Cyanobacterial toxins in Italian freshwaters   总被引：1，自引：0，他引：1  

Valentina Messineo  Serena Melchiorre  Antonella Lugliè  Maria Antonietta Mariani  Antonio Di Corcia  Ermanno Carloni 《Limnologica》2009,39(2):95-106

This study focuses on the occurrence and distribution of cyanobacterial toxins from 1989 to 2006 in several Italian lakes of different characteristics and human uses, the latter including drinking water abstraction and recreation. Phytoplankton and LC/MS/MS toxin analyses were performed on surface water samples collected from 28 lakes. The most widespread species associated with toxin production belonged to the genera Microcystis, Planktothrix and Anabaena. Extracellular concentrations varied from non-detectable values up to 226.16 ng/mL for microcystins (sum of all variants), to 126 ng/mL for total cylindrospermopsin, and to 100 μg/g (dry weight) for anatoxin-a.The toxin concentrations in the lake waters did not always correlate with the cyanobacteria cell densities. This implies a need for control studies including toxin detection in water together with microscopic cell evaluations, in order to avoid possible toxin underestimates.  相似文献   

Recycling and “re-hydration” of degassed magma inducing transient dissolution/crystallization events at Stromboli (Italy)     

Patrizia Landi  Nicole Mtrich  Antonella Bertagnini  Mauro Rosi 《Journal of Volcanology and Geothermal Research》2008,174(4):325-336

Intrusive degassing and recycling of degassed and dense magma at depth have been proposed for a long time at Stromboli. The brief explosive event that occurred at the summit craters on 9 January 2005 threw out bombs and lapilli that could be good candidates to illustrate recycling of shallow degassed magma at depth. We present an extensive data set on both the textures and the mineral, bulk rock and glassy matrix chemistry of the “9 Jan” products. The latter have the common shoshonitic–basaltic bulk composition of lavas and scoriae issued from typical strombolian activity. In contrast they differ by the heterogeneous chemistry of their matrix glasses and their crystal textures that testify to crystal dissolution event(s) just prior magma crystallization upon ascent and eruption. Comparison between mineral paragenesis of the natural products and experimental phase equilibria suggest water-induced magma re-equilibration. We propose that mineral dissolution is related to water enrichment of the recycled degassed magma, via differential gas bubble transfer and to some extents its physical mixing with volatile-rich magma blobs. However, all these features illustrate transient processes. Even though evidence of mineral dissolution is ubiquitous at Stromboli, its effect on the bulk magma chemistry is minor because of the subtle interplay between mineral dissolution and crystallization in magmas having comparable bulk chemistry.  相似文献   

Industrial pollution at Bagnoli (Naples, Italy): benthic foraminifera as a tool in integrated programs of environmental characterisation   总被引：1，自引：1，他引：0  

Romano E  Bergamin L  Finoia MG  Carboni MG  Ausili A  Gabellini M 《Marine pollution bulletin》2008,56(3):439-457

In the 20th century an important industrial plant operated on the coastal area of Bagnoli. After its closing, an integrated study of environmental characterisation aimed at restoration started. The survey conducted was based on chemical and sedimentological analyses integrated with benthic foraminifera analyses. Statistical analysis of the data shows sectors with a distinct type and degree of pollution. Particularly, pollution linked to the silty sediment fraction, mainly due to Pb and Zn, was recognised in front of the southern sector of the plant. The study of benthic foraminifera provides evidence for a pollution-tolerant character in some species like Haynesina germanica and Quinqueloculina parvula. In addition, two species among the 113 recognised show high percentages of abnormal specimens. These percentages show a statistical correlation with some pollutants (PAHs, Mn, Pb and Zn). In addition, Energy Dispersive Spectrometry shows small amounts of Fe ions included in deformed tests of Miliolinella subrotunda. Because the number of these deformations is positively correlated to the concentration of PAHs, Mn and Zn, the inability of some specimens to exclude the foreign elements from the crystalline reticulum of the test could be attributed to the potential toxic effect of these pollutants.  相似文献   

