Structure, ordering and cation interactions in Ca-free P2 1 /c clinopyroxenes     

R. J. Angel  C. McCammon  A. B. Woodland 《Physics and Chemistry of Minerals》1998,25(4):249-258

A suite of 14 synthetic Ca-free P2 ₁ /c low-clinopyroxenes of compositions across the enstatite-ferrosilite (En-Fs) join have been studied by X-ray powder diffraction and Mössbauer spectroscopy. The crystal structure of one sample with composition X _Fs=0.39 was determined by single-crystal X-ray diffraction. The powder diffraction data show that there is no significant (<0.25% at X _Fs=0.5) excess volume of mixing on the enstatite-ferrosilite join. The molar volumes are described by V=31.261(17)+1.677(23) X _Fs cm³.mol(MSiO₃)^–1. The linear behaviour of volume with composition arises from the compensating effects of non-linear changes in the unit-cell parameters with composition. Unweighted fits to the data yielded the relationships: a=9.6100(15)+0.105(2)X _Fs, b=8.8156(28)+0.218(12)X _Fs+0.0481(117)X ² _Fs , c?=5.1702(4)+0.0879(21)X _Fs–0.0214(21)X ² _Fs , β=108.345(8)+0.947(30)X _Fs–0.805(26)X ² _Fs . The strong positive deviation of β from linearity is directly correlated to the difference in site occupancies between M1 and M2 as determined by Mössbauer spectroscopy and arises directly from the expansion of M2-O1 and M2-O3 bonds upon initial substitution of Fe for Mg in enstatite. The hyperfine parameters from Mössbauer spectra are consistent with variations in the average local environment as recorded by the X-ray data. Asymmetric line broadening of the Mössbauer spectra provides evidence for next-nearest neighbour effects, and is consistent with no significant clustering of Fe or Mg within the samples.  相似文献   

Phthalate ester plasticizers,DDT, DDE and polychlorinated biphenyls in biota from the Gulf of Mexico     

C.S Giam  H.S Chan  G.S Neff 《Marine pollution bulletin》1978,9(9):249-251

The levels of phthalate ester plasticizers, DDT, DDE and polychlorinated biphenyls (PCBs) were determined in the tissues of 18 species of marine organisms from the northwestern Gulf of Mexico. Low levels of the most widely used phthalate, di-(2-ethylhexyl) phthalate, were found in the majority of the samples; no other phthalates were detected. DDT, DDE and PCBs were found in all samples, but at somewhat lower levels than those found in our 1971 survey. A decrease in p,p′-DDT/p,p′-DDE ratios relative to 1971 was also noted.  相似文献   

Effects of bottom sediments on the survival of Enterobacter aerogenes in seawater     

Kwong-Yu Chan  S.H. Wong  C.Y. Mak 《Marine pollution bulletin》1979,10(7):205-210

The survival of the coliform bacterium Enterobacter aerogenes in seawater was greatly affected by the underlying bottom sediments. The presence of sediments which contained higher concentrations of organic nutrients than the overlaying seawater prolonged the survival and even enabled growth of the bacterial cells. Results obtained from chemical analysis indicated that sediments of fine-grained, silt-clay type contained highest amounts of organic nutrients as compared with sediments with larger particle sizes such as silt and sand grains. Thus, nutrient contents of the sediments were found to be inversely proportional to sediment particle size. The degree of prolonged survival of E. aerogenes was also found to be inversely proportional to the size of the sediment particles presented. Release of the bound nutrients which became available to cells of E. aerogenes from sediments by action of waves and human activities can explain, at least in part, why high counts of coliform bacteria are obtained in coastal and beach waters.  相似文献   

Electromagnetic induction in the San Juan Bay region of Vancouver Island     

G.H. Chan  H.W. Dosso  L.K. Law 《Physics of the Earth and Planetary Interiors》1981,27(2):114-121

