An improved calibration method for the drift of the conductivity sensor on autonomous CTD profiling floats by θ–S climatology     

W. Brechner Owens  Annie P.S. Wong 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(3):450-457

An improved method to estimate the time-varying drift of measured conductivity from autonomous CTD profiling floats has been developed. This procedure extends previous methods developed by Wong, Johnson and Owens [2003. Delayed-mode calibration of autonomous CTD profiling float salinity data by θ–S climatology. Journal of Atmospheric and Oceanic Technology, 20, 308–318] and Böhme and Send [2005. Objective analyses of hydrographic data for referencing profiling float salinities in highly variable environments. Deep-Sea Research Part II, 52, 651–664]. It uses climatological salinity interpolated to the float positions and observed θ surfaces and chooses 10 ‘best’ levels that are within well-mixed mode waters or deep homogeneous water masses. A piece-wise linear fit is used to estimate the temporally varying multiplicative adjustment to the float potential conductivities. An objective, statistical method is used to choose the breakpoints in the float time series where there are multiple drift trends. In the previous methods these breakpoints were chosen subjectively by manually splitting the time series into separate segments over which the fits were made. Our statistical procedure reduces the subjectivity by providing an automated way for doing the piece-wise linear fit. Uncertainties in this predicted adjustment are estimated using a Monte-Carlo simulation. Examples of this new procedure as applied to two Argo floats are presented.  相似文献   

The grain-size characterisation of coastal sand from the Somme estuary to Belgium: Sediment sorting processes and mixing in a tide- and storm-dominated setting     

Edward J. Anthony  Arnaud Héquette 《Sedimentary Geology》2007,202(3):369-382

Sand-rich Holocene to modern clastic deposits in the eastern English Channel and the southern North Sea coasts of France and Belgium occur extensively as nearshore-sand bank, estuarine-tidal flat, aeolian dune and beach sub-environments. Sand samples (n = 665) collected from these deposits suggest the presence of three different populations: a largely dominant (83%) medium to fine quartz sand population (“b”), and finer- (14%) and coarser-grained (4%) populations (respectively “c” and “a”). The distribution of these populations among the four sub-environments reflects tide- and storm-dominated sorting and transport processes and a variable degree of mixing. These populations are derived from a mixture of very fine- to very coarse-grained fluvial, outwash and paraglacial sediments deposited on the beds of the eastern English Channel and southern North Sea during the late Pleistocene lowstand. The nearshore-sand bank environment, which also corresponds to the main offshore source area of the coastal deposits, exhibits population heterogeneity reflecting the variability of hydrodynamic conditions and sediment sorting in this zone. The nearshore topography of tidal ridges, banks and troughs in these tidal seas leads to variable bed and tide- and storm-induced shear stress conditions. These conditions only allow for the mobilisation and onshore transport of some of the finer fractions (populations “b” and “c”), leaving an offshore mixture of these finer populations with coarser, less mobilisable sediments (population “a”). Once in the coastal zone, these two finer populations undergo further hydrodynamic sorting and segregation. Variably sorted very fine sands to silts (population “c”) are trapped in the low-energy estuarine-tidal flat sub-environment, while the highly homogeneous population “b” is further sorted in aeolian dune and beach sub-environments. This sorting occurs via a coastal sand transport pathway linking the Somme estuary mouth to the southern North Sea bight where tidal range and wave energy decrease relative to the English Channel. Since this sand transport pathway enables longshore transport of hydrodynamically sorted medium to fine sand derived directly from the immediate nearshore zone, it has further contributed to a net flux of this sand population from the eastern English Channel sea bed to the southern North Sea.  相似文献   

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join     

Giancarlo Della Ventura  Günther J. Redhammer  Gianluca Iezzi  Frank C. Hawthorne  Arnaud Papin  Jean-Louis Robert 《Physics and Chemistry of Minerals》2005,32(2):103-113

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.  相似文献   

Pollution au plomb dans la Savoie antique (II–IIIe s. apr. J.-C.) en relation avec une installation métallurgique de la cité de Vienne     

Fabien Arnaud  Joël Serralongue  Thierry Winiarski  Marc Desmet  Martine Paterne 《Comptes Rendus Geoscience》2006,338(4):244-252

