The ortho- to para- ratio of H₂ in the starburst of NGC 253     

Andrew Harrison  Phil Puxley  Adrian Russell  & Peter Brand 《Monthly notices of the Royal Astronomical Society》1998,297(2):624-632

We present measurements of several near-infrared emission lines from the nearby galaxy NGC 253. We have been able to measure four H₂ lines across the circumnuclear starburst, from which we estimate the ortho- to para- ratio of excited H₂ to be ∼2. This indicates that the bulk of the H₂ emission arises from photodissociation regions (PDRs), rather than from shocks. This is the case across the entire region of active star formation.
As the H₂ emission arises from PDRs, it is likely that the ratio of H₂ to Brγ (the bright hydrogen recombination line) is a measure of the relative geometry of O and B stars and PDRs. Towards the nucleus of NGC 253 the geometry is deduced to be tightly clustered O and B stars in a few giant H  II regions that are encompassed by PDRs. Away from the nuclear region, the geometry becomes that of PDRs bathed in a relatively diffuse ultraviolet radiation field.
The rotation curves of 1–0 S(1) and Brγ suggest that the ionized gas is tracing a kinetic system different from that of the molecular gas in NGC 253, particularly away from the nucleus.  相似文献   

Aliphatic and aromatic hydrocarbons in benthic invertebrates from two sites in Antarctica     

Andrew Clarke  Robin Law 《Marine pollution bulletin》1981,12(1):10-14

Samples of marine benthic invertebrates collected from two sites in the Antarctic have been analysed for both aliphatic and aromatic hydrocarbons in order to establish baseline concentrations for some classes of hydrocarbons.Samples from Signy Island, a pristine site, contained low concentrations of the hydrocarbons determined, whereas those from King Edward Cove, South Georgia, contained significantly higher concentrations. King Edward Cove has a known history of pollution from whaling operations.Platt & Mackie (1979) have suggested that the hydrocarbons in sediments from King Edward Cove are a result of the world-wide dissemination of the pyrolysis products of fossil fuels. Our work suggests, in contrast, that the hydrocarbons in the benthos are derived from local sources.  相似文献   

Leachable trace elements in San Francisco bay sediments: Indicators of sources and estuarine processes     

Andrew Eaton 《Environmental Geology》1978,2(6):333-339

Geographic variations of leachable Fe, Mn, Cu, Zn, Co, and Ni in San Francisco Bay sediments indicate that Fe, Mn, Co, and Ni are all predominantly supplied to bay sediments from the San Joaquin-Sacramento River system, with little evidence for direct contributions from municipal and industrial sources. In contrast, both Cu and Zn have significant sources within the Bay system, probably municipal and industrial discharges. Precipitation and coagulation of Fe oxides in the low-salinity region of the estuary results in significantly greater concentrations of that element in the most landward portion of the estuary. Co and Ni appear to be actively coprecipitating with Fe but their distributions are also influenced by other factors. Mn is not a major geochemical agent in this system. Its pattern is different from the other elements and it does not account for any of the other elemental variance. The behavior of Cu and Zn is affected not only by the presence of nonriverine sources but also through surface-active processes and organic complexing, coupled with the transportation of fine-grained sediment.  相似文献   

Atmospheric response to deep-sea injections of fossil-fuel carbon dioxide   总被引：1，自引：0，他引：1  

Martin I. Hoffert  Yeong-Cherng Wey  Andrew J. Callegari  Wallace S. Broecker 《Climatic change》1979,2(1):53-68

