Fractionation of rare-earth elements in plants during experimental growth in varied clay substrates     

Khadija Semhi  Sam Chaudhuri  Norbert Clauer 《Applied Geochemistry》2009

The distribution and content of rare-earth elements (REEs) were determined in two radish species, the cultivated Raphanus sativus and the wild Raphanus raphanistrum, that were grown under laboratory-controlled conditions, in three substrates consisting of illite for one and two smectite substrates for the others, with the two smectite substrates being characterised by different porosities. The plants were split into leaves and stems + roots for analysis. The results indicate that both species take up systematically higher amounts of REEs when grown in the illite substrate, even considering that the smectite equivalent contains about three times more REEs. The REE uptake is also more plant species than mineral composition dependent: R. raphanistrum takes up 3.5–6.7 times more REEs than R. sativus, depending on the substrate, its porosity and the considered plant segments. Increased substrate porosity favours the take up of the REEs, but no specific uptake is observed in leaves relative to that in the combined stems and roots. The transfer of the REEs from minerals to plant organs does not appear to induce systematically identical patterns: (1) in the case of R. sativus, a positive Eu anomaly is visible in all patterns from both segment groups grown in both substrates. When grown in illite, the heavy REEs are also enriched in the stems and roots, which has not been observed in any other organ or in the other substrate and (2) in the case of R. raphanistrum, a very significant positive Gd anomaly, which is not expected to fractionate relative to the other REEs as do Ce and Eu, is observed in all segments of the plants grown in both substrates. A slight negative Ce anomaly is also visible in some of the REE patterns, suggesting some changes in the oxidation–reduction conditions in the substrates near the roots during plant growth. The comparison of the REE patterns from leaves relative to those of the roots + stems shows that those of R. raphanistrum grown in illite provide a spectrum that is very specific with significant deficits in La, Ce, Gd, Tm, Yb and Lu in the leaves. In the other cases, the patterns do not outline significant differences except for R. sativus grown in illite, in which the leaves are enriched in light and medium REEs from La to Gd relative to the stems + roots.  相似文献   

An investigation on the dynamic and scale interactive processes for estimating the predictability of cloudburst over elevated orography     

J. Pal  P. P. Debnath  S. Guhathakuran  S. Chaudhuri 《Natural Hazards》2017,85(1):267-282

The cloudburst is defined as a heavy downpour at a very high rainfall rate over small spatio-temporal scale. The Indian states of Uttarakhand (30°15′N; 79°15′E) and Himachal Pradesh (32°29′N; 75°10′E) are prone to cloudburst due to its geographical setup. The large-scale monsoon flow along with elevated orography makes cloudburst phenomena frequent a well as severe over the regions. However, cloudburst and the heavy rainfall events occasionally, become difficult to distinguish. The present study attempts to identify the processes associated with cloudburst over elevated orography and compare it with one of the most debated event of 2013 which was reported as heavy rainfall but, not a cloudburst by Indian Meteorological Department (IMD). The temporal variations of rainfall and cloud-top pressure (CTP) are considered to identify the genesis of the event. The vertical developments of the system along with large-scale circulation pattern are estimated in the present study. The result of the study reveals that the mid-tropospheric dry entrainment, low-level temperature inversion and cloud height clearly distinguish the “cloudburst” and “heavy rainfall” events and confirms that the system of 2013 was indeed a heavy rainfall event and not a cloudburst.  相似文献   

Probabilistic assessment for seismic performance of port structures   总被引：2，自引：0，他引：2  

Ung Jin Na  Samit Ray Chaudhuri  Masanobu Shinozuka   《Soil Dynamics and Earthquake Engineering》2008,28(2):147-158

Past experience has shown that ports are often susceptible to severe damage during earthquakes. From field damage data of 1995 Kobe earthquake, it is observed that the seismic behavior of port structures shows significant variability. In this study, a 2D numerical model, representing PC1 berth located in Port Island, Kobe and damaged in the 1995 Kobe earthquake, has been developed and used to simulate seismic behavior. It has been found that the uncertainties in the friction angle and the shear modulus of reclaimed soil contribute most to the variability of the residual horizontal displacement (RHD) response of the quay wall of port structures. To investigate the propagation of uncertainties of soil–structure system to the quay wall, a tornado diagram and a first-order second-moment analysis are used. Uncertainty of ground motions has also been investigated. Based on the results, design considerations have been provided.  相似文献   