Visible–near infrared spectral indices for mapping mineralogy and chemistry with OSIRIS‐REx     

Hannah H. Kaplan  Victoria E. Hamilton  Ellen S. Howell  F. Scott Anderson  M. Antonella Barrucci  John Brucato  Thomas H. Burbine  Beth E. Clark  Ed A. Cloutis  Harold C. Connolly  Elisabetta Dotto  Joshua P. Emery  Sonia Fornasier  Cateline Lantz  Lucy F. Lim  Frederic Merlin  Alice Praet  Dennis C. Reuter  Scott A. Sandford  Amy A. Simon  Driss Takir  Dante S. Lauretta 《Meteoritics & planetary science》2020,55(4):744-765

The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS‐REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single‐component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 μm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH‐bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk‐integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 μm. Our study prioritizes spectral indices to be used for OSIRIS‐REx spectral analysis and mapping and informs the reliability of all index‐derived data products, including a science value map for sample site selection.  相似文献   

The study of young substellar objects with ALMA     

Antonella Natta  Leonardo Testi 《Astrophysics and Space Science》2008,313(1-3):113-117

We discuss the potential of ALMA for studying the formation of substellar objects. We first review briefly the various formation mechanisms proposed so far and stress the unique capability of ALMA to detect and study pre-brown dwarf cores and to confirm the core-collapse scenario to the lowest possible masses. We then discuss the properties of disks around substellar objects. We show how it will be possible to detect with ALMA most disks around objects with mass as low as few Jupiter masses, and to resolve spatially their emission in the more favorable cases.  相似文献   

Stratigraphic architecture and anthropic impacts on subsoil to assess the intrinsic potential vulnerability of groundwater: the northeastern Campania Plain case study, southern Italy     

Daniela Ruberti  Marco Vigliotti  Rossana Marzaioli  Annamaria Pacifico  Antonella Ermice 《Environmental Earth Sciences》2014,71(1):319-339

This study attempts to assess the aquifer vulnerability in the northeastern sector of the Campania Plain (southern Italy). The area is a highly populated region with anthropic impacts caused by rapid urban growth, quarrying, agricultural and industrial activities and uncontrolled waste storage. The main geologic feature of this plain is the alternation of alluvial/transitional and volcaniclastic deposits of Late Pleistocene–Holocene age. The study was performed integrating different sets of geologic and environmental data to restore the stratigraphic architecture and to assess anthropic impacts on subsoil. The reconstruction of stratigraphic subsurface architecture was based on remarkable geodatabase, concerning well log stratigraphies. Specific insights have been delineated on the volcaniclastic lithofacies heteropies across the entire area of study to highlight the differences in lithification degree and permeability. The contribution of pedogenesis on the reconstruction of the stratigraphic setting was also considered for the relative implications on groundwater quality concerns, as paleosols are usually regarded as aquitards. All of this information has been managed into a GIS project to produce a detailed 3D geological reconstruction, integrated with hydrogeological information to provide a model of the aquifer under study, highlighting sites of greater vulnerability to pollution. The anthropic impacts on subsoil were assessed by evaluating land-uses and overlaying the ANHI (Agricultural Nitrate Hazard Index) Map. The integration of the above datasets has allowed to check the reliability of the previsional empirical model with respect to the hydrostratigraphic model based on a thorough stratigraphic model and to verify the real potential of contamination.  相似文献   

Innovative monitoring tools for the complex spatial dynamics of river chemistry: case study for the Alpine region     

Caterina Gozzi  Roberta Sauro Graziano  Francesco Frondini  Antonella Buccianti 《Environmental Earth Sciences》2018,77(16):579

