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991.
In the central part of Indo-Gangetic alluvium in the Unnao district, Uttar Pradesh there are many pockets where groundwater shows high fluoride content. Drinking of fluorinated ground water has effected a large population and in many villages more than 80% of the population is suffering from fluorosis. The source of this fluoride appears to be the alluvial sediments deposited in the geological past as no hard rock terrain is present in the nearby areas. The area is dominantly made up of mud with pockets of sand. The sand fraction is made up of quartz, plagioclase, microcline, muscovite and biotite along with some accessory minerals like garnet, epidote, chlorite, tourmaline, hornblende, kyanite and a few opaque minerals. Moreover, the fluoride content in the groundwater varies both spatially and with depth indicating a sporadic occurrence. The surface water is devoid of high content of fluoride but is reported in hand pumps and in the dug wells. This paper deals with the geochemical study of the sediments up to a depth of 45m as most of the hand pumps are up to this depth to understand the source of fluoride. 14C dates of calcretes have suggested that the 45 m thick succession must have been formed in about 45000 years.  相似文献   
992.
In this study, the behavior of thermal fronts along the fracture is studied in the presence of fracture-skin in a coupled fracture-matrix system. Cold water is injected into the fracture, which advances gradually towards production well, while extracting heat from the surrounding reservoir matrix. The heat conduction into the fracture-skin and the rock-matrix from the high permeability fracture is assumed to be one dimensional perpendicular to the axis of fluid flow along the fracture. Constant temperature cold water is injected through an injection well at the fracture inlet. The fluid flow takes place along the horizontal fracture which ensures connectivity between the injection and production wells. Since the rock-matrix is assumed to be tight, the permeability of fracture-skin as well as the rock-matrix is neglected. The present study focuses on the heat flux transfer at the fracture-skin interface as against the earlier studies on fracture-matrix interface, and the sensitivity of additional heterogeneity in the form of fracture skin in a conventional fracture-matrix coupled system is studied. The behavior of thermal fronts for various thermal conductivity values of the fracture-skin and rock-matrix is analyzed. Spatial moment analysis is performed on the thermal distribution profiles resulting from numerical studies in order to investigate the impact on mobility and dispersion behavior of the fluid in the presence of fracture-skin. The presence of fracture skin affects the heat transfer significantly in the coupled fracture-matrix system. The lower order spatial moments indicate that the effective thermal velocity increases with increase in skin thermal conductivity and a significant thermal dispersion is observed at the inlet of the fracture owing to the high thermal conductivity of the fracture-skin at the early stages. Furthermore the higher spatial moments indicate that the asymmetricity increases with decrease in skin thermal conductivity unlike the case with half fracture aperture and fluid velocity and the kurtosis is maximum with higher skin thermal conductivity which implies enhanced heat extraction from the fracture-skin into the fracture. Results suggest that the amount of heat extraction by the circulating fluid within the fracture from the reservoir not only depends on the rock-matrix module of the reservoir characteristics but also the fracture-skin characteristics of the system and subsequently influence the reservoir efficiency.  相似文献   
993.
The role of biofilm proteins in modulating cyprid metamorphosis is not well understood. In the present investigation this possibility was explored by disrupting biofilm proteins using commercially available protease. The influence of natural biofilm and artificial biofilms of Aeromonas salmonicida salmonicida and Bacillus brevis and their culture supernatants and exopolysaccharides obtained under different nutritional conditions was evaluated. Natural biofilm facilitated cyprid metamorphosis in Balanus amphitrite, whereas monospecies biofilms did not. The treatment of biofilms with protease resulted in a decline in metamorphosis, except in B. brevis, where although metamorphosis was negated initially, it increased with the protease concentration and observation days. As the response of cyprids to exopolysaccharides produced by Asalmonicida salmonicida was dependent on protein concentration, protease treatment resulted in a decrease in metamorphosis, whereas in case of B. brevis biofilms, protease hydrolysis products could be important in providing settlement cues. Thus, biofilm bacterial components play an important role in the cyprid metamorphosis of Balanus amphitrite.  相似文献   
994.
Theoretical and Applied Climatology - Temperature and CO2 are the two most important climate parameters that affect crop yield directly. In this study, the impact of these two parameters on the...  相似文献   
995.
A regional tree ring-width index chronology prepared from various tree core samples of the western Himalaya has been analyzed in relation to climate fluctuations. The correlation analysis of tree ring chronology shows significant positive correlations with regional rainfall and standardized precipitation evapotranspiration index (SPEI) and negative correlations with temperature and vapor pressure (VP) during the spring season. The correlation coefficients (CCs) of tree ring-width index chronology with rainfall, temperature, SPEI, and VP during 1901–1990 are 0.50, −0.49, 0.65, and −0.51, respectively. All CCs are significant at 0.1% level. The highly significant CCs between tree ring-width index chronology and SPEI indicate that tree growth over the western Himalaya is more sensitive to soil moisture availability than rainfall, whereas the rising VP is found to have a significant moisture stress condition to tree growth by accelerating the evapotranspiration, which is not conducive for the development of tree growth in the region. So, based on the strong association between tree ring-width index chronology and SPEI; the reconstructions of SPEI and VP are developed back to AD 1861, that show the long period of dryness during 1936–1963.  相似文献   
996.
