Projected changes in diverse ecosystems from climate warming and biophysical drivers in northwest Alaska     

Mark Torre Jorgenson  Bruce G. Marcot  David K. Swanson  Janet C. Jorgenson  Anthony R. DeGange 《Climatic change》2015,130(2):131-144

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The Wide Field Spectrograph (WiFeS): performance and data reduction     

Michael Dopita  Jonghwan Rhee  Catherine Farage  Peter McGregor  Gabe Bloxham  Anthony Green  Bill Roberts  Jon Neilson  Greg Wilson  Peter Young  Peter Firth  Gianni Busarello  Paola Merluzzi 《Astrophysics and Space Science》2010,327(2):245-257

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Exchange of ejecta between Telesto and Calypso: Tadpoles, horseshoes, and passing orbits     

Anthony R. Dobrovolskis  José Luis Alvarellos  Jack J. Lissauer 《Icarus》2010,210(1):436-445

We have numerically integrated the orbits of ejecta from Telesto and Calypso, the two small Trojan companions of Saturn’s major satellite Tethys. Ejecta were launched with speeds comparable to or exceeding their parent’s escape velocity, consistent with impacts into regolith surfaces. We find that the fates of ejecta fall into several distinct categories, depending on both the speed and direction of launch.The slowest ejecta follow suborbital trajectories and re-impact their source moon in less than one day. Slightly faster debris barely escape their parent’s Hill sphere and are confined to tadpole orbits, librating about Tethys’ triangular Lagrange points L₄ (leading, near Telesto) or L₅ (trailing, near Calypso) with nearly the same orbital semi-major axis as Tethys, Telesto, and Calypso. These ejecta too eventually re-impact their source moon, but with a median lifetime of a few dozen years. Those which re-impact within the first 10 years or so have lifetimes near integer multiples of 348.6 days (half the tadpole period).Still faster debris with azimuthal velocity components ?10 m/s enter horseshoe orbits which enclose both L₄ and L₅ as well as L₃, but which avoid Tethys and its Hill sphere. These ejecta impact either Telesto or Calypso at comparable rates, with median lifetimes of several thousand years. However, they cannot reach Tethys itself; only the fastest ejecta, with azimuthal velocities ?40 m/s, achieve “passing orbits” which are able to encounter Tethys. Tethys accretes most of these ejecta within several years, but some 1% of them are scattered either inward to hit Enceladus or outward to strike Dione, over timescales on the order of a few hundred years.  相似文献   

Assessment of the resonant perturbation errors in Galilean satellite ephemerides using precisely measured eclipse times     

Anthony Mallama  Chris Stockdale 《Icarus》2010,210(1):346-357

Astrometric satellite positions are derived from timings of their eclipses in the shadow of Jupiter. The 548 data points span 20 years and are accurate to about 0.006 arcsec for Io and Europa and about 0.015 arcsec or better for Ganymede and Callisto. The precision of the data set and its nearly continuous distribution in time allows measurement of regular oscillations with an accuracy of 0.001 arcsec. This level of sensitivity permits detailed evaluation of modern ephemerides and reveals anomalies at the 1.3 year period of the resonant perturbations between Io, Europa and Ganymede. The E5 ephemeris shows large errors at that period for all three satellites as well as other significant anomalies. The L1 ephemeris fits the observations much more closely than E5 but discrepancies for the resonant satellites are still apparent and the measured positions of Io are drifting away from the predictions. The JUP230 ephemeris fits the observations more accurately than L1 although there is still a measurable discordance between the predictions and observations for Europa at the resonance period.  相似文献   

A hybrid artificial neural network-numerical model for ground water problems     

Szidarovszky F  Coppola EA  Long J  Hall AD  Poulton MM 《Ground water》2007,45(5):590-600

Numerical models constitute the most advanced physical-based methods for modeling complex ground water systems. Spatial and/or temporal variability of aquifer parameters, boundary conditions, and initial conditions (for transient simulations) can be assigned across the numerical model domain. While this constitutes a powerful modeling advantage, it also presents the formidable challenge of overcoming parameter uncertainty, which, to date, has not been satisfactorily resolved, inevitably producing model prediction errors. In previous research, artificial neural networks (ANNs), developed with more accessible field data, have achieved excellent predictive accuracy over discrete stress periods at site-specific field locations in complex ground water systems. In an effort to combine the relative advantages of numerical models and ANNs, a new modeling paradigm is presented. The ANN models generate accurate predictions for a limited number of field locations. Appending them to a numerical model produces an overdetermined system of equations, which can be solved using a variety of mathematical techniques, potentially yielding more accurate numerical predictions. Mathematical theory and a simple two-dimensional example are presented to overview relevant mathematical and modeling issues. Two of the three methods for solving the overdetermined system achieved an overall improvement in numerical model accuracy for various levels of synthetic ANN errors using relatively few constrained head values (i.e., cells), which, while demonstrating promise, requires further research. This hybrid approach is not limited to ANN technology; it can be used with other approaches for improving numerical model predictions, such as regression or support vector machines (SVMs).  相似文献   