In Lake Anterne (NW French Alps), the Roman period is characterised by a lead contamination more important than that of the 1970s, due to the use of leaded gasoline. The maximum of this contamination period has been varve-dated 220 AD, i.e., during the optimum of Roman civilization in the Alps. Crossing palaeoenvironmental and archaeological evidences points out the economic importance of the town of Passy for the City of Vienne and yields a new example of lead contamination due to local metallurgical activity rather than distant impact of the exploitation of the Spanish Rio Tinto mine. To cite this article: F. Arnaud et al., C. R. Geoscience 338 (2005).  相似文献   

In situ acoustic target strength measurements of tuna associated with a fish aggregating device     

Josse  Erwan; Bertrand  Arnaud 《ICES Journal of Marine Science》2000,57(4):911-918

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Reassessment of the ‘Abbevillien’ in the perspective of new discoveries from the Lower Palaeolithic and Quaternary sites of Abbeville (Somme,northern France)     

Marie-hélène Moncel  Pierre Antoine  Arnaud Hurel  Jean-Jacques Bahain 《第四纪科学杂志》2021,36(6):1122-1136

North-West Europe yields few traces of early human occupation, in particular for the Acheulean. In this context, the Somme Valley in northern France offers a route to Britain during various Pleistocene low sea levels, and has provided numerous evidence of Lower Palaeolithic human occupation through fieldwork initiated during the 19th century. These localities are associated with the original definition in the 1930s by the French prehistorian Abbé Henri Breuil of the ‘Abbevillien’ (Abbevillian facies), based on lithic pieces including crudely made bifaces recovered in particular in some famous key localities of Abbeville, Carpentier, Léon and Moulin Quignon quarries. The history of the term and its definition subsequently gave rise to debates concerning the chronocultural framework of Palaeolithic assemblages among the scientific community of prehistorians over time, from Jacques Boucher de Perthes, Gabriel de Mortillet, Geoffroy d'Ault du Mesnil, Victor Commont, Henri Breuil and François Bordes. New investigations at these three localities, all associated with the High Terrace of the Somme system, pushed back the age of the expansion of the Acheulean both in northern France and in Western Europe to c. 670–650 000 years. They imply that early hominins were able to settle in North-West Europe during both climatic temperate and cold phases. Our work, including new excavations and associated field observations of the three Abbeville localities involved at the onset of the controversy, allows a re-examination of the Abbevillian and contributes to the discussion of the history of Prehistoric Science and the Earliest ‘Acheuleans’ in North-West Europe.  相似文献   

Study of the spatial and historical distribution of sediment inorganic contamination in the Toulon bay (France)   总被引：4，自引：0，他引：4  

Tessier E  Garnier C  Mullot JU  Lenoble V  Arnaud M  Raynaud M  Mounier S 《Marine pollution bulletin》2011,62(10):2075-2086

This study presents trace elements levels in surface and deep sediments of the Toulon bay (SE France) subjected to anthropogenic inputs (navy base, harbors, etc.). The studied elements (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn) are defined as priority contaminants in aquatic systems. Fifty-five points scattered on the entire bay were sampled, allowing the determination of contaminants distribution with a high resolution. Several approaches were used to assess the degree of contamination and the potential toxicity of the Toulon bay sediments: comparison to the French legislation, surface-weighted average metal concentrations, enrichment factors (EF), geoaccumulation indices (Igeo), trace element stock calculation and comparison to sediment quality guidelines. A principal component analysis was performed to reveal common behavior of the studied contaminants. Results demonstrated the very high contamination of the small bay, especially in Hg (EF up to 1500), Cu, Pb and Zn, with export to the large bay further governed by hydrodynamics.  相似文献   

Mobilization of actinides by dissolved organic compounds at the Nevada Test Site     

Pihong Zhao  Mavrik Zavarin  Roald N. LeifBrian A. Powell  Michael J. SingletonRachel E. Lindvall  Annie B. Kersting 《Applied Geochemistry》2011,26(3):308-318