Agriculture in India is highly sensitive to climatic variations particularly to rainfall and temperature; therefore, any change in rainfall and temperature will influence crop yields. An understanding of the spatial and temporal distribution and changing patterns in climatic variables is important for planning and management of natural resources. Time series analysis of climate data can be a very valuable tool to investigate its variability pattern and, maybe, even to predict short- and long-term changes in the series. In this study, the sub-divisional rainfall data of India during the period 1871 to 2016 has been investigated. One of the widely used powerful nonparametric techniques namely wavelet analysis was used to decompose and de-noise the series into time–frequency component in order to study the local as well as global variation over different scales and time epochs. On the decomposed series, autoregressive integrated moving average (ARIMA) and artificial neural network (ANN) models were applied and by means of inverse wavelet transform, the prediction of rainfall for different sub-divisions was obtained. To this end, empirical comparison was carried out toward forecast performance of the approaches namely Wavelet-ANN, Wavelet-ARIMA, and ARIMA. It is reported that Wavelet-ANN and Wavelet-ARIMA approach outperforms the usual ARIMA model for forecasting of rainfall for the data under consideration.  相似文献   
997.
This paper combines the climatological and societal perspectives for assessing future climatic extremes over Kangasabati River basin in India using an ensemble of four high resolution (25 km) regional climate model (RCM) simulations from 1970 to 2050. The relevant extreme indices and their thresholds are defined in consultation with stakeholders and are then compared using RCM simulations. To evaluate the performance of RCM in realistically representing atmospheric processes in the basin, model simulations driven with ERAInterim global re-analysis data from 1989 to 2008 are compared with observations. The models perform well in simulating seasonality, interannual variability and climatic extremes. Future climatic extremes are evaluated based on RCM simulations driven by GCMs, for present (1970–1999) and for the SRES A1B scenario for future (2021–2050) period. The analysis shows an intensification of majority of extremes as projected by future ensemble mean. The study suggests that there is a marked consistency in stakeholder observed changes in climate extremes and future predicted trends.  相似文献   
998.
The kinetics of hydrogen atom abstraction reactions of HFE-227pc by OH and Cl was studied by ab initio method. The structural optimization and frequency calculation of the titled compound and the species formed during the abstraction reactions were performed with density functional theory using hybrid meta density functional MPWB1K with 6–31?+?G(d,p) basis set. The energy of the species was further refined by making a single point energy calculation at G3B3 level of theory. The standard enthalpies of formation of reactant and the radical formed after H-atom abstraction was calculated using isodesmic method. The rate constants of abstraction reactions were calculated using Conventional Transition State Theory (CTST) and were found to be 1.5?×?10?15 and 0.53?×?10?16 cm3molecule?1 s?1 for OH and Cl respectively. The calculated value for the abstraction by OH is close to the experimental value of 2.26?×?10?15 cm3molecule?1 s?1 whereas the same for Cl is found to be about five times lower than that of 2.70?×?10?16 cm3molecule?1 s?1. The theoretical studies yielded the enthalpies of formation and the rate constants that are vital in determining the lifetime of HFE-227pc.  相似文献   
999.
The present study is an attempt to analyse the precipitable water vapour (PWV) derived from Global Positioning System (GPS) and observed meteorological data over Almora, Central Himalayan Region. The PWV values derived using GPS study is compared with the corresponding moderate resolution imaging spectro-radiometer (MODIS) data. The statistical analysis reveals a positive correlation between both methods. Moderate resolution imaging spectroradiometer near-infrared (MODIS NIR) clear column water vapour product shows a higher correlation (R 2 = 90–93 %) with GPS-derived precipitable water vapour on annual scale as compared to the seasonal scale (R 2 = 62–87 %). MODIS is found to be overestimating in NIR clear column where the magnitude of bias and RMSE show systematic changes from season to season. Monsoon is an important phenomenon in the Indian weather context and holds significant importance in Central Himalayan ecosystem. The monthly and seasonal variation in precipitable water vapour is related with monsoon onset in the region. Diurnal variations in precipitable water vapour are studied with other meteorological data over Almora during dry and wet season. The precipitable water vapour had minimum value in the morning, increases in the afternoon to evening and again decreases to the midnight in both the dry and wet seasons. These results suggest that diurnal variation of water vapour is caused by the transport of water vapour by thermally induced local circulation.  相似文献   
1000.
To comprehend the characteristics of heterogeneous aerosols, apart from some thematic multi-institutional, multi-platform and multi-parameter campaigns conducted at several places over the globe, presently two major ground-based networks, involving Cimel (AERONET) and Prede (SKYNET) Sun/sky photometers/radiometers have been in progress. In this paper, we report the results of a study that has been undertaken to compare the performance and data products of Cimel and Prede instruments, which were operated concurrently for a period of about 2 years, at the Indian Institute of Tropical Meteorology, Pune, India. The results show a good agreement in the direct Sun observations (aerosol optical depth). The results are also substantiated by making comparison with surface-level black carbon aerosol mass concentration, apart from comparison of other parameters. With regard to the retrieved products such as aerosol size distribution, Prede shows more or less equal concentration of fine mode and relatively more concentration of coarse mode aerosol as compared to those measured by the Cimel. Moreover, the single scattering albedo values measured by the Prede overestimate those observed by the Cimel. These deviations are found to be primarily due to the nature of aerosol loading (turbidity) in the sensing region which is sensitive to the data retrieval techniques including model assumptions employed in both networks. The results of the present study are found useful for multidimensional mapping of aerosol characteristics by integrating the products from both AERONET and SKYNET monitoring stations and thereby help understanding better the impact of aerosols on climate.  相似文献   
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