Comment on “The stability of UO2OH+ and UO2(HPO4)22− complexes at 25°C” by G. Dongarra and D. Langmuir     

Vijay S. Tripathi 《Geochimica et cosmochimica acta》1982,46(10):2001-2004

Equilibrium calculations have shown that all the solutions in the experiments of Dongarra and Langmuir (1980) were super-saturated with respect to uranyl triphosphate; the degree of super-saturation varied from 3 to 857. In spite of the super-saturation, for all of their experiments n? and molal % UO₂(HPO⁴)₂^2? have been found to be <0.5 and <12 respectively. Similarly in all of their experiments 88–98% of ∑U(VI) existed as UO₂²⁺ or hydroxo complexes. Based on the analysis of their data it has been shown that their experimental conditions were not appropriate for determining the stability constant of UO₂(HPO⁴)₂^2?. The significance of careful design of experiments has been demonstrated. The uncertainty in log β (±0.2) as reported by these authors is too small in view of the very small $\text{n}\text{?}$ as well as negligible pH change during titrations. Furthermore, the fact that the β determined by Dongarra and Langmuir is very close to that of Moskvin et al. (1967) certainly does not serve to validate the work of Dongarra and Langmuir, since Dongarra and Langmuir, as well as this writer, have found several problems in the work of Moskvin et al.  相似文献   

Elastic-wave scattering in a random medium characterized by the Von Karman correlation function and small-scale inhomogeneities in the lithosphere     

Jayant N. Tripathi  Avadh Ram 《Geophysical Journal International》1997,131(3):682-698

A Gaussian correlation function characterizes smoothly heterogeneous media, while real heterogeneities in the Earth are often non-Gaussian in nature. Using the Born approximation, mean square amplitudes of the scattered waves have been derived for an elastic media characterized by the Von Karman correlation function. Heterogeneities with different power laws can be defined by the Von Karman correlation function. The sensitivity of fore- and backscattering to heterogeneities with different scales and properties (that is velocity and impedance) is discussed in this paper. The analytical expression for total scattered energy for the incident P waves is also derived for a random medium having the Von Karman correlation function. We find that at high frequencies, the scattered power of converted waves is a function of frequency. In the case of codawave excitation by local earthquakes, which must be handled by the full elastic-wave theory, we can define any type of inhomogeneity by the Von Karman correlation function. It also supports the idea that the lithosphere might have multiple-scale inhomogeneities.  相似文献   

Probabilistic assessment of earthquake recurrence in the January 26, 2001 earthquake region of Gujrat, India     

Jayant Nath Tripathi 《Journal of Seismology》2006,10(1):119-130

Kutch region of Gujrat is one of the most seismic prone regions of India. Recently, it has been rocked by a large earthquake (M _w = 7.7) on January 26, 2001. The probabilities of occurrence of large earthquake (M≥6.0 and M≥5.0) in a specified interval of time for different elapsed times have been estimated on the basis of observed time-intervals between the large earthquakes (M≥6.0 and M≥5.0) using three probabilistic models, namely, Weibull, Gamma and Lognormal. The earthquakes of magnitude ≥5.0 covering about 180 years have been used for this analysis. However, the method of maximum likelihood estimation (MLE) has been applied for computation of earthquake hazard parameters. The mean interval of occurrence of earthquakes and standard deviation are estimated as 20.18 and 8.40 years for M≥5.0 and 36.32 and 12.49 years, for M≥6.0, respectively, for this region. For the earthquakes M≥5.0, the estimated cumulative probability reaches 0.8 after about 27 years for Lognormal and Gamma models and about 28 years for Weibull model while it reaches 0.9 after about 32 years for all the models. However, for the earthquakes M≥6.0, the estimated cumulative probability reaches 0.8 after about 47 years for all the models while it reaches 0.9 after about 53, 54 and 55 years for Weibull, Gamma and Lognormal model, respectively. The conditional probability also reaches about 0.8 to 0.9 for the time period of 28 to 40 years and 50 to 60 years for M≥5.0 and M≥6.0, respectively, for all the models. The probability of occurrence of an earthquake is very high between 28 to 42 years for the magnitudes ≥5.0 and between 47 to 55 years for the magnitudes ≥6.0, respectively, past from the last earthquake (2001).  相似文献   

High resolution simulation of recent Arctic and Antarctic stratospheric chemical ozone loss compared to observations     