The possibility of controlling atmospheric carbon dioxide accumulation and attendant climatic effects from fossil-fuel burning by diverting a fraction of the combustion product and injecting it into the deep-ocean, as proposed by Marchetti, is analyzed using an atmosphere/mixed layer/diffusive deep-ocean model for the carbon cycle. The model includes the nonlinear buffering of CO₂ at the air/sea interface, and considers the long term trends associated with consuming an assumed fossil-fuel reserve equivalent to 7.09 × 10¹⁵ kg carbon as a logistic function of time as in the projections of Siegenthaler and Oeschger, except that atmospheric carbon dioxide levels are computed for five alternate strategies: (a) 100% injected into atmosphere, (b) 50% injected at oceanic depth of 1500 m and 50% into atmosphere, (c) 50% injected at sea floor (4000 m) and 50% into atmosphere, (d) 100% at 1500 m depth and (e) 100% at sea floor. Since no carbon leaves the system, all runs approached the same post-fossil fuel equilibrium after several thousand years, C _a - 1150 ppm, almost four times the pre-fossil fuel value (- 300 ppm). But the transient response of these cases showed a marked variation ranging from a peak overshoot value of 2800 ppm in the year 2130 for 100% atmospheric injection to a slight decrease to the pre-fossil fuel 300 ppm lasting till 2300 with a subsequent slow approach to equilibrium for the 100% deep-ocean injection. The implications of these results for an oceanic injection strategy to mitigate the climatic impact of fossil-fuel CO₂ is discussed, as are the ingredients of a second generation carbon cycle model for carrying out such forecasts on an engineering design basis.  相似文献   

A geochemical study of magmatism associated with the initial stages of back-arc spreading   总被引：4，自引：0，他引：4  

Stephen D. Weaver  Andrew D. Saunders  Robert J. Pankhurst  John Tarney 《Contributions to Mineralogy and Petrology》1979,68(2):151-169

Bransfield Strait is a narrow basin separating the South Shetland Islands from the Antarctic Peninsula and is attributed to recent back-arc extension behind the South Shetland volcanic arc. The volcanic islands of Deception and Bridgeman are situated close to the axis of spreading, whereas Penguin Island lies slightly to the north of this axis. The mineralogy, petrology and geochemistry of the lavas of the three volcanoes have been studied in order to provide information on the nature of magmatism associated with the initial stages of back-arc spreading.Deception Island lavas range from olivine basalt to dacite, and all are highly sodic, with high Na/K, K/Rb, Ba/Rb and Zr/Nb ratios and with Ce_N/Yb_N = 2. Incompatible elements increase systematically between basalt and rhyodacite, while Sr decreases, suggesting that fractional crystallisation is the dominant process relating lava compositions. The rhyodacites have high concentrations of Zr, Y and the REE and negative Eu anomalies and are compositionally similar to oceanic plagiogranite. Bridgeman Island lavas are mostly basaltic andesites, but the levels of many incompatible elements, including REE, are significantly lower than those of Deception lavas, although Ce_N/Yb_N ratios and ⁸⁷Sr/⁸⁶Sr ratios (0.7035) are the same. Penguin Island lavas are magnesian, mildly alkaline olivine basalts with a small range of composition that can be accommodated by fractional crystallisation of olivine, clinopyroxene and/or chromite. Penguin lavas have higher ⁸⁷Sr/⁸⁶Sr (0.7039) and Ce_N/ Yb_N (4) ratios than Deception and Bridgeman lavas. The Rb/Sr ratios of Deception and Penguin basalts (ca. 0.01) are much too low to account for their present ⁸⁷Sr/⁸⁶Sr ratios.Modelling suggests that the source regions of the lavas of the three volcanoes share many geochemical features, but there are also some significant differences, which probably reflects the complex nature of the mantle under an active island arc combined with complex melting relationships attending the initial stages of back-arc spreading. Favoured models suggest that Bridgeman lavas represent 10–20% melting and the more primitive Deception lavas 5–10% melting of spinel-peridotite, whereas Penguin lavas represent less then 5% melting of a garnet-peridotite source. The mantle source for Bridgeman lavas seems to have undergone short-term enrichment in K, Rb and Ba, possibly resulting from dewatering of the subducted slab. Hydrous melting conditions may also account for the more siliceous, high-alumina nature and low trace element contents of Bridgeman lavas.  相似文献   