Development of a benthic index to assess sediment quality in the Tampa Bay Estuary   总被引：1，自引：0，他引：1  

Malloy KJ  Wade D  Janicki A  Grabe SA  Nijbroek R 《Marine pollution bulletin》2007,54(1):22-31

The identification, remedial treatment, and monitoring of contaminated sediments are among the priorities for managers of the Tampa Bay Estuary. Tampa Bay, as an urbanized estuary, is subject to the input of watershed sources of chemical contaminants, including metals, pesticides, and organic chemicals. Although the use of biological indicators and their incorporation into multi-metric indices is not new, the refinement and applications of such techniques for determining environmental condition still require further development and exploration. We present a single Tampa Bay Benthic Index (TBBI) that was developed specifically for Tampa Bay. Stepwise discriminant analysis was applied to a comprehensive list of potential benthic metrics. Results from the stepwise procedure identified the metrics that best discriminated between "healthy" and "degraded" conditions, as defined by sediment contaminant effect levels and dissolved oxygen. Discriminant analysis was then applied to the resultant three variables to determine the linear combination for the index.  相似文献   

Preliminary model of nitrogen loads from southern bluefin tuna aquaculture   总被引：1，自引：0，他引：1  

Fernandes M  Lauer P  Cheshire A  Angove M 《Marine pollution bulletin》2007,54(9):1321-1332

Farming of wild tuna in coastal areas is a relatively new aquaculture industry and little is known about the magnitude of nutrient discharges to the environment. In this work we present a preliminary model of nitrogen loads from southern bluefin tuna (Thunnus maccoyii) aquaculture in lower Spencer Gulf, South Australia. The model was developed based on feed inputs, estimates of fish metabolism and environmental data. Two pens were monitored over a full grow-out season to determine nitrogen sedimentation fluxes, remineralization at the sediment-water interface and accumulation in the sediments. The model suggests that the high metabolic rates of tuna lead to low retention of nitrogen in fish tissues (7-12% of feed inputs) and high environmental losses (260-502kg Ntonne(-1) growth). Considering Australian annual production of 4380tonnes over initial stocked biomass, total loads can reach 1137tonnes N per year, 86-92% lost as dissolved wastes. The nature of wastes suggests low localized impacts at current stocking densities and holding periods.  相似文献   

Saturn eddy momentum fluxes and convection: First estimates from Cassini images     

Anthony D. Del Genio  John M. Barbara  Andrew P. Ingersoll  Ashwin R. Vasavada  Carolyn C. Porco 《Icarus》2007,189(2):479-492

We apply an automated cloud feature tracking algorithm to estimate eddy momentum fluxes in Saturn's southern hemisphere from Cassini Imaging Science Subsystem near-infrared continuum image sequences. Voyager Saturn manually tracked images had suggested no conversion of eddy to mean flow kinetic energy, but this was based on a small sample of <1000 wind vectors. The automated procedure we use for the Cassini data produces an order of magnitude more usable wind vectors with relatively unbiased sampling. Automated tracking is successful in and around the westward jet latitudes on Saturn but not in the vicinity of most eastward jets, where the linearity and non-discrete nature of cloud features produces ambiguous results. For the regions we are able to track, we find peak eddy fluxes and a clear positive correlation between eddy momentum fluxes and meridional shear of the mean zonal wind, implying that eddies supply momentum to eastward jets and remove momentum from westward jets at a rate . The behavior we observe is similar to that seen on Jupiter, though with smaller eddy-mean kinetic energy conversion rates per unit mass of atmosphere (). We also use the appearance and rapid evolution of small bright features at continuum wavelengths, in combination with evidence from weak methane band images where possible, to diagnose the occurrence of moist convective storms on Saturn. Areal expansion rates imply updraft speeds of over the convective anvil cloud area. As on Jupiter, convection preferentially occurs in cyclonic shear regions on Saturn, but unlike Jupiter, convection is also observed in eastward jet regions. With one possible exception, the large eddy fluxes seen in the cyclonic shear latitudes do not seem to be associated with convective events.  相似文献   

Controls on uranium distribution in lake sediments     

Anthony Chappaz  André Tessier 《Geochimica et cosmochimica acta》2010,74(1):203-88

