Geochemical modelling, ionic ratio and GIS based mapping of groundwater salinity and assessment of governing processes in Northern Gujarat, India   总被引：1，自引：0，他引：1  

Kumari Rina  Chander Kumar Singh  P. S. Datta  Neha Singh  S. Mukherjee 《Environmental Earth Sciences》2013,69(7):2377-2391

In semi-arid/arid regions, groundwater is the major source of irrigation, drinking and industrial requirements, water salinity and shortage are major problems of concern. North Gujarat, India, is one such area where highly saline groundwater is generally ascribed to rapid increase of population, agriculture and industries induced decline in water table by unplanned abstraction of groundwater. However, no effort has been made to discriminate the natural and anthropogenic influences on groundwater salinity. In this brief background, the present study attempts to identify the factors and processes controlling the groundwater salinity in the area, based on ionic ratios in integration with various graphical methods, saturation indices and geographical information system. Na⁺/Ca²⁺ > 1 indicates the deficiency of Ca²⁺ possibly due to CaCO₃ precipitation or ion exchange process. Na⁺/Cl^? > 1 and $ {\text{SO}}_{4}{}^{2 - } /{\text{Cl}}^{ - } \gg 0.05 $ suggest salinization is mainly due to wastewater infiltration and/or due to irrigation water return flow. Sea water intrusion in coastal parts, vertical and lateral mixing of water and anthropogenic inputs are also responsible for salinization of groundwater. USSL diagram, Na%, sodium adsorption ratio, residual sodium carbonate and magnesium hazard indicate unsuitability of groundwater for irrigation purposes. To prevent groundwater salinization, appropriate measures need to be taken to control further indiscriminate exploitation of groundwater for irrigation.  相似文献   

Reproducing the Piper trilinear diagram in rectangular coordinates     

Ray RK  Mukherjee R 《Ground water》2008,46(6):893-896

Though several alternatives/modifications to the Piper diagram are available, the Piper diagram is still the most common way of representing chemical analyses. The present note shows how to reproduce the Piper trilinear diagram in rectangular coordinates retaining all the essential features of the trilinear diagram. In this form, it can be generated using commonly used graphics packages without requiring specialized software. A sample data set of six samples from Gurur watershed, Chhattisgarh, India, was used to illustrate the method. The patterns of points produced in the trilinear Piper diagram and the reproduced Piper diagram in rectangular coordinates are essentially identical.  相似文献   

Groundwater discharge along a channelized Coastal Plain stream   总被引：1，自引：1，他引：0  

Danita M. LaSage  Joshua L. Sexton  Abhijit Mukherjee  Alan E. Fryar  Stephen F. Greb 《Journal of Hydrology》2008,360(1-4):252-264

In the Coastal Plain of the southeastern USA, streams have commonly been artificially channelized for flood control and agricultural drainage. However, groundwater discharge along such streams has received relatively little attention. Using a combination of stream- and spring-flow measurements, spring temperature measurements, temperature profiling along the stream-bed, and geologic mapping, we delineated zones of diffuse and focused discharge along Little Bayou Creek, a channelized, first-order perennial stream in western Kentucky. Seasonal variability in groundwater discharge mimics hydraulic-head fluctuations in a nearby monitoring well and spring-discharge fluctuations elsewhere in the region, and is likely to reflect seasonal variability in recharge. Diffuse discharge occurs where the stream is incised into the semi-confined regional gravel aquifer, which is comprised of the Mounds Gravel. Focused discharge occurs upstream where the channel appears to have intersected preferential pathways within the confining unit. Seasonal fluctuations in discharge from individual springs are repressed where piping results in bank collapse. Thereby, focused discharge can contribute to the morphological evolution of the stream channel.  相似文献   

Geometry and kinematics of brittle deformation in the Central Cameroon Shear Zone (Kékem area): Implication for gold exploration within the Central Africa Fold Belt in Cameroon     

De Pesquidoux I Tchaptchet Tchato  Jacqueline Tchakounte  Aurélie Ngamy Kamwa  Jean Pierre Tchouankoue  Soumyajit Mukherjee 《China Geology》2021,4(2):245-255

The Central Africa Fold Belt (CAFB) is a collision belt endowed with gold deposits in Eastern Cameroon area mined for about 50 years. However, favorable areas for gold exploration are poorly known. This paper presents (1) the kinematics of the brittle deformation in the Kékem area in the SW portion of the Central Cameroon Shear Zone and (2) constraints gold mineralization events with respect to the collisional evolution of the CAFB. The authors interpret that the conjugate ENE to E and NNW to NW trending lineament corresponds to the synthetic (R) and the antithetic (R’) shears, which accompanied the dextral slip along the NE to ENE striking shear. The latter coincides with the last 570–552 Ma D₃ dextral simple shear-dominated transpression, which is parallel to the Bétaré Oya shear zone hosting gold deposits. Gold mineralizations, which mainly occurred during the last dextral shearing, are disseminated within quartz veins associated to Riedel’s previous structures reactivated due to late collisional activities of the CAFB as brittle deformation. Gold mineralizations occurred mainly during the 570–552 Ma D₃ event. The reactivation, which might be due to dextral simple shear during mylonitzation, plausibly remobilized the early gold deposits hosted in syn-compressional rocks and/or possibly focused deep-sourced fluid mixed with those released by dehydration. Therefore, the Central Cameroon Shear Zone where Kékem is located, and which shows similar petrographical and structural features to those controling Batouri gold district, is a target area for gold exploration in Cameroon.  相似文献   

