Determination of part-per-trillion levels of atmospheric dimethyl sulfide by isotope dilution gas chromatography/mass spectrometry     

Donald C. Thornton  Alan R. Bandy  Robert G. Ridgeway  Arthur R. Driedger III  Marija Lalevic 《Journal of Atmospheric Chemistry》1990,11(4):299-308

Stable isotopic dilution was applied to the determination of dimethyl sulfide (DMS) in ambient air at the low part-per-trillion by volume (pptrv) levels. Perdeuterated DMS was used as an internal standard in the gas chromatography/mass spectrometry determination. The isotopically labelled internal standard provided insensitivity to possible losses of DMS in sampling and analysis. The lower limit of detection (LLD) was 1 pptrv with a sample acquisition time of 2 min.  相似文献   

Factors influencing the stability of smectite sealants     

Arthur G. Clem 《Engineering Geology》1985,21(3-4):273-278

Smectite is a mineral, but a mineral with distinct chemical properties. Structural changes in minerals may require millions of years of aging to complete, but a chemical reaction may be completed in only 4 to 5 min.

Some of the problems of smectite seals are described in this paper, together with methods of avoiding these hazards.  相似文献   

Pressure-temperature conditions in the Wadi Kid metamorphic complex: Implications for the pan-african event in SE Sinai     

Arthur P. S. Reymer  Alan Matthews  Oded Navon 《Contributions to Mineralogy and Petrology》1984,85(4):336-345

Geothermobarometry using continuous equilibria in pelitic rocks of the central and northeastern Wadi Kid areas, Sinai, yields pressure estimates of 320 MPa (3.2 kbar) and temperature estimates of 565° C and >620° C for staurolite-andalusite zone assemblages and anatectic rocks, respectively. This corresponds to geothermal gradients of 47° C/km and 50° C/km. TheseP-T conditions are shown to be compatible with burial under a volcanic cover. The principal heat source for high-grade metamorphism and anatexis is thought to be rising magmatic diapirs. Uplift was relatively slow and the final stages of heating and early stages of cooling probably occurred isobarically. The data imply a high heat flow regime for the Pan-African event in Sinai.  相似文献   

Boundary skin friction and sediment transport about an animal-tube mimic   总被引：6，自引：0，他引：6  

James E.  Eckman†Arthur R. M.  Nowell‡ 《Sedimentology》1984,31(6):851-862

ABSTRACT
A flume study was made of fluid flow, boundary skin friction, and sediment transport about an animal-tube mimic. The effect of a tube on momentum transfer depends most strongly on its height. A tube increases the net boundary skin friction locally and tends to promote sediment entrainment near its base. Flow in this region appears to be governed by the same similarity laws that apply to cylinders with much larger body Reynolds number. Particles travelling as suspended load may be deposited immediately downstream of the tube. The net sedimentological effect of any tube (i.e. deposition or scour) will depend both on its height and on the boundary shear stress imposed by the external flow. The near-wake region of a tube is dominated by a strong cross-stream exchange of momentum. Wake perturbations decay downstream seemingly in accordance with similarity laws which also govern mounted, two-dimensional structures.  相似文献   

Distribution and mode of occurrence of zinc and lead in glacial soils     

David R. Cole  Arthur W. Rose 《Journal of Geochemical Exploration》1984,20(2):137-160

The distribution and mode of occurrence of zinc and lead have been examined in glacial soils developed over a complex Precambrian marble-paragneiss terrain in the Adirondack Mountains of New York. Based on distribution within the soil profiles, zinc is enriched in the B₁ horizon of soils sampled over marble and lead is generally enriched in the A horizon, particularly in soils developed over paragneiss. Contrast is calculated using , where is the mean of n_A anomalous and n_B background samples, and S_p is the pooled standard deviation) for zinc, lead and cold-extractable heavy metals in soils sampled over marble and paragneiss. The t-values indicate that the B₁, soil horizon is the most suitable for sampling on a regular basis, even though lead is most concentrated in the A horizon.The distribution of zinc and lead among exchangeable, organic, iron-manganese oxide, clay, silt and sand fractions of B₁ horizons from two anomalous and one background soil indicates that both zinc and lead are tied up principally in iron and manganese oxides. The anomalous samples exhibit zinc enrichment in the Fe-oxide digestion and high Mn/Fe ratios for the Mn-oxide digestion (as well as the total analysis). In terms of total contribution to the sample, significant proportions of zinc in the clastic fraction can be attributed to zinc substitution into clays plus the ineffective removal of Fe-oxides by the ammonium oxalate extraction procedure. Lead, on the other hand, occurs in significant concentrations in clay, silt and sand as well as Fe- and Mn-oxides, probably as a trace constituent in feldspars or adsorbed onto clay surfaces.  相似文献   