Uranium geochemistry has been investigated in three acid lakes located on the Canadian Shield and one circumneutral lake in the Appalachian Region of Eastern Canada. In all Shield lakes, dissolved U concentrations were higher in the porewater than in the overlying water. In one of them, whose hypolimnion is perennially oxic, U released to porewater at depths of Fe remobilization was removed from the porewater at depths of Fe oxyhydroxides precipitation; these similarities in the U and Fe profiles indicate that part of the U becomes associated to Fe oxyhydroxides. The dissolved U and Fe profiles in the other two Shield lakes, whose hypolimnions were anoxic when sampled, did not show any significant recycling of these elements in the vicinity of the sediment-water interface and both elements diffused from the sediment to the overlying water. In contrast, in the Appalachian Lake, dissolved U concentrations were higher in the overlying water than in porewater, strongly decreased at the vicinity of the sediment-water interface and then remained relatively constant with sediment depth. Diagenetic modeling of the porewater U profiles, assuming steady-state, reveals that authigenic U always represented ?3% of the total U concentration in the sediments of all lakes. This observation indicates that diagenetic reactions involving U are not quantitatively important and that most of the U was delivered to the sediments at our study sites as particulate U and not through diffusion across the sediment-water interface, as is seen in continental margin sediments. Comparison of the U:C_org and U:Fe molar ratios in diagenetic material collected across the sediment-water interface with Teflon sheets and in surface sediments (0-0.5 cm) of the lake having a perennially oxic hypolimnion suggest that solid phase U was mainly bound to organic matter originating from the watershed; a strong statistical correlation between sediment non-lithogenic U and C_org in the Appalachian Lake supports this contention. Thermodynamic calculations of saturation states suggest that dissolved U was not removed from porewater through precipitation of UO_2(s), U₃O_7(s) and U₃O_8(s) as previously proposed in the literature.  相似文献   

The nature of Cu bonding to natural organic matter     

Alain Manceau  Anthony Matynia 《Geochimica et cosmochimica acta》2010,74(9):2556-2587

Copper biogeochemistry is largely controlled by its bonding to natural organic matter (NOM) for reasons not well understood. Using XANES and EXAFS spectroscopy, along with supporting thermodynamic equilibrium calculations and structural and steric considerations, we show evidence at pH 4.5 and 5.5 for a five-membered Cu(malate)₂-like ring chelate at 100-300 ppm Cu concentration, and a six-membered Cu(malonate))_1-2-like ring chelate at higher concentration. A “structure fingerprint” is defined for the 5.0-7.0 Å⁻¹ EXAFS region which is indicative of the ring size and number (i.e., mono- vs. bis-chelate), and the distance and bonding of axial oxygens (O_ax) perpendicular to the chelate plane formed by the four equatorial oxygens (O_eq) at 1.94 Å. The stronger malate-type chelate is a C₄ dicarboxylate, and the weaker malonate-type chelate a C₃ dicarboxylate. The malate-type chelate owes its superior binding strength to an -OH for -H substitution on the α carbon, thus offering additional binding possibilities. The two new model structures are consistent with the majority of carboxyl groups being clustered and α-OH substitutions common in NOM, as shown by recent infrared and NMR studies. The high affinity of NOM for Cu(II) is explained by the abundance and geometrical fit of the two types of structures to the size of the equatorial plane of Cu(II). The weaker binding abilities of functionalized aromatic rings also is explained, as malate-type and malonate-type structures are present only on aliphatic chains. For example, salicylate is a monocarboxylate which forms an unfavorable six-membered chelate, because the OH substitution is in the β position. Similarly, phthalate is a dicarboxylate forming a highly strained seven-membered chelate.Five-membered Cu(II) chelates can be anchored by a thiol α-SH substituent instead of an alcohol α-OH, as in thio-carboxylic acids. This type of chelate is seldom present in NOM, but forms rapidly when Cu(II) is photoreduced to Cu(I) at room temperature under the X-ray beam. When the sample is wet, exposure to the beam can reduce Cu(II) to Cu(0). Chelates with an α-amino substituent were not detected, suggesting that malate-like α-OH dicarboxylates are stronger ligands than amino acids at acidic pH, in agreement with the strong electronegativity of the COOH clusters. However, aminocarboxylate Cu(II) chelates may form after saturation of the strongest sites or at circumneutral pH, and could be observed in NOM fractions enriched in proteinaceous material. Overall, our results support the following propositions:

(1)

The most stable Cu-NOM chelates at acidic pH are formed with closely-spaced carboxyl groups and hydroxyl donors in the α-position; oxalate-type ring chelates are not observed.

(2)

Cu(II) bonds the four equatorial oxygens to the heuristic distance of 1.94 ± 0.01 Å, compared to 1.97 Å in water. This shortening increases the ligand field strength, and hence the covalency of the Cu-O_eq bond and stability of the chelate.

(3)

The chelate is further stabilized by the bonding of axial oxygens with intra- or inter-molecular carboxyl groups.

(4)

Steric hindrances in NOM are the main reason for the absence of Cu-Cu interactions, which otherwise are common in carboxylate coordination complexes.

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