Mechanisms of galena dissolution in oxygen-saturated solutions: Evaluation of pH effect on apparent activation energies and mineral-water interface   总被引：1，自引：0，他引：1  

Giovanni De Giudici  Antonella Rossi  Pierfranco Lattanzi 《Geochimica et cosmochimica acta》2005,69(9):2321-2331

This work describes a laboratory investigation of processes ruling the dissolution of galena (PbS) under conditions that mimic oxidising Earth surface environments. Freshly cleaved (001) galena surface was partially dissolved in solutions at different pH (HCl, pH between 1.2 and 5.8) and temperature (298 K) levels for several weeks in a flow-through reactor. Analysis of the galena surface after exposure to oxygen-saturated solutions was performed by XPS. The estimated thickness of surface layer formed after interaction for four weeks with solution at pH 5.8 was ∼0.5 nm. After the same time of interaction with solution at pH 1, the surface layer was at least 9 nm thick. Stationary dissolution rates were measured at different pH (between 1 and 5.8) and temperatures (298, 323, 348 K). Reaction order with respect to hydrogen ion averages 0.6 and slightly decreases with temperature. Dissolution rates, plotted vs. the reciprocal values of temperature, follow Arrhenius behaviour. Activation energies show a sharply discontinuous variation with pH. They are 13.5 ± 2 kJmol⁻¹ at pH = 1.2 and 2.87, whereas at pH of 4.08, 4.7, and 5.8, they show, respectively, values of 48.8 ± 3.5, 45 ± 4, and 51 ± 4 kJmol⁻¹. The apparent activation energy was also investigated by starting the experiment from pH 5.8 and then decreasing to pH 1.2. In this case, the apparent activation energies were 44 ± 4 kJmol⁻¹ and 21 ± 4 kJmol⁻¹, respectively.Apparent activation energies indicate a diffusion-controlled kinetic regime for pH <3, and a mixture of surface and diffusion control for pH between ∼4 and 5.8. A strong effect of solution pH on the mineral-water interface is revealed also by the observed pH dependence of surface-layer thickness. On the basis of the high-resolution XPS signals, the dependence of activation energies on solution pH should reflect a change of structure, and also chemical composition, of the mineral-water interface.  相似文献   

Modelling of ground acceleration in the near source range: the case of 1976, Friuli earthquake (M = 6.5), northern Italy     

Aldo Zollo  Antonella Bobbio  Antonio Emolo  André Herrero  Giuseppe De Natale 《Journal of Seismology》1997,1(4):305-319

A mixed statistical-deterministic model of earthquake rupture is developed for evaluating the strong ground motion in the near source range (receiver distance comparable to the fault length). The source parametrization is based on the k-square model and the propagation is computed by asymptotic Green's functions. The method is applied to the case of 1976, Friuli earthquake (M = 6.5) in northern Italy which occurred on a low-dip thrusting fault. Acceleration records at 29 stations are computed for 100 simulations of rupture histories. The mean value map of peak ground accelerations shows clearly a maximum to the south due to the inner geometry and directivity of the source. The variation of the estimated PGA versus the epicentral distance is strongly dependent on azimuth and is not decreasing monotonically. The comparison of these curves with those predicted by empirical acceleration–distance relationships shows discrepancies in the near source distance range. This study shows the importance of considering the complexity of the source rupture process for strong motion estimate in the near source range.  相似文献   

Impact of the 6 April 2009 L'Aquila earthquake on groundwater flow in the Gran Sasso carbonate aquifer,Central Italy     

Antonella Amoruso  Luca Crescentini  Marco Petitta  Sergio Rusi  Marco Tallini 《水文研究》2011,25(11):1754-1764

The Mw = 6·3 L'Aquila earthquake on 6 April 2009 produced a mainshock that caused significant changes in the hydrogeology of the Gran Sasso carbonate fractured aquifer: (i) the sudden disappearance at the time of the mainshock of some springs located exactly along the surface trace of the Paganica normal fault (PF); (ii) an immediate increase in the discharge of the Gran Sasso highway tunnel drainages and of other springs and (iii) a progressive increase of the water table elevation at the boundary of the Gran Sasso aquifer during the following months. Using the data collected since the 1990s that include aftershock monitoring as well as data regarding spring discharge, water table elevations, turbidity and rainfall events, a conceptual model of the earthquake's consequences on the Gran Sasso aquifer is proposed herein. In this model that excludes the contribution of seasonal recharge, the short‐term hydrologic effects registered immediately after the mainshock are determined to have been caused by a pore pressure increase related to aquifer deformation. Mid‐term effects observed in the months following the mainshock suggest that there was a change in groundwater hydrodynamics. Supplementary groundwater that flows towards aquifer boundaries and springs in discharge areas reflects a possible increase in hydraulic conductivity in the recharge area, nearby the earthquake fault zone. This increase can be attributed to fracture clearing and/or dilatancy. Simulations by numerical modelling, related to pore pressure and permeability changes with time, show results in accordance with observed field data, supporting the conceptual model and confirming the processes that influenced the answer of the Gran Sasso aquifer to the L'Aquila earthquake. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Ash erupted during normal activity at Stromboli (Aeolian Islands,Italy) raises questions on how the feeding system works     

