Anhydrite-bearing rocks from the Rožná district (Moldanubian zone,Czech Republic): high-grade metamorphosed exhalites?     

Bohdan Kříbek  Jana Hladíková  Daniel Holeczy 《Mineralium Deposita》2002,37(5):465-479

Several types of anhydrite-bearing rocks have been found in the amphibolite-facies metamorphosed rocks at the north-eastern margin of the Moldanubian Zone. Anhydrite either forms monomineralic bands up to 40 cm thick, or occurs in the form of disseminated grains in surrounding calc-silicate gneiss together with feldspar, scapolite, amphibole, pyroxene, epidote and pyrite. The isotopic composition of sulphur ('³⁴S=30.6 to 32.3‰) and strontium (⁸⁷Sr/⁸⁶Sr=0.70797 to 0.70781) in anhydrite may indicate a marine source of sulphate. The isotopic ratio of strontium is in the same range as that of metamorphosed strata-bound barite-sulphide ores, which have been previously described in the same area. The '³⁴S values of coexisting pyrite range from 21.4 to 22.5‰, the (³⁴S_{anhydrite-pyrite} corresponding to the metamorphic temperature of 600 to 660 °C. In contrast to many submarine-exhalative deposits, the oxygen isotopic compositions of anhydrite ('¹⁸O=9.3 to 10.2‰) are lighter than that of barite ('¹⁸O=10.4 to 13.8‰). This indicates that the both minerals are not in isotopic equilibrium. Therefore, it is probable that anhydrite and barite from the Ro—ná district were deposited from fluids that contained different proportions of seawater and hydrothermal fluids or from hydrothermal fluids that underwent variable extent of oxygen isotope exchange with seafloor rocks. The '¹³C values in calcite ('¹³C=-17.2 to -18.7‰) from anhydrite-bearing rock are lower than those in distant marbles. As graphite is absent in anhydrite- and calcite-bearing rocks, impoverishment in the ¹³C isotope cannot be attributed to the graphite-carbonate isotopic exchange during metamorphism. It is proposed that low '¹³C values in carbonates are caused by pre-metamorphic oxidation of organic matter in course of hydrothermal processes. Anhydrite and anhydrite-bearing calc-silicate gneiss from the north-eastern part of the Moldanubian Zone are interpreted to be the high-grade metamorphosed analogue of anhydrite-rich exhalites commonly found in submarine-exhalative hydrothermal deposits.  相似文献   

Crystallization conditions of Los Angeles, a basaltic Martian meteorite     

Dimitrios Xirouchakis  David S. DraperCraig S. Schwandt  Antonio Lanzirotti 《Geochimica et cosmochimica acta》2002,66(10):1867-1880

The texture of Los Angeles (stone 1) is dominated by relatively large (0.5−2.0 mm) anhedral to subhedral grains of pyroxene, and generally subhedral to euhedral shocked plagioclase feldspar (maskelynite). Minor phases include subhedral titanomagnetite and ilmenite, Fe-rich olivine, olivine+augite-dominated symplectites [some of which include a Si-rich phase and some which do not], pyrrhotite, phosphate(s), and an impact shock-related alkali- and silica-rich glass closely associated with anhedral to euhedral silica grains. Observations and model calculations indicate that the initial crystallization of Mg-rich pigeonitic pyroxenes at ≤1150 °C, probably concomitantly with plagioclase, was followed by pigeonitic and augitic compositions between 1100 and 1050 °C whereas between 1050 and 920 to 905 °C pyroxene of single composition crystallized. Below 920 to 905 °C, single composition Fe-rich clinopyroxene exsolved to augite and pigeonite. Initial appearance of titanomagnetite probably occurred near 990 °C and FMQ-1.5 whereas at and below 990 °C and ≥FMQ-1.5 titanomagnetite and single composition Fe-rich clinopyroxene may have started to react, producing ilmenite and olivine. However, judging from the most common titanomagnetite compositions, we infer that most of this reaction likely occurred between 950 and 900 °C at FMQ-1.0±0.2 and nearly simultaneously with pyroxene exsolution, thus producing assemblages of pigeonite, titanomagnetite, olivine, ilmenite, and augite. We deem this reaction as the most plausible explanation for the formation of the olivine+augite-dominated symplectites in Los Angeles. But we cannot preclude possible contributions to the symplectites from the shock-related alkali- and silica-rich glass or shocked plagioclase, and the breakdown of Fe-rich pigeonite compositions to olivine+augite+silica below 900 °C. Reactions between Fe-Ti oxides and silicate minerals in Los Angeles and other similar basaltic Martian meteorites can control the T-fO₂ equilibration path during cooling, which may better explain the relative differences in fO₂ among the basaltic Martian meteorites.  相似文献   

