银离子和含银不锈钢的抗菌性研究     

段继周  丹治保典  侯保荣  西方篤  水流徹 《海洋科学》2005,29(7):69-72

基于银因其具有良好的广谱抗茵活性和低毒性而在医学方面有着较为广泛的应用,对银离子(硝酸银)和含银不锈钢的抗茵活性进行了初步研究。实验结果表明,在10^6CFu／mL的初始接种浓度下,银离子对枯草杆菌、大肠杆菌和假单胞茵的最小抑茵质量浓度和最小杀菌质量浓度分别为2,6,8mg／L和2,8,10mg／L。大肠杆菌经8mg／L的银离子处理2h后,有99．9％以上的细菌被破坏。含银不锈钢也表现了较强的抗菌性能。在普通的、银合金和银涂层的sus304不锈钢表面附着的单层生物膜浸泡在PBS溶液中3d后,经CFDA-DAPI双染色和荧光显微镜观察计数获得的假单胞菌的平均存活率为98．0％,38．5％和15．1％。  相似文献   

The influence of the Jahn–Teller effect at Fe<Superscript>2+</Superscript> on the structure of chromite at high pressure     

Atsushi?KyonoEmail author  Stephen?A.?Gramsch  Takamitsu?Yamanaka  Daijo?Ikuta  Muhtar?Ahart  Bj?rn?O.?Mysen  Ho-kwang?Mao  Russell?J.?Hemley 《Physics and Chemistry of Minerals》2012,39(2):131-141

The crystal structure of chromite FeCr₂O₄ was investigated to 13.7 GPa and ambient temperature with single-crystal X-ray diffraction techniques. The unit-cell parameter decreases continuously from 8.3832 (5) to 8.2398 (11) Å up to 11.8 GPa. A fit to the Birch–Murnaghan equation of state (EoS) based on the P–V data gives: K ₀ = 209 (13) GPa, K′ = 4.0 (fixed), and V ₀ = 588 (1) ų. The FeO₄ tetrahedra and CrO₆ octahedra are compressed isotropically with pressure with their Fe–O and Cr–O bond distances decreasing from 1.996 (6) to 1.949 (7) Å and from 1.997 (3) to 1.969 (7) Å, respectively. The tetrahedral site occupied by the Fe²⁺ cation is more compressible than the octahedral site occupied by the Cr³⁺ cation. The resulting EoS parameters for the tetrahedral and the octahedral sites are K ₀ = 147 (9) GPa, K′ = 4.0 (fixed), V ₀ = 4.07 (1) ų and K ₀ = 275 (24) GPa, K′ = 4.0 (fixed), V ₀ = 10.42 (2) ų, respectively. A discontinuous volume change is observed between 11.8 and 12.6 GPa. This change indicates a phase transition from a cubic (space group Fd-[`3]{\overline{3}} m) to a tetragonal structure (space group I4₁ /amd). At the phase transition boundary, the two Cr–O bonds parallel to the c-axis shorten from 1.969 (7) to 1.922 (17) Å and the other four Cr–O bonds parallel to the ab plane elongate from 1.969 (7) to 1.987 (9) Å. This anisotropic deformation of the octahedra leads to tetragonal compression of the unit cell along the c-axis. The angular distortion in the octahedron decreases continuously up to 13.7 GPa, whereas the distortion in the tetrahedron rises dramatically after the phase transition. At the pressure of the phase transition, the tetrahedral bond angles along the c-axis direction of the unit cell begin decreasing from 109.5° to 106.6 (7)°, which generates a “stretched” tetrahedral geometry. It is proposed that the Jahn–Teller effect at the tetrahedrally coordinated Fe²⁺ cation becomes active with compression and gives rise to the tetrahedral angular distortion, which in turn induces the cubic-to-tetragonal transition. A qualitative molecular orbital model is proposed to explain the origin and nature of the Jahn–Teller effect observed in this structure and its role in the pressure-induced phase transition.  相似文献   

Improving the scientific assessment of carbon sinks     

Atsushi Ishii 《Climate Policy》2013,13(2):217-224

Abstract

The future role of carbon sinks with reference to the Kyoto Protocol depends significantly on developing an international consensus on carbon-sink assessment and carbon accounting. A clear and practical approach is needed that allows both the scientific community and policy-makers to construct a viable operational framework. This article proposes that a new strategy be developed for carbon-sink assessment based on full carbon accounting (FCA) alongside a separate political tool for carbon accounting. This approach is derived from the experience of the European critical loads (CL) concept, which seeks to quantify levels of pollutants (such as sulfur) that can be absorbed by the environment without causing ecological harm. Crucial to the implementation of such a strategy are robust institutional settings, such as an internationally coordinated monitoring system, open and fair access to the assessment processes, and international research cooperation programs for addressing associated problems of carbon-sink activities.  相似文献   

