A Raman spectroscopic study on the structural disorder of monazite–(Ce)     

Katja Ruschel  Lutz Nasdala  Andreas Kronz  John M. Hanchar  Daniel M. T?bbens  Radek ?koda  Friedrich Finger  Andreas M?ller 《Mineralogy and Petrology》2012,105(1-2):41-55

This study addresses whether Raman spectra can be used to estimate the degree of accumulated radiation damage in monazite-(Ce) samples whose chemical composition was previously determined. Our results indicate that the degree of disorder in monazite–(Ce), as observed from increasing Raman band broadening, generally depends on both the structural state (i.e., radiation damage) and the chemical composition (i.e., incorporation of non-formula elements). The chemical effects were studied on synthetic orthophosphates grown using the Li-Mo flux method, and non radiation-damaged analogues of the naturally radiation-damaged monazite–(Ce) samples, produced by dry annealing. We found that the “chemical” Raman-band broadening of natural monazite–(Ce) can be predicted by the empirical formula, $$ {\hbox{FWHM}} {\hbox{[c}}{{\hbox{m}}^{ - {1}}}{]} = {3}{.95} + {26}{.66} \times {\hbox{(Th}} + {\hbox{U}} + {\hbox{Ca}} + {\hbox{Pb)}} {\hbox{[apfu]}} $$ where, FWHM = full width at half maximum of the main Raman band of monazite–(Ce) (i.e., the symmetric PO₄ stretching near 970?cm^?1), and (Th+U+Ca+Pb) = sum of the four elements in apfu (atoms per formula unit). Provided the chemical composition of a natural monazite–(Ce) is known, this “chemical band broadening” can be used to estimate the degree of structural radiation damage from the observed FWHM of the ν₁(PO₄) band of that particular sample using Raman spectroscopy. Our annealing studies on a wide range of monazite–(Ce) reference materials and other monazite–(Ce) samples confirmed that this mineral virtually never becomes highly radiation damaged. Potential advantages and the practical use of the proposed method in the Earth sciences are discussed.  相似文献   

Phase relations of phlogopite with magnesite from 4 to 8 GPa   总被引：2，自引：2，他引：0  

Andreas?EnggistEmail author  Linglin?Chu  Robert?W.?Luth 《Contributions to Mineralogy and Petrology》2012,163(3):467-481

To evaluate the stability of phlogopite in the presence of carbonate in the Earth’s mantle, we conducted a series of experiments in the KMAS–H₂O–CO₂ system. A mixture consisting of synthetic phlogopite (phl) and natural magnesite (mag) was prepared (phl₉₀-mag₁₀; wt%) and run at pressures from 4 to 8 GPa at temperatures ranging from 1,150 to 1,550°C. We bracketed the solidus between 1,200 and 1,250°C at pressures of 4, 5 and 6 GPa and between 1,150 and 1,200°C at a pressure of 7 GPa. Below the solidus, phlogopite coexists with magnesite, pyrope and a fluid. At the solidus, magnesite is the first phase to react out, and enstatite and olivine appear. Phlogopite melts over a temperature range of ~150°C. The amount of garnet increases above solidus from ~10 to ~30 modal% to higher pressures and temperatures. A dramatic change in the composition of quench phlogopite is observed with increasing pressure from similar to primary phlogopite at 4 GPa to hypersilicic at pressures ≥5 GPa. Relative to CO₂-free systems, the solidus is lowered such, that, if carbonation reactions and phlogopite metasomatism take place above a subducting slab in a very hot (Cascadia-type) subduction environment, phlogopite will melt at a pressure of ~7.5 GPa. In a cold (40 mWm⁻²) subcontinental lithospheric mantle, phlogopite is stable to a depth of 200 km in the presence of carbonate and can coexist with a fluid that becomes Si-rich with increasing pressure. Ascending kimberlitic melts that are produced at greater depths could react with peridotite at the base of the subcontinental lithospheric mantle, crystallizing phlogopite and carbonate at a depth of 180–200 km.  相似文献   

Uncertainties of geochemical modeling during CO<Subscript>2</Subscript> sequestration applying batch equilibrium calculations     

Frank?DethlefsenEmail author  Christoph?Haase  Markus?Ebert  Andreas?Dahmke 《Environmental Earth Sciences》2012,65(4):1105-1117

