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541.
Presence of springs in karst terranes provides a unique opportunity to study the rather complex, multi-porosity, and multi-permeability system. When springs are used to evaluate the integrity of storage facilities for hazardous materials or waste disposal facilities constructed in karst areas, the spatial heterogeneity of karst aquifers makes intra-spring comparisons preferred statistical tests. One of the commonly used statistical tests is water quality control procedure such as Shewhart-CUSUM control charts. Appropriate application of the water quality control procedure to intra-spring monitoring depends on whether the assumptions can be justified about the aquifer that drains to the spring and the dataset collected at the spring. Violation of the assumptions would render the statistical tests invalid, which may result in a failure of the groundwater monitoring program. In intra-spring monitoring, it is the temporal variations of water quality at a karst spring need to be addressed, whereas the water quality at the spring is closely associated with the characteristics of the aquifer. The example datasets presented in the paper indicate that both false negative and false positive detections can occur if the temporal variation is not well characterized.  相似文献   
542.
Energetic materials contamination was investigated at the former Explosives Factory Maribyrnong, Victoria, Australia. Spectrophotometric/high performance liquid chromatography (HPLC) analysis was utilised to delineate a 5 tonne crystalline 2,4,6-trinitrotoluene (TNT) source in a former process waste lagoon that was found to be supplying contaminant leachate to the surficial clay aquitard with a maximum-recorded concentration of 7.0 ppm TNT. Groundwater within underlying sand and gravel aquifers was found to be uncontaminated due to upward hydraulic gradients resulting in slow plume development and propagation. Adsorption and microcosm test results from a parallel study were used as input parameters to simulate aqueous TNT transport in the clay aquitard using ATRANS20 software. The simulated TNT plume was localised within a few metres of the source, and at steady state, though leaching rate calculations suggest that without mitigation or other changes to the system, persistence of the source would be approximately 2,000 years. Remediation strategies may involve removal of the near surface source zone and infilling with an impermeable capping to impede leaching while facilitating ongoing natural attenuation by anaerobic degradation.  相似文献   
543.
544.
The US Army ERDC CRREL and the US Department of Agriculture Natural Resources Conservation Service developed a square electronic snow water equivalent (e‐SWE) sensor as an alternative to using fluid‐filled snow pillows to measure SWE. The sensors consist of a centre panel to measure SWE and eight outer panels to buffer edge stress concentrations. Seven 3 m square e‐SWE sensors were installed in five different climate zones. During the 2011–2012 winter, 1.8 and 1.2 m square e‐SWE sensors were installed and operated in Oregon. With the exception of New York State and Newfoundland, the e‐SWE sensors accurately measured SWE, with R2 values between the sensor and manual SWE measurements of between 0.86 and 0.98. The e‐SWE sensor at Hogg Pass, Oregon, accurately measured SWE during the past 8 years of operations. In the thin, icy snow of New York during midwinter 2008–2009, the e‐SWE sensors overmeasured SWE because of edge stress concentrations associated with strong icy layers and a shallow snow cover. The New York e‐SWE sensors' measurement accuracy improved in spring 2009 and further improved during the 2011–2012 winter with operating experience. At Santiam Junction, measured SWE from the 1.8 and 1.2 m square e‐SWE sensors agreed well with the snow pillow, 3 m square e‐SWE sensor, and manual SWE measurements until February 2013, when dust and gravel blew onto the testing area resulting in anomalous measurements. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.  相似文献   
545.
Since the 1970s, there has been both continuing and growing interest in developing accurate estimates of the annual fluvial transport (fluxes and loads) of suspended sediment and sediment‐associated chemical constituents. This study provides an evaluation of the effects of manual sample numbers (from 4 to 12 year?1) and sample scheduling (random‐based, calendar‐based and hydrology‐based) on the precision, bias and accuracy of annual suspended sediment flux estimates. The evaluation is based on data from selected US Geological Survey daily suspended sediment stations in the USA and covers basins ranging in area from just over 900 km2 to nearly 2 million km2 and annual suspended sediment fluxes ranging from about 4 Kt year?1 to about 200 Mt year?1. The results appear to indicate that there is a scale effect for random‐based and calendar‐based sampling schemes, with larger sample numbers required as basin size decreases. All the sampling schemes evaluated display some level of positive (overestimates) or negative (underestimates) bias. The study further indicates that hydrology‐based sampling schemes are likely to generate the most accurate annual suspended sediment flux estimates with the fewest number of samples, regardless of basin size. This type of scheme seems most appropriate when the determination of suspended sediment concentrations, sediment‐associated chemical concentrations, annual suspended sediment and annual suspended sediment‐associated chemical fluxes only represent a few of the parameters of interest in multidisciplinary, multiparameter monitoring programmes. The results are just as applicable to the calibration of autosamplers/suspended sediment surrogates currently used to measure/estimate suspended sediment concentrations and ultimately, annual suspended sediment fluxes, because manual samples are required to adjust the sample data/measurements generated by these techniques so that they provide depth‐integrated and cross‐sectionally representative data. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.  相似文献   
546.
547.