Length-Scale Similarity of Turbulent Organized Structures over Surfaces with Different Roughness Types     

Hiroshi Takimoto  Atsushi Inagaki  Manabu Kanda  Ayumu Sato  Takenobu Michioka 《Boundary-Layer Meteorology》2013,147(2):217-236

We examine the similarity of turbulent organized structures over smooth and very rough wall flows. Turbulent flow fields in horizontal cross-sections were measured using particle image velocimetry, and the characteristics of turbulent organized structures over four types of surfaces were investigated. Measurements were conducted at several measurement heights across the internal boundary layer. The length and width of turbulence structures were quantified using a two-point correlation method. We selected two thresholds of two-point correlation coefficients to consider both large-scale and small-scale structures; the validity of these choices was examined through the analyses using proper orthogonal decomposition. For large-scale structures, the length and aspect ratios (streamwise length/spanwise width) of structures were highly correlated with the velocity gradient for each measurement height and boundary-layer thickness. This relationship was also examined in the results of previous studies, and the scaling of the aspect ratio with the non-dimensional velocity gradient again showed the importance of the velocity gradient, with slight differences found between smooth and rough surfaces. In contrast, the small-scale structures exhibited weak dependency on the velocity gradient and boundary-layer thickness. Instantaneous snapshots of turbulent organized structures at the same shear level also displayed differences in small-scale structures, but the structures of the organized motions resembled each other, as in the results of the two-point correlation method.  相似文献   

High pressure phase equilibria in the system CaTiO3-CaSiO3: stability of perovskite solid solutions     

Atsushi Kubo  Toshihiro Suzuki  Masaki Akaogi 《Physics and Chemistry of Minerals》1997,24(7):488-494

Phase relations in the system CaTiO₃-CaSiO₃ were experimentally examined at 5.3–14.7 GPa and 1200–1600 °C with a 6–8 type multianvil apparatus. As pressure increases, stability field of perovskite solid solution extends from CaTiO₃ to CaSiO₃, and the perovskite becomes stable for the entire composition range above about 12.3 GPa. The stability field of Ca(Ti_1?X, Si_X)₂O₅ (0.78<x≦1) titanite solid solution +Ca₂SiO₄ larnite exists in the CaSiO₃-rich composition range at 9.3–12.3 GPa and 1200 °C. Perovskite solid solutions containing CaSiO₃ component of 0 to 66 mol% could be quenched to 1 atm. The composition-molar volume relationship of perovskite solid solution showed that molar volume of perovskite solid solution linearly reduces from the value of CaTiO₃ to that of CaSiO₃.  相似文献   

Arc-parallel extension in preparation of the rotation of southwest Japan: Tectonostratigraphy and structures of the Lower Miocene Ichishi Group     

Hideki Kinoshita  Atsushi Yamaji 《Island Arc》2021,30(1):e12418

Opening of the Japan Sea back arc basin was accompanied by extensional tectonics in the drifting southwest Japan arc. Various trends of Early Miocene grabens in the arc suggest multi-directional rifting, which necessarily involved strike-slip components of some of basin-margin faults. However, such components are not well understood. In this work we conducted a field survey in the Early Miocene Ichishi basin on the northern side of the Median Tectonic Line, central southwest Japan. We found that the basin was a compound of grabens that were formed along normal and sinistral strike-slip faults, the latter of which had northeast–southwest trends. The block faulting in this phase produced basement highs between sub-basins, which were filled with the lower part of the Ichishi Group. We found a low-angle angular unconformity at a middle horizon in the group, with which we define the upper and lower part of the group. The upper part onlapped both the basement highs and the lower part. It means that the transtensional basin formation ceased sometime between 18 and 17.5 Ma in the Ichishi area. The Ichishi basin turned subsequently into a sag basin subsided due to normal faulting probably along the Nunobiki-sanchi-toen fault zone. The transtension and the basin sag were driven by ENE–WSW extensional stress. This arc-parallel extension produced grabens various areas including Ichishi in the Early Miocene. The extensional deformation was eventually localized to the deep rift along the Fossa Magna to make the lithosphere under southwest Japan decoupled from that under northeast Japan. The decoupling allowed the rapid rotation of southwest Japan from ~17.5 Ma. The cluster of those grabens around the Ise bay probably determined the southeastern margin of the Kinki triangle.  相似文献   

The application of δ¹³C and C/N ratios as indicators of organic carbon sources and paleoenvironmental change of the mangrove ecosystem from Ba Lat Estuary, Red River, Vietnam     

Nguyen Tai Tue  Hideki Hamaoka  Atsushi Sogabe  Tran Dang Quy  Mai Trong Nhuan  Koji Omori 《Environmental Earth Sciences》2011,64(5):1475-1486

In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ¹³C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ¹³C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ¹³C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ¹³C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ¹³C values in mangrove sediments. However, the shifts of δ¹³C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ¹³C < −25‰, and C/N < 12 and δ¹³C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ¹³C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ¹³C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ¹³C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ¹³C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.  相似文献   