The effect of dissolved organic matter (DOM) on Am(III), Pu(IV), Np(V), and U(VI) sorption was investigated with natural water (pH ∼8) and zeolitized tuff samples collected from the Rainier Mesa tunnel system, Nevada Test Site, where the USA detonated underground nuclear tests prior to 1992. Perched vadose zone water at Rainier Mesa has high levels of DOM as a result of microbial degradation of mining debris (diesel, wood, etc.). The Am and Pu sorption K_ds were up to two orders of magnitude lower in water with high DOM (15-19 mg C/L) compared to the same water with DOM removed (<0.4 mg C/L) or in naturally low DOM (0.2 mg C/L) groundwater. In contrast, K_ds of Np and U were less affected by DOM at these solution conditions. Uranium sorption decreased as a result of high dissolved inorganic C (DIC) resulting from microbial degradation of DOM. Thermodynamic model predictions, based on actinide-humic acid stability constants available in the literature, are in general agreement with measured K_d data, correctly predicting the effects of DIC and DOM on actinide retardation. This agreement is encouraging to future modeling efforts and suggests that effects of DOM and DIC can be incorporated into reactive transport modeling predictions. The Am and Pu transport rates in Rainier Mesa tunnel waters will be substantially faster as a result of the elevated DOM levels. Low diffusion rates of actinide-DOM macromolecular complexes may focus Pu and Am transport into fractures and minimize retardation via matrix diffusion. The resulting transport behavior will affect actinide distribution patterns and associated risk estimates.  相似文献   

Analysis with C- and X-band satellite SAR data of the Portalet landslide area   总被引：1，自引：0，他引：1  

Gerardo Herrera  Davide Notti  Juan Carlos Garc��a-Davalillo  Oscar Mora  Geraint Cooksley  M��nica S��nchez  Alain Arnaud  Michele Crosetto 《Landslides》2011,8(2):195-206

This paper describes the use of the Stable Point Network technique, a Persistent Scatterer Interferometry SAR technique, for the analysis of the Portalet landslide area (Central Pyrenees, Spain). For this purpose, different SAR datasets acquired by ERS-1, ERS-2, ENVISAT and TerraSAR-X satellites have been analysed. The use of different SAR images acquired by satellite radar sensors operating at different microwave lengths has allowed for a comparative assessment and illustration of the advantages and disadvantages of these satellites for landslide detection and monitoring. In the introduction, differential interferometry and the study area are briefly described. Then the specifics of the SPN processing and the results of the different datasets are described and compared. In Analysis of the results: the Portalet landslide area, the Portalet landslide area is introduced and the radar displacement measurements are analysed with available geo-information data. Additionally, X-band measurements are compared with those gathered by a ground-based SAR for a previous project. Finally, the most relevant conclusions of this work are discussed.  相似文献   

LMDZ5B: the atmospheric component of the IPSL climate model with revisited parameterizations for clouds and convection     

Frédéric Hourdin  Jean-Yves Grandpeix  Catherine Rio  Sandrine Bony  Arnaud Jam  Frédérique Cheruy  Nicolas Rochetin  Laurent Fairhead  Abderrahmane Idelkadi  Ionela Musat  Jean-Louis Dufresne  Alain Lahellec  Marie-Pierre Lefebvre  Romain Roehrig 《Climate Dynamics》2013,40(9-10):2193-2222

Based on a decade of research on cloud processes, a new version of the LMDZ atmospheric general circulation model has been developed that corresponds to a complete recasting of the parameterization of turbulence, convection and clouds. This LMDZ5B version includes a mass-flux representation of the thermal plumes or rolls of the convective boundary layer, coupled to a bi-Gaussian statistical cloud scheme, as well as a parameterization of the cold pools generated below cumulonimbus by re-evaporation of convective precipitation. The triggering and closure of deep convection are now controlled by lifting processes in the sub-cloud layer. An available lifting energy and lifting power are provided both by the thermal plumes and by the spread of cold pools. The individual parameterizations were carefully validated against the results of explicit high resolution simulations. Here we present the work done to go from those new concepts and developments to a full 3D atmospheric model, used in particular for climate change projections with the IPSL-CM5B coupled model. Based on a series of sensitivity experiments, we document the differences with the previous LMDZ5A version distinguishing the role of parameterization changes from that of model tuning. Improvements found previously in single-column simulations of case studies are confirmed in the 3D model: (1) the convective boundary layer and cumulus clouds are better represented and (2) the diurnal cycle of convective rainfall over continents is delayed by several hours, solving a longstanding problem in climate modeling. The variability of tropical rainfall is also larger in LMDZ5B at intraseasonal time-scales. Significant biases of the LMDZ5A model however remain, or are even sometimes amplified. The paper emphasizes the importance of parameterization improvements and model tuning in the frame of climate change studies as well as the new paradigm that represents the improvement of 3D climate models under the control of single-column case studies simulations.  相似文献