The response of the electric and magnetic field variations over the San Juan Bay region of Vancouver Island is studied using a scaled laboratory analogue model. The laboratory frequencies simulate periods of 10 and 100 s in the geophysical problem. The model results indicate that, for both E- and H-polarization of the source field, induced current in the ocean is deflected around Cape Flattery and channelled into the Juan de Fuca Strait. With increasing period, the proportion of current channelled into the Strait decreases sharply. Induced current in the strait is also funnelled into San Juan Bay, a finger-shaped bay ca. 4 km wide and 7.5 km long, for both polarizations of the source field. The effect of the Bay on the field response is confined to the local region, within approximately 6 km of the centre of the Bay. Good agreement between field station and analogue model H_z results was obtained for the San Juan Bay. The behaviour of the Parkinson arrow for these two stations is examined with the aid of the analogue model results.  相似文献   

On the role of the Asian monsoon in the angular momentum and kinetic energy balances of the tropics     

Abraham H. Oort  Paul H. Chan 《Pure and Applied Geophysics》1977,115(5-6):1167-1186

The balance conditions of relative angular momentum and time-mean kinetic energy and their annual variations are studied for the Northern Hemisphere tropical belt. The belt is divided into two roughly equal size parts, the monsoon and the extramonsoon regions. The data used consist of all available daily rawinsonde reports from the world areological network for the two 5-year periods 1958–63 and 1968–73.In winter, the trade winds in the monsoon and extramonsoon regions are both sources of westerly relative angular momentum for the middle latitude circulation. However, it is found that the angular momentum gained in the extramonsoon region of the Tropics is mostly destroyed by a net southward flow of mass in that region, and becomes regenerated in the monsoon region by a net northward flow of mass there. This excess of angular momentum together with the angular momentum picked up locally in the monsoon region is almost all exported across its northern boundary. It is further found that in winter the Tropics are also an important source of mean kinetic energy for middle latitudes. Again almost all export of kinetic energy was found to take place across the northern boundary of the monsoon sector. Most of this energy must be generated through the pressure gradient term inside the monsoon region itself, the transformation from transient eddy kinetic energy being very small. The proper evaluation of the pressure gradient appears to be the main stumbling block in the present study, preventing us from estimating the generation and thereby, as a residual, the frictional dissipation in the two regions.In summer, the extramonsoon region remains a source of angular momentum, but the monsoon region with its surface westerlies acts as a sink, leading to a sharp reduction (and even a midsummer reversal) of the export into middle latitudes. Also the export of mean kinetic energy almost vanishes in summer, except for a small southward transfer across the equator. The calculations for two 5-year periods give very similar estimates and thereby show the reliability of the results.Parts of this paper were presented at the International Symposium on Monsoons, March 7–12, 1977 in New Delhi, India.  相似文献   

Regional Seas integrative studies,as a basis for an ecosystem-based approach to management: The case of the Bay of Biscay     

Angel Borja  Michael Collins 《Continental Shelf Research》2009,29(8):951-956

Marine legislation world-wide has, as a recent final objective, the maintenance of a good environmental or ecological status for marine waters, habitats and resources. The concept of environmental status takes into account the structure, function and processes of marine ecosystems, bringing together physical, chemical, physiographic, geographic and climatic factors: subsequently, integrating such conditions, with anthropogenic impacts and activities undertaken in the area concerned. Such an approach is intended to permit an assessment of the environmental status at the ecosystem level, i.e. ‘ecosystem-based approach’, or ‘ecosystem-based management’.Such legislation emphasises the need for the development of methodologies, to assess environmental status. As such the knowledge acquired within Regional Seas, discussed at International Symposia and, finally, published as Special Issues, can serve as the basis for a regional ecosystem-based approach to management and the integrative assessment of marine systems. Hence, the Bay of Biscay is used in this contribution, as an example, to show past and present research, together with perspectives for the future. It is concluded that collaboration between institutions (marine research institutes, universities) and countries (France, Spain, Portugal, the United Kingdom and Ireland) could result in an interesting ‘case-study’, for the further implementation of the European Marine Strategy Framework Directive, at the level of this particular Regional Sea. In this way, the experience gained in the implementation of the Water Framework Directive within the ecoregion, together with the information collated in the eleven International Symposia of Oceanography of the Bay of Biscay, celebrated until now, can be very useful, for an ecosystem-based management approach for this Regional Sea.  相似文献   

