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141.
Cycling plays an important role in low-carbon transitions. Around the globe, cities are constructing bicycle infrastructure. The city of Copenhagen has a bicycle-friendly infrastructure celebrated for its fine-meshed network. This study documents the spatio-temporal development of Copenhagen’s bicycle infrastructure and explores how the development corresponds to other processes of urban transformation. The study builds on historical maps of bicycle infrastructure that are digitised into geographical information, which allows for a comprehensive analysis of the formation of the network. In search for identifying drivers, the study analyses the city’s spatial growth pattern, migration pattern, development of road network and changes in the transport culture. Analyses reveal that the bicycle infrastructure expanded at a relatively constant pace during distinct periods of urban transformation, including periods when the city suffered from spatial, economic and demographic decline, and dominance of car traffic. By discussing reasons and demands for constructing bicycle infrastructure, the study identifies four distinct periods in which bicycle infrastructure was constructed to enhance comfort and safety (first cycling city); the flow for cars (car city); urban liveability for soft transport (liveable city); and, finally, to improve the flow for cyclists as part a strategic re-design of urban space (liveable cycling city).  相似文献   
142.
This paper presents the first release of an Informational System(IS)devoted to the systematic collection of all available data relating to Pliocene-Quaternary faults in southern East Siberia,their critical analysis and their seismotectonic parameterization.The final goal of this project is to form a new base for improving the assessment of seismic hazard and other natural processes associated with crustal deformation.The presented IS has been exploited to create a relational database of active and conditionally active faults in southern East Siberia(between 100°-114° E and 50°-57° N)whose central sector is characterized by the highly seismic Baikal rift zone.The information within the database for each fault segment is organized as distinct but intercorrelated sections(tables,texts and pictures,etc.)and can be easily visualized as HTML pages in offline browsing.The preliminary version of the database distributed free on disk already highlights the general fault pattern showing that the Holocene and historical activity is quite uniform and dominated by NE-SW and nearly E-W trending faults;the former with a prevailing dip-slip normal kinematics,while the latter structures are left-lateral strike-slip and oblique-slip(with different proportion of left-lateral and normal fault slip components).These faults are mainly concentrated along the borders of the rift basins and are the main sources of moderate-to-strong(M≥5.5)earthquakes on the southern sectors of East Siberia in recent times.As a whole,based on analyzing the diverse fault kinematics and their variable spatial distribution with respect to the overall pattern of the tectonic structures formed and/or activated during the late Pliocene-Quaternary,we conclude they were generated under a regional stress field mainly characterized by a relatively uniform NW-SE tension,but strongly influenced by the irregular hard boundary of the old Siberian craton.The obtained inferences are in an agreement with the existing models of the development of  相似文献   
143.
In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Smn ratios (0.02–0.2), whereas those showing variable enrichment have La/Smn ranging up to 3.8 and La/Ybn to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Smn = 1.3–4.1; La/Ybn = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREEN enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup.  相似文献   
144.
Long‐term relative sea‐level cycles (0·5 to 6 Myr) have yet to be fully understood for the Cretaceous. During the Aptian, in the northern Maestrat Basin (Eastern Iberian Peninsula), fault‐controlled subsidence created depositional space, but eustasy governed changes in depositional trends. Relative sea‐level history was reconstructed by sequence stratigraphic analysis. Two forced regressive stages of relative sea‐level were recognized within three depositional sequences. The first stage is late Early Aptian age (intra Dufrenoyia furcata Zone) and is characterized by foreshore to upper shoreface sedimentary wedges, which occur detached from a highstand carbonate platform, and were deposited above basin marls. The amplitude of relative sea‐level drop was in the order of tens of metres, with a duration of <1 Myr. The second stage of relative sea‐level fall occurred within the Late Aptian and is recorded by an incised valley that, when restored to its pre‐contractional attitude, was >2 km wide and cut ≥115 m down into the underlying Aptian succession. With the subsequent transgression, the incision was backfilled with peritidal to shallow subtidal deposits. The changes in depositional trends, lithofacies evolution and geometric relation of the stratigraphic units characterized are similar to those observed in coeval rocks within the Maestrat Basin, as well as in other correlative basins elsewhere. The pace and magnitude of the two relative sea‐level drops identified fall within the glacio‐eustatic domain. In the Maestrat Basin, terrestrial palynological studies provide evidence that the late Early and Late Aptian climate was cooler than the earliest part of the Early Aptian and the Albian Stage, which were characterized by warmer environmental conditions. The outcrops documented here are significant because they preserve the results of Aptian long‐term sea‐level trends that are often only recognizable on larger scales (i.e. seismic), such as for the Arabian Plate.  相似文献   
145.
Abstract– Samples returned by the Stardust mission from comet 81P/Wild 2 provide an unequaled opportunity to investigate cometary formation and evolution. Crystalline silicates have been identified in impact craters in Stardust Al foil, yet their origin is ambiguous. They may be original cometary components, or they may have grown from melt generated by impact. We have now studied experimental impacts of the calcium silicate mineral wollastonite, using scanning and transmission electron microscopy to document the relationship between impact feature shape and crystal lattice orientation in impact residue. Wollastonite can have a characteristic acicular habit, forming crater shapes that indicate crystal orientation upon impact. From extracted impact residue, we determined the lattice orientation of crystalline material for comparison with the whole particle orientation. We assume that crystallization from melt, without surviving seed nuclei, should result in randomly oriented crystallite growth, with no preferred direction for individual crystals. However, we find that the majority of crystalline material in the residue retains b‐axis orientation parallel to the long axis of the crater form. This, together with impact parameter calculations and lack of Al incorporation by the residue (suggesting melting did not occur), indicates that these crystals and, by analogy, the majority of Al‐free crystalline silicates in Stardust foil, are surviving remnants of the impactor. Furthermore, amorphous wollastonite residue probably did not form via melting and subsequent quenching, but instead by high‐pressure amorphization or degradation of unquenchable phases. Finally, one crystal studied appears to be a new high‐pressure/temperature polymorph of CaSiO3, indicating that such polymorphs may be observed in Stardust residues in craters.  相似文献   
146.
