Sesquiterpenoids in sediments of a hypersaline lagoon: A possible algal origin     

V. O. Elias  A. M. A. De Barros  A. B. de Barros  B. R. T. Simoneit  J. N. Cardoso 《Organic Geochemistry》1997,26(11-12)

Core samples were collected in Lagoa Vermelha, a hypersaline lagoon located about 100 km east of Rio de Janeiro (Brazil). The sediment composition is predominantly carbonate in amounts up to 93%. Analysis of δ¹³C of the total organic matter in the sediments showed that marine organic matter predominates throughout the core (δ¹³C ranges from −15.84 to −22.64‰ vs. PDB). Organic carbon contents (TOC) ranged from 0.81 to 13.28%. A series of cadinane-type sesquiterpenoids can be recognized in the gas chromatography-mass spectrometry data. Essentially the same components are present in all the samples, with variations only in their relative abundances. The most abundant compounds are α- and β-cubebene, α- and β-cedrene, cadinenes (different isomers), α-curcumene and calamenene, with minor amounts of calarene, humulene, calacorene and cadalene. Since this lagoon is surrounded by dunes with only minor vegetation typical of this environment (grasses, small non-resinous shrubs and no forest) with no potential source for sesquiterpenoids, a terrestrial origin for these compounds is excluded and an algal origin is more consistent with the locale and the recognition of sesquiterpenoids (including cadinol) in microbial mats from the lagoon. Only the natural product precursor sesquiterpenoids are present in the microbial mats with no detectable diagenetic derivatives (e.g. calamenene and cadalene). This indicates that the compounds in the mats are from recent input and those found in the sediments are most likely derived from former algal biomass in this lagoon, a fact confirmed by the recognition of a series of diagenetic aromatic components in the sediments. Surface sediments contain n-alkanes with no even-to-odd predominance indicating that microbial activity is higher in shallower sediments. Moreover, mass fragmentograms (m/z 191) of biomarkers revealed the presence of 17α(H),21β(H)-hopanes, the mature isomers, together with their ββ precursors and low amounts of the intermediates with the βα configuration (moretanes). This indicates a contribution of mature organic matter to these immature sediments.  相似文献   

How warm was Britain during the Last Interglacial? A critical review of Ipswichian (MIS 5e) palaeotemperature reconstructions   总被引：1，自引：0，他引：1       下载免费PDF全文

Ian Candy  Tom S. White  Scott Elias 《第四纪科学杂志》2016,31(8):857-868

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Flood-related leptospirosis outbreaks in Brazil: perspectives for a joint monitoring by health services and disaster monitoring centers     

Luciana de Resende Londe  Rodrigo Silva da Conceição  Tiago Bernardes  Mariane Carvalho de Assis Dias 《Natural Hazards》2016,84(2):1419-1435

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Production of Reactive Oxygen Species in the Rhizosphere of a <Emphasis Type="Italic">Spartina-</Emphasis>Dominated Salt Marsh Systems     

Dewamunnage Muditha C. Dias  Justin M. Copeland  Carrie L. Milliken  Xiangming Shi  John L. Ferry  Timothy J. Shaw 《Aquatic Geochemistry》2016,22(5-6):573-591

This paper reports the presence of a metastable mixture of Fe(II), O₂, superoxide and hydrogen peroxide in sediment pore water in organic carbon-rich sediments in Spartina alterniflora-dominated salt marsh systems. Field measurements at two different estuarine sites in South Carolina (one heavily urbanized and a protected research reserve) showed a broad region of reactive oxygen species (ROS) production more than 15 cm below the sediment surface within and immediately adjacent to the rhizospheres of S. alterniflora. Dissolved Fe(II) was positively correlated with hydrogen peroxide indicating a possible abiotic pathway to ROS production (r ² = 0.94). The null hypothesis was tested that Fe(II) inventories were maintained by protective ligands and thus unreactive with respect to O₂ consumption and ROS production. The addition of an Fe-binding ligand, DTPA, resulted in rapid decline of ROS in pore water, indicating that Fe(II) was labile. The half-life of superoxide under the measured solution conditions was calculated and found to be less than a second. The combination of high lability and persistent ROS was interpreted to indicate a high rate of Fe(II) and O₂ supply to the pore water. The ²²⁴Ra/²²⁸Th disequilibrium was measured to determine the potential for advective mass transfer of dissolved oxygen via pore water exchange. The estimated pore water exchange of 54 L m^?2 day^?1 was significant but could not support the measured production of ROS alone, the direct exchange of O₂ from the S. alterniflora root system may have contributed significantly to ROS production in the sediments.  相似文献   

