Testing the preservation potential of early diagenetic dolomites as geochemical archives     

Mathias Mueller  Onyedika A. Igbokwe  Benjamin Walter  Chelsea L. Pederson  Sylvia Riechelmann  Detlev K. Richter  Richard Albert  Axel Gerdes  Dieter Buhl  Rolf D. Neuser  Giovanni Bertotti  Adrian Immenhauser 《Sedimentology》2020,67(2):849-881

Early marine diagenetic dolomite is a rather thermodynamically-stable carbonate phase and has potential to act as an archive of marine porewater properties. However, the variety of early to late diagenetic dolomite phases that can coexist within a single sample can result in extensive complexity. Here, the archive potential of early marine dolomites exposed to extreme post-depositional processes is tested using various types of analyses, including: petrography, fluid inclusion data, stable δ¹³C and δ¹⁸O isotopes, ⁸⁷Sr/⁸⁶Sr ratios, and U-Pb age dating of various dolomite phases. In this example, a Triassic carbonate platform was dissected and overprinted (diagenetic temperatures of 50 to 430°C) in a strike-slip zone in Southern Spain. Eight episodes of dolomitization, a dolostone cataclasite and late stage meteoric/vadose cementation were recognized. The following processes were found to be diagenetically relevant: (i) protolith deposition and fabric-preservation, and marine dolomitization of precursor aragonite and calcite during the Middle–Late Triassic; (ii) intermediate burial and formation of zebra saddle dolomite and precipitation of various dolomite cements in a Proto-Atlantic opening stress regime (T ca 250°C) during the Early–Middle Jurassic; (iii) dolomite cement precipitation during early Alpine tectonism, rapid burial to ca 15 km, and high-grade anchizone overprint during Alpine tectonic evolution in the Early Eocene to Early Miocene; (iv) brecciation of dolostones to cataclasite during the onset of the Carboneras Fault Zone activity during the Middle Miocene; and (v) late-stage regression and subsequent meteoric overprint. Data shown here document that, under favourable conditions, early diagenetic marine dolomites and their archive data may resist petrographic and geochemical resetting over time intervals of 10⁸ or more years. Evidence for this preservation includes preserved Late Triassic seawater δ¹³C_DIC values and primary fluid inclusion data. Data also indicate that oversimplified statements based on bulk data from other petrographically-complex dolomite archives must be considered with caution.  相似文献   

The German Bight (North Sea) is a nursery area for both locally and externally produced sprat juveniles     

Hannes Baumann  Arne M. Malzahn  Rudi Voss  Axel Temming 《Journal of Sea Research》2009,61(4):234-243

To better understand the role of the German Bight (GB) as a nursery area for juvenile North Sea sprat Sprattus sprattus we sought to determine whether the area may receive only locally or also externally produced offspring. We sampled juveniles during 3 trawl surveys in the GB in August, September, and October 2004 and applied otolith microstructure analysis in order to reconstruct their distributions of the day-of-first-increment-formation (dif). These were contrasted with spatial and seasonal patterns of sprat egg abundance in the GB and its adjacent areas, observed during 6 monthly plankton surveys. It was found that the majority of juveniles originated mainly from April/May 2004, coinciding with high spawning activity west of the GB, whereas spawning and larval production inside the GB peaked notably later, in May/June. This indicated that a large proportion of juveniles was produced outside the GB and transported subsequently into it through passive and/or active migration. Shifts to later mean difs from one survey to the next and length distributions indicative of the simultaneous presence of multiple cohorts, supported the notion that the GB is a complex retention and nursery area for sprat offspring from different North Sea spawning grounds and times. Later born juveniles had significantly faster initial growth rates than earlier born conspecifics, which was likely temperature-mediated, given the strong correlation between back-calculated growth histories and sea surface temperature as a proxy for thermal histories of juveniles (r² = 0.52).  相似文献   

How to operationalize accounting under Article 6 market mechanisms of the Paris Agreement     

Benito Müller  Axel Michaelowa 《Climate Policy》2019,19(7):812-819

The role of market mechanisms was far from certain in the lead up to the 2015 Paris Climate Conference. The use of ‘constructive ambiguity’ led to Article 6 of the Paris Agreement, with Article 6.2 specifying a mechanism with limited international oversight, and Article 6.4 establishing a ‘Sustainable Development Mechanism’ (SDM) subject to detailed rules. Clear operationalization of these mechanisms remains a challenge, especially regarding the critical accounting issue that could not be resolved at the 2018 Katowice Climate Conference (COP24) – how to apply corresponding adjustments, especially regarding sectors not covered by targets under nationally-determined contributions (NDCs). By using fictitious examples, we explain two possible approaches to using Internationally Transferred Mitigation Outcomes (ITMOs) under Article 6.2 for achieving NDCs: a ‘target-based’ one where the acquiring Party adds the ITMO amount to the target level of its NDC; and a ‘tally-based’ one where the acquiring Party removes the ITMO amount from the final tally of its NDC. We discuss how these approaches influence the way to make corresponding adjustments and to avoid ‘double counting’. The first one leads to ‘target/budget-based accounting’, the second one to ‘emission-based accounting’. For mitigation outside the scope of the host Party's NDC, we propose using a tally-based interpretation of ITMO use, as opposed to the target-based variety used in the 1997 Kyoto Protocol, and stress the need for additionality testing. This interpretation allows for mandatory corresponding adjustments for all ITMO usage, while the host Party NDC level remains unchanged. A buffer registry is created for corresponding non-NDC adjustments of the selling party.