Om Prakash Tripathi  Sophie Godin-Beekmann  Franck Lefèvre  Marion Marchand  Andrea Pazmiño  Alain Hauchecorne  Florence Goutail  Hans Schlager  C. Michael Volk  B. Johnson  G. König-Langlo  Stefano Balestri  Fred Stroh  T. P. Bui  H. J. Jost  T. Deshler  Peter von der Gathen 《Journal of Atmospheric Chemistry》2006,55(3):205-226

Simulations of polar ozone losses were performed using the three-dimensional high-resolution (1^∘ × 1^∘) chemical transport model MIMOSA-CHIM. Three Arctic winters 1999–2000, 2001–2002, 2002–2003 and three Antarctic winters 2001, 2002, and 2003 were considered for the study. The cumulative ozone loss in the Arctic winter 2002–2003 reached around 35% at 475 K inside the vortex, as compared to more than 60% in 1999–2000. During 1999–2000, denitrification induces a maximum of about 23% extra ozone loss at 475 K as compared to 17% in 2002–2003. Unlike these two colder Arctic winters, the 2001–2002 Arctic was warmer and did not experience much ozone loss. Sensitivity tests showed that the chosen resolution of 1^∘ × 1^∘ provides a better evaluation of ozone loss at the edge of the polar vortex in high solar zenith angle conditions. The simulation results for ozone, ClO, HNO₃, N₂O, and NO _y for winters 1999–2000 and 2002–2003 were compared with measurements on board ER-2 and Geophysica aircraft respectively. Sensitivity tests showed that increasing heating rates calculated by the model by 50% and doubling the PSC (Polar Stratospheric Clouds) particle density (from 5 × 10⁻³ to 10⁻² cm⁻³) refines the agreement with in situ ozone, N₂O and NO _y levels. In this configuration, simulated ClO levels are increased and are in better agreement with observations in January but are overestimated by about 20% in March. The use of the Burkholder et al. (1990) Cl₂O₂ absorption cross-sections slightly increases further ClO levels especially in high solar zenith angle conditions. Comparisons of the modelled ozone values with ozonesonde measurement in the Antarctic winter 2003 and with Polar Ozone and Aerosol Measurement III (POAM III) measurements in the Antarctic winters 2001 and 2002, shows that the simulations underestimate the ozone loss rate at the end of the ozone destruction period. A slightly better agreement is obtained with the use of Burkholder et al. (1990) Cl₂O₂ absorption cross-sections.  相似文献   

Use of magnetic hysteresis properties and electron spin resonance spectroscopy for the identification of volcanic ash: a preliminary study   总被引：1，自引：0，他引：1  

Archana Pawse  Suzanne Beske-Diehl  & S.A. Marshall 《Geophysical Journal International》1998,132(3):712-720

This initial study investigates the possible use of hysteresis parameters and electron spin resonance (ESR) spectroscopy to identify and correlate volcanic ash. ESR and hysteresis properties are sensitive to characteristics such as the chemical composition, mineralogy, and grain size and shape. These characteristics are determined by the tectonic setting of the volcano and by the magmatic and eruptive history of the volcanic ash. Hysteresis properties and ESR spectra, therefore, should be distinct for each ash eruption and may help to identify the eruptive source of the ash and to correlate ash from unknown sources. We conducted ESR spectroscopy at room temperature and magnetic hysteresis measurements on 19 samples of a single ash, the 1974 October 14 eruption of the Fuego volcano, Guatemala, and on single samples of ash obtained from eight different volcanoes. The Fuego ash samples were obtained at increasing distances from the volcano. For the single Fuego ash, ESR spectra and hysteresis parameters become increasingly similar as the distance from the volcano increases. At distances greater than 30 km, ESR spectra and hysteresis properties are uniform. The variability of magnetic and ESR properties with distance from Fuego is due to the preferential fall-out of phenocrysts closer to the volcano. At large distances, the ash is more uniform, containing more glass and microcrystals. All eight ash samples from the different volcanoes can be distinguished from the distal Fuego 1974 October 14 ash using ESR spectra and hysteresis parameters. These results suggest that ESR and hysteresis measurements have a potential to be used as tools to identify distal ash when used in conjunction with geochemical, mineralogical and/or other types of data.  相似文献   

Palynochronology of Lower Cretaceous volcano-sedimentary succession of the Rajmahal Formation in the Rajmahal Basin, India     