Particle Image Velocimetry Measurements of Turbulent Flow Within Outdoor and Indoor Urban Scale Models and Flushing Motions in Urban Canopy Layers     

Hiroshi Takimoto  Ayumu Sato  Janet F. Barlow  Ryo Moriwaki  Atsushi Inagaki  Shiho Onomura  Manabu Kanda 《Boundary-Layer Meteorology》2011,140(2):295-314

We investigate the spatial characteristics of urban-like canopy flow by applying particle image velocimetry (PIV) to atmospheric turbulence. The study site was a Comprehensive Outdoor Scale MOdel (COSMO) experiment for urban climate in Japan. The PIV system captured the two-dimensional flow field within the canopy layer continuously for an hour with a sampling frequency of 30 Hz, thereby providing reliable outdoor turbulence statistics. PIV measurements in a wind-tunnel facility using similar roughness geometry, but with a lower sampling frequency of 4 Hz, were also done for comparison. The turbulent momentum flux from COSMO, and the wind tunnel showed similar values and distributions when scaled using friction velocity. Some different characteristics between outdoor and indoor flow fields were mainly caused by the larger fluctuations in wind direction for the atmospheric turbulence. The focus of the analysis is on a variety of instantaneous turbulent flow structures. One remarkable flow structure is termed ‘flushing’, that is, a large-scale upward motion prevailing across the whole vertical cross-section of a building gap. This is observed intermittently, whereby tracer particles are flushed vertically out from the canopy layer. Flushing phenomena are also observed in the wind tunnel where there is neither thermal stratification nor outer-layer turbulence. It is suggested that flushing phenomena are correlated with the passing of large-scale low-momentum regions above the canopy.  相似文献   

Textures of syntaxial quartz veins synthesized by hydrothermal experiments     

Atsushi Okamoto  Kotaro Sekine 《Journal of Structural Geology》2011,33(12):1764-1775

Syntaxial quartz veins were synthesized by hydrothermal flow-through experiments using rock blocks (metachert, sandstone, and granite) containing slits. Based on analyses of vein textures using birefringence imaging microscopy, we identified two stages of crystal growth. During stage 1, quartz grain growth occurs without an increase in grain width. During stage 2, quartz grains develop facets and grow preferentially parallel to the c-axis orientation, and the aspect ratio of quartz grains shifts toward ～2.9. Competitive growth occurs significantly at stage 2, and the transition from stage 1–2 occurs at a critical distance from the vein wall, being approximately equal to the host-rock grain size. Crystal growth in the slits produce various textures controlled by the ratio of slit aperture (H) to host-rock grain size (d). In high H/d cracks, elongate–blocky texture develops by grain impingement during stage 2, whereas in low H/d cracks, crystals that bridge the crack form without competitive growth by grain impingement at stage 1. Heterogeneous structures of fracture porosity are produced during syntaxial vein formation, due to the anisotropy in the growth rate of quartz. Such “incompletely sealed” cracks may act as important fluid pathways and as weak planes in the upper crust.  相似文献   

Ab initio quantum chemical investigation of arsenic sulfide molecular diversity from As4S6 and As4     

Atsushi Kyono 《Physics and Chemistry of Minerals》2013,40(9):717-731

The structural diversity of arsenic sulfide molecules in compositions between As₄S₆ and As₄ was investigated using ab initio quantum chemical calculations. The As₄S₆ molecule consists of four trigonal pyramid coordinations of As atoms bonding to three S atoms. In the As₄S₅ composition, only one type of molecular configuration corresponds to an uzonite-type molecule. In the As₄S₄ composition, two molecular configurations exist with realgar-type and pararealgar-type molecules. Three molecular configurations are in the As₄S₃ composition. The first configuration comprises trigonal pyramidal As atom coordinations of two types: bonding to two S atoms and one As atom, and bonding to one S atom and two As atoms. The second is the molecular configuration of dimorphite. The third comprises trigonal pyramidal As atom coordinations of two types: bonding to three As atoms, and bonding to one As atom and two S atoms. The As₄S₂ composition allows molecular configurations of two types. One is comprised of trigonal pyramidal As atom configurations of one type bonding to two As atoms and one S atom. The other comprises trigonal pyramidal As atom coordinations of three types: bonding to two S atoms and one As atoms, bonding to one S atom and two As atoms, and bonding to three As atoms. The As₄S molecule has trigonal pyramidal As atom coordinations of two types: bonding to one S atom and two As atoms, and bonding to three As atoms. The As₄S composition permits only one molecular configuration, which suggests that the mineral duranusite comprises the As₄S molecular geometry. In all, ten molecular configurations are predicted in the molecular hierarchy of the arsenic sulfide binary system. The simulated Raman spectral profiles are helpful in searching for undiscovered arsenic sulfide minerals.  相似文献