Protein‐like fluorescence intensity as a possible tool for determining river water quality     

Andy Baker  Roger Inverarity 《水文研究》2004,18(15):2927-2945

The results of a comparison between chemical water quality determinants and river water fluorescence on the River Tyne, NE England, demonstrate that tryptophan‐like fluorescence intensity shows statistically significant relationships between nitrate, phosphate, ammonia, biochemical oxygen demand (BOD) and dissolved oxygen. Tryptophan‐like fluorescence intensity at the 280 nm excitation/350 nm emission wavelength fluorescence centre correlates with both phosphate (r = 0·80) and nitrate (r = 0·87), whereas tryptophan‐like fluorescence intensity at the 220 nm excitation/350 nm emission wavelength centre correlates with BOD (r = 0·85), ammonia (r = 0·70) and dissolved oxygen (r = ?0·65). The strongest correlations are between tryptophan‐like fluorescence intensity and nitrate and phosphate, which in the Tyne catchment derive predominantly from point and diffuse source sewage inputs. The correlation between BOD and the tryptophan‐like fluorescence intensity suggests that this fluorescence centre is related to the bioavailable or labile dissolved organic matter pool. The weakest correlations are observed between tryptophan‐like fluorescence intensity and ammonia concentration and dissolved oxygen. The weaker correlation with ammonia is due to removal of the ammonia signal by wastewater treatment, and that with dissolved oxygen due to the natural aeration of the river such that this is not a good indicator of water quality. The observed correlations only hold true when treated sewage, sewerage overflows or cross connections, or agricultural organic pollutants dominate the water quality—this is not true for two sites where airport deicer (propylene glycol, which is non‐fluorescent) or landfill leachate (which contains high concentrations of humic and fulvic‐like fluorescent DOM) dominate the dissolved organic matter in the river. Mean annual tryptophan‐like fluorescence intensity agrees well with the General Water Quality Assessment as determined by the England and Wales environmental regulators, the Environment Agency. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

A novel methodology for identifying environmental exposures using GPS data     

Andreea Cetateanu  Bogdan-Alexandru Luca  Andrei Alin Popescu  Angie Page  Ashley Cooper  Andy Jones 《International journal of geographical information science》2016,30(10):1944-1960

Aim: While studies using global positioning systems (GPS) have the potential to refine measures of exposure to the neighbourhood environment in health research, one limitation is that they do not typically identify time spent undertaking journeys in motorised vehicles when contact with the environment is reduced. This paper presents and tests a novel methodology to explore the impact of this concern.

Methods: Using a case study of exposure assessment to food environments, an unsupervised computational algorithm is employed in order to infer two travel modes: motorised and non-motorised, on the basis of which trips were extracted. Additional criteria are imposed in order to improve robustness of the algorithm.

Results: After removing noise in the GPS data and motorised vehicle journeys, 82.43% of the initial GPS points remained. In addition, after comparing a sub-sample of trips classified visually of motorised, non-motorised and mixed mode trips with the algorithm classifications, it was found that there was an agreement of 88%. The measures of exposure to the food environment calculated before and after algorithm classification were strongly correlated.

Conclusion: Identifying non-motorised exposures to the food environment makes little difference to exposure estimates in urban children but might be important for adults or rural populations who spend more time in motorised vehicles.  相似文献   

Effect of antecedent groundwater conditions on the triggering of static liquefaction landslides     

W. Andy Take  Ryley A. Beddoe  Roya Davoodi-Bilesavar  Ryan Phillips 《Landslides》2015,12(3):469-479

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Equipped to deal with uncertainty in climate and impacts predictions: lessons from internal peer review   总被引：1，自引：0，他引：1  

Anna Wesselink  Andrew Juan Challinor  James Watson  Keith Beven  Icarus Allen  Helen Hanlon  Ana Lopez  Susanne Lorenz  Friederike Otto  Andy Morse  Cameron Rye  Stephane Saux-Picard  David Stainforth  Emma Suckling 《Climatic change》2015,132(1):1-14

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The high hydraulic conductivity of three wooded tropical peat swamps in northeast Peru: measurements and implications for hydrological function          下载免费PDF全文

Thomas J. Kelly  Andy J. Baird  Katherine H. Roucoux  Timothy R. Baker  Eurídice N. Honorio Coronado  Marcos Ríos  Ian T. Lawson 《水文研究》2014,28(9):3373-3387

The form and functioning of peatlands depend strongly on their hydrological status, but there are few data available on the hydraulic properties of tropical peatlands. In particular, the saturated hydraulic conductivity (K) has not previously been measured in neotropical peatlands. Piezometer slug tests were used to measure K at two depths (50 and 90 cm) in three contrasting forested peatlands in the Peruvian Amazon: Quistococha, San Jorge and Buena Vista. Measured K at 50 cm depth varies between 0.00032 and 0.11 cm s^?1, and at 90 cm, it varies between 0.00027 and 0.057 cm s^?1. Measurements of K taken from different areas of Quistococha showed that spatial heterogeneity accounts for ~20% of the within‐site variance and that depth is a good predictor of K. However, K did not vary significantly with depth at Buena Vista and San Jorge. Statistical analysis showed that ~18% of the variance in the K data can be explained by between‐site differences. Simulations using a simple hydrological model suggest that the relatively high K values could lead to lowering of the water table by >10 cm within ~48 m of the peatland edge for domed peatlands, if subjected to a drought lasting 30 days. However, under current climatic conditions, even with high K, peatlands would be unable to shed the large amount of water entering the system via rainfall through subsurface flow alone. We conclude that most of the water leaves these peatlands via overland flow and/or evapotranspiration. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Development of a Neolithic pine tree‐ring chronology for northern Scotland     