Neutrino synchrotron radiation     

Probhas Ray Chaudhuri 《Astrophysics and Space Science》1970,8(3):448-456

The neutrino luminosity of several models of neutron stars has been computed according to the photon-neutrino coupling theory and compared with that of the current-current coupling theory. It is shown that the NSR process alone should have cooled the core of the neutron star created in a supernova explosion in 1954 A.D. to a temperature around 2×10⁹ K according to the photon-neutrino coupling theory.The emission power of the star is greater than the emission power of the X-ray source discovered in the Crab Nebula; so the source may be interpreted as the thermal radiation of the star according to the photon-neutrino coupling theory.  相似文献   

Multimethod (K–Ar, Rb–Sr, Sm–Nd) dating of bentonite minerals from the eastern United States     

Theofilos Toulkeridis  Norbert Clauer  Sam Chaudhuri  & Steve L. Goldstein 《Basin Research》1998,10(2):261-270

Isotopic determinations (K–Ar, Rb–Sr and Sm–Nd), and trace and rare-earth elemental analyses were made on a few biotite and clay fractions of Palaeozoic bentonite units from the eastern United States. The clay fractions were gently leached with dilute hydrochloric acid to study separately the acid-soluble minerals intimately associated with the extracted clay particles. The data highlight interesting potentials for this integrated approach to decipher complex tectonothermal evolutions of sedimentary basins. Biotite K–Ar ages are consistent with a Middle Ordovician stratigraphic age for the bentonite units with a mean age of 459±10 Ma. The clay residues give a Sm–Nd isochron age of 397±44 Ma, indicative of their crystallization during Acadian tectonothermal activity at about 200 °C. The clay leachates, which are considered to represent mineral phases different from clay material, yield a distinct Sm–Nd isochron age of 285±18 Ma which is indistinguishable from K–Ar ages obtained previously on the clays, suggesting a thermally induced diffusion of radiogenic ⁴⁰Ar from clay particles during Alleghenian–Ouachita orogenic activity. The Rb–Sr system of the clay material seems to have been variably disturbed, except for the sample taken near the Allegheny Front for which an age of 179±4 Ma suggests a further localized activity of the thrust system at about 130–150 °C. Clearly the limited number of samples does not allow us to perfectly constrain an evolutionary model. However, analysis of the soluble minerals for their contents in metal and rare-earth elements suggests that metal-carrying fluids migrated during the Alleghenian–Ouachita orogenic activity in the eastern North American continent. Consequently, they could have contributed to the concentration of ore deposits in the region, but this possibility needs to be tested with a larger data base.  相似文献   

Evolution of the Banded Gneissic Complex of central Rajasthan,India     

Dr. K. Naha  A. K. Chaudhuri  P. Mukherji 《Contributions to Mineralogy and Petrology》1967,15(3):191-201

The Banded Gneissic Complex of central Rajasthan, the only gneissic basement in India considered to underlie an early Precambrian sedimentary suite unconformably, comprises composite gneisses formed by extensive migmatization of metasedimentary rocks of diverse composition. The migmatites and the metasedimentaries maintain a structural continuity in a plan of superposed deformations, with the migmatite front involved in the early folding but transgressing the stratigraphic boundaries. Structures in the metasedimentary palaeosomes within the gneisses match in their entirety those in the migmatite host and the metasedimentary bands outside. On a smaller scale of microsections, migmatites show para tectonic crystallization with reference to the first deformation. The Banded Gneissic Complex thus loses its unique position in the Indian Precambrians as older than the earliest decipherable sedimentary series, but is older than the Aravalli rocks of the type area, the partially migmatized metasedimentaries belonging to an earlier series.  相似文献   

The essence of multifractal detrended fluctuation technique to explore the dynamics of soil radon precursor for earthquakes     

Chiranjib Barman  Hirok Chaudhuri  Argha Deb  Debasis Ghose  Bikash Sinha 《Natural Hazards》2015,78(2):855-877

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Medium-range forecast of cyclogenesis over North Indian Ocean with multilayer perceptron model using satellite data     

Sutapa Chaudhuri  Sayantika Goswami  Anirban Middey 《Natural Hazards》2014,70(1):173-193

