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21.
Nadine v. Blohn Karoline Diehl Anke Nölscher Alexander Jost Subir K. Mitra Stephan Borrmann 《Journal of Atmospheric Chemistry》2013,70(2):131-150
Laboratory experiments were carried out in the Mainz vertical wind tunnel to determine the retention of the trace gases ammonia and sulfur dioxide dissolved in supercooled cloud droplets during riming. The conditions during riming were similar to the ones in atmospheric mixed phase clouds: temperatures from ?18 °C to ?5 °C, liquid water contents between 1 and 1.5 g m?3, liquid drop radii between 10 and 20 μm, liquid phase concentrations from 1 to 22 mg/l. As collectors, floating ice particles and snow flakes with diameters between 6 mm and 1.5 cm were used. After riming the retention coefficients, i.e. the fractions of the species which remained in the ice phase after freezing were determined. Retention coefficients lying between 0.1 and 1.0 were measured depending on the solubility and dissociation of the trace gas, liquid phase concentration, ambient air temperature, and shape of rimed collector. This can be explained from the chemists’ point of view by the effective Henry’s law constant of the species and physically with the rate of latent heat removal from the rimed collector during freezing. Parameterizations derived from the different experimental cases describe the retention coefficients as a function of temperature. In general, an average retention of ammonia of 92?±?21 % was determined independently of liquid phase concentration while mean values for sulfur dioxide were 53?±?10 % at low liquid phase concentrations and 29?±?7 % at high liquid phase concentrations. 相似文献
22.
Bastian Joachim Anke Wohlers Nicholas Norberg Emmanuel Gardés Elena Petrishcheva Rainer Abart 《Physics and Chemistry of Minerals》2013,40(1):19-27
Cylinders of synthetic periclase single crystals were annealed at 0.15–0.5 GPa and 900–1200 °C under water-saturated conditions for 45 min to 72 h. Infrared spectra measured on the quenched products show bands at 3,297 and 3,312 cm?1 indicating V OH ? centers (OH-defect stretching vibrations in a half-compensated cation vacancy) in the MgO structure as a result of proton diffusion into the crystal. For completely equilibrated specimens, the OH-defect concentration, expressed as H2O equivalent, was calculated to 3.5 wt ppm H2O at 1,200 °C and 0.5 GPa based on the calibration method of Libowitzky and Rossmann (Am Min 82:1111–1115, 1997). This value was confirmed via Raman spectroscopy, which shows OH-defect-related bands at identical wavenumbers and yields an H2O equivalent concentration of about 9 wt ppm using the quantification scheme of Thomas et al. (Am Min 93:1550–1557, 2008), revised by Mrosko et al. (Am Mineral 96:1748–1759, 2011). Results of both independent methods give an overall OH-defect concentration range of 3.5–9 (+4.5/?2.6) ppm H2O. Proton diffusion follows an Arrhenius law with an activation energy E a = 280 ± 64 kJ mol?1 and the logarithm of the pre-exponential factor logDo (m2 s?1) = ?2.4 ± 1.9. IR spectra taken close to the rims of MgO crystals that were exposed to water-saturated conditions at 1,200 °C and 0.5 GPa for 24 h show an additional band at 3,697 cm?1, which is related to brucite precipitates. This may be explained by diffusion of molecular water into the periclase, and its reaction with the host crystal during quenching. Diffusion of molecular water may be described by logDH2O (m2 s?1) = ?14.1 ± 0.4 (2σ) at 1,200 °C and 0.5 GPa, which is ~ 2 orders of magnitude slower than proton diffusion at identical P-T conditions. 相似文献
23.
