Geochemistry of an acidic chromium sulfate plume     

L. Edmond Eary  Andy Davis 《Applied Geochemistry》2007

The historical disposal of acidic chromium sulfate solutions into unlined lagoons between 1953 and 1970 at an industrial site resulted in formation of a dense aqueous phase liquid (DAPL) plume [specific gravity 1.11 g/cm³, pH 3, up to 4700 mg/L Cr(III), and up to 90,000 mg/L SO₄]. The DAPL sank through the shallow glacial till aquifer to an underlying impermeable gneissic bedrock from where it migrated downgradient along buried channels incised in the bedrock. Because of its high density, the plume chemistry is sharply stratified vertically. Chromium(III) predominates in the DAPL because excess Cr(VI) not reduced in the original process has been reduced by Fe(II) derived from silicates, while Cr(OH)₃(am) occurs as surface coatings on silicate minerals and as discrete particles mixed with Fe(OH)₃(am) and Al(OH)₃(am). The solubility of Cr(OH)₃(am) accurately describes Cr(III) concentrations in the plume and nearby groundwater, while Al and Fe in solution are also consistent with solubility-controlling oxyhydroxides. Because of these solubility controls, metal cations are attenuated relative to more mobile Cl and SO₄, resulting in a chromatographic separation of solutes downgradient from the plume origin. The good agreement between predicted and observed solution concentrations illustrates the utility of equilibrium modeling when interpreting metal transport characteristics and in determining the efficacy of natural attenuation in subsurface systems.  相似文献   

The potential to reduce greenhouse gas emissions in the UK through healthy and realistic dietary change     

Rosemary Green  James Milner  Alan D. Dangour  Andy Haines  Zaid Chalabi  Anil Markandya  Joseph Spadaro  Paul Wilkinson 《Climatic change》2015,129(1-2):253-265

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Big data and machine learning in geoscience and geoengineering: Introduction     

Wengang Zhang  Jianye Ching  Anthony T.C.Goh  Andy Y.F.Leung 《地学前缘(英文版)》2021,12(1):327-329

In recent years,we have entered the so-called Fourth Paradigm with the regular production of huge amount of observational data.Big data is often characterized by the three‘V's:Volume of data,Variety and Velocity.The concept of big data can potentially address some existing issues in areas of geoscience and geoengineering.Large-scale,comprehensive,multidirectional and multifield geotechnical monitoring is becoming a reality in the very near future.  相似文献   

Contemporary rates of chemical denudation and atmospheric CO2 sequestration in glacier basins: an Arctic perspective     

Andy Hodson  Martyn Tranter  Geir Vatne 《地球表面变化过程与地形》2000,25(13):1447-1471

This paper presents new estimates of solute fluxes from five high Arctic glacier basins in Svalbard. These estimates are combined with data from two other glacier basins to assess the effectiveness of chemical denudation on Svalbard and to estimate rates of temporary (or transient) CO₂ drawdown. We use a solute provenance model to partition solutes into marine, aerosol, atmospheric and crustal components and to estimate their annual fluxes. Crustally derived solute fluxes are equivalent to a mean chemical denudation rate of 350 Σmeq⁺ m⁻² a⁻¹ for Svalbard (range: 160–560 Σmeq⁺ m⁻² a⁻¹), which lies within the global range of 94–4200 Σmeq⁺ m⁻² a⁻¹ for 21 glacier basins in the northern hemisphere, and is close to the continental average of 390 Σmeq⁺ m⁻² a⁻¹. Specific annual discharge is the most significant control upon chemical denudation in the glacierized basins, and basin lithology is an important secondary control, with carbonate‐rich and basaltic lithologies currently showing the greatest chemical denudation rates. Estimates of transient CO₂ drawdown are also directly associated with specific annual discharge and rock type. On Svalbard transient CO₂ drawdown lies in the range 110–3000 kg C km⁻² a⁻¹, whilst the range is 110–13000 kg C km⁻² a⁻¹ for the northern hemisphere glacial data set. Transient CO₂ drawdown is therefore usually low in the Svalbard basins unless carbonate or basalt rocks are abundant. The analysis shows that a large area of uncertainty in the transient CO₂ drawdown estimates exists due to the non‐stoichiometric release of solute during silicate hydrolysis. Silicate hydrolysis is particularly non‐stoichiometric in basins where the extent of glacierization is high, which is most probably an artefact of high flushing rates through ice‐marginal and subglacial environments where K‐feldspars are undergoing mechanical comminution. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   