Observational constraints of sterile neutrinos in galaxies     

M. H. Chan  M.-C. Chu 《Astrophysics and Space Science》2009,319(2-4):143-147

We study a model in which degenerate sterile neutrinos account for galactic dark matter. We fit the rotation curves of 5 dwarf galaxies with the degenerate sterile neutrinos in hydrostatic equilibrium. Also we estimate the range of sterile neutrino mass by calculating the upper and lower bounds of the mass densities of sterile neutrino halos in the outermost regions of 21 normal galaxies. The observed rotation curves of 5 dwarf galaxies and 21 normal galaxies are consistent with having sterile neutrinos with mass (26–30) eV, and the similarity of the rotation curves of different galaxies emerges naturally in our model.  相似文献   

The effects of rock fragments on hydrologic and hydraulic responses along a slope     

Kou‐Chan Hung  Ken'ichirou Kosugi  Tim Hau Lee  Takahisa Misuyama 《水文研究》2007,21(10):1354-1362

A model describing the three‐dimensional matrix flow along a slope with rock fragments or impermeable blocks was developed. The model was combined with modified Picard's iteration to ensure mass conservation in the unsaturated flow. We found that rock fragments obstruct water flow along the slope. The groundwater table must be raised to provide a sufficient pore water pressure gradient to facilitate water flow, but higher pore water pressure may induce slope failure. We also conducted a bench‐scale laboratory flume experiment to examine the effects of impermeable blocks on downstream seepage flow. In addition, a numerical experiment was conducted to examine how different arrangements of impermeable blocks affect downstream seepage flow and pore water pressure. This research demonstrated that the hydraulic phenomena were affected when impermeable blocks were present, and pore water pressure increased as the position of impermeable blocks was lowered. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Assessing the benthic quality status of the Bohai Bay (China) with proposed modifications of M-AMBI   总被引：1，自引：1，他引：0  

CAI Wenqian  BORJA Angel  LIN Kuixuan  ZHU Yanzhong  ZHOU Juan  LIU Lusan 《海洋学报(英文版)》2015,34(10):111-121

Multivariate AZTI's Marine Biotic Index (M-AMBI) was designed to indicate the ecological status of European coastal areas. Based upon samples collected from 2009 to 2012 in the Bohai Bay, we have tested the response of variations of M-AMBI, using biomass (M-BAMBI) in the calculations, with different transformations of the raw data. The results showed that the ecological quality of most areas in the study indicated by M-AMBI was from moderate to bad status with the worse status in the coastal areas, especially around the estuaries, harbors and outfalls, and better status in the offshore areas except the area close to oil platforms or disposal sites. Despite large variations in nature of the input data, all variations of M-AMBI gave similar spatial and temporal distribution patterns of the ecological status within the bay, and showed high correlation between them. The agreement of new ecological status obtained from all M-AMBI variations, which were calculated according to linear regression, was almost perfect. The benthic quality, assessed using different input data, could be related to human pressures in the bay, such as water discharges, land reclamation, dredged sediment and drilling cuts disposal sites. It seems that M-BAMBI were more effective than M-NABMI (M-AMBI calculated using abundance data) in indicating human pressures of the Bay. Finally, indices calculated with more severe transformations, such as presence/absence data, could not indicate the higher density of human pressures in the coastal areas of the north part of our study area, but those calculated using mild transformation (i.e., square root) did.  相似文献   

Measuring and managing changes in estuaries and lagoons: morphological and eco-toxicological aspects   总被引：1，自引：0，他引：1  

Zonta R  Guerzoni S  Pérez-Ruzafa A  de Jonge VN 《Marine pollution bulletin》2007,55(10-12):403-406

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