John T. Van Stan Elliott S. Lewis Anke Hildebrandt Corinna Rebmann Jan Friesen 《水文科学杂志》2013,58(11):2071-2083
ABSTRACTTrees concentrate rainfall to near-stem soils via stemflow. When canopy structures are organized appropriately, stemflow can even induce preferential flow through soils, transporting nutrients to biogeochemically active areas. Bark structure significantly affects stemflow, yet bark-stemflow studies are primarily qualitative. We used a LaserBark to compute bark microrelief (MR), ridge-to-furrow amplitude (R) and slope (S) metrics per American Society of Mechanical Engineering standards (ASME-B46.1–2009) for two morphologically contrasting species (Fagus sylvatica L. (European beech), Quercus robur L. (pendunculate oak)) under storm conditions with strong bark water storage capacity (BWSC) influence in central Germany. Smaller R and S for F. sylvatica significantly lowered BWSC, which strongly and inversely correlated to maximum funnelling ratios and permitted stemflow generation at lower rain magnitudes. Larger R and S values in Q. robur reduced funnelling, diminishing stemflow drainage for larger storms. Quercus robur funnelling and stemflow was more reliant on intermediate rain intensities and intermittency to maintain bark channel-dependent drainage pathways. Shelter provided by Q. robur’s ridged bark also appears to protect entrained water, lengthening mean intrastorm dry periods necessary to affect stemflow. Storm conditions where BWSC plays a major role in stemflow accounted for much of 2013’s rainfall at the nearest meteorological station (Wulferstedt).
Editor M.C. Acreman; Associate editor not assigned 相似文献
24.
25.
Iraq, the land of two rivers, has a history that extends back millennia and is the subject of much archaeological research. However, little environmental research has been carried out, and as such relatively little is known about the interaction between Iraq’s vegetation and climate. This research serves to fill this knowledge gap by investigating the relationship between the Normalized Difference Vegetation Index (NDVI) and two climatic factors (precipitation and air temperature) over the last decade. The precipitation and air temperature datasets are from the Water and Global Change Forcing Data ERA-Interim (WFDEI), and the NDVI dataset was extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS) at 250 m spatial resolution and 16 day temporal resolution. Three different climatic regions in Iraq, Sulaymaniyah, Wasit, and Basrah, were selected for the period of 2001–2015. This is the first study to compare these regions in Iraq, and one of only a few investigating vegetation’s relationship with multiple climatic factors, including precipitation and air temperature, particularly in a semi-arid region. The interannual, intra-annual and seasonal variability for each region is analysed to compare the different responses of vegetation growth to climatic factors. Correlations between NDVI and climatic factors are also included. Plotting annual cycles of NDVI and precipitation reveals a coherent onset, fluctuation (peak and decline), with a time lag of 4 months for Sulaymaniyah and Wasit (while for the Basrah region, high temperatures and a short rainy season was observed). The correlation coefficients between NDVI and precipitation are relatively high, especially in Sulaymaniyah, and the largest positive correlation was (0.8635) with a time lag of 4 months. The phenological transition points range between 3 and 4 month time lag; this corresponds to the duration of maturity of the vegetation. However, when correlated with air temperature, NDVI experiences an inverse relationship, although not as strong as that of NDVI and precipitation; the highest negative correlation was observed in Wasit with a time lag of 2 months (? 0.7562). The results showed that there is a similarity between temporal patterns of NDVI and precipitation. This similarity is stronger than that of NDVI and air temperature, so it can be concluded that NDVI is a sensitive indicator of the inter-annual variability of precipitation and that precipitation constitutes the primary factor in germination while the air temperature acts with a lesser effect. 相似文献
26.
Anke Schwarzenberger Sofie D’Hondt Wim Vyverman Eric von Elert 《Aquatic Sciences - Research Across Boundaries》2013,75(3):433-445
Lakes are well known for having a pattern of seasonal succession of phytoplankton and zooplankton. The succession of different taxa of phytoplankton results in a succession of zooplankton taxa, and within the genus Daphnia, into a succession of different genotypes (clones). One cause for this succession of Daphnia clones might be the production of digestive protease inhibitors by cyanobacteria, which usually bloom in summer. Here we report seasonal changes in the frequency and the abundance of Daphnia magna haplotypes in a eutrophic lake, which developed a chymotrypsin-inhibitor-producing cyanobacterial bloom in May. These seasonal changes were not related to changes of biotic and abiotic lake parameters. However, a very high content of chymotrypsin inhibitors was observed in May (but not in other months). This was assumed to have exerted a strong punctual selection pressure on the Daphnia population and on the direct targets of the protease inhibitors, i.e. the digestive chymotrypsins of Daphnia. Actually, D. magna from before and during the cyanobacterial bloom showed a different protease pattern on activity stained SDS-PAGE in comparison to clones from the month after the bloom. However, no difference in tolerance, measured as IC50 values, to inhibition by natural lake seston from May was found between the clones from before and after the bloom. Thus, the hypothesis that a seasonal adaptation of D. magna subpopulations from either April/May or June might have occurred could not be proven. This suggests that the Daphnia population investigated here is locally adapted to cyanobacterial protease inhibitors. 相似文献
27.