Sediment distribution patterns on the Galicia-Minho continental shelf   总被引：1，自引：0，他引：1  

J. M. A. Dias  R. Gonzalez  C. Garcia  V. Diaz-del-Rio 《Progress in Oceanography》2002,52(2-4)

A sedimentological and bathymetric study of the Minho-Galicia Shelf shows a strong contrast between a southern shelf region with a thin partially relict cover of sands and gravel, and a northern region where fine-grained sediments predominate. This contrast is explained through differences in the sediment supply, the oceanographic environment (storms and ocean currents) and the morphology of the shelf which results from its underlying tectonic framework.Most sediment is supplied to the Galicia-Minho Shelf by river discharges onto the Minho Shelf, particularly that from the Douro River. In the northern part of the shelf the Galician Rías act as sediment traps rather than sediment suppliers. The bulk of the sediment washes out of the rivers during episodic storm events. While most of the coarse sediments remain deposited close to the coast, the fine-grained material is exported to the outer areas of the shelf. Subsequently, coarse sediments close to the coast are transported southwards by the littoral drift. Whereas the fine-grained material is frequently resuspended through the action of the large swells who influence reaches deep into the water. This frequent resuspension has a long-term sorting effect on the sediments. Furthermore, resuspended sediments on the middle and outer regions of the shelf are transported northwards by a poleward flowing bottom current.As a consequence of the differential transport of coarse sediments to the south, and of the fine-grained sediments to the north, the outer reaches of the Minho Shelf are relatively poor in recent sediments. In many areas relict sediments as well as features associated with ancient coastlines and river mouths, still appear as seabed features. In contrast, the northern regions of the shelf are covered by a thin veneer of fine-grained material that smooth other most of these fossil features.The fine-grained sediment fractions (mostly very fine sands to coarse silts) are deposited in two large mud patches, the Douro and the Galicia Mud Patches, which are situated at water depths of around 100–120 m. These two mud patches are both controlled by the local hydrodynamics and morphology. The Beiral de Viana, to the west of the Douro Mud Patch is a plateau, up to 20 m high lying parallel to the shelf-break and is a morphological expression of an underlying horst system. This plateau acts as a barrier that prevents the drift of some of the fine-grained material to the west, out over the shelf-break and the continental slope. The Galicia Mud Patch is situated on the eastern part of the Galician Shelf to the north of the Douro Mud Patch. It is situated near the extension of the Porto–Tomar fault, which results in the shelf being usually steep in this region, down to a depth of about 100 m. West of this area the slope is much more gentle. Northward transport of the sediment is strongly reduced by the E–W trending outcrops of plutonic and metamorphic rocks.  相似文献   

Stratigraphic evidence of an upper Pleistocene TST to HST complex on the Gulf of Cádiz continental shelf (south-west Iberian Peninsula)     

F. Lobo  F. Hernández-Molina  L. Somoza  V. Díaz del Río  J. Dias 《Geo-Marine Letters》2002,22(2):95-107

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3D displacement maps of the 2009 L’Aquila earthquake (Italy) by applying the SISTEM method to GPS and DInSAR data     

Francesco Guglielmino  Marco Anzidei  Pierre Briole  Panagiotis Elias  Giuseppe Puglisi 《地学学报》2013,25(1):79-85

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Transverse and longitudinal fluid flow modelling in fractured porous media with non‐matching meshes     

Behnam V. Damirchi  Marcelo R. Carvalho  Luís A. G. Bitencourt  Osvaldo L. Manzoli  Daniel Dias‐da‐Costa 《国际地质力学数值与分析法杂志》2021,45(1):83-107