Archana Tripathi   《Cretaceous Research》2008,29(5-6):913

In the Rajmahal Basin Lower Cretaceous rocks are classified under the Rajmahal Formation. It includes a series of volcanic basalt flows and associated sedimentary intertrappean beds. Up to 15 basalt flows have been recorded in this basin. The intertrappean beds comprise sandstone, shale, siltstone, and clay deposits which are rich in spores and pollen. The palynoflora recovered from intertrappean beds shows definite pattern of evolution and diversification. On the basis of its overall composition, distribution pattern of age marker taxa and the First Appearance Datum of key taxa, four palynological assemblages have been identified. The chronology of these assemblages in ascending order is (1) Ruffordiaspora australiensis, (2) Foraminisporis wonthaggiensis, (3) Foraminisporis asymmetricus, and (4) Coptospora verrucosa. These assemblages ascertain the age of the volcano-sedimentary sequence of the Rajmahal Formation in the Rajmahal Basin as Berriasian to Aptian. The palynochronology of the intertrappean beds enables their correlation in the Rajmahal Basin. In different areas of the basin, the palynological dating of the lowermost intertrappean bed within the Rajmahal Formation which overlies the Dubrajpur Formation, has provided a Berriasian to Aptian age. The palynological assemblage indicating the Berriasian age is inferred as the time of the initiation of volcanic activity which continued up to the Aptian in the Rajmahal Basin.  相似文献   

A Probabilistic Assessment of Earthquake Hazard Parameters in NW Himalaya and the Adjoining Regions     

R. B. S. Yadav  Yusuf Bayrak  J. N. Tripathi  S. Chopra  A. P. Singh  Erdem Bayrak 《Pure and Applied Geophysics》2012,169(9):1619-1639

The maximum likelihood estimation method is applied to study the geographical distribution of earthquake hazard parameters and seismicity in 28 seismogenic source zones of NW Himalaya and the adjoining regions. For this purpose, we have prepared a reliable, homogeneous and complete earthquake catalogue during the period 1500–2010. The technique used here allows the data to contain either historical or instrumental era or even a combination of the both. In this study, the earthquake hazard parameters, which include maximum regional magnitude (M _max), mean seismic activity rate (λ), the parameter b (or β?=?b/log e) of Gutenberg–Richter (G–R) frequency-magnitude relationship, the return periods of earthquakes with a certain threshold magnitude along with their probabilities of occurrences have been calculated using only instrumental earthquake data during the period 1900–2010. The uncertainties in magnitude have been also taken into consideration during the calculation of hazard parameters. The earthquake hazard in the whole NW Himalaya region has been calculated in 28 seismogenic source zones delineated on the basis of seismicity level, tectonics and focal mechanism. The annual probability of exceedance of earthquake (activity rate) of certain magnitude is also calculated for all seismogenic source zones. The obtained earthquake hazard parameters were geographically distributed in all 28 seismogenic source zones to analyze the spatial variation of localized seismicity parameters. It is observed that seismic hazard level is high in Quetta-Kirthar-Sulaiman region in Pakistan, Hindukush-Pamir Himalaya region and Uttarkashi-Chamoli region in Himalayan Frontal Thrust belt. The source zones that are expected to have maximum regional magnitude (M _max) of more than 8.0 are Quetta, southern Pamir, Caucasus and Kashmir-Himanchal Pradesh which have experienced such magnitude of earthquakes in the past. It is observed that seismic hazard level varies spatially from one zone to another which suggests that the examined regions have high crustal heterogeneity and seismotectonic complexity.  相似文献   

Probabilistic Assessment of Earthquake Hazard in Gujarat and Adjoining Region of India     

Ram Bichar Singh Yadav  Jayant Nath Tripathi  Bal Krishna Rastogi  Sumer Chopra 《Pure and Applied Geophysics》2008,165(9-10):1813-1833