Spatial and temporal variation of the nekton and hyperbenthos from a temperate European estuary with regulated freshwater inflow     

Pilar Drake  Alberto M. Arias  Francisco Baldó  José A. Cuesta  Antonio Rodríguez  Alfonso Silva-Garcia  Ignacio Sobrino  Diego García-González  Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468

The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary.  相似文献   

Sub-wavebase cross-bedded grainstones on a distally steepened carbonate ramp, Upper Miocene, Menorca, Spain   总被引：1，自引：0，他引：1  

Luis Pomar  Antonio Obrador†  & Hildegard Westphal‡ 《Sedimentology》2002,49(1):139-169

Cross‐bedded grainstones on carbonate ramps and shelves are commonly related to the locus of major wave energy absorption such as shorelines, shoals or shelf breaks. In contrast, on the Early Tortonian carbonate platform of Menorca (Balearic Islands), coarse‐grained, cross‐bedded grainstones are found at a distance from the palaeoshoreline where they were deposited below the wavebase. Excellent exposures along continuous outcrops on the sea cliffs of Menorca reveal the depositional profile and three‐dimensional distribution of the different facies belts of the Tortonian ramp depositional system. Basinward from the palaeoshoreline, fan deltas and beach deposits pass into 5‐km‐wide gently dipping bioturbated dolopackstone (inner and middle ramp), then into 12–20°‐dipping dolograinstone/rudstone clinobeds (ramp slope) and, finally, into subhorizontal fine‐grained basinal dolowackestone to dolopackstone (outer ramp). In this Miocene example, coarse‐grained grainstones exist in five different settings other than beach deposits: (1) on the middle ramp, where cross‐bedded grainstones were deposited by currents roughly parallel to the shoreline at 40–70 m estimated water depth and are interbedded with gently dipping bioturbated dolomitized packstones; (2) on the upper slope, where clinobeds are composed mostly of in situ rhodoliths and red‐algae fragments; (3) on the lower slope, as small‐scale bedforms (small three‐dimensional subaqueous dunes) migrating parallel to the slope; (4) at the transition between the lower slope and the outer ramp, where mollusc‐rich and rhodolithic rudstones and grainstones, interbedded in dolomitized laminated wackestones containing abundant planktonic foraminifera, infill slide/slump scars as upslope‐backstepping bodies (backsets); (5) at the toe of the slope, where coarse skeletal grainstones indicate bedform migration parallel to the platform margin, induced by currents at more than 150 m estimated water depth. This Late Miocene example also illustrates how changes in intrabasinal environmental conditions (nutrients and/or temperature) may produce changes in stratal patterns and facies architecture if they affect the biological system. Two depositional sequences compose the Miocene platform on Menorca, where a reef‐rimmed platform prograded onto an earlier distally steepened ramp. The transition from the ramp to the reef‐rimmed platform was effected by an increase in accommodation space caused by ecological changes, promoting a shift from a grain‐ to a framework‐producing biota.  相似文献   

Ray tracing in elliptical anisotropic media using the linear traveltime interpolation (LTI) method applied to traveltime seismic tomography   总被引：3，自引：0，他引：3  

Ettore Cardarelli  Antonio Cerreto 《Geophysical Prospecting》2002,50(1):55-72

The linear traveltime interpolation (LTI) method is a suitable ray‐tracing technique for modelling first‐arrival times in isotropic media. LTI is extended to elliptical anisotropic media and applied to a tomographic inversion procedure. A theoretical formulation is first derived and then LTI implementation is discussed in terms of source–receiver arrays and cell size. The method is then combined with the tomographic inversion procedure adopted. The matching of the ray tracing with inversion in elliptical anisotropic media posed a double non‐linear problem. Thus two assumptions were made: the velocity in each cell is uniform and the main directions of anisotropy are known. To take into account the geometrical characteristics of the area under investigation (depth and velocity of the weathering, and thickness of the inner media), cells of varying size were considered. No hypothesis was made on anisotropy weakness.
The algorithm was first tested on synthetic models and then applied to a field survey. On comparing the results of the synthetic models and the field survey with those obtained with a linear raypath approximation, it was found that there were fewer data misfits.  相似文献   