Andy Moir 《第四纪科学杂志》2012,27(5):503-508

The peatlands of northern Scotland (one of the largest and most intact areas of blanket bog in the world) contain a rare widespread horizon of subfossil pine in stratigraphic context. Eighteen bog pine from three new sites are incorporated into a mean Neolithic pine chronology now composed of subfossil pine from 12 sites, which is tree‐ring‐dated against Irish bog pine chronologies to span 3198–2757 BC. Germination and peaks of radial growth infer drier conditions between 3199 and 3130 BC. Dying‐off phases and depression of growth reflect a change to wetter conditions between 3023 and 3002 BC and a terminal decline of pine between 2809 and 2782 BC. The close synchronization of germination/die‐off phases and major ring‐width variations between sites across this region indicates that the environmental changes are probably triggered by climate change. Twenty‐four bog pine samples remain unmatched. Future multi‐discipline research into this important example of climatic change at the Neolithic/Bronze Age transition is recommended. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Semipermeable membrane devices link site-specific contaminants to effects: PART II - A comparison of lingering Exxon Valdez oil with other potential sources of CYP1A inducers in Prince William Sound, Alaska   总被引：1，自引：1，他引：0  

Short JW  Springman KR  Lindeberg MR  Holland LG  Larsen ML  Sloan CA  Khan C  Hodson PV  Rice SD 《Marine environmental research》2008,66(5):487-498

We deployed semipermeable membrane devices (SPMDs) on beaches for 28 days at 53 sites in Prince William Sound (PWS), Alaska, to evaluate the induction potential from suspected sources of cytochrome P450 1A (CYP1A)-inducing contaminants. Sites were selected to assess known point sources, or were chosen randomly to evaluate the region-wide sources. After deployment, SPMD extracts were analyzed chemically for persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAH). These results were compared with hepatic CYP1A enzyme activity of juvenile rainbow trout injected with the same extracts prior to clean-up for the chemical analyses. Increased CYP1A activity was strongly associated with PAH concentrations in extracts, especially chrysene homologues but was not associated with POPs. The only apparent sources of chrysene homologues were lingering oil from Exxon Valdez, asphalt and bunker fuels released from storage tanks during the 1964 Alaska earthquake, creosote leaching from numerous pilings at one site, and PAH-contaminated sediments at Cordova Harbor. Our results indicate that PWS is remarkably free of pollution from PAH when nearby sources are absent as well as from pesticides and PCBs generally.  相似文献   

Rotation of a rigid satellite with a fluid component: a new light onto Titan’s obliquity     

Gwenaël Boué  Nicolas Rambaux  Andy Richard 《Celestial Mechanics and Dynamical Astronomy》2017,129(4):449-485

We revisit the rotation dynamics of a rigid satellite with either a liquid core or a global subsurface ocean. In both problems, the flow of the fluid component is assumed inviscid. The study of a hollow satellite with a liquid core is based on the Poincaré–Hough model which provides exact equations of motion. We introduce an approximation when the ellipticity of the cavity is low. This simplification allows to model both types of satellite in the same manner. The analysis of their rotation is done in a non-canonical Hamiltonian formalism closely related to Poincaré’s “forme nouvelle des équations de la mécanique”. In the case of a satellite with a global ocean, we obtain a seven-degree-of-freedom system. Six of them account for the motion of the two rigid components, and the last one is associated with the fluid layer. We apply our model to Titan for which the origin of the obliquity is still a debated question. We show that the observed value is compatible with Titan slightly departing from the hydrostatic equilibrium and being in a Cassini equilibrium state.  相似文献   

Diversity and burglary: Do community differences matter?     

Usman L. Gulma  Andy Evans  Alison Heppenstall  Nick Malleson 《Transactions in GIS》2019,23(2):181-202

Diversity within a population has been linked to levels of both social cohesion and crime. Neighborhood crimes are the result of a complex set of factors, one of which is weak community cohesion. This article seeks to explore the impacts of diversity on burglary crime in a range of neighborhoods, using Leeds, UK as a case study. We propose a new approach to quantifying the correlates of burglary in urban areas through the use of diversity metrics. This approach is useful in unveiling the relationship between burglary and diversity in urban communities. Specifically, we employ stepwise multiple regression models to quantify the relationships between a number of neighborhood diversity variables and burglary crime rates. The results of the analyses show that the variables that represent diversity were more significant when regressed against burglary crime rates than standard socio‐demographic data traditionally used in crime studies, which do not generally use diversity variables. The findings of this study highlight the importance of neighborhood cohesion in the crime system, and the key place for diversity statistics in quantifying the relationships between neighborhood diversities and burglary. The study highlights the importance of policy planning aimed at encouraging community building in promoting neighborhood safety.  相似文献   

Principles of Geographical Information Systems.: By Peter A. Burrough and Rachael A. McDonnell     

Andy Kliskey 《New Zealand geographer》2000,56(2):62-62

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