Insignificant impact of freezing and compaction on iron solubility in natural snow     

Pami Mukherjee  Mihaela Glamoclija  Yuan Gao 《Journal of Atmospheric Chemistry》2018,75(3):247-270

To explore the freezing effect on iron (Fe) solubility in natural environments, especially in Polar regions, event based freshly fallen snow samples were collected at Newark, New Jersey on the US East Coast for two consecutive winter seasons (2014–2015 and 2015–2016). These samples were analyzed for the concentrations of soluble iron (Fe_sol) using UV-Vis Spectroscopy and filterable iron (Fe_fil) and total iron (Fe_tot) using Atomic Absorption Spectroscopy. The average fractional solubility of the Fe_sol (the portion that passes through a 0.22 μm pore-size filter) with respect to the total Fe in the samples was 23.3?±?12.2%, with the majority of the soluble Fe being present as Fe(III). Approximately 48.5% of the total Fe existed as Fe_fil (the portion that passes through 0.45 μm pore size filter media). No significant correlation was found between the soluble ionic species and soluble Fe. Six snow events were kept frozen for 10 days, and analyzed in periodic intervals to study the post-freezing modification in Fe solubility. Events 1 and 2 showed increasing trend in the soluble Fe concentrations; however, the events 5, 6, 7, and 8 showed no noticeable increments. The pattern shown in Events 1 and 2 is associated with high fraction of Fe_fil and one unit pH drop, suggesting that the freeze-induced modification in Fe solubility could be linked with the amount of Fe_fil and the acidity change in the samples. To further investigate the freeze-induced compaction of particles, samples from three events 6, 7, and 10 were analyzed by SEM-STEM-EDS microscopy, and the results showed that due to freezing, in general, the particles in the ice-melt counterparts tend to compact and cluster and form larger aggregates compared to the particles in snow-melt. These results show, despite the freeze-induced compaction in snow was observed from STEM images, the snow freezing might not have significant effect in increasing Fe solubility from materials in the snow. These results further suggest that freezing process with fresh snow in high-latitude regions may not impose significant modification on Fe solubility in snow.  相似文献   

Urban land-use suitability analysis — A case study of Calcutta Metropolitan Area     

S K Pathan  P Jothimani  Gopal K Choudhary  N N Som  Kalyan Mukherjee 《Journal of the Indian Society of Remote Sensing》1992,20(2-3):73-84

Urban land-use zoning analysis has been carried out to evaluate the suitability of land for urbanisation i.e. a process of assessing the fitness of different land characteristics (soils, physiography, slope, land use etc.) for urban development in Calcutta Metropolitan Development Authority (CMDA) area (1350 sq. km). Remote sensing data in conjunction with Survey of India maps and ancillary data have been employed for the analysis. A GIS-based methodology has been developed for the integration of different physical parameters and generation of urban land development units. In all 82 Urban Land Development Units (ULDUs) were delineated and evaluated with respect to physical constraints and the degree to which each class could limit the development for urban purpose. These ULDUs are categorised into five suitability classes for urban use. The relationships between ULDU classes, suitabilities and urban land development considerations in a generalised form have also been assessed. It has been observed that the physical constraints have become progressively greater from class-I to class-V meaning thereby that the cost for the developing the area for urban purpose increases from class-I and becomes uneconomic for class-V. The suitability map prepared using this methodology would also serve as a sub-set for the preparation of a Master plan of the city.  相似文献   

The origin of chloritoid – 3‐mica pseudomorph growth in staurolite–muscovite schist,Bangriposi (Eastern India)          下载免费PDF全文