Uranium geochemistry in groundwater from tertiary sediments     

Roy F. Spalding  A.Douglas Druliner  Lowell S. Whiteside  Arthur W. Struempler 《Geochimica et cosmochimica acta》1984,48(12):2679-2692

Dissolved U concentrations and activity ratios (ARs) of the U isotopes in the ²³⁸U decay series were measured in ground and surface waters as part of an investigation to delineate the water quality in a proposed uranium mining area of northwest Nebraska. In oxidizing groundwaters from 67 wells completed in the Tertiary sediments, increasing U concentrations in the direction of groundwater flow generally were associated with a maturation of the formation water as evidenced by evolutionary trends in major ion character. The increased U levels probably are associated with leaching as shown by the positive correlation between U concentrations and total dissolved solids (TDS) (r = +0.83). The inverse relationships between TDS and U ARs (r = ?0.73) and U levels and ARs (r = 0.72) indicate that the decay of excess U-234 is related to maturation of the formation water and to sediment leaching along the flowpath. The data are described by a model which incorporates etching, decay and recoil and suggests that aquifer residence time can be estimated from the TDS level.The levels of soluble U in a reducing uraniferous hydrogeologic unit near Crawford, Nebraska are affected by the proximity of the sample collection to ore. In groundwater samples having similar chemistries (Na-SO₄ + Cl type), similar Ehs, and collected from a close-knit pattern, U concentrations ranged from 0.01 to 2,037 μg l^?1 and ARs ranged from 0.75 to 12.6. This high variability in U levels and ARs is indicative of uranium ore in small areal studies where low ARs almost always are associated with high U concentrations.  相似文献   

Occurrence and distribution of sulfur in peat-forming environments of southern Florida     

Arthur D. Cohen  William Spackman  Philip Dolsen 《International Journal of Coal Geology》1984,4(1):73-96

Cores and surface samples of peats from the Everglades—Mangrove region of Southern Florida were analyzed for total sulfur and pyritic sulfur. These values were compared with the petrographic-botanical components of the peats as determined from point-counts of oriented microtome sections. Pyrite occurs as individual euhedral crystals, loosely packed framboids, and lenses or crusts of minute crystals. Framboids and minute crystals are often associated with organic matter and sometimes with bacteria and fungi. Pyrite tends to selectively occur in void spaces in or between peat tissues. In samples containing very small amounts of pyrite, framboidal pyrite is the prevalent form.Marine to brackish peats contain the highest pyrite and total sulfur contents, with brackish peats generally containing more pyrite than marine peats. Pyrite tends to be lower in all peats within 30 cm of the surface, whether marine or brackish.Burial of freshwater peats beneath marine or brackish peats tends to increase the total sulfur and pyritic sulfur in the underlying peats. Burial beneath brackish-water, clay-rich deposits (such as splays) tends to increase total sulfur and pyritic sulfur in the underlying deposits more than burial beneath less clay-rich deposits.  相似文献   

Local member response in offshore structures under earthquake excitations     

Stavros A. Anagnostopoulos  Arthur R. Culbertson 《地震工程与结构动力学》1982,10(3):349-358

It is pointed out that local vibrations of certain members in earthquake excited offshore structures can induce substantial stresses that may often dominate the design of these members. Such vibrations are not accounted for in dynamic analyses of structural models with masses lumped at the joints. A practical, easy to implement solution to this problem is recommended and results from an actual structure, subjected to a three-component real earthquake, are presented demonstrating the importance of local inertia effects.  相似文献   

Handbook of exploration geochemistry. volume 1: analytical methods in geochemical prospecting: W. K. Fletcher,Elsevier, 1981, 256 pp, $59.50     

Arthur W. Rose 《Geochimica et cosmochimica acta》1982,46(5):834-835

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ORGANIC COMPOUNDS AND GROUND-WATER POLLUTION     

Wayne A. Pettyjohn  Arthur W. Hounslow 《Ground Water Monitoring & Remediation》1983,3(4):41-47

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