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71.
Geochemical data are reported for samples from the flanks and floor of the southern Kenya Rift Valley in the Lake Magadi area, and from two central volcanoes located within the rift valley. Rift lavas include samples of Singaraini and Ol Tepesi basalts on the eastern flank, Kirikiti basalts from the western flank, and plateau trachytes from the rift valley floor. Central volcano samples are from Ol Esayeiti and Lenderut located on the eastern flank. The rift basalts are mildly ne-normative, moderately evolved (Mg#=0.39-0.62) alkali basalts and show an overall range in differentiation. Incompatible trace element abundances are moderately elevated (Nb=17-51; Zr=93-274; La=17-55 ppm) and show strongly coherent variations and constant inter-element ratios (e.g. Zr/Nb=4.2-5.5; Nb/Ta=17.5ǂ.4; (La/Sm)n=7.3ǃ.1); isotope ratios are restricted in range (87Sr/86Sr=0.70393-0.70436; 143Nd/144Nd=0.51272-0.51280; 206Pb/204Pb=19.87-19.92; 207Pb/204Pb=15.68-15.70; 208Pb/204Pb=39.56-39.71). Central volcano lavas are more alkaline in character and include basanite (Ol Esayeiti; Mg# >60) and hawaiite to benmoreite (Lenderut; Mg#=0.48-0.38). Incompatible element ratio are similar to those of the rift basalts, although the chondrite normalised REE patterns are steeper (La/Sm)n=17.4ǃ.2). 87Sr/86Sr (0.70358, 0.70391), 143Nd/144Nd (0.51280, 0.51267), 206Pb/204Pb (19.96,20.17), 207Pb/204Pb (15.66,15.76) and 208Pb/204Pb (39.80,40.00) ratios of Ol Esayeiti basanites are similar to the rift basalts, whereas the Lenderut lavas have unusually low143Nd/144Nd (0.512388-0.512453) ratios for their 87Sr/86Sr (0.70370-0.70481) ratios, and distinctly less radiogenic and variable Pb isotope compositions (206Pb/204Pb=17.93-19.01; 207Pb/204Pb=15.43-15.58; 208Pb/204Pb=37.91-39.14). An integrated model is developed in which the geochemical signature of the lavas is attributed to variable degrees of melting to depths within the garnet stability field, and in the presence of residual amphibole. The stability fields of these phases in P-T space indicates that the lavas must have formed within the sub-continental lithosphere rather than within the underlying ambient asthenosphere or a rising mantle plume. The subcontinental lithospheric mantle must therefore extend to a depth of at least 75 km beneath the Lake Magadi area, which contrasts with recent gravity models for the area, which infer that lithospheric mantle is absent beneath this section of the southern Kenya Rift.  相似文献   
72.
Measurements of tritium and 18O concentrations in precipitation and runoff were used to provide further insight into the groundwater storage properties of the Wimbachtal Valley, a catchment area of 33.4 km2, extending between 636 and 2713 m a.s.l. in the Berchtesgaden Alps. The catchment includes three aquifer types: a dominant porous aquifer; a fractured dolomite; a karstic limestone aquifer. Employing a simple hydrological model, information about mean transit times of environmental tracers is derived for the groundwater runoff component and several karst springs from the application of the exponential and dispersion flow models to the isotopic input and output data. The mean transit times calculated from a dispersion model with transit times of 4.1 years for 18O and 4.2 years for tritium, which agree well, allow calculation of total (mobile + stagnant) groundwater storage volume, which is equivalent to 6.6 m of water depth. Direct runoff appears negligible as in many other cases.  相似文献   
73.
Based on a decomposition of the velocity into mean flow, turbulent and wave components, momentum and hereafter a wave-energy equation is derived. It contains a turbulent energy dissipation term which is closed by applying a wave-related mixing length model and linear wave theory solutions. This closure produces a non-linear turbulent wave-energy dissipation including the wave energy in a 5/2 power law. The theory is able to predict correctly the shape of deep-water wave spectra according to Phillips' similarity law.Responsible Editor: Hans Burchard  相似文献   
74.
To prevent the recurrence of a disastrous eruption of carbon dioxide (CO2) from Lake Nyos, a degassing plan has been set up for the lake. Since there are concerns that the degassing of the lake may reduce the stability of the density stratification, there is an urgent need for a simulation tool to predict the evolution of the lake stratification in different scenarios. This paper describes the development of a numerical model to predict the CO2 and dissolved solids concentrations, and the temperature structure as well as the stability of the water column of Lake Nyos. The model is tested with profiles of CO2 concentrations and temperature taken in the years 1986 to 1996. It reproduces well the general mixing patterns observed in the lake. However, the intensity of the mixing tends to be overestimated in the epilimnion and underestimated in the monimolimnion. The overestimation of the mixing depth in the epilimnion is caused either by the parameterization of the k-epsilon model, or by the uncertainty in the calculation of the surface heat fluxes. The simulated mixing depth is highly sensitive to the surface heat fluxes, and errors in the mixing depth propagate from one year to the following. A precise simulation of the mixolimnion deepening therefore requires high accuracy in the meteorological forcing and the parameterization of the heat fluxes. Neither the meteorological data nor the formulae for the calculation of the heat fluxes are available with the necessary precision. Consequently, it will be indispensable to consider different forcing scenarios in the safety analysis in order to obtain robust boundary conditions for safe degassing. The input of temperature and CO2 to the lake bottom can be adequately simulated for the years 1986 to 1996 with a constant sublacustrine source of 18 l s–1 with a CO2 concentration of 0.395 mol l–1 and a temperature of 26 °C. The results of this study indicate that the model needs to be calibrated with more detailed field data before using it for its final purpose: the prediction of the stability and the safety of Lake Nyos during the degassing process.Responsible Editor: Hans Burchard  相似文献   
75.
