High pressure phase equilibria in the system CaTiO3-CaSiO3: stability of perovskite solid solutions     

Atsushi Kubo  Toshihiro Suzuki  Masaki Akaogi 《Physics and Chemistry of Minerals》1997,24(7):488-494

Phase relations in the system CaTiO₃-CaSiO₃ were experimentally examined at 5.3–14.7 GPa and 1200–1600 °C with a 6–8 type multianvil apparatus. As pressure increases, stability field of perovskite solid solution extends from CaTiO₃ to CaSiO₃, and the perovskite becomes stable for the entire composition range above about 12.3 GPa. The stability field of Ca(Ti_1?X, Si_X)₂O₅ (0.78<x≦1) titanite solid solution +Ca₂SiO₄ larnite exists in the CaSiO₃-rich composition range at 9.3–12.3 GPa and 1200 °C. Perovskite solid solutions containing CaSiO₃ component of 0 to 66 mol% could be quenched to 1 atm. The composition-molar volume relationship of perovskite solid solution showed that molar volume of perovskite solid solution linearly reduces from the value of CaTiO₃ to that of CaSiO₃.  相似文献   

Arc-parallel extension in preparation of the rotation of southwest Japan: Tectonostratigraphy and structures of the Lower Miocene Ichishi Group     

Hideki Kinoshita  Atsushi Yamaji 《Island Arc》2021,30(1):e12418

Opening of the Japan Sea back arc basin was accompanied by extensional tectonics in the drifting southwest Japan arc. Various trends of Early Miocene grabens in the arc suggest multi-directional rifting, which necessarily involved strike-slip components of some of basin-margin faults. However, such components are not well understood. In this work we conducted a field survey in the Early Miocene Ichishi basin on the northern side of the Median Tectonic Line, central southwest Japan. We found that the basin was a compound of grabens that were formed along normal and sinistral strike-slip faults, the latter of which had northeast–southwest trends. The block faulting in this phase produced basement highs between sub-basins, which were filled with the lower part of the Ichishi Group. We found a low-angle angular unconformity at a middle horizon in the group, with which we define the upper and lower part of the group. The upper part onlapped both the basement highs and the lower part. It means that the transtensional basin formation ceased sometime between 18 and 17.5 Ma in the Ichishi area. The Ichishi basin turned subsequently into a sag basin subsided due to normal faulting probably along the Nunobiki-sanchi-toen fault zone. The transtension and the basin sag were driven by ENE–WSW extensional stress. This arc-parallel extension produced grabens various areas including Ichishi in the Early Miocene. The extensional deformation was eventually localized to the deep rift along the Fossa Magna to make the lithosphere under southwest Japan decoupled from that under northeast Japan. The decoupling allowed the rapid rotation of southwest Japan from ~17.5 Ma. The cluster of those grabens around the Ise bay probably determined the southeastern margin of the Kinki triangle.  相似文献   

The application of δ¹³C and C/N ratios as indicators of organic carbon sources and paleoenvironmental change of the mangrove ecosystem from Ba Lat Estuary, Red River, Vietnam     

Nguyen Tai Tue  Hideki Hamaoka  Atsushi Sogabe  Tran Dang Quy  Mai Trong Nhuan  Koji Omori 《Environmental Earth Sciences》2011,64(5):1475-1486

In this study, two sediment cores (~70 cm) were collected from separate mangrove forests straddling the Ba Lat Estuary, Red River of northern Vietnam, to examine the origins of sedimentary organic carbon (SOC) and reconstruct the paleoenvironment. In addition, mangrove leaves and particulate organic matter were collected and measured for δ¹³C to trace the origins of SOC. The cores were analyzed by high-resolution sections for δ¹³C, TOC, C/N ratios, sediment grain size, water content, and porosity, with values of δ¹³C, TOC, and C/N ratios ranging from −28.19 to −22.5‰, 2.14–30.94 mg/g, and 10.29–18.32, respectively. The δ¹³C and TOC relationship indicated that there were some small residual effects of diagenetic processes on TOC and δ¹³C values in mangrove sediments. However, the shifts of δ¹³C and C/N ratios from the bottom to the surface sediment of the cores explained the change in organic matter sources, with values of C/N > 12 and δ¹³C < −25‰, and C/N < 12 and δ¹³C > −25‰ indicated terrestrial (e.g., mangrove litter) and marine phytoplankton sources, respectively. The covarying δ¹³C, C/N ratios, and sediment grain sizes during the past 100 years in sediment cores showed that the paleoenvironment may be reconstructed into three environments (subtidal, tidal flat, and intertidal mangrove). General trends in δ¹³C and C/N followed a gradual increase in the C/N ratio and a concomitant decrease in δ¹³C from the subtidal, through to tidal flat, and to the intertidal mangrove. δ¹³C and C/N ratios are therefore effective in measuring the continuum of environmental change in mangrove ecosystem.  相似文献   