The interplay between streamwise flow,curvature-induced secondary flow,sediment transport and bed morphology leads to the formation of a typical bar-pool bed morphology in open-channel bends.The associated scour at the outer bank and deposition at the inner bank may endanger the outer bank’s stability or reduce the navigable width of the channel.Previous preliminary laboratory experiments in a sharply curved flume with a fixed horizontal bed have shown that a bubble screen located near the outer bank can generate an additional secondary flow located between the outer bank and the curvature-induced secondary flow and with a sense of rotation opposite to the latter.This bubble-induced secondary flow redistributes velocities and bed shear stresses.The reported study investigates the implications of a bubble screen on the flow and the morphology in configurations with mobile bed.Velocity measurements show that the bubble-induced secondary flow shifts the curvature-induced secondary flow in inwards direction and reduces its strength.The bubble screen considerably reduces morphological gradients.Maximum bend scour is reduced by about 50%and occurs further away from the outer bank where it does not endanger the bank stability anymore.The location of maximum scour coincides with the junction of the curvature-induced and bubble-induced secondary flows.At this same location,the maximum streamwise velocities and maximum vertical velocities impinging on the bed also occur,which indicates their importance with respect to the formation of bend scour.The bubble screen also substantially reduced deposition at the inner bank.These preliminary experiments show the potential of a bubble screen to influence and modify the bed morphology.  相似文献   
147.
A model with short computational time has previously been developed to predict the rate-dependent gas/oil ratio (GOR) from a horizontal well. The oil flow towards the wellbore is based on a one-dimensional model by Konieczek. The model performs remarkably well for medium-time production optimization (weeks, months), while the predictions during the first days after a large change in the production can be poor. An improved one-dimensional model for the flow towards the wellbore is proposed, where the oil flow is treated as a superposition of three terms:
1)  Radial flow towards the wellbore and towards a mirror well.  相似文献   
148.
149.
Single-crystal electron paramagnetic resonance spectra of electron-irradiated stishovite, measured at temperatures from 3.5 to 294?K, reveal three S?=?1/2 radiation-induced defects: an aluminum-associated oxygen hole center and two nd 1 centers (Ti3+ and W5+). The aluminum-associated oxygen hole center, characterized by an orthorhombic site symmetry, coaxial matrices of the electronic Zeeman g, nuclear hyperfine A(27Al) and nuclear quadrupole P(27Al), and the orientation of the g-minimum axis along an O–O direction and those of the unique A(27Al) and P(27Al) axes perpendicular to the O–O direction, is an Al–O2 3? center, with the unpaired electron equally distributed on two equatorial oxygen atoms of a substitutional Al3+ ion at the octahedral Si site. Fully optimized Al-doped structure, theoretical 27Al nuclear hyperfine and quadrupole coupling constants and directions, and 3D spin densities from periodic hybrid density functional theory calculations provide further support for this structural model. Spin Hamiltonian parameters of the Ti3+ and W5+ centers, which are confirmed by their diagnostic 47Ti, 49Ti and 183W hyperfine structures, arise from electron trapping on substitutional Ti4+ and W6+ ions at the octahedral Si site.  相似文献   
150.
Orange, ochre-coloured, light green and dark blue varieties of kyanite, ideally Al2SiO5, from Loliondo, Tanzania, have been characterised by electron microprobe analysis and polarised infrared and optical absorption spectroscopy. All colour varieties show elevated Fe contents of 0.39 to 1.31 wt.% FeO, but Ti contents only in the range of the EMP detection limit. Orange and ochre-coloured crystals have Mn contents of 0.23 and 0.06 wt.% MnO, respectively, the dark blue kyanite contains 0.28 wt.% Cr2O3, while the light green sample is nearly free from transition metal cations other than Fe. Polarised infrared spectra reveal OH defect concentrations of 3 to 17 wt.ppm H2O with structural OH defects partially replacing the OB (O2) oxygen atoms. Polarised optical absorption spectra show that the colour of all four varieties is governed by crystal field d-d transitions of trivalent cations, i.e. Fe3+ (all samples), Mn3+ (orange and ochre) and Cr3+ (blue kyanite), replacing Al in sixfold coordinated triclinic sites of the kyanite structure. Intervalence charge transfer, the prevalent colour-inducing mechanism in ‘usual’ (Cr-poor) blue kyanites, seems to play a very minor, if any, role in the present samples. Crystal field calculations in both a ‘classic’ tetragonal and in the semiempirical Superposition Model approach, accompanied by distance- and angle-least-squares refinements, indicate that Fe3+ preferably occupies the Al4 site, Cr3+ prefers the Al1 and Al2 sites, and Mn3+ predominantly enters the Al1 site. In each case specific local relaxation effects were observed according to the crystal chemical preferences of these transition metal cations. Furthermore, the high values obtained in the calculations for the interelectronic repulsion parameter Racah B correspond to a high ionic contribution to Me3+–O bonding in the kyanite structure. In the particular case of the blue sample, band positions specifically related to the high Racah B value enable this ‘unusual’ type of blue colouration of kyanite solely due to Cr3+ cations.  相似文献   
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