One of the uncertainties in the field of carbon dioxide capture and storage (CCS) is caused by the parameterization of geochemical models. The application of geochemical models contributes significantly to calculate the fate of the CO₂ after its injection. The choice of the thermodynamic database used, the selection of the secondary mineral assemblage as well as the option to calculate pressure dependent equilibrium constants influence the CO₂ trapping potential and trapping mechanism. Scenario analyses were conducted applying a geochemical batch equilibrium model for a virtual CO₂ injection into a saline Keuper aquifer. The amount of CO₂ which could be trapped in the formation water and in the form of carbonates was calculated using the model code PHREEQC. Thereby, four thermodynamic datasets were used to calculate the thermodynamic equilibria. Furthermore, the equilibrium constants were re-calculated with the code SUPCRT92, which also applied a pressure correction to the equilibrium constants. Varying the thermodynamic database caused a range of 61% in the amount of trapped CO₂ calculated. Simultaneously, the assemblage of secondary minerals was varied, and the potential secondary minerals dawsonite and K-mica were included in several scenarios. The selection of the secondary mineral assemblage caused a range of 74% in the calculated amount of trapped CO₂. Correcting the equilibrium constants with respect to a pressure of 125 bars had an influence of 11% on the amount of trapped CO₂. This illustrates the need for incorporating sensitivity analyses into reaction pathway modeling.  相似文献   

Simulation of DNAPL infiltration and spreading behaviour in the saturated zone at varying flow velocities and alternating subsurface geometries   总被引：3，自引：1，他引：2  

Katharina Erning  Sibylle Grandel  Andreas Dahmke  Dirk Schäfer 《Environmental Earth Sciences》2012,65(4):1119-1131

The influence of varying groundwater flow velocities on DNAPL infiltration and spreading behaviour was investigated by multiphase modelling using TMVOC and PetraSim. The multiphase models were calibrated by results of previously conducted laboratory experiments for the complete spatio-temporal range of the experiments. The small scale 2D scenario modelling was applied to qualify and quantify changes in position, architecture, geometry and dissolution of a TCE body in a fully saturated homogeneous sandy medium. The applied flow velocities ranging from 0.05 up to 40.00 m/day exhibited that the DNAPL TCE is affected even at the lowest flow velocity in its position, its size and its architecture. Additionally, several impermeable lenses with simple geometry were assumed in the model, to investigate the influence of stratified subsoil. In the experimental set-ups, the DNAPL body reacts more sensitive to the applied groundwater flow velocities than to the geometrical set-up of the scenarios. A possible consequence can be the transportation and displacement of a DNAPL pool due to natural or anthropogenic induced high groundwater flow velocities, as by Pump and Treat facilities, complicating site investigation process and planning of remediation activities.  相似文献   

Investigating sediments and rock structures beneath a river using underwater ERT     

Jannis Epting  Andreas Wüest  Peter Huggenberger 《Central European Journal of Geosciences》2012,4(1):81-93

This article presents hydrogeophysical investigations performed in a well-developed, long-term hydrogeological gypsum karst research site where subsurface evaporite dissolution has led to the subsidence of a river dam and an adjacent highway; both constructed on gypsum-containing rock, southeast of Basel, Switzerland. An observation system was set up to improve the protection of surface and subsurface water resources during remedial construction measures of the highway and in order to understand the processes, as well as the temporal evolution, of rock water interaction (flow and dissolution). However, no detailed hydrogeological information beneath the river could be derived from the previous investigations. To supplement the basic knowledge on this area, underwater Electrical Resistivity Tomography (ERT) measurements were conducted in the river bed upstream of the dam. The ERT-data are interpreted together with drill-core information and a conceptual 3D-Model of the area behind the dam and beneath the river. Results help to delineate weathered zones, associated faults and the thickness of sediment deposits behind the dam, as well as to locate voids within the local karst system. The combination of the ERT and modeling allows the optimization of future site-specific remedial construction measures.  相似文献   

Skyline-based registration of 3D laser scans     

Andreas Nüchter  Stanislav Gutev  Dorit Borrmann  Jan Elseberg 《地球空间信息科学学报》2011,14(2):85-90

Acquisition and registration of terrestrial 3D laser scans is a fundamental task in mapping and modeling of cities in three dimensions. To automate this task marker-free registration methods are required. Based on the existence of skyline features, this paper proposes a novel method. The skyline features are extracted from panoramic 3D scans and encoded as strings enabling the use of string matching for merging the scans. Initial results of the proposed method in the old city center of Bremen are pre-sented.  相似文献   

Physical and economic bias in climate change research: a scientometric study of IPCC Third Assessment Report     