N. Prabhakar  A. Bhattacharya  P. K. Mukherjee 《Journal of Metamorphic Geology》2016,34(5):463-482

At Bangriposi, variable stages in replacement of staurolite by chloritoid – Na–K–Ca mica shimmer aggregates in muscovite schists provides insight into the complex interplay between fluid flow, mass transfer, and dissolution–precipitation during pseudomorph growth. Idioblastic chloritoid growing into mica caps without causing visible deformation, and monomineralic chloritoid veins (up to 300 μm wide) within shimmer aggregates replacing staurolite attest to chloritoid nucleation in fluid‐filled conduits along staurolite grain boundaries and crystallographic planes. The growth of shimmer aggregates initiated along staurolite margins, and advanced inwards into decomposing staurolite along networks of crystallographically controlled fluid‐filled conduits. Coalescence among alteration zones adjacent to channel fills led to dismemberment and the eventual demise of staurolite. Mass balance calculation within a volume‐fixed, silica‐conserved reference frame indicate the shimmer aggregates grew via precipitation from fluids in response to mass transport that led to the addition of H₂O, K₂O, Na₂O and CaO in the reaction zone, and Al₂O₃ was transported outward from the inward‐retreating margin of decomposing staurolite. This aided precipitation of chloritoid in veins and in the outer collars, and as disseminated grains in the shimmer aggregates at mid‐crustal condition (~520 ± 20 °C, 5.5 ± 2.0 kbar). Computation using one‐dimensional transport equation suggests that staurolite decomposition involved advection dominating over diffusive transport; the permeation of externally derived H₂O caused flattening of chemical potential gradients in H₂O and aqueous species, for example, and , computed using the Gibbs method. This suggests that staurolite decomposition was promoted by the infiltration of a large volume of H₂O that flattened existing chemical potential gradients. In the initial stages of replacement, chloritoid super‐saturation in fluid caused preferential nucleation and growth of chloritoid at staurolite grain boundaries and in crystallographic planes. As reaction progressed, further chloritoid nucleation was halted, but chloritoid continued to grow as the 3‐mica aggregates continued to replace the remaining staurolite in situ, while the chloritoid‐compatible elements were transported in the water‐rich phase facilitating continued growth of the existing chloritoid grains.  相似文献   

Evaluation of shale gas reservoir in Barakar and barren measures formations of north and south Karanpura Coalfields,Jharkhand     

V. A. Mendhe  Alka D. Kamble  Mollika Bannerjee  Subhashree Mishra  Sabita Mukherjee  Parashar Mishra 《Journal of the Geological Society of India》2016,88(3):305-316

India recognizes the strategic importance for developing shale gas resources like other countries in the world. Shale gas reservoirs are known to be difficult for extracting gas in comparison to conventional reservoirs. Recently, due to high prices of gas, rising demand and enhancement in recovery technologies has attracted the Indian energy industries to explore the shale gas resource. Coal and lignite are the prime source of energy in India and these resources are well explored, while shale is ignored, despite it being associated with coal and lignite bearing formations. The paper presents reservoir characteristics of shale horizons in Barren Measures and Barakar formations of north and south Karanpura coalfields. Shale core samples were collected from exploratory boreholes in air tight canisters. In-situ gas content and adsorption capacities ascertained to be 0.51–1.69 m³/t and 3.90–5.82 m³/trespectively. Desorbed gas derived from canisters contains CH₄, C₂H₆, C₃H₈, CO₂, N₂ and O₂ and varies from 76.19–82.63, 0.38–0.76, 0.10–0.50, 8.65–12.34, 9.89–19.34 and 0.56–2.24 vol. % respectively. The permeability and porosity determined under reservoir simulated confining pressure is varying from 0.41–0.75 mD and 0.89–2.28 % respectively. The plots of Rock Eval S₂vs TOC and HI against Calc. VRo% indicates that all shale samples belong to Type III kerogen, which is prone to generate gas. It is evaluated that insitu gas content, sorption capacity, saturation level and low permeability of shale beds are critical parameters for development of shale gas resource in the studied area.  相似文献   

Efficiency of organic ligands in adsorptive dissolution and photoreductive dissolution of hematite     

P. Mukherjee  Y. Gao 《International Journal of Environmental Science and Technology》2016,13(5):1195-1206

Organic ligands, especially oxalate, play an important role in iron dissolution from iron-containing minerals. To study the effects of organic acid ligands on the dissolution of iron-containing minerals, the dissolution kinetics of hematite in the presence of oxalate, acetate, and formate were studied under ultraviolet radiation with varying ligand concentrations (10–3 mM). The results indicate that for adsorption dissolution, oxalate is the dominating ligand for producing soluble iron (III) from hematite; for photoreductive dissolution under ultraviolet radiation and in oxic conditions, the production of iron (II) is highly proportional to the concentrations of oxalate, whereas the effects of varying concentrations of formate and acetate are not significant. At low oxalate concentrations (10–500 µM), the photoreductive dissolution of iron (II) is substantially low, while at high oxalate concentrations (3 mM), oxalate is equally effective as formate and acetate for producing photoreduced iron (II) from hematite. Combining with field data from other works, it is likely that the ratios of oxalate to total iron need to be higher than a threshold range of ~1.2–5.5 in order for oxalate to effectively produce photoreduced iron (II) from hematite. This study demonstrates that the iron (II) yield from photoreduction of hematite is significantly lower when the hematite surface is pre-coated with organic ligands versus when it is exposed to ultraviolet radiation instantaneously.  相似文献   

Characterizing the 2D shape complexity dynamics of the islands of Sundarbans,Bangladesh: a fractal dimension approach     

Sugata Hazra  Anirban Mukhopadhyay  Abhra Chanda  Parimal Mondal  Tuhin Ghosh  Sandip Mukherjee  Mashfiqus Salehin 《Environmental Earth Sciences》2016,75(20):1367

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