Rapid Determination of Trace and Ultra Trace Level Elements in Diverse Silicate Rocks in Pressed Powder Pellet Targets by LA‐ICP‐MS using a Matrix‐Independent Protocol     

Pulok K. Mukherjee  Param P. Khanna  Naresh K. Saini 《Geostandards and Geoanalytical Research》2014,38(3):363-379

A simple, single sample preparation involving pressed rock powder pellets was utilised to determine the trace and ultra trace abundances of petrogenetically important elements including high field‐strength elements and REEs by laser ablation‐ICP‐MS. One of the elements predetermined by XRF spectrometry served as an internal standard. The influence of sample preparation parameters (grain size, pellet compactness and amount of binding media) on analytical performance was also investigated, including sample homogeneity issues at the laser sampling scale. Line scanning with a high repetition frequency (20 Hz) and large beam diameter (200 μm) ensured ablation from a larger sample surface area, eliminating issues related to sample heterogeneity. A median grain size of about 10 μm for silicate rock powders was found to be sufficiently representative at this scale of laser sampling. Granitic rocks or samples containing resistant minerals such as zircon needed extra grinding to achieve grain sizes down to < 5 μm for better precision for elements that are concentrated in these phases. Using ¹³⁷Ba as an internal standard, reasonable accuracies within 15–20% for most of the high mass trace elements were achieved; in the case of low mass elements, it may deviate up to 40%. Precision of measurements rarely exceeded 15% RSD.  相似文献   

Preparation and Characterisation of Two Geochemical Reference Materials: DG‐H (Granite) and AM‐H (Amphibolite) from the Himalayan Orogenic Belt     

Naresh K. Saini  Param P. Khanna  Pulok K. Mukherjee  Kishor K. Purohit 《Geostandards and Geoanalytical Research》2014,38(1):111-122

Two geochemical reference materials of Himalayan origin named DG‐H (a granite) and AM‐H (an amphibolite) prepared by the Wadia Institute of Himalayan Geology Dehradun are described. Both samples were collected from the NW Himachal Himalaya in India. With the participation of analysts from more than forty international laboratories, element determination data collected during the past 10 years for characterisation of the samples was processed to assign working values using statistical procedures in use for this purpose. Earlier work published on these samples is incorporated in the present communication making it an updated document. The typical chemical and petrological characteristics of these two samples may prove useful for method validation and calibration of analytical instruments used for analysing similar rock types, and for widening the analytical range of several analytical methods used for geochemical analysis.  相似文献   

Changes in concentration and size distribution of aerosols during fog over the south Indian Ocean     

Vimlesh Pant  C. G. Deshpande  A. K. Kamra 《Journal of Earth System Science》2010,119(4):479-487

Measurements of the concentration and size distribution of aerosol particles in the size-ranges of 0.5–20 μm and 16–700 nm diameters were made during six fog episodes over the south Indian Ocean. Observations show that concentrations of particles of all sizes start decreasing 1–2 hours before the occurrence of fog. This decrease is more prominent for coarse particles of >1 μm diameter and continues until 10–20 minutes before the onset of fog when particle concentrations in all size ranges rapidly increase by one/two orders of magnitude in ∼20 minutes. Thereafter, concentrations of particles of all sizes gradually decrease until the dissipation of fog. After the fog dissipation, concentrations of coarse mode particles rapidly increase and restore to their pre-fog levels but concentrations of the Aitken mode particles decrease slowly and reach their pre-fog levels only after 1–2 hours. The net effect of fog is to change the bimodal size distributions of aerosols with a coarse mode at 1.0 μm and an accumulation mode at 40–60 nm to a power law size distribution. It is proposed that the preferential growth and sedimentation of the coarse mode hygroscopic particles in the initial phase cause a large decrease in the aerosol surface area. As a result, the low vapour pressure gases which were initially being used for the growth of coarse mode particles, now accelerate the growth rates of the accumulation and Aitken mode particles.  相似文献   

Impact of land-use and land-cover change on groundwater quality in the Lower Shiwalik hills: a remote sensing and GIS based approach   总被引：2，自引：0，他引：2  

Sudhir Kumar Singh  Chander K Singh  Saumitra Mukherjee 《Central European Journal of Geosciences》2010,2(2):124-131

Human activities have exerted small to large scale changes on the hydrological cycle. The current scenario regarding groundwater resources suggests that globally there is a water crisis in terms of quantity (availability) and quality. Therefore there is a great need for the assessment and monitoring of quality and quantity of groundwater resources at local level. This paper presents a case study of the lower Shiwalik hills, in Rupnagar, Punjab, India, to trace land-use and land-cover changes during the past 17 years, with an emphasis on groundwater quality and quantity. This study was performed in alluvial and hilly terrain. The results show that the quantity of groundwater increased with the help of natural and artificial recharge due to change in land-use and land-cover pattern (increased area of fallow land). The quality of groundwater deteriorated due to input of fertilizers for enhancing the short-term soil fertility. Using a Remote Sensing and GIS based approach, we show the final results in map form. In particular we highlight a potential groundwater exploration site, which could be useful for district level planning. Our research shows that the change in land-use and land-cover affects the quantity and quality of groundwater.  相似文献   

