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161.
The present paper reports the results of a detailed stratigraphical, petrological and geochemical investigation on the island of Stromboli, Aeolian arc, Southern Tyrrhenian sea. Major and trace element data determined on a large quantity of samples from well-established stratigraphic positions indicate that the magmatological evolution of the island through time was more complex than previously known. The activity of the exposed part of Stromboli, which occurred over a time span of about 100 000 years, started with the emission of high-K calc-alkaline (HKCA) volcanics, which were covered by calc-alkaline (CA), shoshonitic (SHO), high-K calc-alkaline (HKCA) and potassic (KS) products. The most recent activity consists of HKCA lavas and the present-day SHO-basaltic volcanics emitted by mildly explosive “strombolian” activity. Most of the products are lavas, with minor amounts of pyroclastic rocks emplaced mainly during the early stages of activity. The transition from the SHO to the KS cycle was associated with the collapse of the upper part of the volcanic apparatus; the transition from KS to the present-day SHO activity has been found to have occurred at the time of the sliding of the western portion of the volcano that generated the “Sciara del Fuoco” depression. The rock series cropping out at Stromboli show variable enrichment in potassium, incompatible trace elements and radiogenic Sr which increase from CA through HKCA, and SHO up to KS rocks. Major, trace element and Sr-isotopic data agree in indicating that the HKCA and SHO series evolved by crystal/liquid fractionation starting from different parental liquids, whereas crustal assimilation appears to have been the leading process during the evolution of KS volcanics. Mixing processes also played a role although they can be well documented only when they occurred between magmas with different isotopic and geochemical characteristics. Geochemical modelling based on trace element and isotopic data indicates that the mafic magmas of the different volcanic series may be generated by melting of an upper mantle heterogeneously enriched in incompatible elements and radiogenic Sr by addition, via subduction, of different amounts of crustal material. Geochemical data, however, are also in agreement with the alternative hypothesis that the most mafic magmas of the different series have been generated by combined processes of fractional crystallization, assimilation and mixing of a CA magma in a deep-sited magma chamber; the mafic magmas formed by these complex processes were successively emplaced in a shallow reservoir where they evolved by simple fractional crystallization (HKCA and SHO series) and by assimilation of crustal material (KS). The occurrence of changes in the geochemical signatures of the magmas at the time of the structural modification of the volcano is believed to favour the hypothesis that the variable composition observed in the volcanic rocks of Stromboli is the result of processes occurring within the volcanic system.  相似文献   
162.
It is shown that also in a rank deficient Gauss-Markov model higher weights of the observations automatically improve the precision of the estimated parameters as long as they are computed in thesame datum. However, the amount of improvement in terms of the trace of the dispersion matrix isminimum for the so-called “free datum” which corresponds to the pseudo-inverse normal equations matrix. This behaviour together with its consequences is discussed by an example with special emphasis on geodetic networks for deformation analysis.  相似文献   
163.
On the basis of the correspondence principle of visco-elasticity, an application is discussed of the boundary integral equation method to the solution of time-dependent stress analysis problems. The adopted solution technique, in addition to the time-dependent stress and strain distributions, enables the determination of a measure of the error affecting the numerical results. The governing equations for the plane strain visco-elastic problem are derived with reference to a generalized Kelvin model consisting of the series of any number of simple kelvin elements, having both volumetric and deviatoric components. To get some insight into the overall performance of the technique, the results obtained in the solution of some test examples are discussed and compared with those dering from the available closed from solutions.  相似文献   
164.
The effect of nonaxisymmetric elasticheterogeneities on the mechanical stability of a nearly axisymmetricvolcanic structure, with particular reference to Mt. Vesuvius (Italy) is investigated. This is done solving numerical models using a finite element codein the framework of linear elasticity. The models include gravity,anisotropic depth-dependent regional stress, the edifice, thepossible presence of a pressurized feeding system and of heterogeneities inthe elastic behavior of country rocks. The criteria to assessinstability are the development of tensile stresses and, in compression, theNavier–Coulomb criterion. The presence of asymmetric heterogeneous structureswith lateral elastic contrast has been considered by solvingthree-dimensional (3D) models. To have computationally tractable models, axis-symmetric models were solved first, considering lateral symmetricheterogeneities of different shapes and sizes around the symmetry axis. This allowed us to assess the minimum size of smallermodels (submodels) to be developed in 3D. Thesubmodels were then solved including asymmetrical heterogeneities.In all the analyzed cases, the main characteristics of theinstabilities/stabilities found with the 3D asymmetric models are verysimilar to those found by the analogous symmetric models.Moreover, the presence of sharp lateral elastic contrast at shallow depthappear to produce a greater instability on the flanks of the volcanicedifice.  相似文献   
165.
Ethane and carbon monoxide were detected in a short-period comet of probable Kuiper Belt origin. Ethane is substantially less abundant compared with Hyakutake and Hale-Bopp, two comets from the giant-planet region of the solar nebula, suggesting a heliocentric gradient in ethane in precometary ices. It is argued that processing by X-rays from the young Sun may be responsible.  相似文献   
166.