Andreas Bjurstr?m  Merritt Polk 《Climatic change》2011,108(1-2):1-22

This study demonstrates that IPCC Third Assessment Report is strongly dominated by Natural sciences, especially the Earth sciences. The Social sciences are dominated by Economics. The IPCC assessment also results in the separation of the Earth, Biological and Social sciences. The integration that occurs is mainly between closely related scientific fields. The research community consequently imposes a physical and economic bias and a separation of scientific fields that the IPCC reproduces in the policy sphere. It is argued that this physical and economic bias distorts a comprehensive understanding of climate change and that the weak integration of scientific fields hinders climate change from being fully addressed as an integral environmental and social problem. If climate change is to be understood, evaluated and responded to in its fullness, the IPCC must broaden its knowledge base and challenge the anthropocentric worldview that places humans outside of nature.  相似文献   

Reversed North Atlantic gyre dynamics in present and glacial climates     

Marisa Montoya  Andreas Born  Anders Levermann 《Climate Dynamics》2011,36(5-6):1107-1118

The dynamics of the North Atlantic subpolar gyre (SPG) are assessed under present and glacial boundary conditions by investigating the SPG sensitivity to surface wind-stress changes in a coupled climate model. To this end, the gyre transport is decomposed in Ekman, thermohaline, and bottom transports. Surface wind-stress variations are found to play an important indirect role in SPG dynamics through their effect on water-mass densities. Our results suggest the existence of two dynamically distinct regimes of the SPG, depending on the absence or presence of deep water formation (DWF) in the Nordic Seas and a vigorous Greenland?CScotland ridge (GSR) overflow. In the first regime, the GSR overflow is weak and the SPG strength increases with wind-stress as a result of enhanced outcropping of isopycnals in the centre of the SPG. As soon as a vigorous GSR overflow is established, its associated positive density anomalies on the southern GSR slope reduce the SPG strength. This has implications for past glacial abrupt climate changes, insofar as these can be explained through latitudinal shifts in North Atlantic DWF sites and strengthening of the North Atlantic current. Regardless of the ultimate trigger, an abrupt shift of DWF into the Nordic Seas could result both in a drastic reduction of the SPG strength and a sudden reversal in its sensitivity to wind-stress variations. Our results could provide insight into changes in the horizontal ocean circulation during abrupt glacial climate changes, which have been largely neglected up to now in model studies.  相似文献   

Comparison of models calculating the sky view factor used for urban climate investigations     

Martin H?mmerle  Tam��s G��l  J��nos Unger  Andreas Matzarakis 《Theoretical and Applied Climatology》2011,105(3-4):521-527

The sky view factor (SVF) describes the surface geometry and is a commonly used and important measure in urban climate investigations whose aim is the exploration of effects of a complex urban surface on climatological processes in built-up areas. A selection of methods and models for calculating the SVF was compared. For this purpose, fish eye images were taken at several locations in the city of Szeged, southern Hungary. The fish eye images equidistantly follow linear transects to cover a range of SVF values and to analyze the reaction of the methods to a continuously changing environment. The fish eye pictures were evaluated by three methods: the method according to Steyn (Atmos-Ocean 18(3):245?C258, 1980) implemented in a GIS-Script, the ??Edit free sky view factor?? tool of the RayMan model and BMSkyView. The SVF values at the coordinates of the fish eye pictures were calculated with three numerical models (SkyHelios, ArcView SVF extension, and SOLWEIG) with a 3D building data base as input. After comparing the results of the first run, a deviation occurs. The deviation disappears after implementing an option to include a weighting factor in some of the models.  相似文献   

Human-biometeorological assessment of heat waves in Athens   总被引：1，自引：1，他引：0  

Andreas Matzarakis  Panagiotis T. Nastos 《Theoretical and Applied Climatology》2011,105(1-2):99-106

The goal of this study is the analysis of heat waves and their impact on humans, using human biometeorological indices, which are based on the energy balance of the human body. The implications for humans are not only described through the intensity of the heat waves, but also through their duration over consecutive days. Both intensity and duration were analyzed for the Greater Athens Area during the period 1955 to 2001. The analysis was carried out using the daily physiologically equivalent temperature and the daily minimum air temperature. Based on these two parameters, the results showed an increase in the average duration of heat waves. Furthermore, the use of the Gaussian filter revealed the intra-annual variation of heat stress conditions and their relevance to humans. The results could be used for the management of the negative consequences of heat waves in cities suffering from environmental pollution and also for climate impact studies.  相似文献