A consistent time series of synoptic and high-frequency bathymetric observations is fundamental to improving our understanding and predictive capabilities regarding the morphological behavior of large coastal inlets. Based on satellite observations, an original approach is proposed to characterize the long-term morphological evolution of the Arcachon lagoon inlet and to describe sediment bypassing and breaching mechanisms. The almost 26-year-long remotely sensed data archive used in this study is built from 78 suitable SPOT images (1986–2012) collected in the framework of the KALIDEOS-Littoral program. Bathymetric information is derived from satellite data using a physics-based model. A validation exercise performed on a large bathymetric survey data set (N?=?43,949) demonstrates that the inversion model performs excellently in estimating the depth of mildly to moderately turbid shallow waters. The performance of the model suggests that the minimum requirements are fulfilled to apply the SPOT-derived bathymetry to morphodynamic applications. We demonstrate that high-spatial-resolution multispectral sensors are well adapted to analyzing the morphological evolution of small- (i.e., sand dunes), medium- (i.e., sandbanks and channels), and large- (i.e., the entire inlet-lagoon system) scale sedimentary structures present in coastal inlets. For the first time, the long-term evolution of a flood and ebb-tidal delta is characterized by observations at a seasonal timescale. Finally, migration rates of sedimentary entities are quantified, and fundamental mechanisms driving the sediment transport cross the inlet are confirmed.  相似文献   
548.
Seismic source characteristics of low-yield (0.5–5 kt) underground explosions are inferred from hydrodynamic simulations using a granite material model on high-performance (parallel) computers. We use a non-linear rheological model for granite calibrated to historical near-field nuclear test data. Equivalent elastic P-wave source spectra are derived from the simulated hydrodynamic response using reduced velocity potentials. Source spectra and parameters are compared with the models of Mueller and Murphy (Bull Seism Soc Am 61:1675–1692, 1971, hereafter MM71) and Denny and Johnson (Explosion source phenomenology, pp 1–24, 1991, hereafter DJ91). The source spectra inferred from the simulations of different yields at normal scaled depth-of-burial (SDOB) match the MM71 spectra reasonably well. For normally buried nuclear explosions, seismic moments are larger for the hydrodynamic simulations than MM71 (by 25 %) and for DJ91 (by over a factor of 2), however, the scaling of moment with yield across this low-yield range is consistent for our calculations and the two models. Spectra from our simulations show higher corner frequencies at the lower end of the 0.5–5.0 kt yield range and stronger variation with yield than the MM71 and DJ91 models predict. The spectra from our simulations have additional energy above the corner frequency, probably related to non-linear near-source effects, but at high frequencies the spectral slopes agree with the f ?2 predictions of MM71. Simulations of nuclear explosions for a range of SDOB from 0.5 to 3.9 show stronger variations in the seismic moment than predicted by the MM71 and DJ91 models. Chemical explosions are found to generate higher moments by a factor of about two compared to nuclear explosions of the same yield in granite and at normal depth-of-burial, broadly consistent with comparisons of nuclear and chemical shots at the US Nevada Test Site (Denny, Proceeding of symposium on the non-proliferation experiment, Rockville, Maryland, 1994). For all buried explosions, the region of permanent deformation and material damage is not spherical but extends along the free surface above and away from the source. The effect of damage induced by a normally buried nuclear explosion on seismic radiation is explored by comparing the motions from hydrodynamic simulations with those for point-source elastic Green’s functions. Results show that radiation emerging at downward takeoff angles appears to be dominated by the expected isotropic source contribution, while at shallower angles the motions are complicated by near-surface damage and cannot be represented with the addition of a simple secondary compensated linear vector dipole point source above the shot point. The agreement and differences of simulated source spectra with the MM71 and DJ91 models motivates the use of numerical simulations to understand observed motions and investigate seismic source features for underground explosions in various emplacement media and conditions, including non-linear rheological effects such as material strength and porosity.  相似文献   
549.
We study the effect of quasar feedback on distributions of baryons in galaxy groups using high-resolution numerical simulations. We use the entropy-conserving gadget code that includes gas cooling and star formation, modified to include a physically based model of quasar feedback. For a sample of 10 galaxy group-sized dark matter haloes with masses in the range of  1–5 × 1013 M  h −1  , star formation is suppressed by more than 50 per cent in the inner regions due to the additional pressure support by quasar feedback, while gas is driven from the inner region towards the outer region of the haloes. As a result, the average gas density is 50 per cent lower in the inner region and 10 per cent higher in the outer region in the simulation, compared to a similar simulation with no quasar feedback. Gas pressure is also higher in the outer region, while temperature and entropy are enhanced in the inner region. The total group gas fraction in the two simulations generally differs by less than 10 per cent. We also find a small change of the total thermal Sunyaev–Zeldovich distortion, leading to 10 per cent changes in the microwave angular power spectrum at angular scales below 2 arcmin.  相似文献   
550.
Due to anthropogenic activities, the nutrient loadings of the Changjiang (Yangtze River) are strickly on the rise. The high nutrient concentrations notwithstanding, river water was pCO2 supersaturated in the inner estuary during summer 2003 but decreased quickly in the mid-estuary due to mixing with low pCO2 waters from offshore. In addition, settling of particles in the estuary resulted in better light conditions so that phytoplankton bloomed, driving down pCO2 to ∼200 μatm. In the outer estuary and outside of the bloom area, pCO2 increased again to near or just below saturation. Literature data also reveal that the mainstream of the Changjiang is always supersaturated with respect to CO2 probably because the decomposition of terrestrial organic matter overwhelms the consumption of CO2 due to biological production.  相似文献   
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