Particle Image Velocimetry Measurements of Turbulent Flow Within Outdoor and Indoor Urban Scale Models and Flushing Motions in Urban Canopy Layers     

Hiroshi Takimoto  Ayumu Sato  Janet F. Barlow  Ryo Moriwaki  Atsushi Inagaki  Shiho Onomura  Manabu Kanda 《Boundary-Layer Meteorology》2011,140(2):295-314

We investigate the spatial characteristics of urban-like canopy flow by applying particle image velocimetry (PIV) to atmospheric turbulence. The study site was a Comprehensive Outdoor Scale MOdel (COSMO) experiment for urban climate in Japan. The PIV system captured the two-dimensional flow field within the canopy layer continuously for an hour with a sampling frequency of 30 Hz, thereby providing reliable outdoor turbulence statistics. PIV measurements in a wind-tunnel facility using similar roughness geometry, but with a lower sampling frequency of 4 Hz, were also done for comparison. The turbulent momentum flux from COSMO, and the wind tunnel showed similar values and distributions when scaled using friction velocity. Some different characteristics between outdoor and indoor flow fields were mainly caused by the larger fluctuations in wind direction for the atmospheric turbulence. The focus of the analysis is on a variety of instantaneous turbulent flow structures. One remarkable flow structure is termed ‘flushing’, that is, a large-scale upward motion prevailing across the whole vertical cross-section of a building gap. This is observed intermittently, whereby tracer particles are flushed vertically out from the canopy layer. Flushing phenomena are also observed in the wind tunnel where there is neither thermal stratification nor outer-layer turbulence. It is suggested that flushing phenomena are correlated with the passing of large-scale low-momentum regions above the canopy.  相似文献   

Textures of syntaxial quartz veins synthesized by hydrothermal experiments     

Atsushi Okamoto  Kotaro Sekine 《Journal of Structural Geology》2011,33(12):1764-1775

Syntaxial quartz veins were synthesized by hydrothermal flow-through experiments using rock blocks (metachert, sandstone, and granite) containing slits. Based on analyses of vein textures using birefringence imaging microscopy, we identified two stages of crystal growth. During stage 1, quartz grain growth occurs without an increase in grain width. During stage 2, quartz grains develop facets and grow preferentially parallel to the c-axis orientation, and the aspect ratio of quartz grains shifts toward ～2.9. Competitive growth occurs significantly at stage 2, and the transition from stage 1–2 occurs at a critical distance from the vein wall, being approximately equal to the host-rock grain size. Crystal growth in the slits produce various textures controlled by the ratio of slit aperture (H) to host-rock grain size (d). In high H/d cracks, elongate–blocky texture develops by grain impingement during stage 2, whereas in low H/d cracks, crystals that bridge the crack form without competitive growth by grain impingement at stage 1. Heterogeneous structures of fracture porosity are produced during syntaxial vein formation, due to the anisotropy in the growth rate of quartz. Such “incompletely sealed” cracks may act as important fluid pathways and as weak planes in the upper crust.  相似文献   

Ab initio quantum chemical investigation of arsenic sulfide molecular diversity from As4S6 and As4     

