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Pore water of sediments plays an important role in aquatic systems as mediator and as the reactive zone between the sediment and surface water. Sediment pore waters with high ionic strength from acidified pit lakes were investigated to obtain information about the influence on the lake water quality. The analysis of soluble reactive phosphorus, nitrate, ammonium, silica, dissolved organic carbon, ferrous iron, sulfate, chloride, sodium, potassium, calcium, magnesium, manganese, and total dissolved iron was predetermined as the dataset required for evaluation of water quality. The data collection procedure was optimised by designing a methodology for stabilisation, dilution of pore water samples and adaptation of analytical methods. The developed methodology was evaluated with respect to the effort required in the laboratory under routine conditions. In the first round of analyses, 72% of 638 individual analyses from a random selection of pore water profiles were found to be within the calibration ranges. Remedial actions to handle the remaining 28% of invalid analytical results are exemplified. Differences between comparative analyses of some ions by continuous flow analysis, ion chromatography, and atomic emission spectroscopy were evaluated. The majority of results measured by ion chromatography differed on a highly significant level from results measured by atomic emission spectroscopy. Possible reasons, originating from the extreme sample matrix, are discussed. Finally, the designed methodology and the results of the method comparison are used to recommend the selection of analytical methods under specific conditions.  相似文献   
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We present 450- and 800-μm images, made with the James Clerk Maxwell Telescope, of the NGC 2024 molecular ridge. The seven previously known compact cores, FIR1–7, have been detected, and FIR5 has been resolved into a compact object and an associated extended source to the east. The estimated masses of the dense cores vary between 1.6 and 5.1 M⊙ per 14-arcsec beam, assuming a dust temperature of 30 K and a dust opacity of κ800 μm = 0.002 m2 kg−1. A spectral index map made from the 450- and 800-μm images shows spatial variations, with the spectral index, α ( F ν ∝ να), being systematically lower towards the dense cores. We interpret this as evidence for a lower value of the frequency dependence of the dust opacity, β, towards the denser cores relative to the surrounding molecular material. This may indicate that grain growth is occurring in the cores, prior to planetesimal formation. By comparing the high-resolution 450-μm image with interferometer maps of the integrated CS(2–1) emission, the previously reported discrepancy between dust continuum emission and molecular line emission is found to be very localized. Depletion and temperature variations are discussed as possible explanations.  相似文献   
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We use the Sloan Digital Sky Survey (SDSS) to construct a sample of 625 brightest group and cluster galaxies (BCGs) together with control samples of non-BCGs matched in stellar mass, redshift and colour. We investigate how the systematic properties of BCGs depend on stellar mass and on their privileged location near the cluster centre. The groups and clusters that we study are drawn from the C4 catalogue of Miller et al. but we have developed improved algorithms for identifying the BCG and for measuring the cluster velocity dispersion. Since the SDSS photometric pipeline tends to underestimate the luminosities of large galaxies in dense environments, we have developed a correction for this effect which can be readily applied to the published catalogue data. We find that BCGs are larger and have higher velocity dispersions than non-BCGs of the same stellar mass, which implies that BCGs contain a larger fraction of dark matter. In contrast to non-BCGs, the dynamical mass-to-light ratio of BCGs does not vary as a function of galaxy luminosity. Hence BCGs lie on a different Fundamental Plane than ordinary elliptical galaxies. BCGs also follow a steeper Faber–Jackson relation than non-BCGs, as suggested by models in which BCGs assemble via dissipationless mergers along preferentially radial orbits. We find tentative evidence that this steepening is stronger in more massive clusters. BCGs have similar mean stellar ages and metallicities to non-BCGs of the same mass, but they have somewhat higher α/Fe ratios, indicating that star formation may have occurred over a shorter time-scale in the BCGs. Finally, we find that BCGs are more likely to host radio-loud active galactic nuclei than other galaxies of the same mass, but are less likely to host an optical active galactic nucleus (AGN). The differences we find are more pronounced for the less massive BCGs, i.e. they are stronger at the galaxy group level.  相似文献   
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The production of animal-based foods is associated with higher greenhouse gas (GHG) emissions than plant-based foods. The objective of this study was to estimate the difference in dietary GHG emissions between self-selected meat-eaters, fish-eaters, vegetarians and vegans in the UK. Subjects were participants in the EPIC-Oxford cohort study. The diets of 2,041 vegans, 15,751 vegetarians, 8,123 fish-eaters and 29,589 meat-eaters aged 20–79 were assessed using a validated food frequency questionnaire. Comparable GHG emissions parameters were developed for the underlying food codes using a dataset of GHG emissions for 94 food commodities in the UK, with a weighting for the global warming potential of each component gas. The average GHG emissions associated with a standard 2,000 kcal diet were estimated for all subjects. ANOVA was used to estimate average dietary GHG emissions by diet group adjusted for sex and age. The age-and-sex-adjusted mean (95 % confidence interval) GHG emissions in kilograms of carbon dioxide equivalents per day (kgCO2e/day) were 7.19 (7.16, 7.22) for high meat-eaters (?>?=?100 g/d), 5.63 (5.61, 5.65) for medium meat-eaters (50-99 g/d), 4.67 (4.65, 4.70) for low meat-eaters (?<?50 g/d), 3.91 (3.88, 3.94) for fish-eaters, 3.81 (3.79, 3.83) for vegetarians and 2.89 (2.83, 2.94) for vegans. In conclusion, dietary GHG emissions in self-selected meat-eaters are approximately twice as high as those in vegans. It is likely that reductions in meat consumption would lead to reductions in dietary GHG emissions.  相似文献   
100.
There is a paucity of data and insight in the mechanisms of, and controls on flow separation and recirculation at natural sharply‐curved river bends. Herein we report on successful laboratory experiments that elucidate flow structure in one constant‐width bend and a second bend with an outer‐bank widening. The experiments were performed with both a flat immobile gravel bed and mobile sand bed with dominant bedload sediment transport. In the constant‐width bend with immobile bed, a zone of mainly horizontal flow separation (vertical rotational axis) formed at the inner bank that did not contain detectable flow recirculation, and an outer‐bank cell of secondary flow with streamwise oriented rotational axis. Surprisingly, the bend with widening at the outer bank and immobile bed did not lead to a transverse expansion of the flow. Rather, flow in the outer‐bank widening weakly recirculated around a vertical axis and hardly interacted with the inner part of the bend, which behaved as a constant‐width bend. In the mobile bed experiment, downstream of the bend apex a pronounced depositional bar developed at the inside of the bend and pronounced scour occurred at the outside. Moreover the deformed bed promoted flow separation over the bar, including return currents. In the constant‐width bend, the topographic steering impeded the generation of an outer‐bank cell of secondary flow. In the bend with outer‐bank widening, the topographic steering induced an outward expansion of the flow, whereby the major part of the discharge was conveyed in the central part of the widening section. Flow in the outer‐bank widening was highly three dimensional and included return currents near the bottom. In conclusion, the experiments elucidated three distinct processes of flow separation common in sharp bends: flow separation at the inner bank, an outer‐bank cell of secondary flow, and flow separation and recirculation in an outer‐bank widening. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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