A new discrete fracture model is introduced to simulate the steady‐state fluid flow in discontinuous porous media. The formulation uses a multi‐layered approach to capture the effect of both longitudinal and transverse permeability of the discontinuities in the pressure distribution. The formulation allows the independent discretisation of mesh and discontinuities, which do not need to conform. Given that the formulation is developed at the element level, no additional degrees of freedom or special integration procedures are required for coupling the non‐conforming meshes. The proposed model is shown to be reliable regardless of the permeability of the discontinuity being higher or lower than the surrounding domain. Four numerical examples of increasing complexity are solved to demonstrate the efficiency and accuracy of the new technique when compared with results available in the literature. Results show that the proposed method can simulate the fluid pressure distribution in fractured porous media. Furthermore, a sensitivity analysis demonstrated the stability regarding the condition number for wide range values of the coupling parameter.  相似文献   

Florida Bay: Modern analogue for Lofer cyclothems?     

Paul Enos  Elias Samankassou 《Sedimentology》2022,69(1):254-281

Lofer cyclothems of the Alpine Upper Triassic have many features in common with Holocene sediments of Florida Bay. The modal ‘complete’ Lofer cycle is essentially symmetrical, having a deepening and shoaling phase, as does the cycle-in-progress in Florida Bay. Lateral discontinuity and thickness variations within members of the Lofer cyclothems indicate syn-depositional relief, possibly in the form of mud banks, the signature feature of Florida Bay sedimentation. Spatial and temporal dimensions, although poorly constrained, appear comparable. Analogous depositional textures, biota and sedimentary structures, while not unique to either environment, strengthen the inferences that can be made about the Triassic depositional environment and regarding future evolution of the modern environment. The striking similarities between the Holocene icehouse sediments and the Late Triassic greenhouse deposits suggest that sedimentation patterns at the scale of individual cycles or parasequences may be largely independent of the global climate regime.  相似文献   

North American transect of stable hydrogen and oxygen isotopes in water beetles from a museum collection     

Maarten van Hardenbroek  Darren R. Gr?cke  Peter E. Sauer  Scott A. Elias 《Journal of Paleolimnology》2012,48(2):461-470

Museum collections contain a wealth of insect remains originating from a wide geographic range, which can be used to investigate their utility as a proxy for environmental isotope ratios. Chitinous remains of insects such as beetles (Coleoptera) are chemically stable and their stable isotope composition is strongly related to that of environmental water in the period of cuticle formation. We present a dataset of chitin ??D and ??¹⁸O in two genera of water beetles from a museum collection containing 40 locations for Helophorus (water scavenging beetles) and 48 locations for Hydroporus (predaceous diving beetles) that were selected from latitudes 27?C82°N in North America. Only two genera were used to minimize inter-sample variation caused by species-specific differences in metabolic effects, feeding strategy, habitat, and life cycle. The isotopic composition of water beetle exoskeletons had a strong latitudinal trend (North?CSouth) from ?160 to +65??? for ??D and from 7 to 34??? for ??¹⁸O, paralleling gradients of isotopes in precipitation. Strong relationships were observed between isotopic composition of beetles and modelled July precipitation (0.71?<?R ²?<?0.82, p?<?0.001). The relationship between ??D and ??¹⁸O in the beetle samples had a systematic offset from the global meteoric water line, which was likely caused by metabolic effects during chitin formation. The offset between ??D values in beetles and in modelled precipitation was 33??? larger, on average, for Hydroporus compared with Helophorus, suggesting fractionation of hydrogen isotopes during passage through the food chain. This trophic level effect was not observed for stable oxygen isotopes. Furthermore, the observed deviations between isotopic composition of water beetles and modelled precipitation at collection sites were not constant and indicated local hydrological deviations from modelled precipitation. The largest deviations were observed for sites in the Southern US and the Arctic that are highly evaporative and at sites in the Rocky Mountains and Coastal Mountains that were fed by snow melt. Our results indicated that the isotopic composition of water beetles from a museum collection was systematically related to ??D and ??¹⁸O values of precipitation at the collection site.  相似文献