The solubilities of the assemblages albite + paragonite + quartz and jadeite + paragonite + quartz in H2O were determined at 500 and 600 °C, 1.0-2.25 GPa, using hydrothermal piston-cylinder methods. The three minerals are isobarically and isothermally invariant in the presence of H2O, so fluid composition is uniquely determined at each pressure and temperature. A phase-bracketing approach was used to achieve accurate solubility determinations. Albite + quartz and jadeite + quartz dissolve incongruently in H2O, yielding residual paragonite which could not be retrieved and weighed. Solution composition fixed by the three-mineral assemblage at a given pressure and temperature was therefore bracketed by adding NaSi3O6.5 glass in successive experiments, until no paragonite was observed in run products. Solubilities derived from experiments bounding the appearance of paragonite thus constrain the equilibrium fluid composition. Results indicate that, at a given pressure, Na, Al, and Si concentrations are higher at 600 °C than at 500 °C. At both 500 and 600 °C, solubilities of all three elements increase with pressure in the albite stability field, to a maximum at the jadeite-albite-quartz equilibrium. In the jadeite stability field, element concentrations decline with continued pressure increase. At the solubility maximum, Na, Al, and Si concentrations are, respectively, 0.16, 0.05, and 0.48 molal at 500 °C, and 0.45, 0.27, and 1.56 molal at 600 °C. Bulk solubilities are 3.3 and 10.3 wt% oxides, respectively. Observed element concentrations are everywhere greater than those predicted from extrapolated thermodynamic data for simple ions, monomers, ion pairs, and the silica dimer. The measurements therefore require the presence of additional, polymerized Na-Al-Si-bearing species in the solutions. The excess solubility is >50% at all conditions, indicating that polymeric structures are the predominant solutes in the P-T region studied. The solubility patterns likely arise from combination of the large solid volume change associated with the albite-jadeite-quartz equilibrium and the rise in Na-Al-Si polymerization with approach to the hydrothermal melting curves of albite + quartz and jadeite + quartz. Our results indicate that polymerization of Na-Al-Si solutes is a fundamental aspect of fluid-rock interaction at high pressure. In addition, the data suggest that high-pressure metamorphic isograds can impose unexpected controls on metasomatic mass transfer, that significant metasomatic mass transfer prior to melting should be considered in migmatitic terranes, and that polymeric complexes may be an important transport agent in subduction zones. 相似文献
28.
Feed forward neural network and interpolation function models to predict the soil and subsurface sediments distribution in Bam,Iran 总被引：1，自引：1，他引：0
Khalil Rezaei Bernard Guest Anke Friedrich Farajollah Fayazi Muhammad Nakhaei Ali Beitollahi Seyed Mahmoud Fatemi Aghda 《Acta Geophysica》2009,57(2):271-293
An application of the artificial neural network (ANN) approach for predicting mean grain size using electric resistivity data
from Bam city is presented. A feed forward back propagation network was developed employing 45 sets of input data. The input
variables in the ANN model are the electrical resistivity, water table as a Boolean value and depth; the output is the mean
grain size. To demonstrate the authenticity of this approach, the network predictions are compared with those from interpolation
methods and the same data. This comparison shows that the ANN approach performs better results. The predicted and observed
mean grain size values were compared and show high correlation coefficients. The ANN approach maps show a high degree of correlation
with well data based grain size maps and can therefore be used conservatively to better understand the influence of input
parameters on sedimentological predictions. 相似文献
29.
