Analyse hyperspectrale des carbonates jurassiques dans le Haut Atlas atlantique marocain : exemple du Lias inférieur de la formation d’Arigh Ouzla (bassin d’Essaouira)     

Rachid Baissa  Kamal Labbassi  Patrick Launeau  Brahim Ouajhain  Anne Gaudin 《Comptes Rendus Geoscience》2010,342(12):911-920

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Upcoming international events     

Anne Marie de Grosbois 《Environmental Earth Sciences》2010,60(5):1131-1136

Events

Upcoming international events  相似文献   

Upcoming international events     

Anne Marie de Grosbois 《Environmental Earth Sciences》2010,60(1):219-224

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Upcoming international events  相似文献   

Investigating dissolution of mechanically activated olivine for carbonation purposes     

Tove Anette Haug  Rolf Arne Kleiv  Ingrid Anne Munz 《Applied Geochemistry》2010

Mineral carbonation is one of several alternatives for CO₂ sequestration and storage. The reaction rates of appropriate minerals with CO₂, for instance olivine and serpentine with vast resources, are relatively slow in a CO₂ sequestration context and the rates have to be increased to make mineral carbonation a good storage alternative. Increasing the dissolution rate of olivine has been the focus of this paper. Olivine was milled with very high energy intensity using a laboratory planetary mill to investigate the effect of mechanical activation on the Mg extraction potential of olivine in 0.01 M HCl solution at room temperature and pressure. Approximately 30–40% of each sample was dissolved and water samples were taken at the end of each experiment. The pH change was used to calculate time series of the Mg concentrations, which also were compared to the final Mg concentrations in the water samples. Percentage dissolved and the specific reaction rates were estimated from the Mg concentration time series. The measured particle size distributions could not explain the rate constants found, but the specific surface area gave a good trend versus dissolution for samples milled wet and the samples milled with a small addition of water. The samples milled dry had the lowest measured specific surface areas (<4 m²/g), but had the highest rate constants. The crystallinity calculated from X-ray diffractograms, was the material parameter with the best fit for the observed differences in the rate constants. Geochemical modelling of mechanically activated materials indicated that factors describing the changes in the material properties related to the activation must be included. The mechanically activated samples in general reacted faster than predicted by the theoretical models. Mechanical activation as a pre-treatment method was found to enhance the initial specific reaction rates by approximately three orders of magnitude for a sample milled dry for 60 min in a planetary mono mill compared to an unactivated sample. Wet milling in the planetary mill did not produce samples with the same maximum reaction rate as dry milling, but wet milling in general might be easier to implement into a wet carbonation process. Mechanical activation in a planetary mill is likely to consume too much energy for CO₂ sequestration purposes, but the increase in obtained olivine rate constants illustrates a potential for using milling as a pre-treatment method.  相似文献   

Preliminary study on the preservation of giant clam (Tridacnidae) shells from the Balobok Rockshelter archaeological site,south Philippines     

Marie Grace Pamela G. Faylona  Claire E. Lazareth  Anne‐Marie Smah  Sandrine Caquineau  Hugues Boucher  Wilfredo P. Ronquillo 《Geoarchaeology》2011,26(6):888-901

Tridacnidae shells, a valuable archive of past environments, are common in the Balobok Rockshelter archaeological site on Sanga‐Sanga Island in the south Philippines. This site was occupied during the mid‐Holocene (ca. 5000–8800 ¹⁴C yr B.P.), a period of Neolithic cultural expansion in the Philippines. This paper focuses on the preservation of two shell specimens, Hippopus hippopus and Tridacna maxima, unearthed from two mid‐Holocene layers within the rockshelter. The shells' mineralogy and microstructure (prismatic and crossed‐lamellar) were studied using micro‐Fourier transform infrared spectroscopy and scanning electron microscopy to determine if the samples were suitable as paleoenvironmental records. Both shells are still aragonitic but aragonite crystals of both microstructure types are partly dissolved. This dissolution, characteristic of meteoric water alteration, precludes their utility in paleoenvironmental geochemical studies. Nevertheless, these shells are abundant in archaeological sites in the region and may be better preserved in other depositional contexts; more studies on Philippine Tridacnidae shell diagenesis are needed. © 2011 Wiley Periodicals, Inc.  相似文献