Atsushi Kyono 《Physics and Chemistry of Minerals》2013,40(9):717-731

The structural diversity of arsenic sulfide molecules in compositions between As₄S₆ and As₄ was investigated using ab initio quantum chemical calculations. The As₄S₆ molecule consists of four trigonal pyramid coordinations of As atoms bonding to three S atoms. In the As₄S₅ composition, only one type of molecular configuration corresponds to an uzonite-type molecule. In the As₄S₄ composition, two molecular configurations exist with realgar-type and pararealgar-type molecules. Three molecular configurations are in the As₄S₃ composition. The first configuration comprises trigonal pyramidal As atom coordinations of two types: bonding to two S atoms and one As atom, and bonding to one S atom and two As atoms. The second is the molecular configuration of dimorphite. The third comprises trigonal pyramidal As atom coordinations of two types: bonding to three As atoms, and bonding to one As atom and two S atoms. The As₄S₂ composition allows molecular configurations of two types. One is comprised of trigonal pyramidal As atom configurations of one type bonding to two As atoms and one S atom. The other comprises trigonal pyramidal As atom coordinations of three types: bonding to two S atoms and one As atoms, bonding to one S atom and two As atoms, and bonding to three As atoms. The As₄S molecule has trigonal pyramidal As atom coordinations of two types: bonding to one S atom and two As atoms, and bonding to three As atoms. The As₄S composition permits only one molecular configuration, which suggests that the mineral duranusite comprises the As₄S molecular geometry. In all, ten molecular configurations are predicted in the molecular hierarchy of the arsenic sulfide binary system. The simulated Raman spectral profiles are helpful in searching for undiscovered arsenic sulfide minerals.  相似文献   

Nuclear energy response in the EMF27 study     

Son H. Kim  Kenichi Wada  Atsushi Kurosawa  Matthew Roberts 《Climatic change》2014,123(3-4):443-460

The nuclear energy response for mitigating global climate change across 18 participating models of the EMF27 study is investigated. Diverse perspectives on the future role of nuclear power in the global energy system are evident in the broad range of nuclear power contributions from participating models of the study. In the Baseline scenario without climate policy, nuclear electricity generation and shares span 0–66 EJ/year and 0–25 % in 2100 for all models, with a median nuclear electricity generation of 39 EJ/year (1,389 GWe at 90 % capacity factor) and median share of 9 %. The role of nuclear energy increased under the climate policy scenarios. The median of nuclear energy use across all models doubled in the 450 ppm CO₂e scenario with a nuclear electricity generation of 67 EJ/year (2,352 GWe at 90 % capacity factor) and share of 17 % in 2100. The broad range of nuclear electricity generation (11–214 EJ/year) and shares (2–38 %) in 2100 of the 450 ppm CO₂e scenario reflect differences in the technology choice behavior, technology assumptions and competitiveness of low carbon technologies. Greater clarification of nuclear fuel cycle issues and risk factors associated with nuclear energy use are necessary for understanding the nuclear deployment constraints imposed in models and for improving the assessment of the nuclear energy potential in addressing climate change.  相似文献   

Big data: techniques and technologies in geoinformatics,edited by Hassan A. Karimi,Boca Raton,FL, CRC Press, 2014, 312 pp., US$129.95 (hardcover), ISBN 13-978-1466586512     

Atsushi Nara 《International journal of geographical information science》2013,27(4):694-696

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Fishing effects on age and spatial structures undermine population stability of fishes     

Chih-hao Hsieh  Atsushi Yamauchi  Takefumi Nakazawa  Wei-Fen Wang 《Aquatic Sciences - Research Across Boundaries》2010,72(2):165-178

Overfishing has caused dramatic changes in structures of exploited populations as well as ecosystems. In this article, we focus on fishing effects on age (size) and spatial structures of exploited fishes. Accumulating evidence has shown that large and experienced spawning individuals are able to produce higher quality and quantity of eggs, known as maternal effects, and that individuals of different age classes tend to spawn in different locations and times. These behaviors are associated with a healthy age structure and contribute to bet-hedging capacity that is important in smoothing out short-term environmental variability. Here, we document a widespread phenomenon of age (size)-truncation of exploited populations driven by size-selective fishery removals. Such size-selective fishing may have evolutionary consequence and may be difficult to reverse. In addition, fishing often reduces population spatial heterogeneity that also contributes importantly to bet-hedging. We review studies showing that the effects of age truncation and reduction of spatial heterogeneity have reduced resilience and elevated the fluctuation amplitude of exploited populations facing a changing environment. Recent analyses indicated that fish populations often exhibit nonlinear nature and have potential to shift dramatically in a short time. All the evidence suggests that fishing, by altering age or spatial structures, may make exploited fishes, more prone to catastrophic shifts. Therefore, to achieve sustainable fisheries, management should conserve the age and spatial structure in addition to viable spawning biomass.  相似文献   

Integrated field spectroscopy of E+A (post-starburst) galaxies with the Kyoto tridimensional spectrograph II     

Tomotsugu Goto  Atsushi Kawai  Atsushi Shimono  Hajime Sugai  Masafumi Yagi  Takashi Hattori 《Monthly notices of the Royal Astronomical Society》2008,386(3):1355-1365

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