The average composition and seasonal variations of atmospheric organic particulates with respect to n-alkanes, n-alkanoic acid, polycyclic aromatic hydrocarbon (PAHs), and nitrated polycyclic aromatic hydrocarbons (N-PAHs) were determined at the biggest municipal waste landfill in Algeria located in Oued Smar, 13 km east of downtown Algiers. Samplings were carried out from August 2002 to February 2003, and organic compounds adsorbed in air particles having an aerodynamic diameter lower than 10 μm (PM10) were characterized using gas chromatography coupled with mass spectrometric detection (GC/MSD). Total concentrations ranged from 828 to 11,068 ng per cubic meter of air for n-alkanes, from 1714 to 21,710 ng per cubic meter of air for n-alkanoic acids, from 13 to 212 ng per cubic meter of air for PAHs and from 93 to 205 pg per cubic meter of air for N-PAHs. n-Alkanoic acids accounted for 85 and 56% of the total organic composition of the aerosol measured in summer and winter, respectively, were the biggest fraction. The distribution profiles and the diagnostic ratios of some marker compounds allowed to identify the combustion and microbial activity as the major sources of particulate organic pollutants associated with direct emission. The year-time dependence of organic fraction content of aerosol in Oued Smar appeared to be related to average meteorological conditions as well as variability of rate and nature of materials wasted into the landfill.  相似文献   
167.
A provenance and stratigraphic study of the Neoproterozoic Pontas do Salso Complex (PSC), western portion of the Dom Feliciano Belt (DFB), was conducted with U–Pb zircon geochronological analysis of the metasediments and the host rocks. The U–Pb isotopic data from detrital zircon of the metasediments indicate the source from the latest Middle Tonian to Late Cryogenian (between 897 and 684 Ma) and maximum depositional age of 685 ± 18 Ma in an arc-related basin setting adjacent in the Sao Gabriel Arc. The metasediments of the PSC form an elongated body in the N35°E direction and occur in the central portion of the São Gabriel Terrane (SGT), which is constituted by ophiolitic complexes and arc-related rocks, generated probably during the final consolidation of Rodinia supercontinent, although this question is still open. Low- to medium-K calc-alkaline, metaluminous affinity, and trace-element geochemistry suggest that the chemical composition of the protoliths was generated from metasomatized mantle sources in subduction zones. The PSC is composed of meta-arkoses, with subordinate metaconglomerates and metapelites. The meta-arkoses are disposed in plane-parallel layers, which also internally feature small-scale cross-bedding structures. The matrix has a blastopsammitic, poorly selected, fine to coarse texture, and hexagonal quartz and plagioclase porphyroclasts with superimposed thermal metamorphism. The polymict metaconglomerates are matrix-supported, with 15–55% of clasts of metavolcanic rocks, metasediments, undeformed granites, and quartz veins. The metapelites comprise mainly muscovite phyllites with syn-tectonic garnet and chloritoid porphyroblasts. The PSC represents a sedimentary succession deposited on an arc-related basin formed during the collapse and uplift of the SGT.  相似文献   
168.
169.
This paper documents the results of nondestructive X‐ray fluorescence (XRF) geochemical analyses and comparisons of silicified rhyolites from the Black Canyon and Sedillo Hill prehistoric quarries near Socorro, New Mexico, and subsequent comparisons of the quarry rhyolites with 11 temporally diagnostic projectile points. At the current level of analysis, findings indicate that (1) the two quarries are chemically distinct and (2) the lithic materials of two projectile points match the silicified rhyolite from the Black Canyon quarry, suggesting quarry use during the Early Archaic period (4800–3200 B.C.) and the Late Archaic period (1800–800 B.C.). A close match between the Black Canyon rhyolite and one other point provides tentative support for use of the quarry during the Clovis Paleoindian period (9500–9000 B.C.). Additional geochemical analyses of the two quarries and other regional sources should be undertaken to verify these results and further expand our understanding of prehistoric mobility in the Southwest. © 2004 Wiley Periodicals, Inc.  相似文献   
170.
We propose a strategy for merging both active and passive data sets in linearized tomographic inversion. We illustrate this in the reconstruction of 3D images of a complex volcanic structure, the Campi Flegrei caldera, located in the vicinity of the city of Naples, southern Italy. The caldera is occasionally the site of significant unrests characterized by large ground uplifts and seismicity. The P and S velocity models of the caldera structure are obtained by a tomographic inversion based on travel times recorded during two distinct experiments. The first data set is composed of 606 earthquakes recorded in 1984 and the second set is composed of recordings for 1528 shots produced during the SERAPIS experiment in 2001. The tomographic inversion is performed using an improved method based on an accurate finite‐difference traveltime computation and a simultaneous inversion of both velocity models and earthquake locations. In order to determine the adequate inversion parameters and relative data weighting factors, we perform massive synthetic simulations allowing one to merge the two types of data optimally. The proper merging provides high resolution velocity models, which allow one to reliably retrieve velocity anomalies over a large part of the tomography area. The obtained images confirm the presence of a high P velocity ring in the southern part of the bay of Pozzuoli and extends its trace inland as compared to previous results. This annular anomaly represents the buried trace of the rim of the Campi Flegrei caldera. Its shape at 1.5 km depth is in good agreement with the location of hydrothermalized lava inferred by gravimetric data modelling. The Vp/Vs model confirms the presence of two characteristic features. At about 1 km depth a very high Vp/Vs anomaly is observed below the town of Pozzuoli and is interpreted as due to the presence of rocks that contain fluids in the liquid phase. A low Vp/Vs body extending at about 3–4 km depth below a large part of the caldera is interpreted as the top of formations that are enriched in gas under supercritical conditions.  相似文献   
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