The Gujarat and adjoining region falls under all four seismic zones V, IV, III and II of the seismic zoning map of India, and is one of the most seismically prone intracontinental regions of the world. It has experienced two large earthquakes of magnitude M _w 7.8 and 7.7 in 1819 and 2001, respectively and several moderate earthquakes during the past two centuries. In the present study, the probability of occurrence of earthquakes of M ≥ 5.0 has been estimated during a specified time interval for different elapsed times on the basis of observed time intervals between earthquakes using three stochastic models namely, Weibull, Gamma and Lognormal. A complete earthquake catalogue has been used covering the time interval of 1819 to 2006. The whole region has been divided into three major seismic regions (Saurashtra, Mainland Gujarat and Kachchh) on the basis of seismotectonics and geomorphology of the region. The earthquake hazard parameters have been estimated using the method of maximum likelihood. The logarithmic of likelihood function (ln L) is estimated and used to test the suitability of models in three different regions. It was found that the Weibull model fits well with the actual data in Saurashtra and Kachchh regions, whereas Lognormal model fits well in Mainland Gujarat. The mean intervals of occurrence of earthquakes are estimated as 40.455, 20.249 and 13.338 years in the Saurashtra, Mainland Gujarat and Kachchh region, respectively. The estimated cumulative probability (probability that the next earthquake will occur at a time later than some specific time from the last earthquake) for the earthquakes of M ≥ 5.0 reaches 0.9 after about 64 years from the last earthquake (1993) in Saurashtra, about 49 years from the last earthquake (1969) in Mainland Gujarat and about 29 years from the last earthquake (2006) in the Kachchh region. The conditional probability (probability that the next earthquake will occur during some specific time interval after a certain elapsed time from last earthquake) is also estimated and it reaches about 0.8 to 0.9 during the time interval of about 57 to 66 years from the last earthquake (1993) in Saurashtra region, 31 to 51 years from the last earthquake (1969) in Mainland Gujarat and about 21 to 28 years from the last earthquake (2006) in Kachchh region.  相似文献   

Rotational circulation-preserving magnetogeostrophic flows     

H. P. Singh  D. D. Tripathi  R. B. Mishra 《Astrophysics and Space Science》1987,138(2):315-321

It has been shown that the only steady, inviscid, magnetogeostrophic rotational circulation-preverving motion whose magnetic field line pattern is that of the irrotational motion is a complex-lamellar motion whose magnetic field magnitude bears a constant value on a magnetic field line.  相似文献   

Intrinsic and scattering attenuation in western India from aftershocks of the 26 January, 2001 Kachchh earthquake   总被引：1，自引：0，他引：1  

A. Ugalde  J.N. Tripathi  M. Hoshiba  B.K. Rastogi   《Tectonophysics》2007,429(1-2):111-123

176 vertical-component, short period observations from aftershocks of the M_w 7.7, 26 January, 2001 Kachchh earthquake are used to estimate seismic wave attenuation in western India using uniform and two layer models. The magnitudes (M_w) of the earthquakes are less than 4.5, with depths less than 46 km and hypocentral distances up to 110 km. The studied frequencies are between 1 and 30 Hz. Two seismic wave attenuation factors, intrinsic absorption (Q_i^− 1) and scattering attenuation (Q_s^− 1) are estimated using the Multiple Lapse Time Window method which compares time integrated seismic wave energies with synthetic coda wave envelopes for a multiple isotropic scattering model. We first assume spatial uniformity of Q_i^− 1, Q_s^− 1 and S wave velocity (β). A second approach extends the multiple scattering hypothesis to media consisting of several layers characterized by vertically varying scattering coefficient (g), intrinsic absorption strength (h), density of the media (ρ) and shear wave velocity structure. The predicted coda envelopes are computed using Monte Carlo simulation. Results show that, under the assumption of spatial uniformity, scattering attenuation is greater than intrinsic absorption only for the lowest frequency band (1 to 2 Hz), whereas intrinsic absorption is predominant in the attenuation process at higher frequencies (2 to 30 Hz). The values of Q obtained range from Q_t = 118, Q_i = 246 and Q_s = 227 at 1.5 Hz to Q_t ≈ 4000, Q_i ≈ 4600 and Q_s ≈ 33,300 at 28 Hz center frequencies, being Q_t^− 1 a measure of total attenuation. Results also show that Q_i^− 1, Q_s^− 1 and Q_t^− 1 decrease proportional to f^−ν. Two rates of decay are clearly observed for the low (1 to 6 Hz) and high (6 to 30 Hz) frequency ranges. Values of ν are estimated as 2.07 ± 0.05 and 0.44 ± 0.09 for total attenuation, 1.52 ± 0.21 and 0.48 ± 0.09 for intrinsic absorption and 3.63 ± 0.07 and 0.06 ± 0.08 for scattering attenuation for the low and high frequency ranges, respectively. Despite the lower resolution in deriving the attenuation parameters for a two layered crust, we find that scattering attenuation is comparable to or smaller than the intrinsic absorption in the crust whereas intrinsic absorption dominates in the mantle. Also, for a crustal layer of thickness 42 km, intrinsic absorption and scattering estimates in the crust are lower and greater than those of the mantle, respectively.  相似文献