, confirming the potential of this non-wood forest product. These production results and corresponding economic values provide a basis for the incorporation of wild mushrooms as significant non-wood forest products in the development of forest policies in mountainous areas.  相似文献   

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest     

Kesang WANGCHUK  András DARABANT  Prem Bahadur RAI  Maria WURZINGER  Werner ZOLLITSCH  Georg GRATZER 《山地科学学报》2014,11(5):1182-1191

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.  相似文献   

Making a Mark: a computational and visual analysis of one researcher’s intellectual domain     

André Skupin 《International journal of geographical information science》2014,28(6):1209-1232

Dr. David Mark is widely regarded as a path-breaking researcher in geographic information science. What are the structural and temporal characteristics of his intellectual contributions, as seen through the eyes of the broader academic community? Aiming to answer that question, this article presents a scientometric analysis of publications that have been cited alongside David Mark’s papers. In deliberate contrast to the widespread focus on using citation data to condense scientific impact into a handful of indicators, the methodological contribution of this study lies in its mix of computational and visualization approaches. In the search for latent domain structures, state-of-the-art practices in information science, bibliometrics, and network visualization are combined and extended. An initial network of 50,000+ publications and 4,000,000+ document co-citations undergoes a series of transformations reducing it to 9000 publications that are then clustered in a two-stage process, leading to 678 communities whose co-citation linkages are used to delineate 19 super-communities. To enable replication of this approach for other studies, much focus in this article is on detailed discussion of that workflow as well as on highlighting the reasoning behind the choices made among data sources and analytical methods. The topical evolution of David Mark’s domain of influence is explored in some detail, based on tabular and graphic representations of extracted community structures. Results confirm not only the enormous overall breadth of his influence but also how lasting and recurrent it has been in some areas.  相似文献