The long-term behaviour of andesite stratovolcanoes is characterised by a repetition of edifice growth phases followed by collapse. This cyclic pattern represents a natural frequency at varying timescales in the growth dynamics of stratovolcanoes worldwide. Around the > 130 ka Mt. Taranaki (Egmont volcano), New Zealand, coastal–cliff successions at 20–40 km distance comprise repeating packages of lithologically and sedimentologically distinctive mass-flow deposits. Varying depositional mechanisms and source properties of these units record growth and collapse cycles of the central edifice. These are used to construct a model for cyclic volcaniclastic sedimentation in the surrounds of stratovolcanoes. During edifice-construction phases, thick packages of tabular, predominantly monolithologic, hyperconcentrated-flow and debris-flow deposits accumulate with intercalated tephra beds. The mass-flow units commonly contain large proportions of fresh pumice or juvenile-lithic andesite. Intervals of quiescence separating eruptive periods are characterised by landscape re-adjustment, accompanied by deposition of fluvial and aeolian sediments, along with steady accretion of medial ash. In contrast, brief episodes of destruction are marked by wide-spread, distinctively clay-rich, polylithologic debris-avalanche deposits and related marginal debris flow units. The growth stages can be terminated by an eruption-triggered sector collapse, or by external forces once the edifice exceeds a critical stable height or profile (dependent on eruptive style and local geo-tectonic conditions). Once the edifice becomes metastable, regional tectonic earthquakes or shallow-level intrusion events are likely triggers for collapse. Although the resulting debris avalanches represent the greatest individual hazard from such andesite stratovolcanoes, their frequency is relatively low compared with other types of mass-flows generated during edifice-growth phases. Accurate forecasts of future hazard from mass-flow events are therefore dependent on recognition of both the frequency of a stratovolcano's growth cycle and its current position in that cycle. 相似文献
30.
Landscape and sedimentary response to catastrophic debris avalanches, western Taranaki, New Zealand 总被引：1，自引：1，他引：0
Catastrophic volcanic debris avalanches reshape volcanic edifices with up to half of pre-collapse cone volumes being removed. Deposition from this debris avalanche deposit often fills and inundates the surrounding landscape and may permanently change the distribution of drainage networks. On the weakly-incised Mt. Taranaki ring-plain, volcanic debris avalanche deposits typically form a large, wedge shape (in plan view), over all flat-lying fans. Following volcanic debris avalanches a period of intense re-sedimentation commonly begins on ring-plain areas, particularly in wet or temperate climates. This is exacerbated by large areas of denuded landscape, ongoing instability in the scarp/source region, damming of river/stream systems, and in some cases inherent instability of the volcanic debris avalanche deposits. In addition, on Mt. Taranaki, the collapse of a segment of the cone by volcanic debris avalanche often generates long periods of renewed volcanism, generating large volumes of juvenile tephra onto unstable and unvegetated slopes, or construction of new domes with associated rock falls and block-and-ash flows. The distal ring-plain impact from these post-debris avalanche conditions and processes is primarily accumulation of long run-out debris flow and hyperconcentrated flow deposits with a variety of lithologies and sedimentary character. Common to these post-debris avalanche units is evidence for high-water-content flows that are typically non-cohesive. Hence sedimentary variations in these units are high in lateral and longitudinal exposure in relation to local topography. The post-collapse deposits flank large-scale fans and hence similar lithological and chronological sequences can form on widely disparate sectors of the ring plain. These deposits on Mt. Taranaki provide a record of landscape response and ring-plain evolution in three stages that divide the currently identified Warea Formation: 1) the deposition of broad fans of material adjacent to the debris avalanche unit; 2) channel formation and erosion of Stage 1 deposits, primarily at the contact between debris avalanche deposits and the Stage 1 deposits and the refilling of these channels; and 3) the development of broad tabular sheet flows on top of the debris avalanche, leaving sediments between debris avalanche mounds. After a volcanic debris avalanche, these processes represent an ever changing and evolving hazard-scape with hazard maps needing to be regularly updated to take account of which stage the sedimentary system is in. 相似文献