Key policy insights

• Under the Paris Agreement, transfers of emissions units between two countries through the Article 6 mechanisms need a corresponding adjustment on both sides to prevent double counting.

• Corresponding adjustments can be applied either to emissions targets under NDCs or measured emissions levels.

• The transfer of emissions reduction credits generated outside an NDC should lead to a corresponding adjustment of a buffer registry of the selling country, but not its emissions level/NDC target. Such credits should only be generated if additionality of the reductions is shown.

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Late Wenlock carbon isotope excursions and associated conodont fauna in the Podlasie Depression,eastern Poland: a not‐so‐big crisis?     

Emilia Jarochowska  Axel Munnecke 《Geological Journal》2016,51(5):683-703

The middle Silurian ‘big crisis’ refers to a graptolite extinction event and faunal turnover at the onset of a double‐peaked positive carbon isotope excursion. The crisis has been proposed to affect conodonts, giving rise to a sophisticated palaeoecological model of their stepwise extinction, known as the Mulde Event. However, the impact of the event on conodont faunas outside Gotland and the Silurian Baltic Basin remains unknown. Here, it is examined in the Widowo IG‐1 core (E Poland). The middle Silurian succession in this core represents foreshoal, shoal, and lagoonal settings on a tropical carbonate ramp on the shelf of the Eastern European Craton. Three positive δ¹³C_carb excursions have been identified; the two upper excursions correlate with the Mulde isotope anomaly and with two global eustatic regressions. Conodont species proposed to be affected by the extinction event either were not observed or ranged through the extinction interval. Changes in their frequencies are best explained by the sequence stratigraphic architecture of the late Wenlock strata in the Widowo IG‐1 core. The little impact of the ‘big crisis’ may reflect facies homogeneity across the studied interval, supporting the hypothesis that the late Wenlock conodont turnover in epicontinental settings was primarily driven by eustatically controlled facies shifts. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Petrography and composition of Martian regolith breccia meteorite Northwest Africa 7475          下载免费PDF全文

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Anthony J. Irving  Desmond E. Moser  Ivan Barker  Douglas Rumble III 《Meteoritics & planetary science》2015,50(2):326-352

The Northwest Africa (NWA) 7475 meteorite is one of the several stones of paired regolith breccias from Mars based on petrography, oxygen isotope, mineral compositions, and bulk rock compositions. Its inventory of lithic clasts is dominated by vitrophyre impact melts that were emplaced while they were still molten. Other clast types include crystallized impact melt rocks, evolved plutonic rocks, possible basalts, contact metamorphosed rocks, and siltstones. Impact spherules and vitrophyre shards record airborne transport, and accreted dust rims were sintered on most clasts, presumably during residence in an ejecta plume. The clast assemblage records at least three impact events, one that formed an impact melt sheet on Mars ≤4.4 Ga ago, a second that assembled NWA 7475 from impactites associated with the impact melt sheet at 1.7–1.4 Ga, and a third that launched NWA 7475 from Mars ~5 Ma ago. Mildly shocked pyroxene and plagioclase constrain shock metamorphic conditions during launch to >5 and <15 GPa. The mild postshock‐heating that resulted from these shock pressures would have been insufficient to sterilize this water‐bearing lithology during launch. Magnetite, maghemite, and pyrite are likely products of secondary alteration on Mars. Textural relationships suggest that calcium‐carbonate and goethite are probably of terrestrial origin, yet trace element chemistry indicates relatively low terrestrial alteration. Comparison of Mars Odyssey gamma‐ray spectrometer data with the Fe and Th abundances of NWA 7475 points to a provenance in the ancient southern highlands of Mars. Gratteri crater, with an age of ~5 Ma and an apparent diameter of 6.9 km, marks one possible launch site of NWA 7475.  相似文献   

Preface     

Axel Nothnagel  Urs Hugentobler  David Salstein 《Journal of Geodesy》2011,85(7):375-376

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Erratum to: Zircon-scale insights into the history of a Supervolcano,Bishop Tuff,Long Valley,California, with implications for the Ti-in-zircon geothermometer     

Mary R. Reid  Jorge A. Vazquez  Axel K. Schmitt 《Contributions to Mineralogy and Petrology》2011,161(2):313-314

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Acigöl rhyolite field,Central Anatolia (part 1): high-resolution dating of eruption episodes and zircon growth rates   总被引：2，自引：1，他引：1  