Claudia?D’OrianoEmail author  Antonella?Bertagnini  Massimo?Pompilio 《Bulletin of Volcanology》2011,73(5):471-477

Ash fallout collected during 4 days of sampling at Stromboli confirms that a crystal-rich (HP) degassed magma erupts during the Strombolian explosions that are characteristic of the normal activity of this volcano. We identified 3 different types of juvenile ash fragments (fluidal, spongy and dense), which formed through different mechanisms of fragmentation of the low-viscosity, physically heterogeneous (in terms of the size and spatial distribution of bubbles) shoshonitic magma. A small amount (less than 3 vol%) of volatile-rich magma with low porphyricity (LP), erupted as highly vesicular ash fragments, has been collected, together with the HP magma, during normal strombolian explosions. Laboratory experiments and the morphological, textural and compositional investigations of ash fragments reveal that the LP ash is fresh and not recycled from the last paroxysm (15 March 2007). We suggest that small droplets of LP magma are dragged to the surface by the time-variable but persistent supply of deep derived CO₂-rich gas bubbles. This coupled ascent of bubbles and LP melts is transient and does not perturb the dynamics of the HP magma within the shallow reservoir. This finding provides a new perspective on how the Stromboli volcano works and has important implications for monitoring strategies.  相似文献   

Overview of the Italian strong motion database ITACA 1.0   总被引：3，自引：2，他引：1  

Francesca Pacor  Roberto Paolucci  Lucia Luzi  Fabio Sabetta  Andrea Spinelli  Antonella Gorini  Mario Nicoletti  Sandro Marcucci  Luisa Filippi  Mauro Dolce 《Bulletin of Earthquake Engineering》2011,9(6):1723-1739

The Italian Strong Motion Database, ITACA, was developed within projects S6 and S4, funded in the framework of the agreements between the Italian Department of Civil Protection (Dipartimento della Protezione Civile, DPC) and the Istituto Nazionale di Geofisica e Vulcanologia (INGV), starting from 2005. The alpha version of the database was released in 2007 and subsequently upgraded to version 1.0 after: (i) including the most recent strong motion data (from 2005 to 2007) recorded in Italy, in addition to the 2008 Parma earthquake, M 5.4, and the M ≥  4.0, 2009 Abruzzo seismic events; (ii) processing the raw strong motion data using an updated procedure; (iii) increasing the number of stations with a measured shear wave velocity profile; (iv) improving the utilities to retrieve time series and ground motion parameters; (v) implementing a tool for selecting time series in agreement with design-response spectra; (vi) compiling detailed station reports containing miscellaneous information such as photo, maps and site parameters; (vii) developing procedures for the automatic generation of station reports and for the updating of the header files. After such improvements, ITACA 1.0 was published at the web site , in 2010. It presently contains 3,955 three-component waveforms, comprising the most complete catalogue of the Italian accelerometric records in the period 1972–2007 (3,562 records) and the strongest events in the period 2008–2009. Records were mainly acquired by DPC through its Accelerometric National Network (RAN) and, in few cases, by local networks and temporary stations or networks. This paper introduces the published version of the Italian Strong Motion database (ITACA version 1.0) together with main improvements and new functionalities.  相似文献   

Opposition Effect of Kuiper Belt Objects: preliminary estimations     

Belskaya  Irina N.  Barucci  Antonella M.  Shkuratov  Yurij G. 《Earth, Moon, and Planets》2003,92(1-4):201-206

Information on the surface structure of the Kuiper Belt objectscan be obtained from studies of their opposition brightening.Although KBOs are observed at a very limited phase angle rangethey represent a unique opportunity to study the backscatteringphenomenon down almost to zero phase angle. Preliminaryestimations of the opposition effect amplitude and width based oncomposite phase curves of four KBOs and two Centaurs showed theexistence of a very narrow opposition surge of about 0.1–0.2 mag at phase angles less than 0.1–0.2 deg. It may indicate a highporosity of the KBOs regoliths. Further observations are needed toconfirm this phenomenon.  相似文献   

Results from the Eso Large Program on Transneptunian Objects and Centaurs     

Boehnhardt  Hermann  Barucci  Antonella  Delsanti  Audrey  De Bergh  Catherine  Doressoundiram  Alain  Romon  Jennifer  Dotto  Elisabetta  Tozzi  Gianpaolo  Lazzarin  Monica  Fornasier  Sonia  Peixinho  Nuno  Hainaut  Olivier  Davies  John  Rousselot  Philippe  Barrera  Luis  Birkle  Kurt  Meech  Karen  Ortiz  JoseLuis  Sekiguchi  Tomohiko  Watanabe  Jun-ichi  Thomas  Nick  West  Richard 《Earth, Moon, and Planets》2003,92(1-4):145-156