Chemical reactions in aqueous geochemical systems are driven by nonequilibrium conditions, and their dynamics can be deduced through the distributional analysis (identification of probability laws) of complex compositional indices. In this perspective, compositional data analysis offers the possibility to investigate the behavior of the composition as a whole instead of isolated chemical species, with the awareness that multispecies systems are characterized by the simultaneous interactions among all their parts. We addressed this problem using D???1 isometric log-ratio coordinates describing the D compositional dataset of the river chemistry of the Alpine region (D number of variables), thus working in the \({{\mathbb{R}}^{D - 1}}\) statistical sample space. The D???1 coordinates were chosen using the decreasing variance criterion so that each one could provide information about different space–time properties for the investigated geochemical system. Coordinates dominated by heterogeneity appear to be able to capture regime shifts only on a long-time period and monitor processes on a very wide scale. On the other hand, coordinates characterized by lower variability present multimodality, thus capturing the presence of alternative states in the analyzed spatial domain also for the current time. Further developments are needed to determine the ranges of conditions for which variability and other statistics can be useful indicators of regime shifts on different time–space scales in geochemical systems.  相似文献   

Ecotoxicological and human health risk in a petrochemical district of southern Italy   总被引：2，自引：0，他引：2  

Ausili A  Gabellini M  Cammarata G  Fattorini D  Benedetti M  Pisanelli B  Gorbi S  Regoli F 《Marine environmental research》2008,66(1):215-217

An ecotoxicological investigation has been carried in the petrochemical district of Priolo (Sicily, Italy), one of the largest in Europe. Results indicated a severe mercury contamination in sediments sampled near a chloro-alkali plant. A clear bioavailability of this element was demonstrated in mussels Mytilus galloprovincialis (both native and translocated) and the benthic fish Mullus barbatus, which also exhibited marked genotoxic damages. The elevated mercury concentrations in marine organisms are a serious concern for human health; according to the national average fish consumption, the provisional tolerable weekly intake (PTWI) of Hg would be easily exceeded by at least 4 to 12 fold. Such toxicological risk is of particular importance for pregnant women, being possibly involved in the elevated frequency of neonatal malformations.  相似文献   

Climatic modulation of seismicity in the Alpine–Himalayan mountain ranges     

Giuliano F. Panza  Antonella Peresan  Elisa Zuccolo 《地学学报》2011,23(1):19-25

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Bioavailability of different chemical forms of dissolved silica can affect marine diatom growth     

Samuela Capellacci  Cecilia Battocchi  Silvia Casabianca  Marco Giovine  Giorgio Bavestrello  Antonella Penna 《Marine Ecology》2013,34(1):103-111

In this study, we demonstrate that dissolved silica obtained from mineral (crystalline quartz), biogenic amorphous (diatomaceous earth) and artificial amorphous sources (Aerosil) influence the growth rate of two marine diatoms, Chaetoceros sp. and Skeletonema marinoi. Diatoms were reared in four different experimental conditions in artificial seawater containing either dissolved silica previously obtained through dissolution of the mineral crystalline quartz or two amorphous substrates, biogenic diatomaceous earth or artificial Aerosil silica. Sodium metasilicate was used as control. When the silica in the different media reached concentrations higher than 107 μm , particles were eliminated by filtration and the diatom cells were inoculated. Maximum cell density, growth and silica assimilation rates of both species in the presence of dissolved silica derived from crystalline quartz and metasilicate were higher than those obtained with the other silica sources. These results are discussed against the background of previous geochemical studies that have shown that silica–water interactions are strictly dependent on the silica polymorphs involved and on the ionic composition of the solution. Our results demonstrate that the soluble silicon compounds generated in seawater by crystalline sources are highly bioavailable compared with those generated by biogenic and amorphous materials. These findings are potentially of considerable ecological importance and may contribute to clarifying anomalous spatial and temporal distributions of siliceous organisms with respect to the presence of lithogenic or biogenic silica sources in marine environments.  相似文献