An attempt is made in this study to develop a model to forecast the cyclonic depressions leading to cyclonic storms over North Indian Ocean (NIO) with 3 days lead time. A multilayer perceptron (MLP) model is developed for the purpose and the forecast quality of the model is compared with other neural network and multiple linear regression models to assess the forecast skill and performances of the MLP model. The input matrix of the model is prepared with the data of cloud coverage, cloud top temperature, cloud top pressure, cloud optical depth, cloud water path collected from remotely sensed moderate resolution imaging spectro-radiometer (MODIS), and sea surface temperature. The input data are collected 3 days before the cyclogenesis over NIO. The target output is the central pressure, pressure drop, wind speed, and sea surface temperature associated with cyclogenesis over NIO. The models are trained with the data and records from 1998 to 2008. The result of the study reveals that the forecast error with MLP model varies between 0 and 7.2 % for target outputs. The errors with MLP are less than radial basis function network, generalized regression neural network, linear neural network where the errors vary between 0 and 8.4 %, 0.3 and 24.8 %, and 0.3 and 32.4 %, respectively. The forecast with conventional statistical multiple linear regression model, on the other hand, generates error values between 15.9 and 32.4 %. The performances of the models are validated for the cyclonic storms of 2009, 2010, and 2011. The forecast errors with MLP model during validation are also observed to be minimum.  相似文献   

Intensity forecast of tropical cyclones over North Indian Ocean using multilayer perceptron model: skill and performance verification     

Sutapa Chaudhuri  Debashree Dutta  Sayantika Goswami  Anirban Middey 《Natural Hazards》2013,65(1):97-113

The coastal regions of India are profoundly affected by tropical cyclones during both pre- and post-monsoon seasons with enormous loss of life and property leading to natural disasters. The endeavour of the present study is to forecast the intensity of the tropical cyclones that prevail over Arabian Sea and Bay of Bengal of North Indian Ocean (NIO). A multilayer perceptron (MLP) model is developed for the purpose and compared the forecast through MLP model with other neural network and statistical models to assess the forecast skill and performances of MLP model. The central pressure, maximum sustained surface wind speed, pressure drop, total ozone column and sea surface temperature are taken to form the input matrix of the models. The target output is the intensity of the tropical cyclones as per the T??number. The result of the study reveals that the forecast error with MLP model is minimum (4.70?%) whereas the forecast error with radial basis function network (RBFN) is observed to be 14.62?%. The prediction with statistical multiple linear regression and ordinary linear regression are observed to be 9.15 and 9.8?%, respectively. The models provide the forecast beyond 72?h taking care of the change in intensity at every 3-h interval. The performance of MLP model is tested for severe and very severe cyclonic storms like Mala (2006), Sidr (2007), Nargis (2008), Aila (2009), Laila (2010) and Phet (2010). The forecast errors with MLP model for the said cyclones are also observed to be considerably less. Thus, MLP model in forecasting the intensity of tropical cyclones over NIOs may thus be considered to be an alternative of the conventional operational forecast models.  相似文献   

Chemically stabilized soil organic carbon fractions in a reclaimed minesoil chronosequence: implications for soil carbon sequestration   总被引：1，自引：0，他引：1  

Sriroop Chaudhuri  Louis M. McDonald  Eugenia M. Pena-Yewtukhiw  Jeff Skousen  Mimi Roy 《Environmental Earth Sciences》2013,70(4):1689-1698

With adoption of appropriate reclamation strategies, minesoils can sequester significant amount of soil organic carbon (SOC). The objective of this study was to isolate different SOC fractions and coal-C in a reclaimed minesoil chronosequence and assess effects of increasing time since reclamation on each SOC fraction and selected soil properties. The chronosequence was comprised of four minesoils with time since reclamation ranging between 2 and 22 years. Total SOC (TSOC, summation of all SOC fractions), ranged between 20 and 8 g kg^?1, respectively, at the oldest (Mylan Park) and youngest (WVO1) minesite, indicating increasing SOC sequestration along the chronosequence. The humin fraction accounted for about 43 and 7 % of TSOC, respectively, at Mylan Park and WVO1, indicating increasing humification and biochemical stabilization of SOC with increasing time since reclamation. At WVO1, >60 % of TSOC was apportioned among the acid-hydrolysable (labile) and mineral-bound SOC fractions. Total soil carbon (TSC, TSOC + coal-C) were significantly (p < 0.05) related to the humin fraction in older minesoils, whereas with the acid-hydrolysable (labile) fraction in the younger minesoils indicating that C stabilization mechanisms differed substantially along the chronosequence. Coal-C was unrelated to any SOC fraction at all minesites indicating that SOC sequestration estimations in this chronosequence was unaffected by coal-C. Soil cation exchange capacity and electrical conductivity were significantly (p < 0.05) related to the humin fraction at Mylan Park while to the acid-hydrolysable and mineral-bound SOC fractions at WVO1 indicating that the relative influences of different SOC fractions on soil quality indicators differed substantially along the chronosequence.  相似文献