BVRI photometry of 107 TNOs and Centaurs establishes the range of spectral gradients to be between –5 to 55%/100 nm (with one exception). A cluster of very red Cubewanos is firmly identified in orbits of low inclination and eccentricity beyond 40 AU from the Sun. Further correlations between surface colours and dynamical parameters (inclination and perihelion distance) are suggested for Cubewanos and scattered disk objects, but lack complete confidence for their reality. Plutinos and Centaurs do not show any clear correlation between surface colours and orbital parameters. We present in this paper 12 spectra obtained in the visible region and nine of them for which we obtained also near infrared spectra up to 2.4 microns. A few other objects have been observed, but the data are still under reduction and analysis. The principal reported results obtained are: (i) a wide range of visible slopes; (ii) evidence for surface variations on 2001 PT₁₃; and (iii) possible detection of few percent of water ice (1999 TC_36}, 2000 EB₁₇₃, 1999 DE₉, 2001 PT₁₃, 2000 QC₂₄₃, 1998 SG₃₅).  相似文献   

Cosmological radiative transfer codes comparison project – I. The static density field tests     

Ilian T. Iliev  Benedetta Ciardi  Marcelo A. Alvarez  Antonella Maselli  rea Ferrara  Nickolay Y. Gnedin  Garrelt Mellema  Taishi Nakamoto  Michael L. Norman  Alexei O. Razoumov  Erik-Jan Rijkhorst  Jelle Ritzerveld  Paul R. Shapiro  Hajime Susa  Masayuki Umemura  Daniel J. Whalen 《Monthly notices of the Royal Astronomical Society》2006,371(3):1057-1086

Radiative transfer (RT) simulations are now at the forefront of numerical astrophysics. They are becoming crucial for an increasing number of astrophysical and cosmological problems; at the same time their computational cost has come within reach of currently available computational power. Further progress is retarded by the considerable number of different algorithms (including various flavours of ray tracing and moment schemes) developed, which makes the selection of the most suitable technique for a given problem a non-trivial task. Assessing the validity ranges, accuracy and performances of these schemes is the main aim of this paper, for which we have compared 11 independent RT codes on five test problems: (0) basic physics; (1) isothermal H  ii region expansion; (2) H  ii region expansion with evolving temperature; (3) I-front trapping and shadowing by a dense clump and (4) multiple sources in a cosmological density field. The outputs of these tests have been compared and differences analysed. The agreement between the various codes is satisfactory although not perfect. The main source of discrepancy appears to reside in the multifrequency treatment approach, resulting in different thicknesses of the ionized-neutral transition regions and the temperature structure. The present results and tests represent the most complete benchmark available for the development of new codes and improvement of existing ones. To further this aim all test inputs and outputs are made publicly available in digital form.  相似文献   

Impact of groundwater withdrawals on the interaction of multi-layered aquifers in the Viterbo geothermal area (central Italy)     

Antonella Baiocchi  Francesca Lotti  Vincenzo Piscopo 《Hydrogeology Journal》2013,21(6):1339-1353

The impact of groundwater withdrawals on the interaction between multi-layered aquifers with different water qualities in the Viterbo geothermal area (central Italy) was studied. In this area, deep thermal waters are used to supply thermal spas and public pools. A shallow overlying aquifer carries cold and fresh water, used for irrigation and the local drinking-water supply. Starting with a conceptual hydrogeological model, two simplified numerical models were implemented: a steady-state flow model of the entire groundwater system, and a steady-state flow and heat transport model of a representative area, which included complex interactions between the aquifers. The impact of increased withdrawals associated with potential future development of the thermal aquifer must be considered in terms of the water temperature of the existing thermal sources. However, withdrawals from the shallow aquifer might also influence the discharge of thermal sources and quality of the water withdrawn from the shallow wells. The exploitation of the two aquifers is dependent on the hydraulic conductivity and thickness of the intervening aquitard, which maintains the delicate hydrogeological equilibrium. Effective methods to control this equilibrium include monitoring the vertical gradient between the two aquifers and the residual discharge of natural thermal springs.  相似文献   

Numerical Investigation of the Impact of Ethanol on Flow in the Vadose Zone     

Sciortino Antonella  Feike J. Leij 《Ground water》2012,50(6):883-894

There is a need to elucidate the impact of ethanol on the subsurface environment because of the application of ethanol as automotive fuel. This study quantifies the effects of changes in surface tension, viscosity, and density induced by ethanol on the transmission and retention of water in the vadose zone. The HYDRUS‐1D model was modified to simulate two different scenarios of flow in a sandy loam involving ponding (constant head) or spillage with a subsequent rainfall event (constant flux). Solutions containing different amounts of the highly miscible ethanol (10, 50, and 100% by weight) as well as pristine water were considered. During ponding, ethanol reduced the amount of fluid entering the soil and slowed down the advancement of the wetting front. Viscosity effects were predominant for this scenario, reducing the average depth of the infiltrating liquid up to 44%. The total amount of pure ethanol that entered the soil was 11.38 vs. 17.64 cm for pure water. For the spillage scenario, the results suggest that density has little impact on the liquid movement. Surface tension effects are predominant in the upper portion of the soil. The changes in hydraulic conductivity due to ethanol‐induced modifications of solution viscosity are responsible for the slower advancement of the moisture front. The 10% ethanol solution moved 43.1% faster than pure ethanol during the first 2 d because of viscosity and surface tension effects.  相似文献