Epistemology and conceptions of people and nature in geography   总被引：1，自引：0，他引：1  

Andrew Sayer 《Geoforum》1979,10(1):19-44

The paper attempts to integrate two major issues of debate in geography which are conventionally discussed separately: epistemology and conceptions of the relationship between people and Nature. Whichever issue we start with, two concepts are essential: intersubjectivity and labour. Knowledge of natural objects is tied to labour, which both subjects ideas to a kind of test and changes our position within Nature. All knowledge depends upon intersubjective understanding between people, but this implies that in social science, and hence in human geography, the traditional subject-object relationship should be recast as a form of communication between ‘knowing-subjects’. These relationships are not limited to some separate sphere of epistemology but are constitutive of society in Nature itself. Labour, though traditionally overlooked in geography, is the most active and transformative process in changing Nature and society, and intersubjectivity is an essential element of the irreducibly social character of human life. In this attempt, the paper outlines and justifies a historical materialist perspective through critical engagement with positivist and humanist approaches. It is then argued that false conceptions of people and Nature in geography are grounded in the structure and selfunderstanding of our own society such that a critique of these ideas becomes a critique of our society.  相似文献   

Sea-level changes. North West England during the flandrian stage,M. J. Tooley,Clarendon Press,Oxford, 1978. No. of paces: 232 Price £12.00     

Andrew Goudie 《地球表面变化过程与地形》1979,4(3):299-299

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Carbonatization and mobility of Ti,Y, and Zr in Ascot Formation metabasalts,SE Quebec   总被引：3，自引：0，他引：3  

Andrew Hynes 《Contributions to Mineralogy and Petrology》1980,75(1):79-87

The middle Ordovician Ascot Formation of southeastern Quebec consists of greenschist facies metamorphosed silicic to mafic pyroclastic rocks and lava flows and associated metasediments. Chemical analyses of lavas reveal a preponderance of metarhyolites and metabasalts, together with some porphyritic rocks with intermediate SiO₂ contents. The metabasalts exhibit wide ranges in concentrations of TiO₂ (0.25–2.0 wt.°), Y (9–46 ppm), and Zr (5–135 ppm). The extent of the ranges, and unusual interelement ratios, suggest that the concentrations of these normally immobile elements have been affected by secondary processes.There is a strong correlation between trace-element concentrations and the degree of carbonatization of the metabasalts. Low carbonate rocks are severely depleted in Ti, Y, and Zr whereas high carbonate rocks are depleted in Y and Zr and enriched in Ti. The differing movement of Ti can be explained in terms of variable chemical potential due to the various carbonatization reactions affecting titaniferous phases. Overall mobility of these generally immobile/rd elements is attributed to high CO₂ levels in the fluid phase during metamorphism.Extrapolation of the two alteration trends to a common origin enables one to infer primary concentrations of the trace-elements. Primary inter-element ratios arrived at in this way are compatible with an island-arc origin for the Ascot Formation although TiO₂ concentrations are a little high (1.5 wt/%).  相似文献   

Nontidal circulation and mixing processes in the lower Potomac estuary     

Andrew D. Hamilton  Robert E. Wilson 《Estuaries and Coasts》1980,3(1):11-19

An analysis of the vertical structure of nontidal longitudinal currents and salinity in a reach of the lower Potomac River Estuary suggests that values for vertical eddy viscosity and eddy diffusivity scale with water depth H, tidal current amplitude U and bulk Richardson number according to conventional empirical formulas. However, the constant which relates the vertical eddy coefficients under conditions of neutral stability to UH is found to be an order of magnitude less than that expected for tidal conditions. Analyses also suggest that the degree of enhancement of longitudinal dispersion by the shear effect associated with the nontidal currents is a strong function of bulk Richardson number.  相似文献   

The Relationship Between Hydrogeologic Properties and Sedimentary Fades: An Example from Pennsylvanian Bedrock Aquifers, Southwestern Indiana     

Andrew T. Fisher  Mark Barnhill  Justin Revenaugh 《Ground water》1998,36(6):901-912

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