Geochemical and statistical analysis of trace metals in atmospheric particulates in Wuhan, central China   总被引：3，自引：0，他引：3  

Weiwei Lv  Yanxin Wang  Xavier Querol  Xinguo Zhuang  Andrés Alastuey  Angel López  Mar Viana 《Environmental Geology》2006,51(1):121-132

The geochemical characteristics of trace metals (As, Cr, Co, Cd, Cu, Mn, Ni, Pb, V and Zn) in PM10 in Wuhan, the biggest metropolitan in central China, as well as their sources and contributions were analyzed. As PM10 has been the principal contaminant of air in Wuhan for years, concentrations of trace metals were measured in PM10 using high-volume samplers at one urban (Hankou) and one industrial (Changqian) site in Wuhan between September 2003 and September 2004. Based on the results, PM10 in Wuhan is characterized by relatively high levels of As, Cd, Mn, Pb and Zn compared with other Asian cities. The time-series of these elements indicated that As, Cu and Zn at both sites have similar trends, whereas Pb levels showed different patterns due to different emission sources. Factor analysis was applied to the datasets focusing on the apportionment of the mass of selected trace metals. Results indicate that Pb, Cd and As have a common source (smelting) at both sites, whereas the sources of Ni vary from coal combustion and steel in Changqian to mineral and traffic in Hankou.  相似文献   

Rainfall spatial organization and areal reduction factors in the metropolitan area of Barcelona (Spain)     

Raul Rodríguez  Xavier Navarro  M. Carmen Casas  Angel Redaño 《Theoretical and Applied Climatology》2013,114(1-2):1-8

The rainfall spatial organization in the metropolitan area of Barcelona (Spain) has been studied from records of an urban rain gauge network in the period 1994–2009. Using statistical and regional analysis techniques, correlation between data recorded by the different rain gauges has been calculated, and the effective number of independent stations (n _eq) equivalent to the used network has been determined. It has been found out that for durations longer than 20 min, the areal rainfall return period observed for a storm registered by the network approximately decreases by a factor of 1/n _eq in relation to the current point rainfall intensity–duration–frequency relationships for the metropolitan area of Barcelona. Using objective analysis techniques, continuous precipitation fields have been generated on a regular grid with a spatial resolution of 300?×?300 m for the storms registered by the rain gauges from 1994 to 2009, for durations from 10 min to 24 h. The precipitation fields obtained have been useful to estimate the characteristic areal reduction factors in the metropolitan area of Barcelona. A direct relationship has been found between the areal reduction factor for all the area corresponding to the urban rainfall network of Barcelona and the effective number of n _eq for every duration considered.  相似文献   

Hybrid loss exceedance curve (HLEC) for disaster risk assessment   总被引：1，自引：1，他引：0  

C. A. Velásquez  O. D. Cardona  M. G. Mora  L. E. Yamin  M. L. Carreño  A. H. Barbat 《Natural Hazards》2014,72(2):455-479

Taken into account that the natural hazard risk is a contingent liability and, therefore, a sovereign risk for national governments, it is important to assess properly the potential losses to design a suitable risk reduction, retention and transfer strategy. In this article, a disaster risk assessment methodology is proposed based on two approaches: on the one hand, the empiric estimation of losses, using information available from local disaster databases, allowing estimating losses due to small-scale events and, on the other hand, probabilistic evaluations to estimate losses for greater or even catastrophic events, for which information usually is not available due to the lack of historical data. A “hybrid” loss exceedance curve is thus determined, which combines the results of these two approaches and represents the disaster risk in a proper and complete way. This curve merges two components: the corresponding to small and moderate losses, calculated using an inductive and retrospective analysis, and the corresponding to extreme losses, calculated using a deductive and prospective analysis. Applications of this risk assessment technique are given in this article for eleven countries.  相似文献   

The new European Marine Strategy Directive: difficulties, opportunities, and challenges   总被引：1，自引：0，他引：1  

Borja A 《Marine pollution bulletin》2006,52(3):239-242

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Off‐reef planktivorous reef fishes respond positively to decadal‐scale no‐take marine reserve protection and negatively to benthic habitat change          下载免费PDF全文

Justin R. Rizzari  Angel C. Alcala 《Marine Ecology》2017,38(3)