Fluvial suspended sediment transport from cold and warm-based glaciers in Svalbard     

Andrew J. Hodson  Robert I. Ferguson 《地球表面变化过程与地形》1999,24(11):957-974

An analysis of temporal variability in proglacial suspended sediment concentration is undertaken using time series data collected from three Svalbard basins which include one largely cold-based glacier (Austre Brøggerbreen), one largely warm-based glacier (Finsterwalderbreen) and one intermediate polythermal glacier (Erdmannbreen). The temporal variability in proglacial suspended sediment concentration is analysed using multiple regression techniques in which discharge is supplemented by other predictors acting as surrogates for variability in sediment supply at diurnal, medium-term and seasonal timescales. These multiple regression models improve upon the statistical explanation of suspended sediment concentration produced by simple sediment rating curves but need to account for additional stochastic elements within the time series before they may be considered successful. An interpretation of the physical processes which are responsible for the regression model characteristics is offered as a basis for comparing the different arctic glaciofluvial suspended sediment transport systems with that of their better known temperate glaciofluvial counterparts. It is inferred that the largely warm-based glacier is dominated by sediment supply from subglacial reservoirs which evolve in a similar manner to temperate glaciers and which cause a pronounced seasonal exhaustion of suspended sediment supply. The largely cold-based glacier, however, is dominated by sediment supply from marginal sources which generate a responsive system at short time scales but no significant seasonal pattern. The intermediate polythermal glacier basin, which was anticipated to be similar to the warm-based glacier, instead shows a highly significant seasonal increase in suspended sediment supply from an unusual subglacial reservoir emerging under pressure in the glacier foreland. The temperate model of glaciofluvial suspended sediment transport is therefore found to be of limited use in an arctic context. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

The hydrochemistry of meltwaters draining a polythermal-based,high Arctic glacier,south Svalbard: I. The ablation season     

J. L. Wadham  A. J. Hodson  M. Tranter  J. A. Dowdeswell 《水文研究》1998,12(12):1825-1849

Solute and runoff time-series at Finsterwalderbreen, Svalbard, provide evidence for considerable basal routing of water and the existence of at least two contrasting subglacial chemical weathering environments. The hydrochemistry of a subglacial upwelling provides evidence for a snowmelt-fed subglacial reservoir that dominates bulk runoff during recession flow. High concentrations of Cl⁻ and crustal ions, high pCO₂ and ratios of [*SO²⁻₄/(*SO²⁻₄+HCO⁻₃)] close to 0·5 indicate the passage of snowmelt through a subglacial weathering environment characterized by high rock:water ratios, prolonged residence times and restricted access to the atmosphere. At higher discharges, bulk runoff becomes dominated by icemelt from the lower part of the glacier that is conveyed through a chemical weathering environment characterized by low rock:water ratios, short residence times and free contact with atmospheric gases. These observations suggest that icemelt is routed via a hydrological system composed of basal/ice-marginal, englacial and supraglacial components and is directed to the glacier margins by the ice surface slope. Upwelling water flows relatively independently of icemelt to the terminus via a subglacial drainage system, possibly constituting flow through a sediment layer. Cold basal ice at the terminus forces it to take a subterranean routing in its latter stages. The existence of spatially discrete flow paths conveying icemelt and subglacial snowmelt to the terminus may be the norm for polythermal-based glaciers on Svalbard. Proglacial mixing of these components to form the bulk meltwaters gives rise to hydrochemical trends that resemble those of warm-based glaciers. These hydrochemical characteristics of bulk runoff have not been documented on any other glacier on Svalbard to date and have significance for understanding interactions between thermal regime and glacier hydrology. © 1998 John Wiley & Sons, Ltd.  相似文献   

Microseismic Full Waveform Modeling in Anisotropic Media with Moment Tensor Implementation     

Peidong Shi  Doug Angus  Andy Nowacki  Sanyi Yuan  Yanyan Wang 《Surveys in Geophysics》2018,39(4):567-611

