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We compare the canonical treatment of calcite’s dissolution rate from the literature in a closed system, particle batch reactor, with the alternative approach suggested by Truesdale (Aquat Geochem, 2015). We show that the decay of rate over time can be understood in terms of the evolution and distribution of reactive sites on the surface of these particles. We also emphasize that interpretation of observed rates must not exclude the fundamental role of crystal defects, whose importance is already implicitly reflected in the common form of rate laws in geochemistry. The empirical behavior of overall rate in closed systems, such as those described by Truesdale, may thus reflect relationships between defect centers and the generation of steps over the calcite surface (previously documented for silicates), such that below a critical free energy limit, there is insufficient driving force to open hollow cores and thus a loss of reaction mechanism. Dissolution in this very-near-equilibrium regime will be dependent on the distribution of extant steps and the energetics of new kink site nucleation. However, these sensitivities are complicated in the case of particle systems by grain boundaries, edges, corners, and other terminations. Such discontinuities constitute a defect class whose overall kinetic importance will be strongly tied to particle diameter and which can act independently of the internal strain field imposed by screw and edge dislocations.  相似文献   
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Air pressure field and circulation pattern frequencies were investigated to (1) locate and compare positions of the underlying pressure fields, (2) analyse the spatial dimension of affected areas, (3) create schematic maps of important circulation types and (4) compare the classification types in their response to the data. Two manual classifications were used, selected for the length of their time series and their applicability to a larger region: the Grosswetterlagen classification (GWLc) and the Vangengeim–Girs classification (VGc). Their time series were correlated with a global set of gridded monthly sea-level pressure data. Results show the different conceptual orientation of VGc (hemispheric) and GWLc (continental). The highest correlation values and the largest affected areas are visible in winter, where patterns frequently extended into northern Africa and western Asia. Schematic maps, illustrating the average location of main pressure centres, are provided for basic classes of both classifications. Re-arranging GWLc subtypes increases the classifications comparability with the VGc. Analysis of moving correlation coefficients reveals high fluctuations in the relation of both classifications over time.  相似文献   
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The Place of the Old Synagogue is a popular place in the city center of Freiburg, a medium-sized city in southwest Germany. It is going to be redesigned soon. In this paper the impact of urban street design and surface material on human thermal comfort is analyzed using the example of the Place of the Old Synagogue. The models SkyHelios, RayMan, and ENVI-met were applied to quantify and qualify the changes. All three models are freely available. Their combination allows analysis of development in long-term conditions, as well as changes in spatial distribution of thermal comfort, as well as of heat stress in summer. Results show that the models can provide valuable information. About the Place of the Old Synagogue, quantitative results show that the period with heat stress will become longer, while the intensity of heat stress increases. The spatial results show that the most significant changes are due to changes in shading. Nevertheless, an increase in thermal stress up to 10 °C is calculated for areas, where ground coverage changes from grass to pavement.  相似文献   
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Air temperature variations in Europe and northern Asia are strongly affected by atmospheric circulation. A large-scale study of temperature signals is presented, using a newly available global gridded daily temperature dataset. Major types of European Grosswetterlagen (large-scale weather patterns) and the Russian Vangengeim–Girs classification are compared in their spatial applicability to air temperatures within the past 110 years (1901–2010). The consistency of spatial patterns in the three most recent decades (1981–2010) is investigated, and temperature changes are interpreted against the backdrop of changes in character and frequency of circulation patterns. Both classifications largely explain the observed temperature variability. Spatial patterns are large-scale and strong in both regions, especially in winter. Both spatial extent and signal magnitude show a distinct seasonality with maximum values in winter and minimum ones in summer. Spatial patterns show little changes in Europe; yet the ability to explain temperature variability in northern Asia decreased within 1981–2010. European winter warming corresponds to increased maritime and to decreased continental air mass inflow, superimposed on the general warming trend. Northern Asian winter warming is partly explainable by circulation changes in January and February, but to a lesser extend in December. These results may be used to advance input variables of global climate models and to improve their performance in the European–Northern Asian area.  相似文献   
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ABSTRACT

The continuous submission and scaling-up of Nationally Determined Contributions (NDCs) constitutes a key feature of the Paris Agreement. In their NDCs, states propose governance mechanisms for implementation of climate action, in turn distinguishing appropriate roles for the state in climate governance. Clarity on Parties’ suggested roles for the state makes explicit assumptions on the premise of climate policy, in turn contributing to enhanced transparency in negotiations on the scaling-up of NDCs. This also speaks to ongoing debates on roles for the state in climate governance literature. This article identifies the governance mechanisms proposed by states in their NDCs and the roles for the state envisioned by those governance mechanisms, and also examines how cross-national patterns of roles for the state break or converge with conventional patterns of international politics. The analysis shows that states propose a plurality of roles, which to different extents may be complementary or conflictual. We conclude that income, region, and the Annexes under the United Nations Framework Convention on Climate Change (UNFCCC) are important for understanding suggested roles for the state, but that there are nuances to be further explored. We argue that this paper has three key findings: i) a majority of states rely on market mechanisms to implement their NDCs while rules on implementation and assessment of market mechanisms are still an outstanding issue in the negotiations, meaning that resolving this issue will be essential; ii) the process for evaluating and assessing qualitative governance mechanisms needs to be specified; and iii) increased awareness of differing views on the state’s roles makes explicit different perspectives on what constitutes an ambitious and legitimate contribution to combating climate change.

Key policy insights
  • A majority of states (> 75%) envision the state as regulator (creating and strengthening legislation), market facilitator (creating and maintaining market structures), or facilitator (creating more favourable material conditions for climate-friendly behaviour).

  • Greater awareness of differing views on roles for the state can increase understanding of different perspectives on ambition and legitimacy of contributions, in turn facilitating trust in negotiations.

  • A distinction between substantive and procedural qualitative governance mechanisms and their function and interaction would facilitate the stocktaking dialogues.

  相似文献   
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