δO of carbonate, quartz and phosphate from belemnite guards: implications for the isotopic record of old fossils and the isotopic composition of ancient seawater     

Antonio Longinelli  Paola IacuminMichele Ramigni 《Earth and Planetary Science Letters》2002,203(1):445-459

Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ¹⁸O values of the diagenetic water within the range of meteoric waters, the δ¹⁸O(SiO₂) yield temperatures in agreement with the apparent secondary origin of this phase. The δ¹⁸O(CO₃²⁻) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an ¹⁸O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ¹⁸O(PO₄³⁻) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ¹⁸O(PO₄³⁻) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the ¹⁸O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time.  相似文献   

Fish zonation in a Mediterranean stream: Effects of human disturbances   总被引：7，自引：0，他引：7  

Anna Vila-Gispert  Emili García-Berthou  Ramon Moreno-Amich 《Aquatic Sciences - Research Across Boundaries》2002,64(2):163-170

  相似文献   

Morphology of the ovotestis of Serranus atricauda (Teleostei,Serranidae)     

María Mercedes García-Díaz  María José Lorente  José Antonio González  Víctor Manuel Tuset 《Aquatic Sciences - Research Across Boundaries》2002,64(1):87-96

  相似文献   

Establishment of a Non-Permanent GPS Network to Monitor the Recent NE-SW Deformation in the Granada Basin (Betic Cordillera,Southern Spain)     

Gil  A. J.  Rodríguez-Caderot  G.  Lacy  M. C.  Ruiz  A. M.  Sanz de Galdeano  C.  Alfaro  P. 《Studia Geophysica et Geodaetica》2002,46(3):395-410

The Granada Basin (Central Betic Cordillera), one of the most seismically active areas of the Iberian Peninsula, is currently subjected to NW-SE compression and NE-SW extension. The present day extension is accommodated by normal faults with various orientations but particularly with a NW-SE strike. At the surface, these active NW-SE normal faults are mainly concentrated on the NE part of the Basin. In this part we have selected a 15-km long segment where several active normal faults crop out. Using the marine Tortonian rocks as a reference, we have calculated a minimum extensional rate of 0.15-0.30 mm/year. The observed block rotation, the listric geometry of faults at depth and the distribution of seismicity over the whole Basin, indicate that this rate is a minimum value. In the framework of an interdisciplinary research project a non-permanent GPS-network has been established in the central sector of Betic Cordillera to monitor the crustal deformations. The first two observation campaigns were done in 1999 and 2000.  相似文献   

Sea cliffs resulting from late Miocene extensional tectonics: the Serra Gelada case study (Betic Cordillera, Spain)     

Alfonso Ybenes  Pedro Alfaro  Jos Delgado  Antonio Estvez  Jesús M. Soria 《Geomorphology》2002,42(3-4)

The Serra Gelada sea cliffs are carved in Mesozoic carbonate rocks belonging to the External Zones of the eastern Betic Cordillera (Alicante, SE Spain). Several normal faults with vertical slips of more than a hundred metres have played an important role in the origin of this coastline. Some previous studies propose that the present cliff morphology was mainly originated by Quaternary fault activity. However, the integration of geomorphological features, stratigraphical and sedimentological data, together with the results of the tectonic analysis of fractures occurring in Serra Gelada, and a detailed study of seismic reflection profiles carried out in the adjacent continental shelf, indicate that these normal faults were active mainly during the late Miocene. Therefore, the Serra Gelada sea cliffs represent a tectonically controlled long-term landscape. Thus, normal faults have not significantly modified the Serra Gelada relief since then. Furthermore, the northern part of the Serra Gelada cliff may be considered as an inherited pre-Quaternary relict palaeocliff since it has only undergone very little erosive recession.  相似文献