Seismic anisotropy which is common in shale and fractured rocks will cause travel-time and amplitude discrepancy in different propagation directions. For microseismic monitoring which is often implemented in shale or fractured rocks, seismic anisotropy needs to be carefully accounted for in source location and mechanism determination. We have developed an efficient finite-difference full waveform modeling tool with an arbitrary moment tensor source. The modeling tool is suitable for simulating wave propagation in anisotropic media for microseismic monitoring. As both dislocation and non-double-couple source are often observed in microseismic monitoring, an arbitrary moment tensor source is implemented in our forward modeling tool. The increments of shear stress are equally distributed on the staggered grid to implement an accurate and symmetric moment tensor source. Our modeling tool provides an efficient way to obtain the Green’s function in anisotropic media, which is the key of anisotropic moment tensor inversion and source mechanism characterization in microseismic monitoring. In our research, wavefields in anisotropic media have been carefully simulated and analyzed in both surface array and downhole array. The variation characteristics of travel-time and amplitude of direct P- and S-wave in vertical transverse isotropic media and horizontal transverse isotropic media are distinct, thus providing a feasible way to distinguish and identify the anisotropic type of the subsurface. Analyzing the travel-times and amplitudes of the microseismic data is a feasible way to estimate the orientation and density of the induced cracks in hydraulic fracturing. Our anisotropic modeling tool can be used to generate and analyze microseismic full wavefield with full moment tensor source in anisotropic media, which can help promote the anisotropic interpretation and inversion of field data.  相似文献   

The georgia rivers land margin ecosystem research program     

R.G. Wiegert  M. Alber  C. Alexander  J.O. Blanton  A. Chalmers  R.E. Hodson  M.A. Moran  L.R. Pomeroy  W.J. Wiebe 《Limnologica》1999,29(3):286

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Risk and trust in the cultural industries     

Mark Banks  Andy Lovatt  Justin O&#x;Connor  Carlo Raffo 《Geoforum》2000,31(4)

Preliminary claims have been made that working practices within cultural industries such as fashion, music, design and the night time economy may differ from Fordist or modernist arrangements. Cultural firms are often imagined to be more innovative, information-rich, dynamic, flexible, non-hierarchical and dependent on local clusters and networks than their Fordist counterparts (Lash and Urry, 1994). As their impact and significance increase, understanding how creative and cultural industries actually work is of high priority. This paper presents preliminary findings from an on-going ESRC funded study of cultural Micro and Small Enterprises (MSEs) within Manchester, England. Drawing on one element of the project, this paper considers the significance of risk and the importance of social trust for the cultural entrepreneur. Following a discussion of Beck’s development of risk as an analytical concept, and its intersection with Giddens’ notion of ‘active trust’, the paper examines how risk and trust are defined, experienced and negotiated by entrepreneurs in Manchester’s cultural industries. It is suggested that senses of risk are constitutive and often pivotal to the whole economic and social basis of cultural entrepreneurship – risk being central to choices made not only in business but in the lifeworld more generally. The paper then investigates the importance of trust for facilitating as well as countering or offsetting risk. Empirical evidence is presented to show how risk and trust co-relate and interact as constitutive elements within a wider set of shifting relationships between work, leisure and lifestyle in the ‘creative city’.  相似文献   

High-resolution radio observations of Seyfert galaxies in the extended 12-μm sample – I. The observations     

Andy Thean  Alan Pedlar  Marek J. Kukula  Stefi A. Baum  Christopher P. O'Dea 《Monthly notices of the Royal Astronomical Society》2000,314(3):573-588

We present 8.4-GHz VLA A-configuration observations of 87 sources from the mid-infrared-selected AGN sample of Rush et al. These 0.25-arcsec-resolution observations allow elongated radio structures tens of pc in size to be resolved, and enable radio components smaller than 3.5 arcsec to be isolated from diffuse galactic disc emission. When combined with previous data, matched radio observations covering 90 per cent of the sample have been collected, and these represent the largest subarcsecond–resolution radio imaging survey of a homogeneously selected sample of Seyfert galaxies to date.
We use our observations to identify five radio-loud AGN in the sample. The nature of the radio emission from Seyfert nuclei will be discussed in subsequent papers.  相似文献