Axel K. Schmitt  Martin Danišík  Noreen J. Evans  Wolfgang Siebel  Elena Kiemele  Faruk Aydin  Janet C. Harvey 《Contributions to Mineralogy and Petrology》2011,162(6):1215-1231

Protracted pre-eruptive zircon residence is frequently detected in continental rhyolites and can conflict with thermal models, indicating briefer magma cooling durations if scaled to erupted volumes. Here, we present combined U-Th and (U-Th)/He zircon ages from the Acigöl rhyolite field (Central Anatolia, Turkey), which is part of a Quaternary bimodal volcanic complex. Unlike other geochronometers, this approach dates crystallization and eruption on the same crystals, allowing for internal consistency testing. Despite the overall longevity of Acigöl rhyolite volcanism and systematic trends of progressive depletion in compatible trace elements and decreasing zircon saturation temperatures, we find that zircon crystallized in two brief pulses corresponding to eruptions in the eastern and western part of the field during Middle and Late Pleistocene times, respectively. For Late Pleistocene zircon, resolvable differences exist between interior (average: 30.7 ± 0.9 ka; 1σ error) and rim (21.9 ± 1.3 ka) crystallization ages. These translate into radial crystal growth rates of ~10^?13 to 10^?14 cm/s, broadly consistent with those constrained by diffusion experiments. Rim crystallization and (U-Th)/He eruption ages (24.2 ± 0.4 ka) overlap within uncertainty. Evidence for brief zircon residence at Acigöl contrasts with many other rhyolite fields, suggesting that protracted zircon crystallization in, or recycling from, long-lived crystal mushes is not ubiquitous in continental silicic magma systems. Instead, the span of pre-eruptive zircon ages is consistent with autochthonous crystallization in individual small-volume magma batches that originated from basaltic precursors.  相似文献   

H/L chondrite LaPaz Icefield 031047 - A feather of Icarus?     

Axel Wittmann  Jon M. Friedrich  Julianne Troiano  Daniel T. Britt  David A. Kring 《Geochimica et cosmochimica acta》2011,75(20):6140-6519

Antarctic meteorite LAP 031047 is an ordinary chondrite composed of loosely consolidated chondritic fragments. Its petrography, oxygen isotopic composition and geochemical inventory are ambiguous and indicate an intermediate character between H and L chondrites. Petrographic indicators suggest LAP 031047 suffered a shock metamorphic overprint below ∼10 GPa, which did not destroy its unusually high porosity of ∼27 vol%. Metallographic textures in LAP 031047 indicate heating above ∼700 °C and subsequent cooling, which caused massive transformation of taenite to kamacite. The depletion of thermally labile trace elements, the crystallization of chondritic glass to microcrystalline plagioclase of unusual composition, and the occurrence of coarsely crystallized chondrule fragments is further evidence for post-metamorphic heating to ∼700-750 °C. However, this heating event had a transient character because olivine and low-Ca pyroxene did not equilibrate. Nearly complete degassing up to very high temperatures is indicated by the thorough resetting of LAP 031047’s Ar-Ar reservoir ∼100 ± 55 Ma ago. A noble gas cosmic-ray exposure age indicates it was reduced to a meter-size fragment at <0.5 Ma. In light of the fact that shock heating cannot account for the thermal history of LAP 031047 in its entirety, we test the hypothesis that this meteorite belonged to the near-surface of an Aten or Apollo asteroid that underwent heating during orbital passages close to the Sun.  相似文献   

Inversion of magnetic measurements of the CHAMP satellite over the Pannonian Basin     

K.I. Kis  P.T. TaylorG. Wittmann  B. ToronyiS. Puszta 《Journal of Applied Geophysics》2011,75(2):412-418

The Pannonian Basin is a deep intra-continental basin that formed as part of the Alpine orogeny. In order to study the nature of the crustal basement we used the long-wavelength magnetic anomalies acquired by the CHAMP satellite. The anomalies were distributed in a spherical shell, some 107,927 data recorded between January 1 and December 31 of 2008. They covered the Pannonian Basin and its vicinity. These anomaly data were interpolated into a spherical grid of 0.5° × 0.5°, at the elevation of 324 km by the Gaussian weight function. The vertical gradient of these total magnetic anomalies was also computed and mapped to the surface of a sphere at 324 km elevation. The former spherical anomaly data at 425 km altitude continued downward to 324 km. To interpret these data at the elevation of 324 km we used an inversion method. A polygonal prism forward model was used for the inversion. The minimum problem was solved numerically by the Simplex and Simulated annealing methods; a L₂ norm in the case of Gaussian distribution parameters and a L₁ norm was used in the case of Laplace distribution parameters. We interpret that the magnetic anomaly was produced by several sources and the effect of the sable magnetization of the exsolution of hemo-ilmenite minerals in the upper crustal metamorphic rocks.  相似文献