Adakite-like features are recognized in the Late Miocene (~10 Ma) porphyritic intrusions of the Los Pelambres giant porphyry copper deposit, central Chile (32°S). Located within the southern portion of the flat-slab segment (28–33°S) of the Chilean Andes, the Al- and Na-rich porphyries of Los Pelambres display distinctly higher Sr/Y (~100–300) and LaN/YbN (~25–60) ratios than contemporaneous and barren magmatic units (e.g., La Gloria pluton, Cerro Aconcagua volcanic rocks) of the same Andean magmatic belt. Strong fractionation of heavy rare earth elements (HREE), absence of Eu anomalies, high Sr/Y and Zr/Sm and low Nb/Ta ratios suggest melt extraction from a garnet-amphibolite source. The Late-Miocene adakite-like porphyritic intrusions at Los Pelambres formed closely related in time and space to the subduction of the Juan Fernández Ridge (JFR) hotspot chain along the Chilean margin. Current tectonic reconstructions reveal that, at the time of formation of the Los Pelambres rocks, a W-E segment of the JFR started to subduct beneath them, producing a slow-down of a previously rapid southward migration of a NE-ridge—trench collision. These particular tectonic conditions are favorable for the origin of the Los Pelambres porphyry suite by melting of subducting young hotspot rocks under flat-slab conditions. The incorporation of crustal components into the oceanic lithopheric magma source by subduction erosion is evidenced by the Sr-Nd isotope composition of the Los Pelambres rocks different from the MORB signatures of true adakites. A close relationship apparently exists between the origin of this adakite-like magmatism and the source of the mineralization in the Los Pelambres porphyry copper deposit.Editorial handling: R.J. Goldfarb  相似文献   
76.
Prior to the 7/9/1999 MS = 5.9 Athens earthquake, regional seismicity has exhibited a power-law increase, of the form = K+A(tc - t)n, where is estimated using an expression log = cM + d and tc is the time of the culminating event. Such changes appeared after the 17/8/1999 M7.4 Izmit event. We quantified the performance of the power law vs. the null hypothesis of constant seismic release rates, by defining the curvature C as the ratio of the power law fit RMS/linear fit RMS, so that the smaller C is, the better the power law behaviour. By mapping C, we have established a critical radius of 110 km and observed that the region of correlated accelerating seismic release extended from the N. Aegean, through Euboea and Attica to the SW Peloponnese. A few days prior to the Athens event, min(C) was centred at the epicentral area and numerical simulation yielded tc = 1999.676 and predicted MS = 5.77. Seismicity rates returned to normal (quasi-constant) after the Athens event. We interpret this effect as critical point behaviour, following remote excitation of a broad area by stress redistribution due to the Izmit event which, at Athens, has triggered `premature' failure of a fault nearing its load bearing capacity. If this is correct, we have documented a case of remote earthquake triggering by another earthquake, as well as insight into the mechanisms producing it. As a corollary, we note that a large event may beget another large event in its broader region of interaction, which may be preceded by characteristic precursory seismicity changes.  相似文献   
77.
Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   
78.
A new method of estimating the fractal dimension of the percolation backbone of karst systems, which are discharged through karst springs, is presented. This method is based on the simulation of the spring by the MODKARST deterministic mathematical model. Application has been made to the Psiloritis karst formation in Crete, which feeds the periodically brackish karst spring “Almiros” in Crete. Furthermore, the estimated dimension justifies an independently determined power law that quantifies the sea intrusion into the karst system.  相似文献   
79.
This paper describes the fusion of information extracted from multispectral digital aerial images for highly automatic 3D map generation. The proposed approach integrates spectral classification and 3D reconstruction techniques. The multispectral digital aerial images consist of a high resolution panchromatic channel as well as lower resolution RGB and near infrared (NIR) channels and form the basis for information extraction.Our land use classification is a 2-step approach that uses RGB and NIR images for an initial classification and the panchromatic images as well as a digital surface model (DSM) for a refined classification. The DSM is generated from the high resolution panchromatic images of a specific photo mission. Based on the aerial triangulation using area and feature-based points of interest the algorithms are able to generate a dense DSM by a dense image matching procedure. Afterwards a true ortho image for classification, panchromatic or color input images can be computed.In a last step specific layers for buildings and vegetation are generated and the classification is updated.  相似文献   
80.
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