Impact of physical parameterization schemes on numerical simulation of super cyclone Gonu   总被引：2，自引：0，他引：2  

Medha Deshpande  S. Pattnaik  P. S. Salvekar 《Natural Hazards》2010,55(2):211-231

The objective of this study is to investigate in detail the sensitivity of cumulus, planetary boundary layer and explicit cloud microphysics parameterization schemes on intensity and track forecast of super cyclone Gonu (2007) using the Pennsylvania State University-National Center for Atmospheric Research Fifth-Generation Mesoscale Model (MM5). Three sets of sensitivity experiments (totally 11 experiments) are conducted to examine the impact of each of the aforementioned parameterization schemes on the storm’s track and intensity forecast. Convective parameterization schemes (CPS) include Grell (Gr), Betts–Miller (BM) and updated Kain–Fritsch (KF2); planetary boundary layer (PBL) schemes include Burk–Thompson (BT), Eta Mellor–Yamada (MY) and the Medium-Range Forecast (MRF); and cloud microphysics parameterization schemes (MPS) comprise Warm Rain (WR), Simple Ice (SI), Mixed Phase (MP), Goddard Graupel (GG), Reisner Graupel (RG) and Schultz (Sc). The model configuration for CPS and PBL experiments includes two nested domains (90- and 30-km resolution), and for MPS experiments includes three nested domains (90-, 30- and 10-km grid resolution). It is found that the forecast track and intensity of the cyclone are most sensitive to CPS compared to other physical parameterization schemes (i.e., PBL and MPS). The simulated cyclone with Gr scheme has the least forecast track error, and KF2 scheme has highest intensity. From the results, influence of cumulus convection on steering flow of the cyclone is evident. It appears that combined effect of midlatitude trough interaction, strength of the anticyclone and intensity of the storm in each of these model forecasts are responsible for the differences in respective track forecast of the cyclone. The PBL group of experiments has less influence on the track forecast of the cyclone compared to CPS. However, we do note a considerable variation in intensity forecast due to variations in PBL schemes. The MY scheme produced reasonably better forecast within the group with a sustained warm core and better surface wind fields. Finally, results from MPS set of experiments demonstrate that explicit moisture schemes have profound impact on cyclone intensity and moderate impact on cyclone track forecast. The storm produced from WR scheme is the most intensive in the group and closer to the observed strength. The possible reason attributed for this intensification is the combined effect of reduction in cooling tendencies within the storm core due to the absence of melting process and reduction of water loading in the model due to absence of frozen hydrometeors in the WR scheme. We also note a good correlation between evolution of frozen condensate and storm intensification rate among these experiments. It appears that the Sc scheme has some systematic bias and because of that we note a substantial reduction in the rain water formation in the simulated storm when compared to others within the group. In general, it is noted that all the sensitivity experiments have a tendency to unrealistically intensify the storm at the later part of the integration phase.  相似文献   

Solid waste management through multi-criteria decision making: using analytic hierarchy process as an assessment framework for the Hooghly district,West Bengal     

Das  Amit Kumar  Chatterjee  Uday  Mukherjee  Jenia 《GeoJournal》2022,87(4):911-930

Solid waste management (SWM) is a crucial service governed by urban local bodies (ULB). Hence, it is essential to identify challenges and opportunities in the SWM procedures and practices towards improved delivery of services. In this study, analytic hierarchy process (AHP) has been applied in the three sub-divisional towns of the Hooghly district, West Bengal (India), namely Chandannagar, Hooghly-Chinsurah and Serampore to analyze the existing SWM scenario. As AHP is a Multi-Criteria Decision Making tool, hence, it has been deployed by experts to come up with SWM performance index, clearly demonstrating the strengths and weaknesses of management strategies in selected study sites. This article further advances the significance of the AHP method by carving out multi-layered realities through the quantification of qualitative insights across various segments of waste management in the three towns. While interviews with waste management officials led to the formulation of key performance indicators and sub-indicators matrix, the obtained normalized weights brought to the fore the real engagement and actions executed by each of these towns in managing solid wastes. The application of this innovative AHP method ensured accuracy in the ranking system across performance of the specified ULBs. This AHP-induced situational analysis of SWM is not only significant in terms of policy formulation in the ULBs of the Hooghly district but has potentials to work at scales.

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