The effects of no‐take marine reserve (NTMR) protection and changes in benthic habitat on fusiliers (family Caesionidae) were investigated at four small Philippine offshore islands on time scales of 10–31 years. Fusiliers are highly mobile, schooling, medium‐sized planktivorous fish that generally feed “off‐reef.” For these reasons, and given the small size of the NTMRs (3.6–37.5 ha) in this study, it was predicted that fusilier density would be unlikely to show clear effects of NTMR protection, or to respond to changes in benthic habitat. In contrast to predictions, clear NTMR effects were observed on fusilier density at three of the four NTMRs, with durations of protection from 14 to 31 years. Furthermore, the study provided strong evidence that benthic variables, specifically cover of live hard coral and dead substratum, affect the density of fusiliers. This effect of benthic habitat on density was highlighted by several major environmental disturbances that caused shifts in the benthic habitat from live hard coral to dead substratum. For two of the three most abundant species of fusiliers individually, and for all three of them combined (Pterocaesio pisang + Caesio caerulaurea + Pterocaesio digramma/tessellata), as live hard coral cover decreased, fish density decreased. It is hypothesized that these “off‐reef” daytime feeders may have such a strong association with live hard coral cover because they use this habitat as nocturnal sleeping sites. Multivariate analyses indicated that, across all sites and times sampled, cover of live hard coral and dead substratum accounted for 38% of the variation in fish assemblage structure. These results are important as there are very few reports in the published literature of strong effects of NTMR protection or changes in benthic habitat on the density and assemblage structure of fusiliers.  相似文献   

High-pressure behaviour and equation of state of calcite, CaCO3     

Simon A. T. Redfern  Ross J. Angel 《Contributions to Mineralogy and Petrology》1999,134(1):102-106

The high-pressure response of the cell parameters of calcite, CaCO₃, has been investigated by single crystal X-ray diffraction. The unit cell parameters have been refined from 0 to 1.435?GPa, and the linear and volume compressibilities have been measured as β _a =2.62(2)?×?10^?3?GPa^?1,β _c =7.94(7)?×?10^?3?GPa^?1, β _v =13.12?×?10^?3?GPa^?1. The bulk modulus has been obtained from a fit to the Birch-Murnaghan equation of state, giving K ₀=73.46?±?0.27?GPa and V ₀=367.789 ±?0.004?ų with K′=4. Combined with earlier data for magnesite, ankerite and dolomite, these data suggest that K ₀ V ₀ is a constant for the Ca-Mg rhombohedral carbonates.  相似文献   

Structural characterisation of the high-pressure phase CaAl4Si2O11     

L. Gautron  R. J. Angel  R. Miletich 《Physics and Chemistry of Minerals》1999,27(1):47-51

Single crystals of CaAl₄Si₂O₁₁ were synthesised at 1,500?°C and 14 GPa in a multi-anvil press, and the structure of the phase determined by single-crystal X-ray diffraction at room conditions. The structure-type is that of the “hexagonal barium ferrites”. The space group of the average structure is P6 ₃ /mmc and the cell parameters are a?=?5.4223(4) Å, c?=?12.7041(6) Å, V?=?323.28(5) ų, with Z?=?2, and its density is 3.905?g?cm^?3, which is reasonable for a high-pressure alumino-silicate phase. The 22 oxygen and two calcium atoms within the unit-cell form an approximate hexagonal-close-packed array. Ten of the twelve octahedral interstices within this array that have only oxygen atoms for apices are filled with Si and/or Al. M1 octahedra share edges to form a spinel-like sheet of octahedra. The average bond length ?=?1.833 Å suggests mixed occupancy by Si and Al. The M1 octahedral sheets are linked by shared corners to pairs of face-sharing M2 octahedra containing Al, with ?= 1.918 Å. The remaining two cations of the unit-cell contents statistically occupy four tetrahedrally-coordinated interstices, which occur as face-sharing pairs. The average bond length for these sites (1.742 Å) suggests that they are occupied by Al, although Si occupancy cannot be excluded by the data. It is proposed that only one interstice of each pair is locally occupied, with the possibility of some short-range ordering of such occupancies. Complete long-range order leading to the acentric space group P6 ₃ mc is excluded by the data, as is the possibility of the average structure being comprised of merohedral (0?0?0?1) twins of P6 ₃ mc symmetry.  相似文献